CA2831273C - Anode d'extraction electrolytique et procede d'extraction electrolytique l'utilisant - Google Patents
Anode d'extraction electrolytique et procede d'extraction electrolytique l'utilisant Download PDFInfo
- Publication number
- CA2831273C CA2831273C CA2831273A CA2831273A CA2831273C CA 2831273 C CA2831273 C CA 2831273C CA 2831273 A CA2831273 A CA 2831273A CA 2831273 A CA2831273 A CA 2831273A CA 2831273 C CA2831273 C CA 2831273C
- Authority
- CA
- Canada
- Prior art keywords
- electrowinning
- anode
- oxide
- catalytic layer
- amorphous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000005363 electrowinning Methods 0.000 title claims abstract description 260
- 238000000034 method Methods 0.000 title claims description 44
- 230000003197 catalytic effect Effects 0.000 claims abstract description 126
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 100
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 99
- 229910052751 metal Inorganic materials 0.000 claims abstract description 77
- 239000002184 metal Substances 0.000 claims abstract description 76
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims abstract description 75
- 229910001936 tantalum oxide Inorganic materials 0.000 claims abstract description 75
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 claims abstract description 62
- 229910001925 ruthenium oxide Inorganic materials 0.000 claims abstract description 59
- 239000000758 substrate Substances 0.000 claims abstract description 39
- 239000010936 titanium Substances 0.000 claims abstract description 37
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 34
- 150000002739 metals Chemical class 0.000 claims abstract description 13
- HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 claims description 33
- 229910000457 iridium oxide Inorganic materials 0.000 claims description 33
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 24
- 229910052715 tantalum Inorganic materials 0.000 claims description 24
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 24
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 23
- 229910052725 zinc Inorganic materials 0.000 claims description 23
- 239000011701 zinc Substances 0.000 claims description 23
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 21
- 229910052707 ruthenium Inorganic materials 0.000 claims description 21
- 229910017052 cobalt Inorganic materials 0.000 claims description 19
- 239000010941 cobalt Substances 0.000 claims description 19
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 19
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 19
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 15
- 239000010949 copper Substances 0.000 claims description 15
- 229910052697 platinum Inorganic materials 0.000 claims description 12
- 229910052741 iridium Inorganic materials 0.000 claims description 11
- 229910045601 alloy Inorganic materials 0.000 claims description 10
- 239000000956 alloy Substances 0.000 claims description 10
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- 239000010955 niobium Substances 0.000 claims description 5
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 239000010931 gold Substances 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 3
- 229910052703 rhodium Inorganic materials 0.000 claims description 3
- 239000010948 rhodium Substances 0.000 claims description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 41
- 229910052760 oxygen Inorganic materials 0.000 abstract description 41
- 239000001301 oxygen Substances 0.000 abstract description 41
- 230000002829 reductive effect Effects 0.000 abstract description 38
- 229910000978 Pb alloy Inorganic materials 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 125
- 230000000052 comparative effect Effects 0.000 description 79
- 238000005979 thermal decomposition reaction Methods 0.000 description 39
- 239000000243 solution Substances 0.000 description 29
- 230000000694 effects Effects 0.000 description 23
- 238000007086 side reaction Methods 0.000 description 22
- 239000002243 precursor Substances 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 13
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 12
- -1 cobalt oxyhydroxide Chemical compound 0.000 description 11
- 238000005868 electrolysis reaction Methods 0.000 description 11
- 229910021645 metal ion Inorganic materials 0.000 description 10
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 9
- 239000011133 lead Substances 0.000 description 9
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 9
- 238000002441 X-ray diffraction Methods 0.000 description 8
- 238000000151 deposition Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 229910003460 diamond Inorganic materials 0.000 description 5
- 239000010432 diamond Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- RTBHLGSMKCPLCQ-UHFFFAOYSA-N [Mn].OOO Chemical compound [Mn].OOO RTBHLGSMKCPLCQ-UHFFFAOYSA-N 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 238000005229 chemical vapour deposition Methods 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000012423 maintenance Methods 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 238000005240 physical vapour deposition Methods 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 230000000452 restraining effect Effects 0.000 description 4
- 238000004544 sputter deposition Methods 0.000 description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 description 4
- 239000011686 zinc sulphate Substances 0.000 description 4
- 235000009529 zinc sulphate Nutrition 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 229910001429 cobalt ion Inorganic materials 0.000 description 3
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 3
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 3
- 229910001437 manganese ion Inorganic materials 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- OEIMLTQPLAGXMX-UHFFFAOYSA-I tantalum(v) chloride Chemical compound Cl[Ta](Cl)(Cl)(Cl)Cl OEIMLTQPLAGXMX-UHFFFAOYSA-I 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 150000002697 manganese compounds Chemical class 0.000 description 2
- 239000002905 metal composite material Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 229910021518 metal oxyhydroxide Inorganic materials 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- JODOMBGKVAIYRQ-UHFFFAOYSA-N [Nb].[Ta].[Ti] Chemical compound [Nb].[Ta].[Ti] JODOMBGKVAIYRQ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000006263 metalation reaction Methods 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- 229910000484 niobium oxide Inorganic materials 0.000 description 1
- RJSRQTFBFAJJIL-UHFFFAOYSA-N niobium titanium Chemical compound [Ti].[Nb] RJSRQTFBFAJJIL-UHFFFAOYSA-N 0.000 description 1
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- BIXNGBXQRRXPLM-UHFFFAOYSA-K ruthenium(3+);trichloride;hydrate Chemical compound O.Cl[Ru](Cl)Cl BIXNGBXQRRXPLM-UHFFFAOYSA-K 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- VSSLEOGOUUKTNN-UHFFFAOYSA-N tantalum titanium Chemical compound [Ti].[Ta] VSSLEOGOUUKTNN-UHFFFAOYSA-N 0.000 description 1
- PBACCOSPRYQTNC-UHFFFAOYSA-J tetrachloroiridium hexahydrate dihydrochloride Chemical compound O.O.O.O.O.O.Cl.Cl.Cl[Ir](Cl)(Cl)Cl PBACCOSPRYQTNC-UHFFFAOYSA-J 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- ZTWIEIFKPFJRLV-UHFFFAOYSA-K trichlororuthenium;trihydrate Chemical compound O.O.O.Cl[Ru](Cl)Cl ZTWIEIFKPFJRLV-UHFFFAOYSA-K 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
- C25C1/08—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/16—Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Catalysts (AREA)
Abstract
L'invention propose une anode d'extraction électrolytique telle que, lors d'une opération d'extraction électrolytique utilisant une solution d'électrolyte à base d'acide sulfurique, le potentiel électrique pour la production d'oxygène est inférieur à celui nécessaire pour une électrode en plomb, une électrode en alliage de plomb et une électrode enrobée en titane, la tension d'électrolyse pour l'extraction électrolytique peut être réduite, et les unités de base pour l'énergie électrique peuvent être réduites pour un métal souhaité. Cette anode peut servir d'anode d'extraction électrolytique pour divers types de métaux et se prête davantage à la production en masse. L'anode d'extraction électrolytique est utilisée dans la méthode d'extraction électrolytique utilisant une solution d'électrolyte à base d'acide sulfurique, et une couche de catalyseur comprenant de l'oxyde de ruthénium non cristallin et de l'oxyde de tantale non cristallin est formée sur une substance de base conductrice.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011067365A JP4916040B1 (ja) | 2011-03-25 | 2011-03-25 | 電解採取用陽極および該陽極を用いた電解採取法 |
| JP2011-067365 | 2011-03-25 | ||
| PCT/JP2012/057426 WO2012133136A1 (fr) | 2011-03-25 | 2012-03-23 | Anode d'extraction électrolytique et procédé d'extraction électrolytique l'utilisant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2831273A1 CA2831273A1 (fr) | 2012-10-04 |
| CA2831273C true CA2831273C (fr) | 2016-02-23 |
Family
ID=46171009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2831273A Expired - Fee Related CA2831273C (fr) | 2011-03-25 | 2012-03-23 | Anode d'extraction electrolytique et procede d'extraction electrolytique l'utilisant |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20140054180A1 (fr) |
| EP (1) | EP2690200B1 (fr) |
| JP (1) | JP4916040B1 (fr) |
| KR (1) | KR101577664B1 (fr) |
| CN (1) | CN103476970B (fr) |
| AU (1) | AU2012234150B2 (fr) |
| CA (1) | CA2831273C (fr) |
| CL (1) | CL2013002745A1 (fr) |
| ES (1) | ES2557194T3 (fr) |
| RU (1) | RU2568546C2 (fr) |
| WO (1) | WO2012133136A1 (fr) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103974769B (zh) | 2011-09-01 | 2018-11-09 | 西蒙·特鲁德尔 | 电催化材料及其制造方法 |
| JP5522484B2 (ja) * | 2011-09-13 | 2014-06-18 | 学校法人同志社 | 電解めっき用陽極および該陽極を用いる電解めっき法 |
| JP5008043B1 (ja) * | 2011-09-13 | 2012-08-22 | 学校法人同志社 | 塩素発生用陽極 |
| US9178219B2 (en) * | 2012-12-20 | 2015-11-03 | Ford Global Technologies, Llc | Electrochemical device including amorphous metal oxide |
| US9790605B2 (en) | 2013-06-27 | 2017-10-17 | Yale University | Iridium complexes for electrocatalysis |
| US10081650B2 (en) | 2013-07-03 | 2018-09-25 | Yale University | Metal oxide-organic hybrid materials for heterogeneous catalysis and methods of making and using thereof |
| JP5804484B1 (ja) * | 2014-02-12 | 2015-11-04 | 学校法人同志社 | イオンセンサ用触媒およびこれを用いたイオンセンサならびに定量法 |
| RU2657747C2 (ru) * | 2016-04-20 | 2018-06-15 | Общество с ограниченной ответственностью "БИНАКОР-ХТ" (ООО "БИНАКОР-ХТ") | Анод электролизера для получения порошков сплавов металлов |
| CA3036352C (fr) * | 2016-09-09 | 2020-09-15 | De Nora Permelec Ltd | Methode de production d'anode d'electrolyse d'eau alcaline et anode destinee a l'electrolyse d'eau alcaline |
| DK3763849T3 (da) * | 2018-03-07 | 2022-12-12 | De Nora Permelec Ltd | Elektrolyseelektrode og fremgangsmåde til fremstilling af samme |
| US11639142B2 (en) | 2019-01-11 | 2023-05-02 | Ford Global Technologies, Llc | Electronic control module wake monitor |
| JP7341395B2 (ja) * | 2019-10-30 | 2023-09-11 | 住友金属鉱山株式会社 | 廃リチウムイオン電池からの銅、ニッケル、コバルトの回収方法 |
| WO2023208026A1 (fr) * | 2022-04-28 | 2023-11-02 | 中国石油化工股份有限公司 | Catalyseur composite à base d'iridium dopé par un métal de transition, sa préparation et son application |
| CN115466985A (zh) * | 2022-09-23 | 2022-12-13 | 中国船舶重工集团公司第七二五研究所 | 一种含非晶氧化铑中间层金属氧化物电极制备方法 |
| WO2024263955A1 (fr) | 2023-06-21 | 2024-12-26 | SiTration, Inc. | Procédés et appareil d'extraction de métaux à partir de matériaux |
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| IT1151365B (it) | 1982-03-26 | 1986-12-17 | Oronzio De Nora Impianti | Anodo per procedimenti elettrilitici |
| JPS61281889A (ja) * | 1985-06-06 | 1986-12-12 | Koji Hashimoto | 電解用電極材料 |
| JPS6233790A (ja) * | 1985-08-02 | 1987-02-13 | Koji Hashimoto | 活性化非晶質合金電極 |
| US5314601A (en) | 1989-06-30 | 1994-05-24 | Eltech Systems Corporation | Electrodes of improved service life |
| JP3463966B2 (ja) | 1995-09-25 | 2003-11-05 | 石福金属興業株式会社 | 電解用電極の製造方法 |
| US6139705A (en) * | 1998-05-06 | 2000-10-31 | Eltech Systems Corporation | Lead electrode |
| IT1302581B1 (it) * | 1998-10-01 | 2000-09-29 | Nora De | Anodo con migliorato rivestimento per la reazione di evoluzione diossigeno in elettroliti contenenti manganese. |
| JP3914162B2 (ja) * | 2003-02-07 | 2007-05-16 | ダイソー株式会社 | 酸素発生用電極 |
| US7258778B2 (en) | 2003-03-24 | 2007-08-21 | Eltech Systems Corporation | Electrocatalytic coating with lower platinum group metals and electrode made therefrom |
| CA2567127C (fr) * | 2004-06-03 | 2012-08-28 | Moltech Invent S.A. | Anodes exemptes de carbone a ecoulement continu et a stabilite elevee permettant d'extraire de l'aluminium par voie electrolytique |
| JP4771130B2 (ja) * | 2005-11-25 | 2011-09-14 | ダイソー株式会社 | 酸素発生用電極 |
| JP2007246987A (ja) | 2006-03-16 | 2007-09-27 | Japan Carlit Co Ltd:The | 電極製造用塗布液、及び該塗布液を使用して製造された電解用電極 |
| JP2008050675A (ja) | 2006-08-28 | 2008-03-06 | Ishifuku Metal Ind Co Ltd | 電解用電極 |
| ITMI20061974A1 (it) * | 2006-10-16 | 2008-04-17 | Industrie De Nora Spa | Anodo per elettrolisi |
| CN101861412B (zh) | 2007-11-16 | 2013-04-24 | 阿克佐诺贝尔股份有限公司 | 电极 |
| US8022004B2 (en) | 2008-05-24 | 2011-09-20 | Freeport-Mcmoran Corporation | Multi-coated electrode and method of making |
| JP4516617B2 (ja) * | 2008-06-09 | 2010-08-04 | 学校法人同志社 | 亜鉛の電解採取用陽極および電解採取法 |
| CN102057081B (zh) * | 2008-06-09 | 2013-04-03 | 学校法人同志社 | 一种阳极在锌及钴的电解提取中的应用、以及电解提取方法 |
| JP4516618B2 (ja) * | 2008-06-23 | 2010-08-04 | 学校法人同志社 | コバルトの電解採取用陽極および電解採取法 |
| JP5013438B2 (ja) * | 2009-12-08 | 2012-08-29 | 学校法人同志社 | 金属の電解採取用陽極および電解採取方法 |
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- 2012-03-23 RU RU2013147642/02A patent/RU2568546C2/ru active
- 2012-03-23 CN CN201280016122.9A patent/CN103476970B/zh not_active Expired - Fee Related
- 2012-03-23 US US14/007,488 patent/US20140054180A1/en not_active Abandoned
- 2012-03-23 EP EP12763572.0A patent/EP2690200B1/fr not_active Not-in-force
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- 2012-03-23 WO PCT/JP2012/057426 patent/WO2012133136A1/fr not_active Ceased
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- 2012-03-23 AU AU2012234150A patent/AU2012234150B2/en not_active Ceased
- 2012-03-23 CA CA2831273A patent/CA2831273C/fr not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| CN103476970B (zh) | 2016-07-06 |
| CN103476970A (zh) | 2013-12-25 |
| AU2012234150A1 (en) | 2013-11-14 |
| CA2831273A1 (fr) | 2012-10-04 |
| US20140054180A1 (en) | 2014-02-27 |
| ES2557194T3 (es) | 2016-01-22 |
| JP4916040B1 (ja) | 2012-04-11 |
| RU2568546C2 (ru) | 2015-11-20 |
| EP2690200B1 (fr) | 2015-10-07 |
| CL2013002745A1 (es) | 2014-04-25 |
| JP2012201925A (ja) | 2012-10-22 |
| EP2690200A4 (fr) | 2014-03-19 |
| KR20140002749A (ko) | 2014-01-08 |
| AU2012234150B2 (en) | 2015-07-02 |
| EP2690200A1 (fr) | 2014-01-29 |
| KR101577664B1 (ko) | 2015-12-15 |
| RU2013147642A (ru) | 2015-04-27 |
| WO2012133136A1 (fr) | 2012-10-04 |
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