CH208539A - Process for the preparation of a disazo dye. - Google Patents
Process for the preparation of a disazo dye.Info
- Publication number
- CH208539A CH208539A CH208539DA CH208539A CH 208539 A CH208539 A CH 208539A CH 208539D A CH208539D A CH 208539DA CH 208539 A CH208539 A CH 208539A
- Authority
- CH
- Switzerland
- Prior art keywords
- disazo dye
- preparation
- alkaline solution
- tetrazotized
- disazo
- Prior art date
Links
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 title claims description 7
- 238000000034 method Methods 0.000 title claims description 4
- 239000012670 alkaline solution Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 3
- 239000010985 leather Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims 2
- 239000000975 dye Substances 0.000 description 6
- YGOFNNAZFZYNIX-UHFFFAOYSA-N 3-N-phenylbenzene-1,2,3-triamine Chemical class NC=1C(=C(C=CC1)NC1=CC=CC=C1)N YGOFNNAZFZYNIX-UHFFFAOYSA-N 0.000 description 1
- QZHXKQKKEBXYRG-UHFFFAOYSA-N 4-n-(4-aminophenyl)benzene-1,4-diamine Chemical compound C1=CC(N)=CC=C1NC1=CC=C(N)C=C1 QZHXKQKKEBXYRG-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- -1 oxy compound Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
- C09B35/02—Disazo dyes
- C09B35/039—Disazo dyes characterised by the tetrazo component
- C09B35/24—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of a diaryl amine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
Verfahren zur Herstellung eines Disazofarbstoffes. Wie gefunden wurde, erhält man wert volle grünstichig blaue bis schwarze Disazo- farbstoffe, wenn man tetrazotierte Diamino- diphenylamine und ihre Derivate in alkali scher Lösung mit einem Mol einer in der Aminogruppe durch Alkyl substitnierten 1-Amino-8-oxynaplithalinmono- oder -disul- fonsäure und einem
Mol einer kupplungs fähigen Oxyverbindung der Benzolreihe, z. B. <B>1 -</B> 3-Dioxybenzol oder 3-Diplienylamin, ver einigt. Die Farbstoffe sind in erster Linie zum Färben von Leder bestimmt.
Gegenstand des vorliegenden Patentes ist ein Verfahren zur Herstellung eines Disazo- farbstoffes, welches dadurch gekennzeichnet ist, dass man tetrazotiertes 4. 4-Diamino- diphenylamin in alkalischer Lösung mit<B>je</B> <B>1</B> Mol 1-Äthylamino-8-oxynaphtlialin-3 -6- clisulionsäure und 3-Oxydiphenylamin verei nigt.
<I>Beispiel:</I> <B>19,9</B> Teile 4.4'-Diaminodiphenylamin werden tetrazotiert und mit<B>31,9</B> Teilen einer alkalischen Lösung von 1-Athylamino-8-exy- naphthalin-3 -6-clisulfonsäure vereinigt. So bald die Bildung des Monoazofarbstoffes beendigt ist, fügt man eine alkalische Lösung von<B>18,5</B> Teilen 3-Oxydiphenylamin zu.
Der fertige, Disazo-farbstoff wird ausgesalzen und gibt auf Leder dunkelblaue bis schwarze, etwas grünstieIiige'Töne von guten Ec'hilieits- eigenschaften.
Process for the preparation of a disazo dye. As has been found, valuable greenish blue to black disazo dyes are obtained if tetrazotized diamino diphenylamines and their derivatives are mixed in alkaline solution with one mole of a 1-amino-8-oxynaplithalin mono- or disulene substituted by alkyl in the amino group - fonsäure and one
Moles of a coupling capable oxy compound of the benzene series, z. B. 1 - 3-dioxybenzene or 3-diplienylamine, united. The dyes are primarily intended for dyeing leather.
The subject of the present patent is a process for the production of a disazo dye, which is characterized in that tetrazotized 4,4-diaminodiphenylamine is added in alkaline solution with <B> each </B> <B> 1 </B> mol 1-Ethylamino-8-oxynaphthalene-3-6-clisulionic acid and 3-oxydiphenylamine combined.
<I> Example: </I> <B> 19.9 </B> parts of 4,4'-diaminodiphenylamine are tetrazotized and mixed with <B> 31.9 </B> parts of an alkaline solution of 1-ethylamino-8-exy - Naphthalene-3-6-clisulfonic acid combined. As soon as the formation of the monoazo dye has ended, an alkaline solution of <B> 18.5 </B> parts of 3-oxydiphenylamine is added.
The finished disazo dye is salted out and gives leather dark blue to black, somewhat greenish tones with good ecologic properties.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE208539X | 1937-10-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH208539A true CH208539A (en) | 1940-02-15 |
Family
ID=5794293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH208539D CH208539A (en) | 1937-10-07 | 1938-08-13 | Process for the preparation of a disazo dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH208539A (en) |
-
1938
- 1938-08-13 CH CH208539D patent/CH208539A/en unknown
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