CH306975A - Process for the manufacture of a powdery stain remover. - Google Patents
Process for the manufacture of a powdery stain remover.Info
- Publication number
- CH306975A CH306975A CH306975DA CH306975A CH 306975 A CH306975 A CH 306975A CH 306975D A CH306975D A CH 306975DA CH 306975 A CH306975 A CH 306975A
- Authority
- CH
- Switzerland
- Prior art keywords
- silicate
- stain remover
- silicates
- way
- dependent
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 10
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000000843 powder Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000000391 magnesium silicate Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 235000012243 magnesium silicates Nutrition 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 229950011008 tetrachloroethylene Drugs 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 2
- 101100495769 Caenorhabditis elegans che-1 gene Proteins 0.000 claims 1
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 claims 1
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- NEMFQSKAPLGFIP-UHFFFAOYSA-N magnesiosodium Chemical compound [Na].[Mg] NEMFQSKAPLGFIP-UHFFFAOYSA-N 0.000 claims 1
- 235000019792 magnesium silicate Nutrition 0.000 claims 1
- 229910052919 magnesium silicate Inorganic materials 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/01—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using only solid or pasty agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Description
Verfahren zur Herstellung eines pulverförmigen Fleckentferners. Die Erfindung bezieht sich auf ein Ver fahren zur Herstellung eines pulverförmigen Fleckentferners, der durch einfaches Auf legen auf den zu entfernenden Fleck ange wendet wird.
Die Erfindung ist dadurch gekennzeichnet, dass man fein gesiebte synthetische Aluminium und/oder Magnesiumsilikate, die bei einer Fällungstemperatur bis zu 100 C erhalten wurden, mit fettlösenden Substanzen derart durchtränkt, so dass in den kleinen Hohl räumen der Teilchen das Tränkungsmittel ge speichert wird, wonach man das so im prägnierte Pulver so weit trocknen lässt, bis dasselbe äusserlich trocken erscheint.
Zur Fleckentfernung wird das Pulver auf rlen Fleek aufgestreut, mit Vorteil etwas ver rieben und anschliessend ausgebürstet. Hier bei üben die in den Hohlräumen gespeicher ten Lösungsmittel ihre fleckentfernende Wir kung rasch und kräftig aus.
Als Lösungs mittel kommen in Betracht: Benzin, Terpen tin, Aceton, Tetrachlorkohlenstoff, Mono chlorbenzol, Trichlor- und Tetrachloräthylen, Methylalkohol, Ammoniaklösung oder irgend welche andere Flüssigkeiten, die als Fleck- entferner oder entfettende Substanzen ver wendet werden können und die geeignet sind, die Silikate zu durchtränken und durch die Hohlräume derselben bis zum Gebrauch fest gehalten werden.
Die Herstellung des Silikates kann mit Vorteil folgendermassen vorgenommen wer den. Natriumsilikatlösung (Wasserglas ent- haltend 26 /o Si02 und 17 /o NaOH), wird zu einer Lösung von Aluminiumsulfat und/oder Magnesiumsulfat gegeben. Die Mischung wird mit Vorteil bis zu einer Temperatur von 100 C erwärmt. Die alkalische Lösung wird hierauf mit Säure abgestumpft und stehen gelassen, bis die Sedimentation des Nieder schlages vollzogen ist.
Hierauf wird abdekan- tiert, der Niederschlag mit Wasser ausgewa schen, das Waschwasser durch Filtrieren oder Zentrifugieren entfernt, mittels einer hydrau- lisehen Presse ausgepresst und getrocknet.
Ein so hergestelltes Silikat besitzt eine vermehrt aktive Oberfläche und dadurch eine Saugfähigkeit, die 5 -10mal grösser ist als diejenige natürlicher Diatomeenerde oder Kieselgur.
Die Erfindung wird an folgendem Aus führungsbeispiel erläutert.
500 g eines nach obigen Angaben gewon nenen Aluminiumsilikats werden gesiebt, bis ein Höchstmass an Feinheit erreicht ist. Als dann schüttet man das gesiebte Aluminium silikat in einen Behälter, der mit einer sol- ehen Menge Tetrachlorkohlenstoff angefüllt ist, dass derselbe das Aluminiumsilikat völlig bedeckt. Hierauf schüttelt man einige Augen blicke, um das Silikat mit der Flüssigkeit in innige Berührung zu bringen. Nach dem Sedimentieren giesst man vorsichtig die über schüssige Flüssigkeit ab und lässt das von der Flüssigkeit völlig durchtränkte Silikat trocknen.
Vor dem Tränken des Silikates mit dem Fleckentferner kann das Silikat erhitzt wer den, wonach dasselbe eine bräunliche Farb- tönung erhält und eine gesteigerte Ober flächenaktivität aufweist. INTach der Trocknung kann das Produkt in eeignete Behälter gebracht werden und ist sodann gebrauchsfertig. Die Anwendung er folgt im allgemeinen in Pulverform. Man kann jedoch seine Wirkung durch Anfeuchten mit etwas Wasser unterstützen.
Process for the manufacture of a powdery stain remover. The invention relates to a process for the production of a powdery stain remover, which is applied by simply placing on the stain to be removed.
The invention is characterized in that finely sieved synthetic aluminum and / or magnesium silicates, which were obtained at a precipitation temperature of up to 100 C, are soaked with fat-dissolving substances so that the impregnating agent is stored in the small cavities of the particles, after which the powder impregnated in this way is allowed to dry until it appears dry on the outside.
To remove stains, the powder is sprinkled onto the fleece, it is advantageous to rub it in a little and then brush it out. Here, the solvents stored in the cavities exercise their stain-removing effects quickly and vigorously.
Possible solvents are: gasoline, terpene, acetone, carbon tetrachloride, monochlorobenzene, trichlorethylene and tetrachlorethylene, methyl alcohol, ammonia solution or any other liquids that can be used as stain removers or degreasing substances and that are suitable to soak the silicates and hold them firmly through the cavities of the same until use.
The production of the silicate can advantageously be carried out as follows. Sodium silicate solution (water glass containing 26 / o SiO2 and 17 / o NaOH) is added to a solution of aluminum sulfate and / or magnesium sulfate. The mixture is heated to a temperature of 100 ° C. with advantage. The alkaline solution is then blunted with acid and left to stand until the sedimentation of the precipitate is complete.
It is then decanted, the precipitate washed out with water, the washing water removed by filtration or centrifugation, pressed out using a hydraulic press and dried.
A silicate produced in this way has a more active surface and therefore an absorbency that is 5 to 10 times greater than that of natural diatomaceous earth or kieselguhr.
The invention is explained using the following exemplary embodiment.
500 g of an aluminum silicate obtained according to the above information are sieved until a maximum degree of fineness is reached. Then the sieved aluminum silicate is poured into a container which is filled with such an amount of carbon tetrachloride that it completely covers the aluminum silicate. Then shake a few moments to bring the silicate into intimate contact with the liquid. After sedimentation, the excess liquid is carefully poured off and the silicate, completely soaked in the liquid, is allowed to dry.
Before the silicate is soaked with the stain remover, the silicate can be heated, after which it acquires a brownish tint and has increased surface activity. After drying, the product can be placed in suitable containers and is then ready for use. It is generally used in powder form. However, you can support its effect by moistening it with a little water.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH306975T | 1952-04-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH306975A true CH306975A (en) | 1955-05-15 |
Family
ID=4492990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH306975D CH306975A (en) | 1952-04-30 | 1952-04-30 | Process for the manufacture of a powdery stain remover. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH306975A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2324725A1 (en) * | 1975-09-18 | 1977-04-15 | Gerland | Powder for removing hydrocarbons, greases and lubricants - contg. absorbent powder, degreasing organic solvent and surfactant |
| EP0534298A1 (en) * | 1991-09-25 | 1993-03-31 | Henkel KGaA | Liquid or pasty washing or cleaning composition |
| EP1712612A1 (en) * | 2005-04-15 | 2006-10-18 | Reckitt Benckiser N.V. | Method for treating a laundry item |
-
1952
- 1952-04-30 CH CH306975D patent/CH306975A/en unknown
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2324725A1 (en) * | 1975-09-18 | 1977-04-15 | Gerland | Powder for removing hydrocarbons, greases and lubricants - contg. absorbent powder, degreasing organic solvent and surfactant |
| EP0534298A1 (en) * | 1991-09-25 | 1993-03-31 | Henkel KGaA | Liquid or pasty washing or cleaning composition |
| WO1993006201A1 (en) * | 1991-09-25 | 1993-04-01 | Henkel Kommanditgesellschaft Auf Aktien | Washing or cleaning agent in liquid or paste form |
| US5441661A (en) * | 1991-09-25 | 1995-08-15 | Henkel Kommanditgesellschaft Auf Aktien | Non-aqueous liquid detergent preparations containing a hydrated zeolite a stabilized by a polar deactivating agent |
| EP1712612A1 (en) * | 2005-04-15 | 2006-10-18 | Reckitt Benckiser N.V. | Method for treating a laundry item |
| WO2006109089A1 (en) * | 2005-04-15 | 2006-10-19 | Reckitt Benckiser N.V. | Method for treating a laundry item |
| AU2006235739B2 (en) * | 2005-04-15 | 2011-09-01 | Reckitt Benckiser Vanish B.V. | Method for treating a laundry item |
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