CA2788384A1 - Procede et systeme de recuperation de dioxyde de titane et de metaux de valeur par reduction de la concentration d'acide chlorhydrique dans une solution de lixiviation - Google Patents
Procede et systeme de recuperation de dioxyde de titane et de metaux de valeur par reduction de la concentration d'acide chlorhydrique dans une solution de lixiviation Download PDFInfo
- Publication number
- CA2788384A1 CA2788384A1 CA2788384A CA2788384A CA2788384A1 CA 2788384 A1 CA2788384 A1 CA 2788384A1 CA 2788384 A CA2788384 A CA 2788384A CA 2788384 A CA2788384 A CA 2788384A CA 2788384 A1 CA2788384 A1 CA 2788384A1
- Authority
- CA
- Canada
- Prior art keywords
- solution
- titanium dioxide
- hydrochloric acid
- leach solution
- outlet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 148
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 title claims abstract description 147
- 238000000034 method Methods 0.000 title claims abstract description 69
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 59
- 230000008569 process Effects 0.000 title claims abstract description 55
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 45
- 239000002184 metal Substances 0.000 title claims abstract description 45
- 150000002739 metals Chemical class 0.000 title claims abstract description 26
- 238000011084 recovery Methods 0.000 title claims description 34
- 239000007787 solid Substances 0.000 claims abstract description 70
- 239000010936 titanium Substances 0.000 claims abstract description 48
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 42
- 239000011159 matrix material Substances 0.000 claims abstract description 37
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000002386 leaching Methods 0.000 claims abstract description 35
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 20
- 238000001556 precipitation Methods 0.000 claims abstract description 19
- 230000007062 hydrolysis Effects 0.000 claims abstract description 18
- 239000002002 slurry Substances 0.000 claims abstract description 17
- 239000000243 solution Substances 0.000 claims description 140
- 239000002253 acid Substances 0.000 claims description 27
- 239000007789 gas Substances 0.000 claims description 26
- 239000007788 liquid Substances 0.000 claims description 22
- 238000000926 separation method Methods 0.000 claims description 20
- 229910052720 vanadium Inorganic materials 0.000 claims description 20
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000012716 precipitator Substances 0.000 claims description 13
- 238000000638 solvent extraction Methods 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 9
- 230000003647 oxidation Effects 0.000 claims description 9
- 238000007254 oxidation reaction Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000009835 boiling Methods 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 229910001447 ferric ion Inorganic materials 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- 238000002347 injection Methods 0.000 claims description 5
- 239000007924 injection Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000011541 reaction mixture Substances 0.000 claims description 5
- 239000011592 zinc chloride Substances 0.000 claims description 5
- 235000005074 zinc chloride Nutrition 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 4
- 229910001510 metal chloride Inorganic materials 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 238000004064 recycling Methods 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 53
- 229910052742 iron Inorganic materials 0.000 description 27
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 16
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 16
- 229910052595 hematite Inorganic materials 0.000 description 15
- 239000011019 hematite Substances 0.000 description 15
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 14
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 13
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 239000002585 base Substances 0.000 description 8
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 8
- 229960002089 ferrous chloride Drugs 0.000 description 8
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- 239000012141 concentrate Substances 0.000 description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 5
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910001448 ferrous ion Inorganic materials 0.000 description 4
- 238000009854 hydrometallurgy Methods 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- -1 titanium ions Chemical class 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000012527 feed solution Substances 0.000 description 3
- 239000000543 intermediate Substances 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000005070 sampling Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 2
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000012433 hydrogen halide Substances 0.000 description 2
- 229910000039 hydrogen halide Inorganic materials 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000005272 metallurgy Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000003828 vacuum filtration Methods 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 102220496562 Aryl hydrocarbon receptor nuclear translocator-like protein 1_H19C_mutation Human genes 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229910010066 TiC14 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910001617 alkaline earth metal chloride Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229960004424 carbon dioxide Drugs 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 235000010269 sulphur dioxide Nutrition 0.000 description 1
- 239000004291 sulphur dioxide Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1236—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching
- C22B34/124—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching using acidic solutions or liquors
- C22B34/1245—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching using acidic solutions or liquors containing a halogen ion as active agent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1236—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching
- C22B34/1259—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching treatment or purification of titanium containing solutions or liquors or slurries
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/20—Obtaining niobium, tantalum or vanadium
- C22B34/22—Obtaining vanadium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30145810P | 2010-02-04 | 2010-02-04 | |
| US61/301,458 | 2010-02-04 | ||
| US30571810P | 2010-02-18 | 2010-02-18 | |
| US61/305,718 | 2010-02-18 | ||
| US42050010P | 2010-12-07 | 2010-12-07 | |
| US61/420,500 | 2010-12-07 | ||
| PCT/CA2011/000142 WO2011094858A1 (fr) | 2010-02-04 | 2011-02-04 | Procédé et système de récupération de dioxyde de titane et de métaux de valeur par réduction de la concentration d'acide chlorhydrique dans une solution de lixiviation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2788384A1 true CA2788384A1 (fr) | 2011-08-11 |
| CA2788384C CA2788384C (fr) | 2019-02-19 |
Family
ID=44354839
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2788384A Expired - Fee Related CA2788384C (fr) | 2010-02-04 | 2011-02-04 | Procede et systeme de recuperation de dioxyde de titane et de metaux de valeur par reduction de la concentration d'acide chlorhydrique dans une solution de lixiviation |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20130195738A1 (fr) |
| EP (1) | EP2531628A1 (fr) |
| AU (2) | AU2011213512A1 (fr) |
| CA (1) | CA2788384C (fr) |
| WO (1) | WO2011094858A1 (fr) |
| ZA (1) | ZA201206582B (fr) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2471010C2 (ru) | 2007-05-21 | 2012-12-27 | Орбит Элюминэ Инк. | Способ извлечения алюминия и железа из глиноземистых руд |
| JP2014508863A (ja) | 2011-03-18 | 2014-04-10 | オーバイト アルミナ インコーポレイテッド | アルミニウム含有材料から希土類元素を回収する方法 |
| JP5894262B2 (ja) | 2011-05-04 | 2016-03-23 | オーバイト アルミナ インコーポレイテッドOrbite Aluminae Inc. | 種々の鉱石から希土類元素を回収する方法 |
| AU2012308068B2 (en) | 2011-09-16 | 2015-02-05 | Aem Technologies Inc. | Processes for preparing alumina and various other products |
| WO2013104059A1 (fr) | 2012-01-10 | 2013-07-18 | Orbite Aluminae Inc. | Procédés de traitement de boue rouge |
| CA2862307C (fr) | 2012-03-29 | 2015-12-01 | Orbite Aluminae Inc. | Procedes de traitement de cendres volantes |
| WO2014008586A1 (fr) | 2012-07-12 | 2014-01-16 | Orbite Aluminae Inc. | Procédés pour la préparation d'oxyde de titane et de divers autres produits |
| BR112015006536A2 (pt) | 2012-09-26 | 2017-08-08 | Orbite Aluminae Inc | processos para preparar alumina e cloreto de magnésio por lixiviação com hcl de vários materiais. |
| US9534274B2 (en) | 2012-11-14 | 2017-01-03 | Orbite Technologies Inc. | Methods for purifying aluminium ions |
| CN103276207B (zh) * | 2013-05-17 | 2015-02-18 | 中国科学院过程工程研究所 | 一种湿法处理钒钛磁铁精矿制备钛液的方法 |
| CN103276211B (zh) * | 2013-05-17 | 2015-02-18 | 中国科学院过程工程研究所 | 一种从钒钛磁铁精矿中提取铁和钒的方法 |
| WO2015131266A1 (fr) * | 2014-03-05 | 2015-09-11 | Kamaleddine Fouad F | Production de rutile synthétique de haute qualité à partir de minerais contenant du titane de qualité |
| EP3214190A1 (fr) * | 2016-03-01 | 2017-09-06 | SMS Siemag Process Technologies GmbH | Procédé de séparation de vanadium |
| RU2769875C2 (ru) * | 2017-04-05 | 2022-04-07 | ТиЭнДжи Лимитед | Способ получения сырья для выщелачивания |
| CN107475540B (zh) * | 2017-08-30 | 2019-03-29 | 河南理工大学 | 一种钛白废液回收钒和钛的工艺 |
| AU2019271388B2 (en) | 2018-05-18 | 2023-05-18 | California Institute Of Technology | Process to convert reduced sulfur species and water into hydrogen and sulfuric acid |
| WO2020237312A1 (fr) * | 2019-05-28 | 2020-12-03 | Avanti Materials Ltd | Récupération de produits à base de titane à partir de minerais de titanomagnétite |
| CA3147352A1 (fr) | 2019-08-13 | 2021-02-18 | California Institute Of Technology | Procede de fabrication d'oxyde de calcium ou de ciment portland ordinaire a partir de roches et de mineraux contenant du calcium |
| WO2021056110A1 (fr) * | 2019-09-25 | 2021-04-01 | 9203-5468 Quebec Inc. Dba Nmr360 | Procédé de récupération d'oxydes de vanadium à partir de divers matériaux |
| WO2021072534A1 (fr) * | 2019-10-15 | 2021-04-22 | 9203-5468 Quebec Inc. Dba Nmr360 | Procédé de récupération de composés de dioxyde de titane, de vanadium et de fer à partir de divers matériaux |
| CN114729419A (zh) * | 2019-10-31 | 2022-07-08 | Tng有限公司 | 钒回收方法 |
| US12331380B2 (en) | 2020-05-26 | 2025-06-17 | Commonwealth Scientific And Industrial Research Organisation | Process for recovering titanium dioxide |
| CN112126794A (zh) * | 2020-09-02 | 2020-12-25 | 衡阳百赛化工实业有限公司 | 一种次氧化锌除杂富集有价金属锌的烟尘净化处理设备 |
| CN112759164A (zh) * | 2020-12-31 | 2021-05-07 | 北京永新环保有限公司 | 一种氯化法制钛白粉收尘废渣水资源化处理方法 |
| EP4587598A1 (fr) * | 2022-09-15 | 2025-07-23 | Fodere Titanium Limited | Procédé de production de dioxyde de titane et/ou d'oxyde de vanadium |
| CN116103516B (zh) * | 2022-11-15 | 2025-10-28 | 中南大学 | 一种从赤泥中选择性提取钛的工艺 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2167628A (en) | 1937-10-06 | 1939-08-01 | Nat Lead Co | Preparation of titanium dioxide pigments |
| US2406577A (en) | 1942-08-08 | 1946-08-27 | Nat Lead Co | Extraction of iron from titaniferous ores |
| GB1008676A (en) | 1960-11-17 | 1965-11-03 | Laporte Titanium Ltd | Improvements in and relating to the manufacture of titanium dioxide |
| NL281655A (fr) | 1961-08-05 | 1900-01-01 | ||
| US3682592A (en) | 1970-07-20 | 1972-08-08 | Pori Inc | Treatment of waste hci pickle liquor |
| US3903239A (en) | 1973-02-07 | 1975-09-02 | Ontario Research Foundation | Recovery of titanium dioxide from ores |
| AU8223375A (en) | 1974-06-21 | 1976-12-23 | Univ Melbourne | Benefication of titaniferous ores |
| AU5051985A (en) * | 1984-12-10 | 1986-06-19 | Grampian Mining Co. Limited | T102 pigment from ilmenite using chloride route with regeneration of hcl from fecl2 |
| US6500396B1 (en) | 1998-11-17 | 2002-12-31 | Vaikuntam Iyer Lakshmanan | Separation of titanium halides from aqueous solutions |
| US6375923B1 (en) | 1999-06-24 | 2002-04-23 | Altair Nanomaterials Inc. | Processing titaniferous ore to titanium dioxide pigment |
| CN1761765A (zh) | 2003-11-19 | 2006-04-19 | 方法研究奥特克公司 | 回收混合氯化物介质中钛的方法 |
| CN102066262B (zh) | 2008-06-19 | 2013-08-28 | Sms西马格股份公司 | 用于回收氧化铁和盐酸的处理方法 |
-
2011
- 2011-02-04 EP EP11739307A patent/EP2531628A1/fr not_active Withdrawn
- 2011-02-04 WO PCT/CA2011/000142 patent/WO2011094858A1/fr not_active Ceased
- 2011-02-04 AU AU2011213512A patent/AU2011213512A1/en not_active Abandoned
- 2011-02-04 CA CA2788384A patent/CA2788384C/fr not_active Expired - Fee Related
-
2012
- 2012-08-04 US US13/567,013 patent/US20130195738A1/en not_active Abandoned
- 2012-09-03 ZA ZA2012/06582A patent/ZA201206582B/en unknown
-
2016
- 2016-06-16 AU AU2016204038A patent/AU2016204038B2/en not_active Ceased
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| Publication number | Publication date |
|---|---|
| AU2016204038A1 (en) | 2016-07-14 |
| AU2011213512A1 (en) | 2012-08-16 |
| AU2016204038B2 (en) | 2018-05-24 |
| US20130195738A1 (en) | 2013-08-01 |
| CA2788384C (fr) | 2019-02-19 |
| ZA201206582B (en) | 2014-03-26 |
| EP2531628A1 (fr) | 2012-12-12 |
| WO2011094858A1 (fr) | 2011-08-11 |
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