CA2829605A1 - Procede de production en masse de nanofils ou nano-ceintures de silicium et batteries et anodes au lithium utilisant les nanofils ou nano-ceintures de silicium - Google Patents

Procede de production en masse de nanofils ou nano-ceintures de silicium et batteries et anodes au lithium utilisant les nanofils ou nano-ceintures de silicium Download PDF

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Publication number
CA2829605A1
CA2829605A1 CA2829605A CA2829605A CA2829605A1 CA 2829605 A1 CA2829605 A1 CA 2829605A1 CA 2829605 A CA2829605 A CA 2829605A CA 2829605 A CA2829605 A CA 2829605A CA 2829605 A1 CA2829605 A1 CA 2829605A1
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CA
Canada
Prior art keywords
silicon
phase
alloy
nanobelts
nanowires
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2829605A
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English (en)
Other versions
CA2829605C (fr
Inventor
Xueliang Sun
Yuhai Hu
Xifei Li Li
Ruying Li
Quanmin Yang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanosienergy Inc
Original Assignee
Springpower International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Springpower International Inc filed Critical Springpower International Inc
Priority to CA2829605A priority Critical patent/CA2829605C/fr
Priority to US14/144,774 priority patent/US9531006B2/en
Priority to CN201480055273.4A priority patent/CN105612277A/zh
Priority to KR1020167008361A priority patent/KR20160065844A/ko
Priority to PCT/CA2014/000724 priority patent/WO2015051442A1/fr
Priority to JP2016520027A priority patent/JP6383412B2/ja
Publication of CA2829605A1 publication Critical patent/CA2829605A1/fr
Application granted granted Critical
Publication of CA2829605C publication Critical patent/CA2829605C/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386—Silicon or alloys based on silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C28/00—Alloys based on a metal not provided for in groups C22C5/00 - C22C27/00
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C30/00—Alloys containing less than 50% by weight of each constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C5/00—Alloys based on noble metals
    • C22C5/04—Alloys based on a platinum group metal
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/043—Processes of manufacture in general involving compressing or compaction
    • H01M4/0435—Rolling or calendering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Silicon Compounds (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Dispersion Chemistry (AREA)

Abstract

La présente invention concerne un procédé de production en série de nanofils et/ou de nanoceintures de silicium. Le procédé de linvention est un procédé dattaque chimique qui utilise un agent dattaque chimique qui, de préférence, attaque et retire dautres phases dun alliage de silicium multiphase, sur une phase de silicium, et permet de récupérer les nanofils et/ou les nanoceintures de silicium résiduels. Lalliage de silicium comprend, ou est traité de façon à comprendre, des nanostructures de silicium unidimensionnelles et/ou bidimensionnelles dans la microstructure de lalliage de silicium multiphase avant lattaque chimique. Lorsquils sont utilisés comme anode pour des batteries secondaires au lithium, les nanofils ou nanoceintures de silicium produits par le procédé de linvention présentent une capacité de stockage élevée.
CA2829605A 2013-10-07 2013-10-07 Procede de production en masse de nanofils ou nano-ceintures de silicium et batteries et anodes au lithium utilisant les nanofils ou nano-ceintures de silicium Expired - Fee Related CA2829605C (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CA2829605A CA2829605C (fr) 2013-10-07 2013-10-07 Procede de production en masse de nanofils ou nano-ceintures de silicium et batteries et anodes au lithium utilisant les nanofils ou nano-ceintures de silicium
US14/144,774 US9531006B2 (en) 2013-10-07 2013-12-31 Method for mass production of silicon nanowires and/or nanobelts, and lithium batteries and anodes using the silicon nanowires and/or nanobelts
CN201480055273.4A CN105612277A (zh) 2013-10-07 2014-10-03 用于大量生产硅纳米线和/或纳米带的方法以及使用所述硅纳米线和/或纳米带的锂电池和阳极
KR1020167008361A KR20160065844A (ko) 2013-10-07 2014-10-03 실리콘 나노와이어 및/또는 나노벨트의 대량 제조 방법, 및 실리콘 나노와이어 및/또는 나노벨트를 이용한 리튬 전지 및 애노드
PCT/CA2014/000724 WO2015051442A1 (fr) 2013-10-07 2014-10-03 Procédé de production en série de nanofils et/ou de nanoceintures de silicium, et batteries au lithium et anodes utilisant les nanofils et/ou les nanoceintures de silicium
JP2016520027A JP6383412B2 (ja) 2013-10-07 2014-10-03 ケイ素ナノワイヤー及び／又はナノベルトの大量生産方法、並びに、ケイ素ナノワイヤー及び／又はナノベルトを用いたリチウム電池及びアノード

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA2829605A CA2829605C (fr) 2013-10-07 2013-10-07 Procede de production en masse de nanofils ou nano-ceintures de silicium et batteries et anodes au lithium utilisant les nanofils ou nano-ceintures de silicium

Publications (2)

Publication Number Publication Date
CA2829605A1 true CA2829605A1 (fr) 2015-04-07
CA2829605C CA2829605C (fr) 2016-06-14

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2829605A Expired - Fee Related CA2829605C (fr) 2013-10-07 2013-10-07 Procede de production en masse de nanofils ou nano-ceintures de silicium et batteries et anodes au lithium utilisant les nanofils ou nano-ceintures de silicium

Country Status (6)

Country Link
US (1) US9531006B2 (fr)
JP (1) JP6383412B2 (fr)
KR (1) KR20160065844A (fr)
CN (1) CN105612277A (fr)
CA (1) CA2829605C (fr)
WO (1) WO2015051442A1 (fr)

Cited By (1)

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CN110098404A (zh) * 2019-05-16 2019-08-06 四川大学 梯级结构纳米多孔硅、其烧结-刻蚀制备方法及其应用

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WO2016063281A1 (fr) 2014-10-21 2016-04-28 Ramot At Tel-Aviv University Ltd Anode à base de nanofil de silicium à haute capacité pour batteries au lithium-ion
US9601763B2 (en) * 2015-03-27 2017-03-21 Nanotek Instruments, Inc. Process for mass-producing silicon nanowires and silicon nanowire-graphene hybrid particulates
KR20180001518A (ko) * 2016-06-27 2018-01-04 주식회사 네패스 리튬이차전지 음극용 조성물, 이를 이용한 리튬이차전지 음극 제조 방법, 이로부터 제조된 리튬이차전지 음극 및 리튬이차전지
US11171325B2 (en) * 2016-07-11 2021-11-09 Nanograf Corporation Optimized electrode design for graphene based anodes
KR102374121B1 (ko) * 2017-08-02 2022-03-14 삼성전자주식회사 나노입자형 구조체에 내장된 위상구조 양자 프레임워크, 이를 포함하는 복합음극활물질, 음극, 리튬전지, 반도체, 소자 및 이의 제조 방법
TWI690112B (zh) * 2017-08-29 2020-04-01 國立成功大學 複合電極材料及其製作方法、包含該複合電極材料之複合電極、以及包含該複合電極之鋰電池
CN109742385A (zh) * 2019-01-07 2019-05-10 国联汽车动力电池研究院有限责任公司 一种硅基合金材料及其制备的锂离子电池负极材料
CN110010864A (zh) * 2019-03-21 2019-07-12 中国科学院半导体研究所 硅-石墨烯电池负极材料及其制备方法、锂电池
CN110482553A (zh) * 2019-08-20 2019-11-22 上海纳米技术及应用国家工程研究中心有限公司 一种硅纳米棒的制备方法及其产品和应用
TWI740400B (zh) * 2020-03-02 2021-09-21 力哲科技股份有限公司 電池材料及其製備方法
CN111204767A (zh) * 2020-03-13 2020-05-29 山东大学 一种二维硅的制备方法及其应用
CN115010137B (zh) * 2021-03-05 2023-12-19 中国科学院过程工程研究所 一种利用切割废硅粉快速制备硅纳米线的方法及应用
CN114560464B (zh) * 2022-03-01 2023-06-09 山东大学 一种硅负极材料及其制备方法和应用
CN115403046B (zh) * 2022-09-26 2023-06-30 山东大学 一种二维硅的制备方法及应用
CN115852194B (zh) * 2022-11-29 2024-05-03 上海交通大学 一种多级纳米多孔金属的制备方法
CN116514124A (zh) * 2023-03-28 2023-08-01 合肥综合性国家科学中心能源研究院(安徽省能源实验室) 由三元层状Zintl化合物制备纳米硅片的方法及应用
CN117902580B (zh) * 2024-01-11 2025-12-12 江汉大学 一种六氟硅酸亚铁、铁硅复合材料的制备方法及应用
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Publication number Priority date Publication date Assignee Title
CN110098404A (zh) * 2019-05-16 2019-08-06 四川大学 梯级结构纳米多孔硅、其烧结-刻蚀制备方法及其应用

Also Published As

Publication number Publication date
JP2016539065A (ja) 2016-12-15
US20150099173A1 (en) 2015-04-09
US9531006B2 (en) 2016-12-27
KR20160065844A (ko) 2016-06-09
JP6383412B2 (ja) 2018-08-29
WO2015051442A1 (fr) 2015-04-16
CA2829605C (fr) 2016-06-14
CN105612277A (zh) 2016-05-25

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