CH161479A - Process for the preparation of a new sulfur-containing derivative of a higher olefin. - Google Patents
Process for the preparation of a new sulfur-containing derivative of a higher olefin.Info
- Publication number
- CH161479A CH161479A CH161479DA CH161479A CH 161479 A CH161479 A CH 161479A CH 161479D A CH161479D A CH 161479DA CH 161479 A CH161479 A CH 161479A
- Authority
- CH
- Switzerland
- Prior art keywords
- new
- molecule
- product
- sulfur
- higher olefin
- Prior art date
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 5
- 239000011593 sulfur Substances 0.000 title claims description 5
- 229910052717 sulfur Inorganic materials 0.000 title claims description 5
- 150000001336 alkenes Chemical class 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 4
- 238000002360 preparation method Methods 0.000 title description 3
- 239000000047 product Substances 0.000 claims description 9
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- 230000001476 alcoholic effect Effects 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 125000004434 sulfur atom Chemical group 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 claims description 2
- 239000013067 intermediate product Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000004753 textile Substances 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- ZLCCLBKPLLUIJC-UHFFFAOYSA-L disodium tetrasulfane-1,4-diide Chemical compound [Na+].[Na+].[S-]SS[S-] ZLCCLBKPLLUIJC-UHFFFAOYSA-L 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Herstellung eines neuen schwefelhaltigen Derivates eines höheren Olefins. Vorliegendes Patent bezieht sich auf Hin Verfahren zur Herstellung eines neuen ehwefelhaltigen Derivates eines höheren Olefins, welches dadurch gekennzeichnet ist, dass man ein durch Erhitzen eines Hexachlor- hartparaffins mit.
einer methylalkoholischen Ammoniaklösung erhältliches ungesättig*@es Produkt, das ausser basischen N-haltipen Gruppen noch ungefähr 2 Chloratome im Holekül enthält, mit einer Alkalitetrasulfid- lösung erhitzt.
Das neue Schwefelungsprodukt ist ein braunes<B>01</B> und enthält annähernd drei Schwefelatome im Molekül und die unver ändert gebliebenen N-haltigen basischen Gruppen. Es ist daher leicht in verdünnten Säuren löslich. Es soll textile und pharnna- zeutiselie Verwendung finden. Es stellt fer ner ein geeignetes Zwischenprodukt für die Herstellung von neur@n wertvollen Hilfspro- dukten. zum Beispiel der Färberei, dar.
<I>Beispiel:</I> 40 Teile eines durch Erhitzen eines Hega- chlorhartparaffins mit einer metliyla,lkoho- lischen Ammoniaklösung erhältlichen unge sättigten Produktes, das ausser basischen N- haltigen Gruppen noch ungefähr 2 Chlor atome im Molekül enthält, werden mit einer Lösung von 34 Teilen Natriumtetrasulfid in 180 Teilen Cykloheganol mehrere Stunden im Autoklaven unter Rühren auf 130 bis 140' erhitzt.
Nach dem Erkalten wird das Cyklohexanol abdestilliert, der Rückstand mit Wasser gewaschen, aus Alkohol umgelöst und getrocknet. Man, erhält ein bräunliches <B>Öl,</B> das auf Grund der Analyse annähernd 3 Sehwefelatome im bolekül enthält, die gleichzeitig durch Ersatz der Chloratome des Ausgangsproduktes durch Merkaptogruppen und durch Anlagerung von Schwefel an die im Ausgangsprodukt vorhanden gewesenen Doppelbindungen in das Molekül eingeführt sind.
Process for the preparation of a new sulfur-containing derivative of a higher olefin. The present patent relates to a process for the preparation of a new sulfur-containing derivative of a higher olefin, which is characterized in that one by heating a hexachlorinated paraffin with
An unsaturated product obtainable from a methyl alcoholic ammonia solution, which, in addition to basic N-containing groups, also contains about 2 chlorine atoms in the molecule, is heated with an alkali tetrasulfide solution.
The new sulfurization product is a brown <B> 01 </B> and contains almost three sulfur atoms in the molecule and the unchanged N-containing basic groups. It is therefore easily soluble in dilute acids. It should be used in textiles and pharmaceuticals. It is also a suitable intermediate product for the manufacture of neur @ n valuable auxiliary products. for example dyeing.
<I> Example: </I> 40 parts of an unsaturated product which can be obtained by heating a hegachlorine hard paraffin with a metal, alcoholic ammonia solution and which, in addition to basic N-containing groups, also contains about 2 chlorine atoms in the molecule, are mixed with a A solution of 34 parts of sodium tetrasulfide in 180 parts of cycloheganol was heated to 130 to 140 'in an autoclave with stirring for several hours.
After cooling, the cyclohexanol is distilled off, the residue is washed with water, redissolved from alcohol and dried. The result is a brownish <B> oil </B> which, based on the analysis, contains approximately 3 sulfur atoms in the molecule, which at the same time by replacing the chlorine atoms of the starting product with mercapto groups and by adding sulfur to the double bonds present in the starting product Molecule are introduced.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE161479X | 1930-02-20 | ||
| CH159937T | 1930-10-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH161479A true CH161479A (en) | 1933-04-30 |
Family
ID=25717282
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH161479D CH161479A (en) | 1930-02-20 | 1930-10-17 | Process for the preparation of a new sulfur-containing derivative of a higher olefin. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH161479A (en) |
-
1930
- 1930-10-17 CH CH161479D patent/CH161479A/en unknown
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