CH112327A - Process for the preparation of a tanning agent. - Google Patents
Process for the preparation of a tanning agent.Info
- Publication number
- CH112327A CH112327A CH112327DA CH112327A CH 112327 A CH112327 A CH 112327A CH 112327D A CH112327D A CH 112327DA CH 112327 A CH112327 A CH 112327A
- Authority
- CH
- Switzerland
- Prior art keywords
- preparation
- tanning
- tanning agent
- solution
- parts
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 4
- 238000002360 preparation method Methods 0.000 title claims description 3
- HSJKGGMUJITCBW-UHFFFAOYSA-N 3-hydroxybutanal Chemical compound CC(O)CC=O HSJKGGMUJITCBW-UHFFFAOYSA-N 0.000 claims description 6
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229930003836 cresol Natural products 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000001828 Gelatine Substances 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 159000000014 iron salts Chemical class 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QWIWYBUPJLCBSE-UHFFFAOYSA-N 3-chloro-2-nitrobenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC(Cl)=C1[N+]([O-])=O QWIWYBUPJLCBSE-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
- C14C3/18—Chemical tanning by organic agents using polycondensation products or precursors thereof
- C14C3/20—Chemical tanning by organic agents using polycondensation products or precursors thereof sulfonated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
- C08G16/02—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
- C08G16/0212—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds
- C08G16/0218—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen
- C08G16/0237—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Description
Verfahren zur Darstellung eines Gerbstoffes. Es wurde in weiterer Ausarbeitung des Verfahrens gemäss Hauptpatent gefunden, dass ein Gerbstoff mit wertvollen Eigen schaften entsteht, wenn man Kresol mit Al- dol und Chlornitrobenzolsulfosäure umsetzt. Man kondensiert zweckmässig das Kresol mit Aldol und setzt das entstandene Konden sationsprodukt mit Chlornitrobenzolsulfo- säure um. Es kann von Vorteil sein, die Um setzung unter Druck vorzunehmen.
Der Gerb stoff stellt eine homogene, bräunlich gefärbte, sirupartige Lösung dar. ist leicht löslich in N,#'asser und Alkalien, fällt Gelatine aus ihrer Lösung und gibt charakteristische Fär bungen mit Eisensalzen. <I>Beispiel</I> ?0 Teile Kresol werden mit 40 Teilen Aldo,l in Gegenwart eines Katalysators, z. B. G Teilen konzentrierte Salzsäure, in bekann ter Weise zu einem harzartigen Körper kon densiert. Dieser wird in 90 Teilen Wasser und 60 Teilen Natronlauge (40' B6) warm gelöst.
In die Lösung bringt. man unter gu- tem Rühren 120 Teile chlornitrobenzolsulfo- saures Natrium ein und erwärmt, nachdem alles gelöst ist,,die Masse langsam bis zum schwachen Sieden. Die Siedetemperatur wird so lange eingehalten. bis eine Probe naeli Verdünnen mit Wasser auf Zusatz von Säure leinen Niederschlag mehr ausscheidet. Die erhaltene wässerige Lösung kann zur Trockne eingedampft oder auch als solche nach erforderlicher Verdünnung und Ein stellung auf die erwünschte Acidität zum Gerben verwendet werden.
Man erzielt eine rasche Durchgerbung. Die erhaltenen Leder zeichnen sich durch helle Farbe, vollen Griff und hohe Reissfestigkeit aus. Die Ger bung kann natürlich auch ausgeführt wer den in Gegenwart anderer vegetabilischer oder künstlicher Gerbstoffe.
Process for the preparation of a tanning agent. In a further elaboration of the process according to the main patent, it was found that a tanning agent with valuable properties is created when cresol is reacted with aldol and chloronitrobenzenesulfonic acid. The cresol is expediently condensed with aldol and the condensation product formed is reacted with chloronitrobenzenesulfonic acid. It can be advantageous to carry out the implementation under pressure.
The tanning material is a homogeneous, brownish, syrupy solution. It is easily soluble in N, water and alkalis, gelatine falls out of its solution and gives characteristic colorations with iron salts. <I> Example </I>? 0 parts of cresol are mixed with 40 parts of Aldo, l in the presence of a catalyst, e.g. B. G parts concentrated hydrochloric acid, condensed in a well-known manner to form a resinous body. This is dissolved warm in 90 parts of water and 60 parts of sodium hydroxide solution (40 'B6).
Brings into the solution. 120 parts of sodium chloronitrobenzenesulphate are added while stirring well and, after everything has dissolved, the mass is slowly heated to a low boiling point. The boiling temperature is maintained for so long. until a sample after dilution with water on the addition of acid, no more precipitate separates out. The aqueous solution obtained can be evaporated to dryness or used as such for tanning after the required dilution and adjustment to the desired acidity.
Quick tanning is achieved. The leathers obtained are distinguished by their light color, full handle and high tear strength. The tanning can of course also be carried out in the presence of other vegetable or artificial tanning agents.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE107632X | 1923-02-07 | ||
| CH112327T | 1924-09-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH112327A true CH112327A (en) | 1925-10-16 |
Family
ID=25708015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH112327D CH112327A (en) | 1923-02-07 | 1924-09-15 | Process for the preparation of a tanning agent. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH112327A (en) |
-
1924
- 1924-09-15 CH CH112327D patent/CH112327A/en unknown
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