CA2841469C - Absorbent liquid control strip - Google Patents
Absorbent liquid control strip Download PDFInfo
- Publication number
- CA2841469C CA2841469C CA2841469A CA2841469A CA2841469C CA 2841469 C CA2841469 C CA 2841469C CA 2841469 A CA2841469 A CA 2841469A CA 2841469 A CA2841469 A CA 2841469A CA 2841469 C CA2841469 C CA 2841469C
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- CA
- Canada
- Prior art keywords
- strip
- sleeve
- liquid
- indicia
- roll
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B23/00—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose
- B32B23/04—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
- B01J20/28038—Membranes or mats made from fibers or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
- B01J2220/68—Superabsorbents
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- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Laminated Bodies (AREA)
Abstract
Description
BACKGROUND OF THE INVENTION
FIELD OF THE INVENTION
[0001] This invention generally relates to a liquid control strips utilizing super absorbent polymers impregnated or otherwise seeded in a substrate and improvements in the substrate impregnated or otherwise seeded with a super absorbent polymer.
Liquid control strips can be used to contain spills prior to cleaning, minimize damage from leaks or control floor stripping chemical solution. Suitable for a wide range of cleaning applications including: refrigerator leaks, floor stripping, kitchen, restroom, window, swimming pool, hospital room and many more applications. In one embodiment the disclosure relates to a substrate for use in a liquid control strip impregnated or otherwise seeded with a super absorbent polymer where the substrate is treated to de-activate the super absorbent polymer in selected areas. In another embodiment the disclosure relates to liquid control strips of indeterminate length, perforated at periodic lengths to permit selection of a strip of the desired length with a substrate treated in areas adjacent the perforations to de-activate the super absorbent polymer.
DESCRIPTION OF THE PRIOR ART
SUMMARY OF THE INVENTION
100101 In another embodiment the invention relates to a method of forming the sleeve for a liquid control strip having pleats along its outer edges with indicia in the pleat that is exposed when the control strip is hydrated.
[0011] In another embodiment the invention relates to a method of forming a liquid control strip according to one or more embodiments of the present invention..
[0012] Further features of the invention will be described or will become apparent in the course of the following detailed description.
BRIEF DESCRIPTION OF THE DRAWINGS
[0013] In order that the invention may be more clearly understood, embodiments thereof will now be described in detail by way of example, with reference to the accompanying illustrations, in which:
Fig. 1 is a perspective view of one embodiment of an end section of a liquid control strip of indeterminate length according to the present invention.
Fig. 2 is a perspective view of the ends of a substrate formed of layers of cellulose material, each layer having a super absorbent polymer impregnated within each layer;
Fig. 3 is another perspective view of a substrate formed of layers of cellulose material, each layer having a super absorbent polymer impregnated within each layer;
Fig. 4 is a perspective view of a portion of the liquid control strip of Fig.
1 before hydration;
Fig. 5 is a perspective view of the portion of the liquid control strip of Fig. 4 after hydration;
Fig. 6 is an end view of the liquid control strip of Fig. 1 showing both the substrate un-treated and treated to de-activate the super absorbent polymer;
Fig. 7 is a side view of the liquid control strip of Fig. 1 with area adjacent a perforation treated to de-activate the super absorbent polymer;
Fig.8 is a perspective view of another embodiment of a liquid control strip according to the present invention with a different indicator means when the strip should be replaced; and Fig. 9 is a schematic drawing of one process of making a liquid control strip of Fig. 4 and 5.
[0014] Similar references are used in different figures to denote similar components.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
[0015] Referring to the Figs, one embodiment of a liquid control strip 1 of indeterminate length according to the present invention is illustrated. The liquid control strip 1 comprises a sleeve 2 with a substrate 3 in one or more layers within the sleeve. The sleeve 2 can be formed from non-woven polypropylene or polyethylene or non-woven synthetic fibres of polythene and rayon or spun bound fibres. The outer surface of the sleeve is marked for the application it is intended to control. Each jurisdiction has regulations regarding the colour of the sleeve and warning symbols and other indicia on the sleeve. In the embodiment illustrated in Fig. 1 the sleeve is a yellow colour indicating it is to be used for water based liquids. If the strip was intended to control different Date Recue/Date Received 2020-05-19 substances it may be a different colour such as orange if used for Hazmat applications.
Warning symbols in Fig 1 include the symbol 4 warning of slippery conditions.
[0016] The substrate 3 can be any material typically used in absorbent liquid strips such as cellulose or lofty hydrophilic polypropylene as two examples. The substrate 3 is impregnated or otherwise seeded with a super absorbent polymer such as sodium polyacrylate. Other known super absorbents can be used depending on the application.
[0017] The substrate 3 used in the illustrated embodiment as best illustrated in Figs 2 and 3 comprise a series of elongated strips 5 of cellulose fibre 6. Each cellulose strip 5 has a super absorbent polymer embedded in the strip. In the embodiment illustrated each strip has a layer of super absorbent polymer sandwiched between layers of the cellulose fibre.
The embodiment illustrated uses sodium polyacylate as the super absorbent polymer.
[0018] Superabsorbents have been made from chemically modified starch and cellulose and other polymers like poly(vinyl alcohol) PVA, poly(ethylene oxide) PEO all of which are hydrophilic and have a high affinity for water. When lightly cross-linked, chemically or physically, these polymers became water-swellable but not water-soluble.
[0019] Currently superabsorbent polymers are typically made from partially neutralised, lightly cross-linked poly(acrylic acid), which is generally believed to give the best performance versus cost ratio. The polymers are manufactured at low solids levels for both quality and economic reasons, and are dried and milled in to granular white solids.
In water they swell to a rubbery gel that in some cases can be up to 99wt %
water.
[0020] Natural super absorbent polymers may also be used. One reported example is a material developed by Exotech Bio Solutions in Israel.
[0021] As noted above the liquid control strip 1 of Fig. 1 is made in long lengths such as 100 ft. perforated at regular intervals such as 12 ¨ 24 inches. When a length of the liquid control strip is removed from a longer length along a perforation, the substrate impregnated or otherwise seeded with the super absorbent polymer is exposed along the perforation. It is possible for gel to ooze from the strip after absorption of the liquid. This can create a hazard. Efforts to address the problem have so far proven less than satisfactory.
[0022] In the present disclosure it has been determined that the super absorbent can be treated to de-activate the super absorbent polymer in areas adjacent the perforations. The super absorbent polymer used in the illustrated embodiment (Sodium Polyacrylate) may be deactivated by applying slurry of starch and salt on the cellulose fibre strip on either side of the location where the perforation will be before its inserted into the sleeve. In the embodiment illustrated the starch and salt were mixed 50-50 by weight but variation in the composition is possible. In the embodiment illustrated the super absorbent polymer is deactivated two inches on either side of where the perforation will be.
Variation in the distance is possible as long as the substrate when hydrated does not leak from the exposed end of the control strip but the strip is still able to absorb the liquid along its length without the liquid seeping under the control strip.
[0023] Figs 6 and 7 show an embodiment of the liquid control strip where the super absorbent polymer has selected areas deactivated. Fig 6 shows an exposed end of a conventional liquid strip 8 after being severed from the long length. The conventional .. strip 8 on the left utilized a substrate that was untreated to deactivate the super absorbent polymer. The strip 9 on the right in Fig 6 utilized a substrate that was treated to deactivate the super absorbent polymer according to the present invention thereby preventing any SAP (Sodium Polyacrylate) from spilling on to the floor from the exposed end creating a slip and fall hazard. The front of the strip 9 on the right in Fig. 6 shows a section of the .. substrate that has been treated to deactivate the SAP. Fig 7 shows the strip 9 from the side and shows that the section 10 of the strip 9 with the substrate that has been treated rests on the horizontal surface, preventing any liquid from seeping under the strip before being absorbed. The section 10 includes a treated perforation area on either side of the perforation that is treated to dc-activate the super absorbent polymer. The perforation area .. may be treated for 2 inches on either side of a perforation.
[0024] In the embodiment illustrated in Figs 4 and 5, the sleeve is formed with a pleat 13 on its edges 11, 12. Fig. 4 shows the absorbent strip 1 before hydration. Note that the strip 1 lies flat before use as shown in Fig 4. The pleat 13 is closed hiding the indicia of the words "REPLACE" inside the pleat 13. Fig. 5 shows the absorbent strip 1 after hydration. When the liquid is absorbed the pleat 13 opens as shown in Fig 5 to expose the word "REPLACE" printed 6a on the sleeve within the pleat. This indicates the liquid control strip has absorbed liquid and should be replaced. In Fig. 5, the absorbent strip I shown is fully hydrated and has expanded opening the pleat 13 and exposing the words "REPLACE".
[0025] In Fig. 8 another embodiment of the invention is illustrated. In this embodiment the indicia provided for indicating the control strip should be replaced is printing the word REPLACE in an invisible ink on top of the strip that will show up when the strip gets wet.
[0026] As noted earlier known liquid control strips fowl the sleeve by sonic welding the outer edges of a top and bottom sheet. In the embodiment illustrated in Fig. 1 the sleeve is formed by wrapping the material around the substrate and gluing the overlap using an adhesive that is impervious to all chemical attack from the liquids to be absorbed.
[0027] In Fig. 9 one process for forming the substrate according to the present invention with selected areas of the super absorbent polymer deactivated, is illustrated. A plurality of rolls 20, 21, 22, 23, 24, 25 of elongated strips 26, 27, 28, 29, 3 0, 33 of cellulose fibre are provided. Fewer or more rolls than are illustrated can be used. Each cellulose strip 26, 27, 28, 29, 30, 33 has a super absorbent polymer embedded in the strip. Each strip is passed through a dosing station 31 where a slurry of starch and salt is applied at periodic locations along the strips surrounding where the perforations will be when the liquid control strip is formed. The super absorbent polymer in the areas treated is deactivated.
The elongated strips are pulled through nip rolls 32 to form a substrate 3. A
roll 34 of material to form the sleeve 2 is pulled from the roll and the pleat is formed at stage 35.
The sleeve 2 passes below substrate 3 through nip rolls 36 after which the outer edges are folded over glued and sealed at glue head 37. The liquid control strip 1 is perforated across its width at 38 every 12 or 24 inches corresponding to the locations where the super absorbent polymer was deactivated. The finished control strip 1 is wounded on rewinder 39.
[0028] While the principles of the invention have been shown and described in connection with specific embodiments, it is to be understood that such embodiments are by way of example and are not limiting. As is evident from the foregoing description, certain aspects of the present invention are not limited by the particular details of the mobile stand illustrated in the drawings. Other modifications and applications, or equivalents, will occur to those skilled in the art. The terms "having", "comprising" and "including" and similar terms as used in the foregoing specification are used in the sense of "optional" or "may include" and not as "required". Many changes, modifications, variations and other uses and applications of the present construction will, however, become apparent to those skilled in the art after considering the specification and attached drawings. All such changes, modifications, variations and other uses and applications .. which do not depart from the spirit and scope of the invention are deemed to be covered by the invention which is limited only by the claims that follow. The scope of the disclosure is not intended to be limited to the embodiments shown herein, but is to be accorded the full scope consistent with the claims, wherein reference to an element in the singular is not intended to mean "one and only one" unless specifically so stated, but rather one or more. All structural and functional equivalents to the elements of the embodiment described throughout the disclosure that are known or later come to be known to those of ordinary skill in the art are intended to be encompassed by the claims.
Date Recue/Date Received 2020-05-19
Claims (30)
a) a longitudinally extending sleeve having an outer surface and a longitudinally extending pleat; and, b) an interior portion comprising an absorbent layer housed within the sleeve, the absorbent layer comprising a superabsorbent polymer;
wherein the strip is transitionable between an unused configuration in which the pleat is folded and a used expanded configuration in which the pleat is unfolded.
a) a longitudinally extending sleeve having an outer surface and a longitudinally extending pleat, the sleeve being transitionable between an unused configuration in which the pleat is folded and a used expanded configuration in which the pleat is unfolded; and b) an interior portion comprising an absorbent layer housed within the sleeve, the absorbent layer comprising a superabsorbent polymer;
wherein a liquid absorbent strip comprising a longitudinally extending section of the sleeve and the interior portion is detachable from the roll.
a) providing a longitudinally extending length of non-woven material, the non-woven material having first and second transversely spaced apart longitudinally extending sides;
b) forming a longitudinally extending pleat in the non-woven material;
c) positioning an absorbent layer on an inner surface of the non-woven material, the absorbent layer comprising a super absorbent polymer;
d) moving a longitudinally extending side transversely and encasing the absorbent layer in the non-woven material whereby the absorbent layer is secured within the non-woven material without fully expanding the pleat.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2841469A CA2841469C (en) | 2014-01-24 | 2014-01-24 | Absorbent liquid control strip |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2841469A CA2841469C (en) | 2014-01-24 | 2014-01-24 | Absorbent liquid control strip |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2841469A1 CA2841469A1 (en) | 2015-07-24 |
| CA2841469C true CA2841469C (en) | 2020-12-15 |
Family
ID=53675733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2841469A Active CA2841469C (en) | 2014-01-24 | 2014-01-24 | Absorbent liquid control strip |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA2841469C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2958663C (en) * | 2017-02-22 | 2018-11-06 | Can-Ross Environmental Services Ltd. | Liquid absorbent sock and method of manufacture thereof |
-
2014
- 2014-01-24 CA CA2841469A patent/CA2841469C/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2841469A1 (en) | 2015-07-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20190107 |
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| U00 | Fee paid |
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| U00 | Fee paid |
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| U11 | Full renewal or maintenance fee paid |
Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL Effective date: 20260114 |