CA2694632A1 - Catalyseur destine au traitement de gaz d'echappement - Google Patents

Catalyseur destine au traitement de gaz d'echappement Download PDF

Info

Publication number
CA2694632A1
CA2694632A1 CA2694632A CA2694632A CA2694632A1 CA 2694632 A1 CA2694632 A1 CA 2694632A1 CA 2694632 A CA2694632 A CA 2694632A CA 2694632 A CA2694632 A CA 2694632A CA 2694632 A1 CA2694632 A1 CA 2694632A1
Authority
CA
Canada
Prior art keywords
catalyst
exhaust gas
support
treating exhaust
mercury
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2694632A
Other languages
English (en)
Other versions
CA2694632C (fr
Inventor
Katsumi Nochi
Yoshiaki Obayashi
Masashi Kiyosawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2694632A1 publication Critical patent/CA2694632A1/fr
Application granted granted Critical
Publication of CA2694632C publication Critical patent/CA2694632C/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8665—Removing heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/10—Oxidants
    • B01D2251/108—Halogens or halogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20707—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20723—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20769—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20776—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24149—Honeycomb-like

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)

Abstract

L'invention porte sur un catalyseur pour le traitement de gaz de décharge avec lequel la quantité d'un agent de chloration du mercure, qui est hautement corrosif, à ajouter dans un traitement de gaz de décharge peut être réduite tout en maintenant un rendement élevé d'oxydation de mercure. Le catalyseur est destiné à être utilisé dans un traitement de gaz de décharge dans lequel de l'ammoniac est utilisé comme agent réducteur pour éliminer par voie catalytique les oxydes d'azote à partir d'un gaz de décharge, et un halogène est utilisé comme agent oxydant pour oxyder le mercure. Ce catalyseur comprend : TiO2 comme support ; un oxyde d'au moins un élément choisi dans le groupe constitué par le vanadium, le tungstène et le molybdène, l'oxyde étant déposé comme ingrédient actif sur le support ; et au moins un élément choisi dans le groupe constitué par le bismuth, le phosphore et un composé comprenant le bismuth et/ou le phosphore, comme activateur déposé sur le support.
CA2694632A 2008-02-27 2009-02-26 Catalyseur destine au traitement de gaz d'echappement Expired - Fee Related CA2694632C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2008-045818 2008-02-27
JP2008045818A JP5386096B2 (ja) 2008-02-27 2008-02-27 排ガス処理触媒
PCT/JP2009/053573 WO2009107729A1 (fr) 2008-02-27 2009-02-26 Catalyseur pour le traitement de gaz de décharge

Publications (2)

Publication Number Publication Date
CA2694632A1 true CA2694632A1 (fr) 2009-09-03
CA2694632C CA2694632C (fr) 2012-10-16

Family

ID=41016116

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2694632A Expired - Fee Related CA2694632C (fr) 2008-02-27 2009-02-26 Catalyseur destine au traitement de gaz d'echappement

Country Status (9)

Country Link
US (1) US8410013B2 (fr)
EP (1) EP2248583B1 (fr)
JP (1) JP5386096B2 (fr)
KR (1) KR101195633B1 (fr)
CN (1) CN102083529B (fr)
BR (1) BRPI0903918A2 (fr)
CA (1) CA2694632C (fr)
RU (1) RU2429908C1 (fr)
WO (1) WO2009107729A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102218266A (zh) * 2010-04-15 2011-10-19 中国科学院城市环境研究所 一种用于催化氧化燃煤烟气中单质汞的方法
US9802180B2 (en) * 2013-12-11 2017-10-31 Zhejiang University Catalyst for synergistic control of oxynitride and mercury and method for preparing the same
JP6697287B2 (ja) * 2016-03-02 2020-05-20 三菱日立パワーシステムズ株式会社 金属水銀の酸化反応および窒素酸化物の還元反応用触媒、ならびに排ガスの浄化方法
GB201715663D0 (en) 2017-03-31 2017-11-08 Johnson Matthey Plc A Catalyst for treating an exhaust gas, an exhaust system and a method
CN111760595A (zh) * 2020-07-08 2020-10-13 河南城建学院 一种用于低温脱硝除Hg0的杂多酸/CeO2基催化剂及其制备方法和应用

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4085122A (en) * 1975-01-10 1978-04-18 Lonza, Ltd. Production of maleic anhydride using a mixed-oxide oxidation catalyst containing vanadium and pentavalent phosphorus
CH598863A5 (fr) * 1975-01-10 1978-05-12 Lonza Ag
DE2925682A1 (de) * 1979-06-26 1981-01-29 Basf Ag Vanadinpentoxid, titandioxid, phosphor, rubidium und/oder caesium und ggf. zirkondioxid enthaltender traegerkatalysator
JPS56168835A (en) 1980-05-31 1981-12-25 Mitsubishi Petrochem Co Ltd Denitrating catalyst and denitrating method
US4537874A (en) * 1982-10-22 1985-08-27 Nippon Shokubai Kagaku Kogyo Co Ltd Catalyst for production of unsaturated aldehydes
JPS59213442A (ja) 1983-05-17 1984-12-03 Mitsubishi Petrochem Co Ltd 脱硝触媒の調製方法
JP3935547B2 (ja) 1997-02-19 2007-06-27 三菱重工業株式会社 排ガス処理方法及び排ガス処理装置
DE19707943C2 (de) * 1997-02-27 1999-07-08 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid und Katalysator hierfür
US6960329B2 (en) * 2002-03-12 2005-11-01 Foster Wheeler Energy Corporation Method and apparatus for removing mercury species from hot flue gas
RU2202402C1 (ru) * 2002-05-17 2003-04-20 ОАО "Московский комитет по науке и технологиям" Способ очистки воздуха от токсичных компонентов выхлопных и отходящих газов
JP2005342711A (ja) * 2004-05-07 2005-12-15 Mitsubishi Chemical Engineering Corp ディーゼルエンジン排ガスの脱硝方法
US8242049B2 (en) * 2005-12-08 2012-08-14 The Hong Kong University Of Science And Technology Low temperature ammonia remediation catalysts
JP4981318B2 (ja) 2005-12-19 2012-07-18 三菱重工業株式会社 排ガス処理装置および排ガス処理方法
KR101450360B1 (ko) 2007-01-30 2014-10-14 바브콕-히다찌 가부시끼가이샤 배기 가스 정화용 촉매 및 그의 제조방법
JP5495001B2 (ja) 2007-06-27 2014-05-21 バブコック日立株式会社 触媒の再生方法
CN101605602B (zh) * 2007-09-07 2012-10-10 巴布考克日立株式会社 废气净化催化剂
US20110250114A1 (en) * 2010-04-13 2011-10-13 Millennium Inorganic Chemicals, Inc. Vanadia-Based DeNOx Catalysts and Catalyst Supports

Also Published As

Publication number Publication date
EP2248583A1 (fr) 2010-11-10
WO2009107729A1 (fr) 2009-09-03
EP2248583A4 (fr) 2011-09-14
CA2694632C (fr) 2012-10-16
BRPI0903918A2 (pt) 2015-06-30
KR101195633B1 (ko) 2012-10-30
US8410013B2 (en) 2013-04-02
RU2429908C1 (ru) 2011-09-27
CN102083529B (zh) 2014-12-10
US20100210455A1 (en) 2010-08-19
EP2248583B1 (fr) 2019-04-03
JP2009202084A (ja) 2009-09-10
CN102083529A (zh) 2011-06-01
JP5386096B2 (ja) 2014-01-15
KR20100034046A (ko) 2010-03-31

Similar Documents

Publication Publication Date Title
WO2009025185A1 (fr) Catalyseur de traitement de gaz d'échappement et système de traitement de gaz d'échappement
WO2009031234A1 (fr) Catalyseur de purification de gaz d'échappement
EP3323504B1 (fr) Catalyseur de réduction catalytique sélective pour l'élimination d'oxydes d'azote et son procédé de production
EA200900074A1 (ru) Катализатор окисления
CA2694632A1 (fr) Catalyseur destine au traitement de gaz d'echappement
WO2007021472A3 (fr) Procede de preparation d'un support catalytique et utilisation de celui-ci dans la preparation de catalyseur
MX2018013204A (es) Configuracion zonificada para combinaciones de catalizador de oxidacion.
WO2009017011A1 (fr) Catalyseur d'électrode en oxyde de métal, utilisation de celui-ci et procédé servant à produire un catalyseur d'électrode en oxyde de métal
WO2012091913A3 (fr) Support de catalyseur thermiquement stable comprenant du sulfate de baryum
WO2009123575A8 (fr) Composition photosensibilisante et ses utilisations
WO2010096616A8 (fr) Nanoparticules de cose2 à support carbone pour la réduction de l'oxygène et le dégagement de l'hydrogène dans des environnements acides
WO2005001954A3 (fr) Catalyseur pour electrodes a oxygene de pile a combustible
US20130287640A1 (en) Base metal exhaust gas control apparatus and base metal exhaust gas control system for internal combustion engine
WO2008031865A3 (fr) Procédé de préparation d'alkylène glycols
JP2009202084A5 (fr)
WO2007056775A3 (fr) Nouvelle cathode metal-air comprenant de l'oxyde de manganese contenu dans un tamis moleculaire octaedrique
WO2007055938A3 (fr) Reduction selective catalytique d’oxydes d’azote avec de l’hydrogene
CN103736455A (zh) 一种铜铁改性金属有机骨架吸附剂及其制备方法
UA90931C2 (ru) Способ очистки газовой смеси, содержащей оксид азота (и)
BR0212561A (pt) Composição que adsorve óxidos de nitrogênio presentes nos gases de escapamento produzidos por um motor de combustão, processo para conversão de óxidos de nitrogênio presentes no gás de escapamento produzido por um motor de combustão, e, sistema de escapamento para conversão de óxidos de nitrogênio presentes no gás de escapamento produzido por um motor de combustão
WO2008090450A8 (fr) Procédé de décomposition catalytique du protoxyde d'azote
CN102407136A (zh) 一种包含堇青石蜂窝陶瓷的车用尾气催化剂及其制备方法
TW200531740A (en) Nitrogen oxide selective reduction catalyst, catalyst body using the same, method of manufacturing catalyst body, method of eliminating nitrogen oxides and device for decreasing nitrogen oxides in exhaust gas
CN111530454A (zh) 一种低温脱硝催化剂及其制备方法和应用
EP1230407A4 (fr) Reduction d'oxydes sous forme solide

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20220228