CA3012554C - Procede de production de methanol - Google Patents

Procede de production de methanol Download PDF

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Publication number
CA3012554C
CA3012554C CA3012554A CA3012554A CA3012554C CA 3012554 C CA3012554 C CA 3012554C CA 3012554 A CA3012554 A CA 3012554A CA 3012554 A CA3012554 A CA 3012554A CA 3012554 C CA3012554 C CA 3012554C
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CA
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Prior art keywords
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space velocity
catalyst
process according
methanol
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CA3012554A
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CA3012554A1 (fr
Inventor
Atsushi URAKAWA
Atul BANSODE
Rohit Vilas GAIKWAD
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Institut Catala dInvestigacio Quimica ICIQ
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Institut Catala dInvestigacio Quimica ICIQ
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Publication of CA3012554A1 publication Critical patent/CA3012554A1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/04—Methanol
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La présente invention concerne un procédé pour produire du méthanol, ledit procédé consistant à mettre en contact du H2 et du CO2 avec un catalyseur solide, à une température de 200 °C à 300 °C et à une pression de réaction de 150 à 500 bar, ladite pression de réaction étant la somme des pressions partielles de H2 et de CO2, où : le rapport molaire de H2 sur CO2 étant de x : 1,0, où x est compris entre 2,5 et 3,5 ; et le catalyseur comprend : (i) un composant de cuivre qui est Cu, CuO ou CU2O, ou un mélange de deux ou trois de ceux-ci, et (ii) ZnO, où ce catalyseur présente une surface spécifique de cuivre d'au moins 10 m2/g de catalyseur.
CA3012554A 2016-02-16 2017-02-16 Procede de production de methanol Active CA3012554C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16382062.4 2016-02-16
EP16382062.4A EP3208258A1 (fr) 2016-02-16 2016-02-16 Procede pour la preparation de methanol
PCT/EP2017/053535 WO2017140800A1 (fr) 2016-02-16 2017-02-16 Procédé de production de méthanol

Publications (2)

Publication Number Publication Date
CA3012554A1 CA3012554A1 (fr) 2017-08-24
CA3012554C true CA3012554C (fr) 2023-10-31

Family

ID=55443216

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3012554A Active CA3012554C (fr) 2016-02-16 2017-02-16 Procede de production de methanol

Country Status (12)

Country Link
US (1) US11603342B2 (fr)
EP (2) EP3208258A1 (fr)
JP (1) JP6918018B2 (fr)
CN (1) CN108779051B (fr)
CA (1) CA3012554C (fr)
DK (1) DK3416936T3 (fr)
ES (1) ES2877355T3 (fr)
LT (1) LT3416936T (fr)
PL (1) PL3416936T3 (fr)
RU (1) RU2736494C2 (fr)
SA (1) SA518392201B1 (fr)
WO (1) WO2017140800A1 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019111155A1 (fr) 2017-12-04 2019-06-13 Cri, Ehf Système de séparation de gaz dissous par distillation et réextraction
CN110270384B (zh) * 2018-03-13 2021-08-13 中国石油化工股份有限公司 一种甲醇合成催化剂的制备方法
EP3769837A1 (fr) 2019-07-22 2021-01-27 Fundació Institut Català d'Investigació Química (ICIQ) Méthode de co-précipitation et son catalyseur
WO2021149013A1 (fr) 2020-01-24 2021-07-29 Cri Hf Système de réacteur de suivi de charge, installations associées, et procédé de fonctionnement de celui-ci
US12491484B2 (en) 2021-01-15 2025-12-09 CRI, hf Reactor for synthesis of methanol or other products
CN113209975A (zh) * 2021-05-13 2021-08-06 合肥工业大学 一种P/N异质结ZnO@CuO/Cu2O纳米复合材料的制备方法
US12098657B2 (en) 2022-02-01 2024-09-24 CRI, hf Heat integration
JPWO2024004833A1 (fr) * 2022-06-30 2024-01-04
AU2023335011A1 (en) * 2022-09-01 2025-02-27 Ngk Insulators, Ltd. Method for producing liquid fuel and liquid fuel synthesis system
CN118045595A (zh) * 2024-02-23 2024-05-17 北京工业大学 一种二氧化碳加氢制甲醇的反相金属氧化物催化剂

Family Cites Families (39)

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DE462837C (de) 1923-04-06 1928-07-24 I G Farbenindustrie Akt Ges Verfahren zur Herstellung von sauerstoffhaltigen organischen Verbindungen aus Oxyden des Kohlenstoffs durch Reduktion
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US1558559A (en) 1923-09-06 1925-10-27 Basf Ag Production of oxygenated organic compounds
DE441433C (de) 1923-09-27 1927-03-07 I G Farbenindustrie Akt Ges Verfahren zur Gewinnung organischer Verbindungen durch katalytische Gasreaktionen
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Also Published As

Publication number Publication date
RU2736494C2 (ru) 2020-11-17
RU2018132745A (ru) 2020-03-17
CA3012554A1 (fr) 2017-08-24
WO2017140800A1 (fr) 2017-08-24
CN108779051B (zh) 2022-01-04
US20200207689A1 (en) 2020-07-02
ES2877355T3 (es) 2021-11-16
LT3416936T (lt) 2021-07-12
DK3416936T3 (da) 2021-06-28
EP3416936B1 (fr) 2021-03-24
RU2018132745A3 (fr) 2020-04-02
CN108779051A (zh) 2018-11-09
PL3416936T3 (pl) 2021-11-02
JP6918018B2 (ja) 2021-08-11
JP2019506458A (ja) 2019-03-07
SA518392201B1 (ar) 2022-03-01
EP3208258A1 (fr) 2017-08-23
US11603342B2 (en) 2023-03-14
EP3416936A1 (fr) 2018-12-26

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