CA2825324C - Catalyseurs d'hydrocraquage contenant des agregats stabilises de petites cristallites de zeolite y et procedes associes de conversion d'hydrocarbures - Google Patents

Catalyseurs d'hydrocraquage contenant des agregats stabilises de petites cristallites de zeolite y et procedes associes de conversion d'hydrocarbures Download PDF

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Publication number
CA2825324C
CA2825324C CA2825324A CA2825324A CA2825324C CA 2825324 C CA2825324 C CA 2825324C CA 2825324 A CA2825324 A CA 2825324A CA 2825324 A CA2825324 A CA 2825324A CA 2825324 C CA2825324 C CA 2825324C
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Prior art keywords
zeolite
hydrocracking catalyst
catalyst
secondary particles
aggregated
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CA2825324A
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CA2825324A1 (fr
Inventor
Christopher G. Oliveri
Wenyih Frank Lai
Ajit B. Dandekar
Scott J. Weigel
Robert Ellis Kay
Jianxin Jason Wu
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ExxonMobil Technology and Engineering Co
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ExxonMobil Research and Engineering Co
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Priority claimed from US13/041,597 external-priority patent/US8852326B2/en
Priority claimed from US13/412,945 external-priority patent/US8778171B2/en
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Publication of CA2825324A1 publication Critical patent/CA2825324A1/fr
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7026—MFS-type, e.g. ZSM-57
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1059—Gasoil having a boiling range of about 330 - 427 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention concerne des catalyseurs d'hydrocraquage utilisant des agrégats stabilisés de petites cristallites de zéolite Y qui sont agglomérées en des particules secondaires plus grandes. Au moins 80% des particules secondaires peuvent comprendre au moins 5 cristallites primaires. La taille des cristallites primaires peut être d'environ 0.5 microns maximum, ou d'environ 0.3 microns maximum, et la taille des particules secondaires peut être d'environ 0.8 microns minimum, ou d'environ1.0 µm minimum. Le rapport entre la silice et l'oxyde d'aluminium de la zéolite Y agglomérée stabilisée résultante peut être de 4: 1 ou plus. L'invention concerne également l'utilisation de tels catalyseurs dans des procédés d'hydrocraquage pour la conversion de pétrole lourd en produits pétroliers plus légers. L'invention est particulièrement adaptée à la production sélective d'une gamme de produits diesel à partir de matières de charge d'alimentation de la gamme gazole dans des conditions d'hydrocraquage.
CA2825324A 2011-03-07 2012-03-07 Catalyseurs d'hydrocraquage contenant des agregats stabilises de petites cristallites de zeolite y et procedes associes de conversion d'hydrocarbures Expired - Fee Related CA2825324C (fr)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US13/041,597 US8852326B2 (en) 2011-03-07 2011-03-07 Aggregates of small particles of synthetic faujasite zeolite
US13/041,597 2011-03-07
US201161512042P 2011-07-27 2011-07-27
US201161512067P 2011-07-27 2011-07-27
US61/512,042 2011-07-27
US61/512,067 2011-07-27
US13/412,945 US8778171B2 (en) 2011-07-27 2012-03-06 Hydrocracking catalysts containing stabilized aggregates of small crystallites of zeolite Y associated hydrocarbon conversion processes
US13/412,945 2012-03-06
PCT/US2012/027960 WO2012122208A1 (fr) 2011-03-07 2012-03-07 Catalyseurs d'hydrocraquage contenant des agrégats stabilisés de petites cristallites de zéolite y et procédés associés de conversion d'hydrocarbures

Publications (2)

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CA2825324A1 CA2825324A1 (fr) 2012-09-13
CA2825324C true CA2825324C (fr) 2017-09-05

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CA (1) CA2825324C (fr)
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DE102015001504B4 (de) 2014-02-11 2025-11-13 GIMATIC S.r.l. Schutzgehäuse für Robotergreifer
CN103934019B (zh) * 2014-04-21 2015-11-11 四川省中明环境治理有限公司 一种生产超清洁低凝柴油催化剂的制备及应用方法
CN105435837B (zh) * 2014-08-29 2019-01-08 中国石油化工股份有限公司 一种加氢裂化催化剂及其制备和应用
CN105435835B (zh) * 2014-08-29 2019-01-08 中国石油化工股份有限公司 一种加氢裂化催化剂及其制备和应用
US11311866B2 (en) * 2020-08-27 2022-04-26 Saudi Arabian Oil Company Cracking catalyst comprising platinum encapsulated in microporous silica
CN119911927B (zh) * 2023-10-31 2025-12-12 中国石油化工股份有限公司 Y/Beta复合双微孔材料及其制备方法

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US4897178A (en) * 1983-05-02 1990-01-30 Uop Hydrocracking catalyst and hydrocracking process
JP3257509B2 (ja) * 1997-11-27 2002-02-18 東ソー株式会社 低シリカフォージャサイト型ゼオライトおよびその製造方法
US6261441B1 (en) * 1998-09-24 2001-07-17 Mobil Oil Corporation Integrated hydroprocessing scheme with segregated recycle
US6500329B2 (en) * 1998-12-30 2002-12-31 Exxonmobil Research And Engineering Company Selective ring opening process for producing diesel fuel with increased cetane number
ES2168208B1 (es) * 2000-03-24 2003-04-01 Univ Valencia Politecnica Catalizadores de craqueo basados en zeolitas.
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PL1651738T3 (pl) * 2003-06-26 2012-03-30 Haldor Topsoe As Sposób przekształcania węglowodorów i katalizator
FR2865663B1 (fr) * 2004-01-29 2006-06-09 Inst Francais Du Petrole Catalyseur sous forme de grains comportant un coeur poreux acide entoure d'une couche externe uniforme
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US8298403B2 (en) * 2008-12-16 2012-10-30 Exxonmobil Research And Engineering Company Dewaxing catalysts and processes

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EP2683479A4 (fr) 2014-08-20
EP2683479A1 (fr) 2014-01-15
SG192577A1 (en) 2013-09-30
CA2825324A1 (fr) 2012-09-13
WO2012122208A1 (fr) 2012-09-13

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