CH206906A - Process for the preparation of a quaternary amino fatty acid amide derivative. - Google Patents

Process for the preparation of a quaternary amino fatty acid amide derivative.

Info

Publication number
CH206906A
CH206906A CH206906DA CH206906A CH 206906 A CH206906 A CH 206906A CH 206906D A CH206906D A CH 206906DA CH 206906 A CH206906 A CH 206906A
Authority
CH
Switzerland
Prior art keywords
fatty acid
acid amide
amide derivative
quaternary amino
preparation
Prior art date
Application number
Other languages
German (de)
Inventor
A-G J R Geigy
Original Assignee
Geigy Ag J R
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Geigy Ag J R filed Critical Geigy Ag J R
Publication of CH206906A publication Critical patent/CH206906A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

  Verfahren zur Herstellung eines     quaternären        Aminofettsäureamidderivates.       Gegenstand des vorliegenden     Patentes        ist     ein Verfahren zur     Herstellung    eines     quater-          nären        Aminofettsäureamidderivates,dadurch     gekennzeichnet, dass man     Di-(chloraceto)-          4,4'-,diaminobenzoph-enon,darstellbar        aus        4,4'-          Diaminobenzophenon    und     CMoraeetylchlorid,

       mit     Dimethylamin        umsetzt    und das erhal  tene     Di-(dimethylaminoaceto)-4,4'-diamino-          benzophenon    mit     Benzylchlorid    in die bis  quaternäre Verbindung überführt.  



  Die neue Verbindung, eine bräunliche, in  Wasser lösliche Masse, eignet sich zum  Schützen von Pelzwerk, Federn,     Haaren,     Leder,     fibrösen    Materialien und dergleichen  vor     Mottenraupen    und andern     Frassschäd-          lingen    und als     fungicides        und        bactericides          Mittel.     



  <I>Beispiel:</I>  Zu 39 Teilen wässriger     Dimethylamin-          lösung    von 33 % werden 200     Vol.-Teile    Alko  hol und 22 Teile     Di-(chloraceto)-4,4'-,diamino-          benzophenon,    hergestellt aus     4,4'-Diamino-          benzophenon    und     Cliloracetylchlorid,

      zu-    gesetzt     und.    die     Mischung        während    15     Stun-          den    bei 40     bis   <B>50'</B>     .gerührt.    Hierauf werden  der Alkohol und das     überschüssige        Dimethyl-          amin    mit Wasserdampf     abgeblasen.    Das zu  rückbleibende 01 wird mit Chloroform auf  genommen, getrocknet und das     Lösungs-          mittel        abdestilliert.    Ausbeute: 24     Teile.     



  12     Teile    des so erhaltenen     Di-(dimethyl-          aminoa@ceto)-4,4'-diaminobenzophenons    wer  den mit 8 Teilen     Benzylchlorid    während  2 Stunden auf     70-80'C    erwärmt. Beim  Abkühlen wird die erhaltene dicke     Paste          glashart.    Die neue     bisquaternäre        Verbindung     bildet eine     bräunliche,    in     Wasser    lösliche  Masse.     Ausbeute:    18 Teile.



  Process for the preparation of a quaternary amino fatty acid amide derivative. The subject of the present patent is a process for the preparation of a quaternary amino fatty acid amide derivative, characterized in that di- (chloraceto) 4,4 '-, diaminobenzoph-enone, which can be prepared from 4,4'-diaminobenzophenone and CMoraeetyl chloride,

       reacts with dimethylamine and the obtained di- (dimethylaminoaceto) -4,4'-diamino-benzophenone is converted into the quaternary compound with benzyl chloride.



  The new compound, a brownish, water-soluble mass, is suitable for protecting fur, feathers, hair, leather, fibrous materials and the like from caterpillars and other feeding pests and as a fungicidal and bactericidal agent.



  <I> Example: </I> To 39 parts of aqueous dimethylamine solution of 33%, 200 parts by volume of alcohol and 22 parts of di- (chloraceto) -4,4 '-, diamino-benzophenone, prepared from 4, 4'-diamino benzophenone and chloroacetyl chloride,

      added and. the mixture was stirred for 15 hours at 40 to 50 '. The alcohol and the excess dimethylamine are then blown off with steam. The oil that remains is taken up in chloroform, dried and the solvent is distilled off. Yield: 24 parts.



  12 parts of the di- (dimethylaminoa @ ceto) -4,4'-diaminobenzophenone obtained in this way are heated to 70-80 ° C. with 8 parts of benzyl chloride for 2 hours. The thick paste obtained becomes as hard as glass on cooling. The new bisquaternary compound forms a brownish mass that is soluble in water. Yield: 18 parts.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines quater- nären Aminofettsäureamidderivates, dadurch gekennzeichnet, dass man Di-(chloraeeto)- 4,4'-.diaminobenzophenon mit Dimethylamin umsetzt und das erhaltene Di-(dimethyl- aminoaceto) - 4,4' - , PATENT CLAIM: Process for the production of a quaternary amino fatty acid amide derivative, characterized in that di- (chloraeeto) - 4,4 '-. Diaminobenzophenone is reacted with dimethylamine and the resulting di- (dimethylaminoaceto) - 4,4' -, diaminobenzophenon mit Benzylchlorid in die bisquaternäre Verbin dung überführt. Die neue Verbindung, eine bräunliche, in Wasser lösliche Masse, eignet sich zum Schützen von Pelzwerk, Federn, Haaren, Leder, fibrösen Materialien und dergleichen vor Mottenraupen und andern Frassschäd- lingen und als fungieides und bactericides Mittel. diaminobenzophenone converted into the bisquaternary connec tion with benzyl chloride. The new compound, a brownish, water-soluble mass, is suitable for protecting fur, feathers, hair, leather, fibrous materials and the like from moth worms and other feeding pests and as a fungicidal and bactericidal agent.
CH206906D 1935-12-23 1938-02-04 Process for the preparation of a quaternary amino fatty acid amide derivative. CH206906A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE198052X 1935-12-23
DE206906X 1937-02-05

Publications (1)

Publication Number Publication Date
CH206906A true CH206906A (en) 1939-08-31

Family

ID=25758414

Family Applications (1)

Application Number Title Priority Date Filing Date
CH206906D CH206906A (en) 1935-12-23 1938-02-04 Process for the preparation of a quaternary amino fatty acid amide derivative.

Country Status (1)

Country Link
CH (1) CH206906A (en)

Similar Documents

Publication Publication Date Title
CH206906A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
CH206898A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
CH206907A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
CH206911A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
CH206914A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
CH206905A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
CH206912A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
CH206900A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
AT134626B (en) Process for the preparation of amino alcohols.
CH206897A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
DE515544C (en) Process for the preparation of reduction products of N-acetylated indoxyls
CH206910A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
CH206899A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
DE865143C (en) Process for the preparation of benzene sulfonamides of the dioxalane series
AT336592B (en) PROCESS FOR PREPARING NEW 3- (4- BIPHENYLYL) BUTTER ACIDS, THEIR ESTERS, AMIDES AND SALT
DE537188C (en) Process for the preparation of aminoketo alcohols
CH206909A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
CH206903A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
CH206913A (en) Process for the preparation of a quaternary amino fatty acid amide derivative.
CH212562A (en) Process for the preparation of a quaternary aminoacetic acid amide derivative.
CH159045A (en) Process for the preparation of 1- (di- (a-menaphtyl)) - aminoethan-2-ol.
CH228211A (en) Process for the production of a water-soluble, higher molecular weight, α-substituted benzylamine derivative.
CH212563A (en) Process for the preparation of a quaternary aminoacetic acid amide derivative.
CH131250A (en) Process for the preparation of m-Oxy-N-methyldiethylaminoethylaniline.
CH447146A (en) Process for the production of adamantane derivatives