CH164811A - Process for the production of a wetting agent for alkaline baths. - Google Patents

Process for the production of a wetting agent for alkaline baths.

Info

Publication number
CH164811A
CH164811A CH164811DA CH164811A CH 164811 A CH164811 A CH 164811A CH 164811D A CH164811D A CH 164811DA CH 164811 A CH164811 A CH 164811A
Authority
CH
Switzerland
Prior art keywords
wetting agent
production
alkaline baths
alkali
alkaline
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH164811A publication Critical patent/CH164811A/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/288—Phosphonic or phosphonous acids or derivatives thereof

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

      Verfahren    zur Herstellung eines Netzmittels für alkalische Bäder.    Es     wurde    gefunden, dass man zu     einem     wertvollen Netzmittel für alkalische Bäder  gelangt, wenn man einen     Terpenalkohol        mit     einem     alkalibeständigen    sulfonierten Fett  körper     vermischt.     



  Als     Terpenalkohole    lassen sich     gesättigte     wie ungesättigte Alkohole der     Terpenreihe,     wie a-,     ss-    und     y-Terpineol,        Terpineol-1,        2-          Menthanol,        Fenchylalkohol,        Borneol    und der  gleichen verwenden. Es ist vorteilhaft, von  natürlich anfallenden Mischungen, die solche       Terpenalkohole    in wesentlichen Mengen ent  halten, auszugehen, beispielsweise von     Pineöl.     



  Als     alkalibeständige    sulfonierte Fett  körper kann man beispielsweise die     Sulfonie-          rungsprodukte    von ungesättigten oder     Oxy-          gruppen    enthaltenden Fettsäuren, deren     Gly-          ceriden    oder     Estern    mit einwertigen Alko  holen verwenden.

   Derartige Produkte können  beispielsweise erhalten werden durch     Sulfo-          nierung    von höheren ungesättigten     Fettsäuren     und deren     Umwandlungsprodukten,    wie         Ricinusöl,    in Gegenwart -von sulfonierten  aromatischen     Karbonsäuren    und -deren An  hydriden, wovon das Verfahren der Schwei  zer     Patentschrift    Nr.     146540    ein -Beispiel  gibt.  



  Zur Herstellung des neuen Netzmittels  kann man das     neutralisierte        Sulfierungsprö-          dukt    des     Fettkörpers    mit dem     Terpenalkohol     vermischen; man kann den letzteren aber  auch vor dem Neutralisieren     hinzufügen    und  die Mischung mit     Alkalihydroxyden    oder       Alkalikarbonaten    neutralisieren.  



  Das gemäss vorliegender Erfindung her  gestellte Netzmittel erhöht die Netzfähigkeit  von alkalischen Flotten in hervorragender  Weise. Es eignet .sich insbesondere als Zusatz  zu     Mercerisierlaugen,    wobei die Oberflächen  spannung der     Alkalihydroxydlösungen    so  stark herabgesetzt wird, dass man Rohware  ohne vorherige Benetzung der -     Mercerisätion          unterwerfen    kann. Man erzielt dabei in kür  zester Zeit eine vollständige     Schrumpfung          -und    ein Maximum an Glanz.

             Beispiel:          Ricinusöl    wird in Gegenwart von     Phthal-          säureanhydrid-ss-sülfosäure    nach einer     Aus-          führungsform-    des Verfahrens der Schweizer       Patentschrift    Nr. 146540 mit Schwefelsäure       sülfonisiert,    neutralisiert und mit soviel     Pine-          öl    versetzt,     däss    das Endprodukt bei einem  Gehalt von     .etwa-   <B>30</B> % Fettsäure etwa 5       Pineöl    enthält:

   Man erhält ein klares<B>01,</B> das  von Wasser leicht- zu einer beim Schütteln       schäumenden    Lösung aufgenommen wird.  



  Beim     -Mercerisieren,    beispielsweise von  trockenem     Rohzwirn,    setzt man der     Merceri-          sierlauge        (23;5%igeNatriumhydrogydlösunb)     5 % des     beschriebenen    Hilfsstoffes zu.     Der.          Mercersationsprözess    verläuft darnach sehr  rasch.

   Die Netzwirkung der     Mercerisierlauge,          kann    noch     etwas    erhöht- werden,     wenn    man    dem sulfonierten Öl     ausser    5     %        Pineöl    2       Amylalkohol    zusetzt.



      Process for the production of a wetting agent for alkaline baths. It has been found that a valuable wetting agent for alkaline baths is obtained if a terpene alcohol is mixed with an alkali-resistant sulfonated fatty substance.



  As terpene alcohols, saturated and unsaturated alcohols of the terpene series, such as α-, β- and γ-terpineol, terpineol-1,2-menthanol, fenchyl alcohol, borneol and the like can be used. It is advantageous to start from naturally occurring mixtures containing such terpene alcohols in substantial amounts, for example from pine oil.



  The sulfonation products of unsaturated fatty acids or fatty acids containing oxy groups, their glycerides or esters with monovalent alcohols can be used as alkali-resistant sulfonated fatty substances.

   Such products can be obtained, for example, by sulfonating higher unsaturated fatty acids and their conversion products, such as castor oil, in the presence of sulfonated aromatic carboxylic acids and their anhydrides, of which the process of Swiss Patent No. 146540 gives an example.



  To produce the new wetting agent, the neutralized sulphonation product of the fatty substance can be mixed with the terpene alcohol; but you can also add the latter before neutralizing and neutralize the mixture with alkali hydroxides or alkali carbonates.



  The wetting agent produced according to the present invention increases the wetting ability of alkaline liquors in an outstanding manner. It is particularly suitable as an additive to mercerising liquors, the surface tension of the alkali hydroxide solutions being reduced so much that raw materials can be subjected to mercerising without prior wetting. Complete shrinkage and maximum gloss are achieved in a very short time.

             Example: Castor oil is sulphonized with sulfuric acid in the presence of phthalic anhydride-ss-sulphonic acid according to an embodiment of the process of Swiss patent specification No. 146540, neutralized and mixed with enough pine oil that the end product with a content of - <B> 30 </B>% fatty acid contains about 5 pine oil:

   A clear 01 is obtained, which is easily absorbed by water to form a solution which foams when shaken.



  When mercerizing, for example dry raw twine, 5% of the auxiliary substance described is added to the mercerizing liquor (23; 5% sodium hydrogen solution). The. The mercury process then proceeds very quickly.

   The wetting effect of the mercerizing liquor can be increased somewhat if amyl alcohol is added to the sulfonated oil in addition to 5% pine oil.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines Netz mittels für alkalische Bäder, dadurch gekenn zeichnet, dass man einen Terpenalkohol mit einem alkalibeständigen sulfonierten Fett körper vermischt. UNTERANSPRUCH: Verfahren gemäss Patentanspruch, da durch gekennzeichnet, dass man als Terpen- alkohol - Pineöl und als alkalibeständigen. sulfonierten Fettkörper das Produkt der Schweizer Patentschrift -Nr. 146540 ver wendet. PATENT CLAIM: Process for the production of a network means for alkaline baths, characterized in that a terpene alcohol is mixed with an alkali-resistant sulfonated fatty body. SUBSTANTIAL CLAIM: Method according to patent claim, characterized in that the terpene alcohol - pine oil and the alkali-resistant. sulfonated fat is the product of the Swiss patent specification no. 146540 used.
CH164811D 1932-11-26 1932-11-26 Process for the production of a wetting agent for alkaline baths. CH164811A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH164811T 1932-11-26

Publications (1)

Publication Number Publication Date
CH164811A true CH164811A (en) 1933-10-31

Family

ID=4417757

Family Applications (2)

Application Number Title Priority Date Filing Date
CH164811D CH164811A (en) 1932-11-26 1932-11-26 Process for the production of a wetting agent for alkaline baths.
CH173382D CH173382A (en) 1932-11-26 1933-12-09 Process for the production of wetting agents for alkaline baths and wetting agent produced therefrom.

Family Applications After (1)

Application Number Title Priority Date Filing Date
CH173382D CH173382A (en) 1932-11-26 1933-12-09 Process for the production of wetting agents for alkaline baths and wetting agent produced therefrom.

Country Status (3)

Country Link
CH (2) CH164811A (en)
FR (2) FR763716A (en)
GB (1) GB442047A (en)

Also Published As

Publication number Publication date
FR763716A (en) 1934-05-04
CH173382A (en) 1934-11-30
FR45649E (en) 1935-11-02
GB442047A (en) 1936-01-31

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