CH149751A - Process for the production of articles with high notch toughness and scaling resistance. - Google Patents
Process for the production of articles with high notch toughness and scaling resistance.Info
- Publication number
- CH149751A CH149751A CH149751DA CH149751A CH 149751 A CH149751 A CH 149751A CH 149751D A CH149751D A CH 149751DA CH 149751 A CH149751 A CH 149751A
- Authority
- CH
- Switzerland
- Prior art keywords
- notch toughness
- production
- steel
- content
- chromium
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 11
- 239000010959 steel Substances 0.000 claims description 11
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 10
- 229910052804 chromium Inorganic materials 0.000 claims description 10
- 239000011651 chromium Substances 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 4
- 229910018125 Al-Si Inorganic materials 0.000 description 2
- 229910018520 Al—Si Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Articles (AREA)
Description
Verfahren zur Herstellung von Gegenständen mit hoher Kerbzähigkeit und Zunderbeständigkeit. Bei dem bekannten. Verfahren zur Her stellung von Gegenständen durch Auswalzen, zum Beispiel zur Herstellung von Röhren aus Stählen, die mit Aluminium und Chrom legiert sind und sich unter anderem durch Zunderbeständigkeit bei hohen Temperatu ren, gute Bearbeitbarkeit und hohe Warm streckgrenze auszeichnen, ist es nötig, die Walztemperaturen unterhalb bestimmter Grenzen zu halten, wenn die Gegenstände hohe Kerbzähigkeit aufweisen sollen,
wenn es sich also beispielsweise um Überhitzer- röhren von Dampfkesseln handelt, bei denen die Kerbzähigkeit gewissen gesetzlichen Vor schriften, zum Beispiel der Bördelprobe, ge nügen muss.
Es wurde gefunden, dass diese Beschrän kung des Temperaturbereiches, innerhalb dessen das Auswalzen erfolgen muss, auf gehoben werden kann, wenn. ein Stahl ver wendet wird, welcher Chrom, Silizium und Aluminium enthält. Diese Wirkung wird er- zielt, ohne dass eine Beeinträchtigung der Zunderbeständigkeit stattfindet.
Es kann zum Beispiel ein Stahl verwen det werden, welcher bei einem Gehalt von etwa<B>5-6%</B> Chrom und<B>0,5-0,9%</B> Alu minium einen Gehalt von etwa 0,8-l,2 Silizium aufweist. Ein solcher Kohlenstoff stahl mit einem Gehalt von 0,05/o Kohlen stoff, 5,5% Chrom,<B>0,92%</B> Silizium und 0,74% Aluminium besitzt bei guter Zunder beständigkeit die folgenden Festigkeitseigen schaften:
EMI0001.0019
bei <SEP> 20 <SEP>
<tb> Bruchgrenze <SEP> 46,1 <SEP> kg/mm'
<tb> Streckgrenze <SEP> 26,2 <SEP> kg/mm'
<tb> Dehnung <SEP> 33,4
<tb> Kontraktion <SEP> 68,7
<tb> Kerbzähigkeit <SEP> 17,7 <SEP> m <SEP> kg/cm' an der kleinen Probe mit 10 X 5 mm Schlag querschnitt.
Während ein bei dem bekannten Verfah ren verwendeter Stahl, der etwa 5 - 6 % Chrom und 1-2 % Aluminium enthält, nach dem Verarbeiten bei 800 eine Kerbzähigkeit von 20,4 m kg/cm\ und nach dem Verarbei ten bei<B>1000</B> eine Kerbzähigkeit von nur 3 m kg/cm' besitzt, weist der Cr-Al-Si-Stahl nach dem Behandeln bei der tiefen Tempe ratur eine Kerbzähigkeit von 17,7 und bei der höheren Temperatur eine Kerbzähigkeit von 16,2 auf.
Beim Cr-Al-Stahl beträgt der Abfall der Kerbzähigkeit demnach etwa 17,4, beim Cr-Al-Si-Stahl tritt dagegen kein wesentlicher Abfall der Kerbzähigkeit ein.
Der ebenfalls Gegenstand der Erfindung bildende, nach dem Verfahren hergestellte Gegenstand enthält somit Zusätze von Alu minium bei gleichzeitiger Anwesenheit von Chrom und Silizium und besteht aus einer ferritisch-perlitischen zunderbeständigen Le gierung, welche ausgezeichnete Pestigkeits- eigenschaften besitzt.
Ausser den erwähnten Legierungsbestand teilen können zur Erzielung einer hohen Warmstreckgrenze Molybdän, Vanadin oder Titan, zur Erzielung einer hohen Verschleiss festigkeit Titan oder Wolfram, zur Erzielung einer besseren Desoxydation Vanadin hinzu gesetzt werden, und zwar in Gehalten bis zu etwa 1 % .
Process for the production of articles with high notch toughness and scaling resistance. With the known. Process for the manufacture of objects by rolling, for example for the production of tubes made of steels that are alloyed with aluminum and chromium and are characterized, among other things, by scaling resistance at high temperatures, good machinability and high hot yield strength, it is necessary to adjust the rolling temperatures to keep below certain limits if the objects are to have high notch toughness,
For example, when it comes to superheater tubes for steam boilers, the notch toughness of which has to meet certain legal regulations, for example the flare test.
It has been found that this limitation of the temperature range within which the rolling must take place can be lifted if. a steel is used which contains chromium, silicon and aluminum. This effect is achieved without the scaling resistance being impaired.
For example, a steel can be used which, with a content of about <B> 5-6% </B> chromium and <B> 0.5-0.9% </B> aluminum, has a content of about 0.8-1.2 silicon. Such a carbon steel with a content of 0.05 / o carbon, 5.5% chromium, <B> 0.92% </B> silicon and 0.74% aluminum has the following strength properties with good scale resistance:
EMI0001.0019
at <SEP> 20 <SEP>
<tb> Breaking limit <SEP> 46.1 <SEP> kg / mm '
<tb> yield point <SEP> 26.2 <SEP> kg / mm '
<tb> elongation <SEP> 33.4
<tb> contraction <SEP> 68.7
<tb> Notch toughness <SEP> 17.7 <SEP> m <SEP> kg / cm 'on the small sample with a 10 X 5 mm impact cross-section.
While a steel used in the known process, which contains about 5-6% chromium and 1-2% aluminum, has a notch toughness of 20.4 m kg / cm \ after processing at 800 and after processing at <B> 1000 </B> has a notch toughness of only 3 m kg / cm ', the Cr-Al-Si steel has a notch toughness of 17.7 after treatment at the low temperature and a notch toughness of 16 at the higher temperature, 2 on.
In the case of Cr-Al steel, the drop in notch toughness is accordingly around 17.4, whereas in Cr-Al-Si steel there is no significant decrease in notch toughness.
The object also forming the subject of the invention, manufactured by the method thus contains additions of aluminum with the simultaneous presence of chromium and silicon and consists of a ferritic-pearlitic scale-resistant alloy, which has excellent pestibility properties.
In addition to the alloy components mentioned, molybdenum, vanadium or titanium can be added to achieve a high hot yield strength, titanium or tungsten to achieve high wear resistance, and vanadium can be added to achieve better deoxidation, in contents of up to about 1%.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DESCH91256D DE589271C (en) | 1929-08-13 | 1929-08-13 | Manufacture of pipes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH149751A true CH149751A (en) | 1931-09-30 |
Family
ID=7444608
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH149751D CH149751A (en) | 1929-08-13 | 1930-08-11 | Process for the production of articles with high notch toughness and scaling resistance. |
Country Status (4)
| Country | Link |
|---|---|
| AT (1) | AT128334B (en) |
| CH (1) | CH149751A (en) |
| DE (1) | DE589271C (en) |
| GB (1) | GB367377A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE941797C (en) * | 1940-05-28 | 1956-04-19 | Phoenix Rheinrohr Ag Vereinigt | Ferritic chromium-aluminum, chromium-silicon and chromium-aluminum-silicon steels for objects that have to endure a high permanent load above 800íÒ |
-
1929
- 1929-08-13 DE DESCH91256D patent/DE589271C/en not_active Expired
-
1930
- 1930-08-08 AT AT128334D patent/AT128334B/en active
- 1930-08-11 CH CH149751D patent/CH149751A/en unknown
- 1930-08-13 GB GB2425130A patent/GB367377A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| AT128334B (en) | 1932-05-25 |
| GB367377A (en) | 1932-02-15 |
| DE589271C (en) | 1935-01-08 |
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