CH257579A - Process for the preparation of a new mercury compound. - Google Patents
Process for the preparation of a new mercury compound.Info
- Publication number
- CH257579A CH257579A CH257579DA CH257579A CH 257579 A CH257579 A CH 257579A CH 257579D A CH257579D A CH 257579DA CH 257579 A CH257579 A CH 257579A
- Authority
- CH
- Switzerland
- Prior art keywords
- preparation
- new
- mercury compound
- ethylmercurithio
- new mercury
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 3
- 229940100892 mercury compound Drugs 0.000 title claims 2
- 150000002731 mercury compounds Chemical class 0.000 title claims 2
- 238000002360 preparation method Methods 0.000 title description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000000645 desinfectant Substances 0.000 claims description 2
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229940100890 silver compound Drugs 0.000 description 2
- 150000003379 silver compounds Chemical class 0.000 description 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
- C07F3/12—Aromatic substances containing mercury
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Herstellung einer neuen Queeksilberverbindung. Ge-;ensta.nd des vorliegenden Patentes ist t in V e rfaliren zur Herstellung einer neuen Qiieelc,ilberverbindung, das dadurch gekenn- z@@icliiiet ist, da.ss man p-Äthylmercurithio-di- ni"ytliy'anilin mit Dimethylsulfa.t umsetzt.
Das so erhaltene p-Äthylmercurithio-phe- it@-l-trimethyl-ammoniummethosulfat ist in Wasser gut löslich und schmilzt bei 140 bis 1t1 Die neue Verbindung soll als" Des.infek- tionsmittel Verwendung finden.
<I>Beispiel:</I> 6,2? Teile Äthylquecluilberbromid werden in Alkohol suspendiert und mit Natronlauge umge,etzt. llan filtriert und versetzt die Lösung mit einer alkoholischen Lösung von ?,6 Teilen p-lllercapto-dimethylanilin. Es fällt: das p-Äthylmercurithio-dimethylanilin ii;teh kurzem Wärmen kristallisiert aus.
Die -Base schmilzt nach (lern Umkrista.lliseren au, Alkohol bei 80 C und ist in Wasser un- löslich. 3,8 Teile des p-Äthylmercurithio- dimethylanilins werden in wenig Alkohol gelöst und mit 1 Volumteil Dimethylsulfat versetzt.
Man destilliert den Alkohol auf dem Wasserbade ab und erhält so das gut in Wasser lösliche p-Äthylmercurithio-phenyl- trimethyl-ammonium-methosulfat. Es schmilzt nach dem Umkristallisieren aus Methylalko- hol-Essigester bei 140-141 C.
Process for the preparation of a new Queek Silver Compound. The subject of the present patent is in cases for the production of a new high-grade silver compound which is characterized in that p-ethylmercurithio-di-nylethylaniline with dimethyl sulfa is used .t implements.
The p-ethylmercurithio-phe- it @ -l-trimethylammonium methosulfate obtained in this way is readily soluble in water and melts at 140 to 1t1. The new compound is said to be used as a disinfectant.
<I> Example: </I> 6.2? Parts of ethylquecluilber bromide are suspended in alcohol and reacted with sodium hydroxide solution. llan filtered and the solution mixed with an alcoholic solution of?, 6 parts p-lllercapto-dimethylaniline. It precipitates: the p-ethylmercurithio-dimethylaniline ii; after brief warming crystallizes out.
The base melts afterwards (learned to recrystallize it, alcohol at 80 ° C and is insoluble in water. 3.8 parts of p-ethylmercurithio-dimethylaniline are dissolved in a little alcohol and 1 part by volume of dimethyl sulfate is added.
The alcohol is distilled off on the water bath and p-ethylmercurithio-phenyl-trimethyl-ammonium methosulfate, which is readily soluble in water, is obtained. After recrystallization from methyl alcohol / ethyl acetate, it melts at 140-141 C.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH257579T | 1944-08-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH257579A true CH257579A (en) | 1948-10-15 |
Family
ID=4472246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH257579D CH257579A (en) | 1944-08-04 | 1944-08-04 | Process for the preparation of a new mercury compound. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH257579A (en) |
-
1944
- 1944-08-04 CH CH257579D patent/CH257579A/en unknown
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