CA2701252C - Attenuation des polymeres - Google Patents

Attenuation des polymeres Download PDF

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Publication number
CA2701252C
CA2701252C CA2701252A CA2701252A CA2701252C CA 2701252 C CA2701252 C CA 2701252C CA 2701252 A CA2701252 A CA 2701252A CA 2701252 A CA2701252 A CA 2701252A CA 2701252 C CA2701252 C CA 2701252C
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CA
Canada
Prior art keywords
ethylene
reactor
catalyst
polymer
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2701252A
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English (en)
Other versions
CA2701252A1 (fr
Inventor
Isam Jaber
Charles Ashton Garret Carter
Eric Clavelle
Andrzej Krzywicki
Ian Ronald Jobe
P. Scott Chisholm
Kamal Elias Serhal
Russell Kirk Archer
Keith Wayne Besenski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nova Chemicals Corp
Original Assignee
Nova Chemicals Corp
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Filing date
Publication date
Application filed by Nova Chemicals Corp filed Critical Nova Chemicals Corp
Priority to CA2701252A priority Critical patent/CA2701252C/fr
Priority to EP11771427.9A priority patent/EP2560997B1/fr
Priority to PCT/CA2011/000318 priority patent/WO2011130822A1/fr
Priority to US13/066,077 priority patent/US20110257350A1/en
Publication of CA2701252A1 publication Critical patent/CA2701252A1/fr
Application granted granted Critical
Publication of CA2701252C publication Critical patent/CA2701252C/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/20—Non-coordinating groups comprising halogens
    • B01J2540/22—Non-coordinating groups comprising halogens comprising fluorine, e.g. trifluoroacetate
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Léthylène est oligomérisé de manière sélective dans un réacteur à cuve à agitation continue (CSTR) qui fonctionne de préférence dune manière isotherme en utilisant un catalyseur de chrome. La formation non souhaitée dun sous-produit de polyéthylène est atténuée par la mise en contact de léthylène avec de lhydrogène avant lajout déthylène au réacteur et lintroduction déthylène et dhydrogène par un orifice dalimentation commun.
CA2701252A 2010-04-20 2010-04-20 Attenuation des polymeres Active CA2701252C (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CA2701252A CA2701252C (fr) 2010-04-20 2010-04-20 Attenuation des polymeres
EP11771427.9A EP2560997B1 (fr) 2010-04-20 2011-03-29 Réduction des sous-produits dans un procédé d'oligomérisation de l'éthylène
PCT/CA2011/000318 WO2011130822A1 (fr) 2010-04-20 2011-03-29 Réduction des sous-produits dans un procédé d'oligomérisation de l'éthylène
US13/066,077 US20110257350A1 (en) 2010-04-20 2011-04-06 Polymer mitigation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA2701252A CA2701252C (fr) 2010-04-20 2010-04-20 Attenuation des polymeres

Publications (2)

Publication Number Publication Date
CA2701252A1 CA2701252A1 (fr) 2011-10-20
CA2701252C true CA2701252C (fr) 2017-01-03

Family

ID=44788682

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2701252A Active CA2701252C (fr) 2010-04-20 2010-04-20 Attenuation des polymeres

Country Status (4)

Country Link
US (1) US20110257350A1 (fr)
EP (1) EP2560997B1 (fr)
CA (1) CA2701252C (fr)
WO (1) WO2011130822A1 (fr)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2747501C (fr) * 2011-07-26 2018-01-23 Nova Chemicals Corporation Oligomerisation d'ethylene en vrac
CA2765429C (fr) 2012-01-25 2019-12-31 Nova Chemicals Corporation Ligand p-n-p
KR101846031B1 (ko) * 2012-03-16 2018-04-05 에스케이이노베이션 주식회사 에틸렌으로부터 1-헥센 및/또는 1-옥텐을 제조하기 위한 촉매계
SG11201407130XA (en) * 2012-05-09 2014-11-27 Sasol Tech Pty Ltd Tetramerisation of ethylene
ES2750659T3 (es) * 2012-05-09 2020-03-26 Sasol Tech Pty Ltd Tetramerización de etileno
KR101638980B1 (ko) * 2013-09-30 2016-07-12 주식회사 엘지화학 리간드 화합물, 유기크롬 화합물, 에틸렌 올리고머화용 촉매 시스템, 및 이를 이용한 에틸렌 올리고머화 방법
KR101657259B1 (ko) * 2013-11-19 2016-09-13 주식회사 엘지화학 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법
CA2837590C (fr) * 2013-12-23 2020-12-15 Nova Chemicals Corporation Oligomerisation continue d'ethylene avec preparation de catalyseur in situ
US9175109B1 (en) 2014-05-20 2015-11-03 Chevron Phillips Chemical Company Lp Oligomerization processes and polymer compositions produced therefrom
US9505675B2 (en) 2015-02-09 2016-11-29 Chevron Phillips Chemical Company Lp Deactivation of a process by-product
KR101679515B1 (ko) 2015-02-12 2016-11-24 주식회사 엘지화학 올리고머화 촉매계의 제조방법 및 이에 의해 제조된 올리고머화 촉매계
WO2017010998A1 (fr) 2015-07-14 2017-01-19 Chevron Phillips Chemical Company Lp Compositions d'oléfines
US10519077B2 (en) 2015-09-18 2019-12-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US10513473B2 (en) 2015-09-18 2019-12-24 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US10329212B2 (en) 2016-05-27 2019-06-25 Chevron Phillips Chemical Company Lp Reduced polymer formation for selective ethylene oligomerizations
US10414699B2 (en) 2016-05-27 2019-09-17 Chevron Phillips Chemical Company Lp Process improvements in selective ethylene oligomerizations
US10414698B2 (en) 2016-05-27 2019-09-17 Chevron Phillips Chemical Company Lp Reduced polymer formation for selective ethylene oligomerizations
US10232339B2 (en) 2017-06-06 2019-03-19 Chevron Phillips Chemical Company Lp Fouling protection for an oligomerization reactor inlet
FR3068620B1 (fr) * 2017-07-10 2020-06-26 IFP Energies Nouvelles Procede d’oligomerisation mettant en oeuvre un dispositf reactionnel comprenant un moyen de dispersion
US10493442B2 (en) 2017-09-22 2019-12-03 Chevron Phillips Chemical Company Lp Fluorinated N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene
US10294171B2 (en) 2017-09-22 2019-05-21 Chevron Phillips Chemical Company Lp Carbonyl-containing perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes and their use to oligomerize ethylene
US10183960B1 (en) 2017-09-22 2019-01-22 Chevron Phillips Chemical Company Lp Perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene
US10464862B2 (en) 2017-09-28 2019-11-05 Chevron Phillips Chemical Company Lp Oligomerization reactions using aluminoxanes
US11583843B1 (en) 2021-11-08 2023-02-21 Chevron Phillips Chemical Company, Lp Chromium phosphinyl isoindole amidine complexes for tetramerization of ethylene
US11505513B1 (en) 2021-11-08 2022-11-22 Chevron Phillips Chemical Company, Lp Chromium bicyclic phosphinyl amidine complexes for tetramerization of ethylene
US11492305B1 (en) 2021-11-08 2022-11-08 Chevron Phillips Chemical Company, Lp Chromium phosphinyl hydroisoindole amidine complexes for tetramerization of ethylene

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9918635D0 (en) * 1999-08-06 1999-10-13 Bp Chem Int Ltd Polymerisation process
US20070043181A1 (en) * 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
CA2583007C (fr) * 2007-03-29 2015-03-31 Nova Chemicals Corporation Aminophosphine

Also Published As

Publication number Publication date
EP2560997A1 (fr) 2013-02-27
US20110257350A1 (en) 2011-10-20
EP2560997A4 (fr) 2013-10-23
CA2701252A1 (fr) 2011-10-20
WO2011130822A1 (fr) 2011-10-27
EP2560997B1 (fr) 2017-12-20

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