CH158703A - Process for the production of a neutral-soluble complex salt of trivalent antimony. - Google Patents
Process for the production of a neutral-soluble complex salt of trivalent antimony.Info
- Publication number
- CH158703A CH158703A CH158703DA CH158703A CH 158703 A CH158703 A CH 158703A CH 158703D A CH158703D A CH 158703DA CH 158703 A CH158703 A CH 158703A
- Authority
- CH
- Switzerland
- Prior art keywords
- antimony
- neutral
- complex salt
- production
- gluconic acid
- Prior art date
Links
- FAWGZAFXDJGWBB-UHFFFAOYSA-N antimony(3+) Chemical compound [Sb+3] FAWGZAFXDJGWBB-UHFFFAOYSA-N 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 6
- 150000003839 salts Chemical class 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 6
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 6
- 239000000174 gluconic acid Substances 0.000 claims description 6
- 235000012208 gluconic acid Nutrition 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 6
- SZOADBKOANDULT-UHFFFAOYSA-K antimonous acid Chemical compound O[Sb](O)O SZOADBKOANDULT-UHFFFAOYSA-K 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000002244 precipitate Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims 1
- UGYBMTHDCKRQQE-ZBHRUSISSA-N [Na].[Sb].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O Chemical compound [Na].[Sb].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O UGYBMTHDCKRQQE-ZBHRUSISSA-N 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 2
- -1 Hydrogen sulphide antimony sulphide Chemical compound 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- YQDGWZZYGYKDLR-UZVLBLASSA-K sodium stibogluconate Chemical compound O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].O1[C@H]([C@H](O)CO)[C@H](O2)[C@H](C([O-])=O)O[Sb]21([O-])O[Sb]1(O)(O[C@H]2C([O-])=O)O[C@H]([C@H](O)CO)[C@@H]2O1 YQDGWZZYGYKDLR-UZVLBLASSA-K 0.000 description 1
- 229960001567 sodium stibogluconate Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Herstellung eines neutrallöslichen Komplexsalzes des dreiwertigen Antimons. Im Hauptpatent ist ein Verfahren zur Herstellung eines neutrallöslichen Komplex salzes des dreiwertigen Antimons beschrie ben, das dadurch gekennzeichnet ist, dass man eine dreiwertige Antimonverbindung auf Glukonsäure im molekularen Verhältnis un ter Zusatz von soviel Natronlauge einwirken lässt, dass eine neutrale Endreaktion entsteht.
Gegenstand vorliegender Erfindung ist nun ein Verfahren zur Herstellung eines neu trallöslichen Komplexsalzes des dreiwertigen Antimons, welches dadurch gekennzeichnet ist, dass man 1 Mol Antimonhydroxyd auf 2 Mol Glukonsäure unter Zusatz von soviel Natronlauge einwirken. lässt, dass eine neu trale Endreaktion entsteht. Vorteilhaft ver wendet man Antimonhydroxyd, das aus Antimontrichlorid bei Gegenwart von Glu- konsäure gebildet wurde.
Das erhaltene neue Produkt kann als Zwi schenprodukt für technische 7vTecke Verwen dung finden.
<I>Beispiel:</I> 12 gr Antimontrichlorid werden in 30 cm"' Methylalkohol gelöst und 40 cm' 50%ige Glukonsäure hinzugefügt. Man gibt 5 norm. Natronlauge zu bis zur neutralen Reaktion. Das zu Anfang ausgefällte Antimonhydro- xyd löst sich gegen Schluss grösstenteils auf. Man fügt 40 cm' Wasser hinzu und erwärmt etwa i/2 Stunde auf dem Wasserbade. Man filtriert die ganz oder nahezu klare Lösung, kühlt und fällt durch Einrühren in Methyl alkohol das gebildete Komplexsalz aus. wäscht mit Methylalkohol, trocknet im Ex sikkator und dann an der Luft.
Man erhält etwa 20 gr eines farblosen Pulvers, das leicht mit neutraler Reaktion in Wasser gelöst wer- den kann. Die Lösung bleibt auf Zusatz von verdünnter Natronlauge klar. Aus der mit Weinsäure angesäuerten Lösung fällt Schwe felwasserstoff Antimonsulfid aus.
Der Antimongehalt des so erhältlichen antimon-glukonsauren Natriums beträgt etwa 23%.
Process for the production of a neutral-soluble complex salt of trivalent antimony. The main patent describes a process for the preparation of a neutral-soluble complex salt of trivalent antimony, which is characterized in that a trivalent antimony compound is allowed to act on gluconic acid in a molecular ratio with the addition of enough sodium hydroxide solution to produce a neutral final reaction.
The present invention now relates to a process for the preparation of a newly soluble complex salt of trivalent antimony, which is characterized in that 1 mol of antimony hydroxide is acted on 2 mol of gluconic acid with the addition of that much sodium hydroxide solution. lets a neutral final reaction arise. It is advantageous to use antimony hydroxide, which was formed from antimony trichloride in the presence of gluconic acid.
The new product obtained can be used as an intermediate product for technical use.
<I> Example: </I> 12 g of antimony trichloride are dissolved in 30 cm "'methyl alcohol and 40 cm" 50% gluconic acid is added. 5 normal sodium hydroxide solution is added until it reacts neutral. The antimony hydroxide precipitated at the beginning dissolves towards the end. 40 cm of water are added and the mixture is heated for about 1/2 hour on the water bath. The completely or almost clear solution is filtered, cooled and the complex salt formed is precipitated by stirring in methyl alcohol. Washed with methyl alcohol, dries in a desiccator and then in the air.
About 20 g of a colorless powder are obtained which can easily be dissolved in water with a neutral reaction. The solution remains clear on addition of dilute sodium hydroxide solution. Hydrogen sulphide antimony sulphide precipitates from the solution acidified with tartaric acid.
The antimony content of the sodium antimony-gluconate obtainable in this way is about 23%.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE158703X | 1929-12-12 | ||
| CH152604T | 1930-11-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH158703A true CH158703A (en) | 1932-11-30 |
Family
ID=25715995
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH158703D CH158703A (en) | 1929-12-12 | 1930-11-28 | Process for the production of a neutral-soluble complex salt of trivalent antimony. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH158703A (en) |
-
1930
- 1930-11-28 CH CH158703D patent/CH158703A/en unknown
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