CH185046A - Process for the preparation of an azo dye. - Google Patents
Process for the preparation of an azo dye.Info
- Publication number
- CH185046A CH185046A CH185046DA CH185046A CH 185046 A CH185046 A CH 185046A CH 185046D A CH185046D A CH 185046DA CH 185046 A CH185046 A CH 185046A
- Authority
- CH
- Switzerland
- Prior art keywords
- preparation
- azo dye
- dye
- dinitro
- oxy
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 4
- 239000000987 azo dye Substances 0.000 title description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 150000008049 diazo compounds Chemical class 0.000 claims 1
- KWMDHCLJYMVBNS-UHFFFAOYSA-N 2-bromo-4,6-dinitroaniline Chemical compound NC1=C(Br)C=C([N+]([O-])=O)C=C1[N+]([O-])=O KWMDHCLJYMVBNS-UHFFFAOYSA-N 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- OZIRORHUKSXTLG-UHFFFAOYSA-N naphtho[1,2-h]quinoline Chemical compound C1=CC2=CC=CN=C2C2=C1C1=CC=CC=C1C=C2 OZIRORHUKSXTLG-UHFFFAOYSA-N 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Coloring (AREA)
Description
Verfahren zur Darstellung eines Azofarbstoffes. Nach dem im Hauptpatent beschriebenen Verfahren erhält man einen blauen Acetat- seidenfarbstoff,wenn man dianotiertes 6-Brom- 2.4-dinitro-l-aminobenzol mit 1-Amirionaph- thalin kuppelt.
Wie nun weiter gefunden wurde, erhält man einen Farbstoff mit ganz ähnlichen Eigenschaften, wenn man 6-Brom-2.4-dinitro- 1-aminobenzol dianotiert und mit Tetrabydro- 3-oxy-10-chlor-a-naphthoehinoliii der Formel
EMI0001.0012
kuppelt.
Beispiel 26,2 Teile 6-Brom-2.4-dinitro-l-amino- benzol werden in der üblichen Weise diazo- tiert und die mineralsäurehaltige Diazolösung wird in eine kalte Lösung von 25 Teilen Tetrahydro- 3-oxy-10-chlor-a-naphthochinolin einlaufen gelassen. Man stumpft mit soviel Natriumacetat ab, bis die Kupplung beendet ist. Der erhaltene Farbstoff färbt Acetatseide klar grünblau.
Process for the preparation of an azo dye. According to the process described in the main patent, a blue acetate silk dye is obtained when dianotated 6-bromo-2,4-dinitro-1-aminobenzene is coupled with 1-amirionaphthalene.
As has now been found, a dye with very similar properties is obtained if 6-bromo-2,4-dinitro-1-aminobenzene is dianotized and tetrabydro-3-oxy-10-chloro-a-naphthoehinoliii of the formula
EMI0001.0012
clutch.
Example 26.2 parts of 6-bromo-2,4-dinitro-1-aminobenzene are diazo- in the usual way and the mineral acid-containing diazo solution is added to a cold solution of 25 parts of tetrahydro-3-oxy-10-chloro-a- run in naphthoquinoline. It is blunted with enough sodium acetate until the coupling has ended. The dye obtained gives acetate silk a clear green-blue color.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH168144T | 1933-04-27 | ||
| DE185046X | 1934-08-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH185046A true CH185046A (en) | 1936-06-30 |
Family
ID=25718536
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH185046D CH185046A (en) | 1933-04-27 | 1934-11-21 | Process for the preparation of an azo dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH185046A (en) |
-
1934
- 1934-11-21 CH CH185046D patent/CH185046A/en unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CH185048A (en) | Process for the preparation of an azo dye. | |
| CH185044A (en) | Process for the preparation of an azo dye. | |
| CH185049A (en) | Process for the preparation of an azo dye. | |
| CH185045A (en) | Process for the preparation of an azo dye. | |
| CH185043A (en) | Process for the preparation of an azo dye. | |
| CH185042A (en) | Process for the preparation of an azo dye. | |
| CH183113A (en) | Process for the preparation of an azo dye. | |
| CH185038A (en) | Process for the preparation of an azo dye. | |
| CH185037A (en) | Process for the preparation of an azo dye. | |
| CH185041A (en) | Process for the preparation of an azo dye. | |
| CH185047A (en) | Process for the preparation of an azo dye. | |
| CH185039A (en) | Process for the preparation of an azo dye. | |
| CH185040A (en) | Process for the preparation of an azo dye. | |
| CH188780A (en) | Process for the preparation of an insoluble azo dye. | |
| CH187924A (en) | Process for the preparation of an insoluble azo dye. | |
| CH187921A (en) | Process for the preparation of an insoluble azo dye. | |
| CH188775A (en) | Process for the preparation of an insoluble azo dye. | |
| CH187923A (en) | Process for the preparation of an insoluble azo dye. | |
| CH188778A (en) | Process for the preparation of an insoluble azo dye. | |
| CH188774A (en) | Process for the preparation of an insoluble azo dye. | |
| CH188781A (en) | Process for the preparation of an insoluble azo dye. | |
| CH177822A (en) | Process for the preparation of an o-oxyazo dye. | |
| CH188773A (en) | Process for the preparation of an insoluble azo dye. | |
| CH177823A (en) | Process for the preparation of an o-oxyazo dye. | |
| CH170926A (en) | Process for the preparation of an azo dye. |