CH165384A - Process for the preparation of an oxidation product of a sulfur-containing derivative of aliphatic higher hydrocarbons. - Google Patents
Process for the preparation of an oxidation product of a sulfur-containing derivative of aliphatic higher hydrocarbons.Info
- Publication number
- CH165384A CH165384A CH165384DA CH165384A CH 165384 A CH165384 A CH 165384A CH 165384D A CH165384D A CH 165384DA CH 165384 A CH165384 A CH 165384A
- Authority
- CH
- Switzerland
- Prior art keywords
- product
- sulfur
- hydroxyl
- oxidation product
- preparation
- Prior art date
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 7
- 229910052717 sulfur Inorganic materials 0.000 title claims description 7
- 239000011593 sulfur Substances 0.000 title claims description 7
- 230000003647 oxidation Effects 0.000 title claims description 6
- 238000007254 oxidation reaction Methods 0.000 title claims description 6
- 125000001931 aliphatic group Chemical group 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 4
- 229930195733 hydrocarbon Natural products 0.000 title description 3
- 150000002430 hydrocarbons Chemical class 0.000 title description 3
- 238000002360 preparation method Methods 0.000 title description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 238000005987 sulfurization reaction Methods 0.000 claims description 2
- 239000004753 textile Substances 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 3
- FHHJDRFHHWUPDG-UHFFFAOYSA-N peroxysulfuric acid Chemical compound OOS(O)(=O)=O FHHJDRFHHWUPDG-UHFFFAOYSA-N 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- -1 alkali metal salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Herstellung eines Oxydationsproduktes eines schwefelhaltigen, Derivates aliphatischer höherer liohlenwasserstoffe. Vorliegendes Patent bezieht sich auf ein Verfahren zur Herstellung eines Oxydations produktes eines schwefelhaltigen Derivate aliphatischer höherer Kohlenwasserstoffe, da durch gekennzeichnet, .dass man das hydroxyl- haltige Schwefelungsprodukt,
das man aits Trichlorhartparaffin durch Erhitzen mit Na tronlauge und Erhitzen des so erhaltenen hydroxylhaltigen Üls mit einer Schwefel- alkalilösun g; gemäss -zcliweiz. Patent Nr. 158140 erhält, mit einem Gemisch von Schwefelsäure und Wasserstoffsuperoxyd oxydiert.
Das neue Oxydationsprodukt ist die dem Ausgangsprodukt entsprechende hydroxyl- haltige Sulfosä.ure, es stellt ein fast farbloses, salbenartiges, in Wasser leicht lösliches Pro dukt dar. Es soll als Hilfsprodukt für ver schiedene textilistische Zwecke Verwendung finden.
<I>Beispiel:</I> 9 Teile eines hydroxylhaltigen Schwe- felungsproduktes, das man aus Trichlorhart- pa.raffin durch Erhitzen mit Natronlauge und Erhitzen des so erhaltenen hydroxylhaltigen Öls mit einer Sehwefelalkalilösung gemäss Schweizer Patent Nr. 158440 erhält, werden mit 25 Teilen Wasser suspendiert und auf <B>1.00</B> erhitzt.
Unter starkem Rühren lässt man bei 95 bis<B>100</B> eine Mischung von 8,5 Teilen konzentrierter Schwefelsäure mit 10 Teilen 33%igem Wasserstoffsuperoxyd (Caro'sehe Säure) langsam einlaufen. Es bildet sich zuerst das weisse in Wasser un lösliche Disulfid, das bei weiterem Zusatz der Caro'schen Säure allmählich dünnflüssig wird und nach einigen Stunden weiteren Erhitzens vollständig in die entsprechende Sulfosäure umgewandelt ist. Das ausgeschiedene Öl wird von der sauren @ösün;
getrennt und eventuell noch getrocknet. 31an erhält: ein fast farbloses, salbenartiges Produkt, das in Wasser leicht löslich ist. Die neue Sulfosäure kann in,die Alkalisalze umgewandelt werden und als solche zur Verwendung gelangen.
Process for the preparation of an oxidation product of a sulfur-containing derivative of aliphatic higher hydrocarbons. The present patent relates to a process for the preparation of an oxidation product of a sulfur-containing derivative of aliphatic higher hydrocarbons, as characterized by, that the hydroxyl-containing sulfurization product,
that one aits trichloride hard paraffin by heating with sodium hydroxide solution and heating the hydroxyl-containing oil thus obtained with an alkali sulfur solution; according to -zcliweiz. Patent No. 158140 received, oxidized with a mixture of sulfuric acid and hydrogen peroxide.
The new oxidation product is the hydroxyl-containing sulfonic acid corresponding to the starting product, it is an almost colorless, ointment-like product that is easily soluble in water. It is to be used as an auxiliary product for various textile purposes.
<I> Example: </I> 9 parts of a hydroxyl-containing sulphurisation product that is obtained from Trichlorhart- pa.raffin by heating with caustic soda and heating the hydroxyl-containing oil obtained in this way with an alkali sulfur solution according to Swiss patent no Share suspended water and heated to <B> 1.00 </B>.
With vigorous stirring, a mixture of 8.5 parts of concentrated sulfuric acid with 10 parts of 33% hydrogen peroxide (Caro's acid) is slowly run in at 95 to 100. The white disulphide, which is insoluble in water, is formed first, which gradually becomes thin with further addition of Caro's acid and is completely converted into the corresponding sulphonic acid after a few hours of further heating. The separated oil is from the acid @ ösün;
separated and possibly still dried. 31an receives: an almost colorless, ointment-like product that is easily soluble in water. The new sulfonic acid can be converted into the alkali metal salts and used as such.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE165384X | 1930-02-25 | ||
| CH162142T | 1930-10-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH165384A true CH165384A (en) | 1933-11-15 |
Family
ID=25717534
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH165384D CH165384A (en) | 1930-02-25 | 1930-10-20 | Process for the preparation of an oxidation product of a sulfur-containing derivative of aliphatic higher hydrocarbons. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH165384A (en) |
-
1930
- 1930-10-20 CH CH165384D patent/CH165384A/en unknown
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