CA3107128A1 - Activation catalytique de melanges enrichis en isopentane - Google Patents

Activation catalytique de melanges enrichis en isopentane Download PDF

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Publication number
CA3107128A1
CA3107128A1 CA3107128A CA3107128A CA3107128A1 CA 3107128 A1 CA3107128 A1 CA 3107128A1 CA 3107128 A CA3107128 A CA 3107128A CA 3107128 A CA3107128 A CA 3107128A CA 3107128 A1 CA3107128 A1 CA 3107128A1
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CA
Canada
Prior art keywords
fraction
hydrocarbons
effluent
reactor
feed stream
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CA3107128A
Other languages
English (en)
Inventor
Anthony O. BALDRIDGE
Neal D. Mcdaniel
James A. SUTTIL
Soumen KUNDU
Jianhua Yao
Bruce B. Randolph
Maziar Sardashti
Steven E. Lusk
Jr. Robert M. Walston
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips 66 Co
Original Assignee
Phillips 66 Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips 66 Co filed Critical Phillips 66 Co
Priority claimed from US16/364,836 external-priority patent/US10487277B2/en
Priority claimed from US16/364,764 external-priority patent/US10745328B2/en
Priority claimed from US16/364,799 external-priority patent/US10815438B2/en
Priority claimed from US16/364,737 external-priority patent/US10774017B2/en
Publication of CA3107128A1 publication Critical patent/CA3107128A1/fr
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/68—Aromatisation of hydrocarbon oil fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G51/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only
    • C10G51/06—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural parallel stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G59/00—Treatment of naphtha by two or more reforming processes only or by at least one reforming process and at least one process which does not substantially change the boiling range of the naphtha
    • C10G59/06—Treatment of naphtha by two or more reforming processes only or by at least one reforming process and at least one process which does not substantially change the boiling range of the naphtha plural parallel stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1081—Alkanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention concerne d'une manière générale des procédés et des systèmes permettant de produire des carburants liquides pour le transport par conversion d'un flux d'alimentation d'hydrocarbures comprenant à la fois de l'isopentane et du n-pentane, et éventuellement, certains hydrocarbures en C6+. L'isopentane et des hydrocarbures plus petits sont séparés pour former une première fraction tandis que le n-pentane et des composants plus grands de la charge d'alimentation forment une seconde fraction. La première fraction est ensuite activée de manière catalytique dans un premier réacteur contenant un premier catalyseur d'activation, tandis que la seconde fraction est convertie séparément dans un second réacteur contenant un second catalyseur d'activation. Les conditions maintenues dans chaque réacteur sont sélectionnées pour maximiser la conversion de chaque fraction en oléfines et en composés aromatiques, tout en réduisant au minimum la production de paraffines légères en C1-C4. Selon certains modes de réalisation de la présente invention, la première fraction est activée à une température inférieure à celle de la seconde fraction. Certains modes de réalisation permettent de mélanger au moins une partie des effluents provenant des première et seconde zones d'activation et de convertir l'effluent mélangé résultant dans un réacteur d'oligomérisation contenant un catalyseur d'oligomérisation ou un réacteur d'oligomérisation contenant un catalyseur d'alkylation, ce qui permet d'obtenir des rendements améliorés de produits hydrocarbonés de plus grande valeur ajoutée qui sont caractérisés en tant que carburant liquide pour le transport ou composant de mélange de ceux-ci.
CA3107128A 2018-03-27 2019-03-26 Activation catalytique de melanges enrichis en isopentane Pending CA3107128A1 (fr)

Applications Claiming Priority (17)

Application Number Priority Date Filing Date Title
US201862648570P 2018-03-27 2018-03-27
US201862648592P 2018-03-27 2018-03-27
US201862648557P 2018-03-27 2018-03-27
US201862648584P 2018-03-27 2018-03-27
US62/648,584 2018-03-27
US62/648,592 2018-03-27
US62/648,570 2018-03-27
US62/648,557 2018-03-27
PCT/US2019/024095 WO2019191113A1 (fr) 2018-03-27 2019-03-26 Activation catalytique de mélanges enrichis en isopentane
US16/364,799 2019-03-26
US16/364,764 2019-03-26
US16/364,836 US10487277B2 (en) 2018-03-27 2019-03-26 Systems for catalytic activation of isopentane-enriched mixtures
US16/364,836 2019-03-26
US16/364,764 US10745328B2 (en) 2018-03-27 2019-03-26 Catalytic activation and oligomerization of isopentane-enriched mixtures
US16/364,799 US10815438B2 (en) 2018-03-27 2019-03-26 Catalytic activation and alkylation of isopentane-enriched mixtures
US16/364,737 US10774017B2 (en) 2018-03-27 2019-03-26 Catalytic activation of isopentane-enriched mixtures
US16/364,737 2019-03-26

Publications (1)

Publication Number Publication Date
CA3107128A1 true CA3107128A1 (fr) 2019-10-03

Family

ID=68060495

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3107128A Pending CA3107128A1 (fr) 2018-03-27 2019-03-26 Activation catalytique de melanges enrichis en isopentane

Country Status (3)

Country Link
EP (1) EP3774700A4 (fr)
CA (1) CA3107128A1 (fr)
WO (1) WO2019191113A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3864115A4 (fr) * 2018-10-08 2022-06-22 Phillips 66 Company Isomérisation et activation catalytique de mélanges d'hydrocarbures enrichis en pentane

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2350628A (en) * 1940-11-22 1944-06-06 Phillips Petroleum Co Catalytic dehydrogenation process
US2376077A (en) * 1941-03-14 1945-05-15 Phillips Petroleum Co Production of motor fuel
US2855446A (en) * 1956-03-28 1958-10-07 Phillips Petroleum Co Production of olefinic c5 hydrocarbons
NL104749C (fr) * 1956-10-31
US3305476A (en) * 1964-12-14 1967-02-21 Standard Oil Co Balanced-octane gasoline manufacture
DE69913164T2 (de) * 1998-08-17 2004-08-26 Chevron Phillips Chemical Co. Lp, The Woodlands Verfahren zur herstellung von aromatischen kohlenwasserstoffen in parallelreformern
US20130102826A1 (en) * 2011-05-24 2013-04-25 James R. Lattner Systems And Methods For Generating Alpha Olefin Oligomers
US20140171704A1 (en) * 2012-12-13 2014-06-19 Uop Llc Methods and apparatuses for producing ethylene and propylene from naphtha feedstock

Also Published As

Publication number Publication date
EP3774700A1 (fr) 2021-02-17
WO2019191113A1 (fr) 2019-10-03
EP3774700A4 (fr) 2021-12-29

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