CH140332A - Process for the preparation of an acidic wool dye. - Google Patents
Process for the preparation of an acidic wool dye.Info
- Publication number
- CH140332A CH140332A CH140332DA CH140332A CH 140332 A CH140332 A CH 140332A CH 140332D A CH140332D A CH 140332DA CH 140332 A CH140332 A CH 140332A
- Authority
- CH
- Switzerland
- Prior art keywords
- preparation
- dye
- amino
- water
- dissolves
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 6
- 230000002378 acidificating effect Effects 0.000 title claims description 4
- 238000002360 preparation method Methods 0.000 title claims description 4
- 210000002268 wool Anatomy 0.000 title claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- QZZSAWGVHXXMID-UHFFFAOYSA-N 1-amino-4-bromo-9,10-dioxoanthracene-2-sulfonic acid Chemical compound C1=CC=C2C(=O)C3=C(Br)C=C(S(O)(=O)=O)C(N)=C3C(=O)C2=C1 QZZSAWGVHXXMID-UHFFFAOYSA-N 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 3
- 240000007817 Olea europaea Species 0.000 claims description 2
- 150000001879 copper Chemical class 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims 2
- 150000001447 alkali salts Chemical class 0.000 claims 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims 1
- 150000004056 anthraquinones Chemical class 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- MUQQKIMNQFFGRV-UHFFFAOYSA-N n-(4-aminophenyl)formamide Chemical compound NC1=CC=C(NC=O)C=C1 MUQQKIMNQFFGRV-UHFFFAOYSA-N 0.000 claims 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims 1
- 235000017557 sodium bicarbonate Nutrition 0.000 claims 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 235000002639 sodium chloride Nutrition 0.000 description 3
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- -1 alkali metal salt Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- CHMBIJAOCISYEW-UHFFFAOYSA-N n-(4-aminophenyl)acetamide Chemical compound CC(=O)NC1=CC=C(N)C=C1 CHMBIJAOCISYEW-UHFFFAOYSA-N 0.000 description 1
- QZESMRVKWNVBCR-UHFFFAOYSA-N n-[4-(aminomethyl)phenyl]formamide Chemical compound NCC1=CC=C(NC=O)C=C1 QZESMRVKWNVBCR-UHFFFAOYSA-N 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Darstellung eines sauren Wollfarbstoffes. Gegenstand der vorliegenden Erfindung ist ein Verfahren zur Darstellung eines sau ren Wollfarbstoffes, den man erhält, wenn man 1-Amino-4-bromanthrachinon - 2-sulfo- säure mit p-Amino-methylformanilid in Ge genwart von Wasser, eines Alkalisalzes der Kohlensäure und eines Kupfersalzes umsetzt.
Der Farbstoff bildet ein schwarzblaues Pulver. Er löst sich leicht in Wasser mit blauer Farbe. In Schwefelsäure löst er sich dunkelolivegrün; unter Zugabe von Formal dehyd jedoch klarer und heller grünw2r- dend.
<I>Beispiel:</I> 20 kg 1-Amino-4-bromanthrachinon-2-sul- fosäure, 22 kg Natriumbicarbonat, 10 kg p- Aminomethylformanilid, 1 kg Kupfersulfat und 750 kg Wasser werden zu einer homo genen Masse verrührt und 10 Stunden lang auf<B>60</B> bis<B>70'</B> erwärmt, wobei die Konden sation stattfindet. Sobald die Kondensation beendet ist, verdünnt man mit 750 kg hei- ssem Wasser, filtriert vom Kupferschlamm ab und salzt den Farbstoff aus der Lösung mit 150 kg Kochsalz aus.
Der Farbstoff wird durch Lösen in hei ssem Wasser und Ausfällen mit Kochsalz ge reinigt.
Process for the preparation of an acidic wool dye. The present invention relates to a process for the preparation of an acidic wool dye which is obtained when 1-amino-4-bromoanthraquinone - 2-sulfonic acid with p-amino-methylformanilide in the presence of water, an alkali metal salt of carbonic acid and of a copper salt.
The dye forms a black-blue powder. It dissolves easily in water with a blue color. In sulfuric acid it dissolves dark olive green; with the addition of formaldehyde, however, it turns clearer and lighter green.
<I> Example: </I> 20 kg of 1-amino-4-bromoanthraquinone-2-sulphonic acid, 22 kg of sodium bicarbonate, 10 kg of p-aminomethylformanilide, 1 kg of copper sulphate and 750 kg of water are stirred into a homogeneous mass and Heated to <B> 60 </B> to <B> 70 '</B> for 10 hours, during which time condensation takes place. As soon as the condensation has ended, it is diluted with 750 kg of hot water, the copper sludge is filtered off and the dye is salted out of the solution with 150 kg of sodium chloride.
The dye is purified by dissolving it in hot water and precipitating it with common salt.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE140332X | 1927-08-03 | ||
| CH132315T | 1928-07-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH140332A true CH140332A (en) | 1930-05-31 |
Family
ID=25711823
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH140332D CH140332A (en) | 1927-08-03 | 1928-07-18 | Process for the preparation of an acidic wool dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH140332A (en) |
-
1928
- 1928-07-18 CH CH140332D patent/CH140332A/en unknown
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