CH145871A - Process for the production of a new dye. - Google Patents
Process for the production of a new dye.Info
- Publication number
- CH145871A CH145871A CH145871DA CH145871A CH 145871 A CH145871 A CH 145871A CH 145871D A CH145871D A CH 145871DA CH 145871 A CH145871 A CH 145871A
- Authority
- CH
- Switzerland
- Prior art keywords
- new dye
- red
- dye
- production
- orange
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 3
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000000975 dye Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229920000742 Cotton Polymers 0.000 claims description 2
- 239000007859 condensation product Substances 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- VLTJLHULNWDGBP-UHFFFAOYSA-N 3-nitro-6-[2-(4-nitrophenyl)ethenyl]cyclohexa-2,4-diene-1,1-disulfonic acid Chemical compound OS(=O)(=O)C1(S(O)(=O)=O)C=C([N+]([O-])=O)C=CC1C=CC1=CC=C([N+]([O-])=O)C=C1 VLTJLHULNWDGBP-UHFFFAOYSA-N 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000243 solution Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- ZAJAQTYSTDTMCU-UHFFFAOYSA-N 3-aminobenzenesulfonic acid Chemical compound NC1=CC=CC(S(O)(=O)=O)=C1 ZAJAQTYSTDTMCU-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-N methanesulfonic acid Substances CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B56/00—Azo dyes containing other chromophoric systems
- C09B56/04—Stilbene-azo dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
<B>Zusatzpatent</B> zum Hauptpatent Nr. 143025. Verfahren zur Herstellung eines neuen Farbstoffes. Es wurde gefunden, dass man einen neuen wertvollen Farbstoff erhält, wenn man 2 Mol 4-Amino-3-methoxyazobenzol-3'-sulfosäuremit einem Mol 4. 4'-Dinitrostilberr-2, 2'-disulfo- säure unter Druck kondensiert und das er haltene Kondensationsprodukt mit einem Oxy dationsmittel behandelt.
Der neue Farbstoff stellt getrocknet ein rotes Pulver dar, welches sich in Wasser und verdünnten Alkalien mit orangeroter, in konzentrierter Schwefelsäure mit grüner Farbe löst und Baumwolle in sehr licht- und alkali- echten rotorangen Tönen anfärbt <I>Beispiel:
</I> Man beschickt einen Rührautoklaven mit 900 Teilen Wasser, 66 Teilen 4-amirro-3-metlr- oxyazobenzol-3'-sulfosaurem Natrium, herge stellt durch Kuppeln von diazotierter Metanil- säure und o-Anisidin-co-methansulfosäure und Verseifung des erhaltenen Azofarbstoffes, 47 Teilen p. p'-dinitrostilben-0.0'disulfosaurem Natrium und 130 Teilen Natronlauge von 36 B6. Man erwärmt auf<B>130</B> und kondensiert 6 Stunden bei dieser Temperatur.
Man lässt er kalten und salzt scharf aus. Der ausgeschiedene Farbstoff wird abgenutscht, mit Salzsole ge waschen und gepresst. Der so gewonnene Presskuchen wird mit 600 Teilen Wasser von 40 angeteigt, alsdann gibt man 25 Teile Natronlauge von 36() B6 und 360 Teile Hypochloritlösung, enthaltend 13 % aktives Chlor, zu, erwärmt auf<B>65'</B> und hält diese Temperatur zirka eine Stunde.
Man lässt er kalten, salzt aus und scheidet den Farbstoff wie üblich ab.
<B> Additional patent </B> to the main patent No. 143025. Process for the production of a new dye. It has been found that a new valuable dye is obtained if 2 moles of 4-amino-3-methoxyazobenzene-3'-sulfonic acid are condensed with one mole of 4,4'-dinitrostilberr-2,2'-disulfonic acid under pressure and that he kept condensation product treated with an oxidizing agent.
The new dye is a red powder when dried, which dissolves in water and diluted alkalis with orange-red, in concentrated sulfuric acid with green color and dyes cotton in very light and alkali-real red-orange tones <I> Example:
A stirred autoclave is charged with 900 parts of water, 66 parts of 4-amirro-3-metlr-oxyazobenzene-3'-sulfonic acid sodium, produced by coupling diazotized metanilic acid and o-anisidine-co-methanesulfonic acid and saponification of the azo dye obtained, 47 parts of p. sodium p'-dinitrostilben-0.0'disulfosaurem and 130 parts of sodium hydroxide solution of 36 B6. The mixture is heated to 130 and condensed for 6 hours at this temperature.
It is left cold and salted out sharply. The precipitated dye is filtered off with suction, washed with brine and pressed. The press cake obtained in this way is made into a paste with 600 parts of 40 water, then 25 parts of sodium hydroxide solution of 36 () B6 and 360 parts of hypochlorite solution containing 13% active chlorine are added, heated to 65 'and held this temperature for about an hour.
It is left cold, salted out and the dye is separated off as usual.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH143025T | 1929-03-16 | ||
| CH145871T | 1929-03-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH145871A true CH145871A (en) | 1931-03-15 |
Family
ID=25714168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH145871D CH145871A (en) | 1929-03-16 | 1929-03-16 | Process for the production of a new dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH145871A (en) |
-
1929
- 1929-03-16 CH CH145871D patent/CH145871A/en unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CH145871A (en) | Process for the production of a new dye. | |
| CH145872A (en) | Process for the production of a new dye. | |
| CH145873A (en) | Process for the production of a new dye. | |
| CH145877A (en) | Process for the production of a new dye. | |
| CH145874A (en) | Process for the production of a new dye. | |
| CH145878A (en) | Process for the production of a new dye. | |
| CH145881A (en) | Process for the production of a new dye. | |
| CH145884A (en) | Process for the production of a new dye. | |
| CH145883A (en) | Process for the production of a new dye. | |
| CH145880A (en) | Process for the production of a new dye. | |
| CH145875A (en) | Process for the production of a new dye. | |
| CH145879A (en) | Process for the production of a new dye. | |
| CH145882A (en) | Process for the production of a new dye. | |
| CH145876A (en) | Process for the production of a new dye. | |
| CH178111A (en) | Process for the production of a new azo dye. | |
| CH145870A (en) | Process for the production of a new dye. | |
| CH185588A (en) | Process for the preparation of an acidic dye of the anthraquinone series. | |
| CH197183A (en) | Process for the production of a vat dye. | |
| CH143025A (en) | Process for the production of a new dye. | |
| CH181721A (en) | Process for the production of a new dye of the anthraquinone series. | |
| CH145869A (en) | Process for the production of a new dye. | |
| CH140330A (en) | Process for the production of a new metal-containing dye. | |
| CH199368A (en) | Process for the preparation of an azo dye. | |
| CH274434A (en) | Process for the preparation of an azo-related dye. | |
| CH302402A (en) | Process for the preparation of a trisazo dye. |