CA2950294C - Procede et systeme pour la reduction electrochimique de dioxyde de carbone au moyen d'une electrode a diffusion gazeuse - Google Patents

Procede et systeme pour la reduction electrochimique de dioxyde de carbone au moyen d'une electrode a diffusion gazeuse Download PDF

Info

Publication number
CA2950294C
CA2950294C CA2950294A CA2950294A CA2950294C CA 2950294 C CA2950294 C CA 2950294C CA 2950294 A CA2950294 A CA 2950294A CA 2950294 A CA2950294 A CA 2950294A CA 2950294 C CA2950294 C CA 2950294C
Authority
CA
Canada
Prior art keywords
anode
cathode
anolyte
catholyte
alkali metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2950294A
Other languages
English (en)
Other versions
CA2950294A1 (fr
Inventor
Jerry J. Kaczur
Prasad Lakkaraju
Kyle Teamey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Avantium Knowledge Centre BV
Original Assignee
Avantium Knowledge Centre BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/US2014/046555 external-priority patent/WO2015195149A1/fr
Application filed by Avantium Knowledge Centre BV filed Critical Avantium Knowledge Centre BV
Priority claimed from US14/726,061 external-priority patent/US10329676B2/en
Priority claimed from PCT/US2015/033378 external-priority patent/WO2015184388A1/fr
Publication of CA2950294A1 publication Critical patent/CA2950294A1/fr
Application granted granted Critical
Publication of CA2950294C publication Critical patent/CA2950294C/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/24—Halogens or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C25B11/032—Gas diffusion electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/083—Separating products
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/07—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/13—Organo-metallic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Abstract

La présente invention concerne un procédé et un système pour la réduction du dioxyde de carbone. Le procédé peut comprendre la réception d'hydrogène gazeux au niveau d'une région d'anolyte d'une cellule électrochimique comprenant une anode, l'anode comprenant une électrode à diffusion gazeuse, la réception d'une alimentation en anolyte au niveau d'une région d'anolyte de la cellule électrochimique, et la réception d'une alimentation en catholyte comprenant du dioxyde de carbone et un bicarbonate de métal alcalin au niveau d'une région de catholyte de la cellule électrochimique comprenant une cathode. Le procédé peut comprendre l'application d'un potentiel électrique entre l'anode et la cathode, qui est suffisant pour réduire le dioxyde de carbone en au moins un produit de réduction.
CA2950294A 2014-05-29 2015-05-29 Procede et systeme pour la reduction electrochimique de dioxyde de carbone au moyen d'une electrode a diffusion gazeuse Active CA2950294C (fr)

Applications Claiming Priority (11)

Application Number Priority Date Filing Date Title
US201462004544P 2014-05-29 2014-05-29
US62/004,544 2014-05-29
US201462014465P 2014-06-19 2014-06-19
US62/014,465 2014-06-19
PCT/US2014/046555 WO2015195149A1 (fr) 2014-06-19 2014-07-14 Procédé intégré de co-production d'acides carboxyliques et de produits d'halogène à partir de dioxyde de carbone
USPCT/US14/46555 2014-07-14
US201562108407P 2015-01-27 2015-01-27
US62/108,407 2015-01-27
US14/726,061 US10329676B2 (en) 2012-07-26 2015-05-29 Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode
PCT/US2015/033378 WO2015184388A1 (fr) 2014-05-29 2015-05-29 Procédé et système pour la réduction électrochimique de dioxyde de carbone au moyen d'une électrode à diffusion gazeuse
US14/726,061 2015-05-29

Publications (2)

Publication Number Publication Date
CA2950294A1 CA2950294A1 (fr) 2015-12-03
CA2950294C true CA2950294C (fr) 2022-07-19

Family

ID=57483085

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2950294A Active CA2950294C (fr) 2014-05-29 2015-05-29 Procede et systeme pour la reduction electrochimique de dioxyde de carbone au moyen d'une electrode a diffusion gazeuse

Country Status (2)

Country Link
JP (1) JP6599367B2 (fr)
CA (1) CA2950294C (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12286716B2 (en) 2018-01-22 2025-04-29 Twelve Benefit Corporation System and method for carbon dioxide reactor control
US12577690B2 (en) 2021-12-08 2026-03-17 Twelve Benefit Corporation Systems and methods for ethylene production
US12595572B2 (en) 2018-04-25 2026-04-07 The University Of British Columbia Systems and methods for electrochemical generation of syngas and other useful chemicals

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3008173A1 (fr) * 2015-12-22 2017-06-29 Avantium Holding B.V. Systeme et procede de co-production d'acide oxalique et d'acide acetique
WO2019051609A1 (fr) * 2017-09-14 2019-03-21 The University Of British Columbia Systèmes et procédés de réduction électrochimique de dioxyde de carbone
JP6845114B2 (ja) 2017-09-20 2021-03-17 株式会社東芝 二酸化炭素電解装置および二酸化炭素電解方法
DE102018202337A1 (de) * 2018-02-15 2019-08-22 Linde Aktiengesellschaft Elektrochemische Herstellung eines Gases umfassend CO mit Zwischenkühlung des Elektrolytstroms
JP6813526B2 (ja) 2018-03-16 2021-01-13 株式会社東芝 二酸化炭素の電解セルと電解装置
JP6813525B2 (ja) 2018-03-16 2021-01-13 株式会社東芝 二酸化炭素の電解セルと電解装置
EP3626861A1 (fr) * 2018-09-18 2020-03-25 Covestro Deutschland AG Cellule d'électrolyse, électrolyseur et procédé de réduction de co2
US11193212B2 (en) 2018-09-25 2021-12-07 Sekisui Chemical Co., Ltd. Synthetic method and synthetic system
US10811711B2 (en) 2018-11-20 2020-10-20 University Of Delaware Electrochemical devices and fuel cell systems
HUE057982T2 (hu) * 2019-05-27 2022-06-28 Covestro Deutschland Ag Eljárás poliuretán anyag hulladék újrafeldolgozására izocianátok és poliuretánok elõállításában alkalmazható vegyi nyersanyagok elõállításához
KR102232536B1 (ko) * 2019-10-15 2021-03-25 한국조선해양 주식회사 가스확산전극을 이용한 이산화탄소 및 평형수 처리장치
KR102305660B1 (ko) * 2019-11-26 2021-09-30 한국에너지기술연구원 무기 폐기물을 이용한 통합 공정 기반 이산화탄소 광물화 장치 및 방법
KR102305657B1 (ko) * 2019-11-26 2021-09-29 한국에너지기술연구원 무기 폐기물을 이용한 저전력 통합공정 기반 이산화탄소 광물화 장치 및 방법
KR102305659B1 (ko) * 2019-11-26 2021-09-29 한국에너지기술연구원 통합 공정 기반 이산화탄소 광물화 장치 및 방법
KR102305656B1 (ko) * 2019-11-26 2021-09-29 한국에너지기술연구원 저전력 통합공정 기반 이산화탄소 광물화 장치 및 방법
KR102279080B1 (ko) * 2019-12-11 2021-07-16 부경대학교 산학협력단 염수 전기분해를 이용한 이산화탄소 전환 방법 및 시스템
US12521673B2 (en) 2020-05-20 2026-01-13 University Of Delaware Electrochemically driven carbon dioxide separator
CN114452822A (zh) * 2020-11-09 2022-05-10 鼎佳能源股份有限公司 二氧化碳回收产生一氧化碳再利用系统
US12331414B2 (en) * 2021-01-21 2025-06-17 The University Of British Columbia Methods and apparatus for performing electrolytic conversion
CN113120866B (zh) * 2021-03-31 2022-04-22 中南大学 一种利用二氧化硫制备单质硫的方法
CN114318383A (zh) * 2022-01-25 2022-04-12 山东中教金源精密仪器有限公司 一种气固液三相界面光电催化反应池
CN114772682B (zh) * 2022-03-31 2023-07-25 北京化工大学 金基修饰电极、氯甘油的去除方法及其用途
CN115337933B (zh) * 2022-07-11 2024-03-22 华东理工大学 一种高效光催化还原co2的锡掺杂带有氧空位的四氧化三钴材料的制备方法及其应用
CN116231176A (zh) * 2023-03-02 2023-06-06 中国华能集团清洁能源技术研究院有限公司 一种利用空气源的移动式金属-二氧化碳电池系统
JP7743847B2 (ja) * 2023-03-06 2025-09-25 株式会社豊田中央研究所 二酸化炭素還元装置および人工光合成装置
WO2024250018A1 (fr) * 2023-06-02 2024-12-05 Hunt Energy Enterprises, L.L.C. Système, appareil et procédé pour créer un carburant synthétique
CN119332256A (zh) * 2024-09-18 2025-01-21 万华化学集团股份有限公司 一种草酸的制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO824150L (no) * 1981-12-11 1983-06-13 British Petroleum Co Elektrokemisk organisk syntese.
JPH0693485A (ja) * 1992-09-10 1994-04-05 Tanaka Kikinzoku Kogyo Kk 二酸化炭素の還元方法
JPH07258877A (ja) * 1994-03-23 1995-10-09 Tanaka Kikinzoku Kogyo Kk ガスの電解還元方法
US20120171583A1 (en) * 2010-12-30 2012-07-05 Liquid Light, Inc. Gas phase electrochemical reduction of carbon dioxide
US20130034489A1 (en) * 2011-02-14 2013-02-07 Gilliam Ryan J Electrochemical hydroxide system and method using fine mesh cathode
WO2012128148A1 (fr) * 2011-03-18 2012-09-27 国立大学法人長岡技術科学大学 Système de réduction et de fixation de dioxyde de carbone, procédé de réduction de fixation de dioxyde de carbone et procédé de fabrication d'une ressource de carbone utile
WO2014042782A1 (fr) * 2012-09-14 2014-03-20 Liquid Light, Inc. Système et électrodes de surface élevée pour la réduction électrochimique du dioxyde de carbone
CN104919088A (zh) * 2012-09-19 2015-09-16 液体光有限公司 由二氧化碳生产羧酸的综合方法
KR20160040614A (ko) * 2013-07-31 2016-04-14 아쿠아하이드렉스 프로프라이어터리 리미티드 기체 확산 전극(들)을 가지는 전기-합성 또는 전기-에너지 전지
WO2015035521A1 (fr) * 2013-09-12 2015-03-19 Mantra Energy Alternatives Ltd Réacteur sans membrane permettant l'électroréduction du dioxyde de carbone

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12286716B2 (en) 2018-01-22 2025-04-29 Twelve Benefit Corporation System and method for carbon dioxide reactor control
US12320022B2 (en) 2018-01-22 2025-06-03 Twelve Benefit Corporation System and method for carbon dioxide reactor control
US12595572B2 (en) 2018-04-25 2026-04-07 The University Of British Columbia Systems and methods for electrochemical generation of syngas and other useful chemicals
US12577690B2 (en) 2021-12-08 2026-03-17 Twelve Benefit Corporation Systems and methods for ethylene production

Also Published As

Publication number Publication date
JP2017521555A (ja) 2017-08-03
CA2950294A1 (fr) 2015-12-03
JP6599367B2 (ja) 2019-10-30

Similar Documents

Publication Publication Date Title
US11131028B2 (en) Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode
CA2950294C (fr) Procede et systeme pour la reduction electrochimique de dioxyde de carbone au moyen d'une electrode a diffusion gazeuse
EP3149228B1 (fr) Procédé pour la réduction électrochimique de dioxyde de carbone au moyen d'une électrode à diffusion gazeuse
EP2898117B1 (fr) Procédé intégré pour la production d'acide oxalique à partir de dioxyde de carbone
EP2898118B1 (fr) Procédé pour la production électrochimique conjointe d'halogène et de monoxyde de carbone pour des produits carbonylés
US8691069B2 (en) Method and system for the electrochemical co-production of halogen and carbon monoxide for carbonylated products
US20130292257A1 (en) Integrated Process for Producing Carboxylic Acids from Carbon Dioxide
US20190017183A1 (en) System and Method for the Co-Production of Oxalic Acid and Acetic Acid
EP3157897B1 (fr) Procédé intégré de co-production d'acides carboxyliques et de produits d'halogène à partir de dioxyde de carbone
WO2017118712A1 (fr) Procédé et système destiné à la réduction électrochimique du dioxyde de carbone au moyen d'une anode à diffusion gazeuse
CARBON Kaczur et al.

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20200525

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 10TH ANNIV.) - STANDARD

Year of fee payment: 10

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20250523

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20250523