CH278403A

CH278403A - Process for giving the hair suppleness and a shiny appearance.

Info

Publication number: CH278403A
Authority: CH
Inventors: Schaedeli Theodore
Original assignee: Schaedeli Theodore
Priority date: 1939-05-20
Filing date: 1947-06-20
Publication date: 1951-10-15

Description

  

  



  Procédé pour conférer aux cheveux souplesse et aspect brillant.



   L'invention a pour objet un procédé pour conférer aux cheveux souplesse et aspect brillant. Ce procédé permet en même temps de protéger les cheveux contre les effets nocifs de certains produits utilisés dans les opérations usuelles, telles que permanente, coloration ou décoloration, etc.



   Il est caractérisé en ce que l'on imprègne les cheveux avec une solution   d'un    produit comprenant au moins un composé de l'azote   pentavalent    de formule générale :
 An-X-R dans laquelle An désigne un anion,   R    désigne un radical organique comportant au moins   12       9    atomes de carbone, et   X    désigne un radical contenant un atome d'azote   pentavalent.      



   Les composés du type mentionné ci-dessus    comprennent notamment des dérivés des   ami-    nes primaires, secondaires, tertiaires, des diamines, des bases   pyridique    et   quinoléique    et de leurs produits d'hydrogénation, des urées, de la morpholine,   etc.,    et en particulier leurs chlorures, sulfates,   iodures.      bromures, acéta-    tes, lactates, etc.



   Parmi ces composés, on peut citer plus spécialement : l'iodure de   tribenzyloléylammo-    nium, le sulfate de méthyle et de   triéthyloeta-       décylammonium, l'acétate de pentadécyldi-      hydro-imidazole,    le bromure de laurométhoxy  octadécyl-pipéridinium,    le sulfate de   B-octa-       décylamino-phényl-éthyldimétliyl-ammonium.    le chlorure de   ss-hydroxyéthyl-oetadéeylmor-      pholium.   



   Ces substances peuvent être utilisées en solution aqueuse ou alcoolique ou dans   d'au-    tres solvants avec ou sans addition d'autres produits connus.



   Les préparations peuvent contenir une ou plusieurs des substances citées ci-dessus.



   L'emploi de ces préparations confère donc aux cheveux brillant et souplesse tout en   assu-    rant leur protection   contre les-effets nocifs    des produits qui sont nécessaires pour certains traitements.



   On va maintenant exposer quelques   exem-    ples d'exécution du présent procédé.



   Exemple 1 :
 On traite les cheveux avec une solution aqueuse à 13    /a    de sulfate de   jg-octadécyl-      amino-phényl-éthyl-diméthyl-ammonium    ; on   obtient ainsi un apprêt    brillant et souple. Si on le désire, on peut ajouter à cette solution un sel soluble du type   RSOgH ou ROSOgH,    où R est un radical aliphatique saturé ou non, comprenant une chaîne ayant au moins 12 atomes de carbone.



   Exemple 2:
 On imprègne les cheveux avec une solution   ammoniaeale diluée à 18  /o    de chlorure de   -hydroxyéthyl-méthyl.-éthyl-hexadécyl-    ammonium, de formule :
EMI1.1     
 
 afin de conférer aux cheveux souplesse et aspect brillant. Le cas échéant, on peut combiner ce traitement avee les   traitements con-    nus pour décolorer les cheveux. Dans ce cas, on mélange la solution susmentionnée à quatre fois son volume de peroxyde d'hydrogène à 12 et 3 %d'un sel soluble du type   RSOgII    ou   ROS03II,    où   R    est un radical aliphatique saturé ou non comprenant une chaîne ayant au moins 12 atomes de carbone.



      E. @emple 3:   
 On emploie une solution alcoolique diluée à   40 /o eontenant lO /o d'iodure d'oetadéeyl-      a-picolinium pour imprégner    les cheveux qui seront ensuite souples et présenteront le brillant désiré. Si tel est désiré, on peut ajouter à cette   solut. ion aleoolique 1  /o d'éther mono-    éthylique du   diéthylèneglycol, la présence    de cet éther assurant alors simultanément le dégraissage.



   Exemple 4:
 On emploie une solution aqueuse à   12 O/o    de   bromure d'hydroxyéthyl-heptadéeyl-mor-    pholium pour donner souplesse et brillant aux cheveux. A cette solution, on peut ajouter   6"/o de myristate d'oetadecényle êmulsionné    ; dans ce cas, on obtiendra un   nettoyage simul-    tané des cheveux.




  



  Process for giving the hair suppleness and a shiny appearance.



   The subject of the invention is a process for imparting suppleness and a shiny appearance to the hair. At the same time, this process makes it possible to protect the hair against the harmful effects of certain products used in usual operations, such as perming, coloring or bleaching, etc.



   It is characterized in that the hair is impregnated with a solution of a product comprising at least one compound of pentavalent nitrogen of general formula:
 An-X-R in which An denotes an anion, R denotes an organic radical comprising at least 12 9 carbon atoms, and X denotes a radical containing a pentavalent nitrogen atom.



   The compounds of the type mentioned above include in particular derivatives of primary, secondary, tertiary amines, diamines, pyridic and quinoleic bases and their hydrogenation products, ureas, morpholine, etc., and in particular in particular their chlorides, sulphates, iodides. bromides, acetates, lactates, etc.



   Among these compounds, there may be mentioned more especially: tribenzyloleylammonium iodide, methyl and triethyloetadecylammonium sulphate, pentadecyldihydroimidazole acetate, lauromethoxy octadecyl-piperidinium bromide, B sulphate -octadecylamino-phenyl-ethyldimethyl-ammonium. ss-hydroxyethyl-oetadéeylmorpholium chloride.



   These substances can be used in aqueous or alcoholic solution or in other solvents with or without the addition of other known products.



   The preparations may contain one or more of the substances mentioned above.



   The use of these preparations therefore gives the hair shine and suppleness while ensuring their protection against the harmful effects of the products which are necessary for certain treatments.



   Some examples of execution of the present process will now be described.



   Example 1:
 The hair is treated with a 13 µl aqueous solution of 8-octadecylamino-phenyl-ethyl-dimethyl-ammonium sulfate; a shiny and flexible finish is thus obtained. If desired, a soluble salt of the RSOgH or ROSOgH type, where R is a saturated or unsaturated aliphatic radical, comprising a chain having at least 12 carbon atoms, can be added to this solution.



   Example 2:
 The hair is impregnated with an ammonia solution diluted to 18% of -hydroxyethyl-methyl.-ethyl-hexadecylammonium chloride, of formula:
EMI1.1
 
 in order to give the hair suppleness and a shiny appearance. Where appropriate, this treatment can be combined with the known treatments for bleaching the hair. In this case, the above-mentioned solution is mixed with four times its volume of 12 and 3% hydrogen peroxide of a soluble salt of the RSOgII or ROS03II type, where R is a saturated or unsaturated aliphatic radical comprising a chain having at least 12 carbon atoms.



      E. @ample 3:
 A 40% dilute alcoholic solution containing 10% oetadéeyl-a-picolinium iodide is used to impregnate the hair which will then be supple and present the desired shine. If desired, one can add to this solution. aleoolic ion 1 / o of monoethyl ether of diethylene glycol, the presence of this ether then simultaneously ensuring the degreasing.



   Example 4:
 A 12 O / o aqueous solution of hydroxyethyl-heptadéeyl-morpholium bromide is used to impart suppleness and shine to the hair. To this solution, 6% of emulsified oetadecenyl myristate can be added, in which case a simultaneous cleansing of the hair will be obtained.

Claims

CLAIM: Process for giving the hair flexibility and shiny appearance, characterized in that the latter are impregnated with a solution of a product comprising at least one pentavalent nitrogen compound of general formula: An-XR in which An denotes a anion, R denotes an organic radical comprising at least 12 carbon atoms, and X denotes a radical containing a pentavalent nitrogen atom.

SUB-CLAIMS: 1. A method according to claim, characterized in that said compound is tribenzylolÚyl-ammonium iodide.

2. Method according to claim, characterized in that said compound is sulphate of melln-je and triÚthyloctadÚcylaminoninm.

3. ProcÚdÚ according to claim, characterized in that said compound is pentadecyldihydroimidazole acetate.

4. A method according to claim, charac- tÚrisÚ in that said compound is lauromethoxyoctadecylpiperidinium bromide.

5. The method of claim, characterized in that said compound is -octadecylaminophenyl-ethyldimethyl-ammonium sulfate. fi. A process according to claim, characterized in that said compound is? -HydroxyÚthyl-octadÚcylmorpholium chloride.

7. Process. according to claim, characterized in that one uses a solution obtained by mixing a 13 / o aqueous solution of? -octadÚcylamino-phÚnyl ethyl-dimethyl-ammonium sulfate with 3 O / o of a soluble salt of R-SO3II type, R representing an alkyl group whose chain contains at least 12 carbon atoms.

8. Process according to claim, in which a decoloration of the hair is carried out at the same time, characterized in that a solution obtained by mixing a dilute ammoniacal solution of Ó 18 / e of -hydroxyethyl-methyl chloride is used. -ethyl- hexadecyl-ammonium with four times its volume of hydroaene peroxide at 12 and 3 / o of a soluble salt of the type R-SOgI-1, R representing an alkyl group whose chain comprises at least 12 carbon atoms.

9. A method according to claim, carae terized in that one uses an alcoholic solution diluted to 40 "/ o containing 10 / o of octadÚcyl-a-picolinium iodide and 1% of monoethyl ether of diethylene-glyeol .

10. A method according to claim, ea actérisé in that an aqueous solution of 12 "/ o of hydroxyethyl-heptadecyl-morpholium bromide supplemented with 6 / e of emulsified oetadecenyl myristate.