CH373919A - Method of controlling weeds - Google Patents
Method of controlling weedsInfo
- Publication number
- CH373919A CH373919A CH6904859A CH6904859A CH373919A CH 373919 A CH373919 A CH 373919A CH 6904859 A CH6904859 A CH 6904859A CH 6904859 A CH6904859 A CH 6904859A CH 373919 A CH373919 A CH 373919A
- Authority
- CH
- Switzerland
- Prior art keywords
- phenyl
- weeds
- chloropyridazon
- parts
- controlling weeds
- Prior art date
Links
- 241000196324 Embryophyta Species 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 5
- 239000004480 active ingredient Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical group [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052801 chlorine Chemical group 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 231100000208 phytotoxic Toxicity 0.000 claims description 2
- 230000000885 phytotoxic effect Effects 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 125000004179 3-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C(Cl)=C1[H] 0.000 description 1
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
- 235000007319 Avena orientalis Nutrition 0.000 description 1
- 235000003805 Musa ABB Group Nutrition 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 244000239204 Plantago lanceolata Species 0.000 description 1
- 235000010503 Plantago lanceolata Nutrition 0.000 description 1
- 235000015266 Plantago major Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 241001233957 eudicotyledons Species 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000000636 p-nitrophenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)[N+]([O-])=O 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000004476 plant protection product Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Verfahren zum Bekämpfen von Unkräutern Gegenstand der vorliegenden Erfindung ist ein Verfahren zum Bekämpfen von Unkräutern, dadurch gekennzeichnet, dass man die Unkräuter mit für sie phytotoxischen Mengen von Verbindungen der For mel:
EMI0001.0005
worin X ein Wasserstoffatom oder ein Chloratom und R einen gegebenenfalls durch mindestens ein Halogen atom, mindestens eine Nitrogruppe oder mindestens eine Methylgruppe substituierten Phenylrest bedeuten.
Als Wirkstoffe der Formel (I) seien beispielsweise genannt: 1-Phenyl-3-chlor-pyridazon-(6), 1-[p-Chlor- phenyl]-3-chlor-pyridazon-(6), 1-Phenyl-3,5-dichlor- pyridazon-(6), 1- [p - Chlorphenyl] - 3,5-dichlor-pyrid- azon-(6), 1- [p -Nitrophenyl] - 3 - chlor-pyridazon-(6), 1-[p-Methylphenyl]-3-chlor-pyridazon-(6), 1-[m- Chlorphenyl]-3-chlor-pyridazon-(6), 1-[2',4',
5'-Tri- chlor-phenyl]-3-chlor-pyridazon-(6).
Pflanzen, die an Stellen aufwachsen, wo sie un erwünscht sind, sollen im Sinne dieser Anmeldung als Unkraut gelten. Die Vertreter der obgenannten Stoffklassen wirken bereits bei niederen Konzentra tionen als Herbizide, und zwar sowohl gegen kei mende Samen wie gegen ausgewachsene Pflanzen.
Die Anwendung der Verbindungen kann so er folgen, dass man die Produkte mit einer mechanischen Handspritz- oder Sprüheinrichtung gleichmässig auf die Oberfläche des Bodens bzw. der Pflanzen auf- bringt. Um eine gleichmässige Verteilung zu erzielen, wer den die Verbindungen bevorzugt zusammen mit einem Streck- oder Verdünnungsmittel benutzt. Als Ver dünnungsmittel kann z. B. Wasser undloder Öl ver wendet werden, indem der Wirkstoff gelöst, emulgiert oder suspendiert wird.
Das Streckmittel kann aber auch ein fester Trägerstoff, wie z. B. Kieselerde, Ton oder Talkum, sein. Ebenso kann der Wirkstoff auch handelsüblichen Düngmitteln zugegeben werden und mit diesen zusammen entweder auf die Oberfläche des Bodens aufgetragen oder aber in den Boden ein gearbeitet werden. Eine Mischung mit anderen Herbiziden oder anderen Pflanzenschutzmitteln, wie z.
B. chlorierten Kohlenwasserstoffen, Harnstoffderi- vaten bzw. Urethanen oder Phosphorsäureestern, ist gleichfalls möglich.
In den folgenden Beispielen bedeuten Teile Ge wichtsteile.
<I>Beispiel 1</I> 80 Teile 1-Phenyl-3,5-dichlor-pyridazon-(6) wer den mit 19,5 Teilen fester inerter Trägersubstanz, z. B. Kaolin, und 0,5 Teilen Haftmittel, z. B. Carboxy- methylcellulose, in einer geeigneten Kugelmühle zu grösster Feinheit vermahlen. Das Gemisch dient als Stäubemittel. Bei der Behandlung eines Versuchs ackers mit diesem Stäubemittel, Wobei 1 kg Wirk substanz pro Hektare zur Anwendung gelangte, wurde in stark selektiver Weise das Wachstum von Spitz wegerich verhindert bzw. dieser zum Absterben ge bracht.
<I>Beispiel 2</I> 5 Teile 1-Phenyl-3,5-dichlor-pyridazon-(6) werden in 90 Teilen eines organischen Lösungsmittels, z. B. Xylol, gelöst und mit 5 Teilen eines nichtionogenen Emulgators, z. B. eines Alkylphenol-Äthylenoxyd- Kondensationsproduktes, versetzt. Die Lösung wird im gewünschten Verhältnis mit Wasser versetzt und bildet eine milchige Emulsion zur Unkrautbekämp- fung, speziell zur Bekämpfung von Spitzwegerich.
<I>Beispiel 3</I> Man stellt ein Stäubemittel zur Unkrautbekämp- fung, anälog wie in Beispiel 1, her, verwendet jedoch anstelle von 80 Teilen 1-Phenyl-3,5-dichlor-pyrid- azon-(6) eine gleiche Menge 1-Phenyl-3-chlor-pyrid- azon (6).
Das Mittel wirkt bevorzugt gegen Dikotyledonen und ist geeignet, z. B. bei Anwendung von 1-3 kg Wirksubstanz pro Hektare, breitblätterige Unkräuter zu zerstören, während Hafer und Mais vollkommen normal wachsen. Das Mittel ist auch geeignet, z. B. Kartoffelstauden wunschgemäss abzubrennen.
Method for controlling weeds The present invention relates to a method for controlling weeds, characterized in that the weeds are treated with amounts of compounds of the formula which are phytotoxic for them:
EMI0001.0005
where X is a hydrogen atom or a chlorine atom and R is a phenyl radical which is optionally substituted by at least one halogen atom, at least one nitro group or at least one methyl group.
Examples of active ingredients of the formula (I) are: 1-phenyl-3-chloropyridazon- (6), 1- [p-chlorophenyl] -3-chloropyridazon- (6), 1-phenyl-3 , 5-dichloropyridazon- (6), 1- [p - chlorophenyl] - 3,5-dichloropyridazon- (6), 1- [p -nitrophenyl] -3 - chloropyridazon- (6) , 1- [p-methylphenyl] -3-chloropyridazon- (6), 1- [m-chlorophenyl] -3-chloropyridazon- (6), 1- [2 ', 4',
5'-trichlorophenyl] -3-chloro-pyridazon- (6).
Plants that grow in places where they are undesirable should be considered weeds for the purposes of this application. The representatives of the above-mentioned classes of substances act as herbicides even at low concentrations, both against kei emerging seeds and against adult plants.
The compounds can be used by applying the products evenly to the surface of the soil or of the plants using a mechanical hand spray or spray device. In order to achieve uniform distribution, whoever uses the compounds preferably together with an extender or diluent. As a United diluent z. B. water and / or oil can be used by the active ingredient being dissolved, emulsified or suspended.
The extender can also be a solid carrier, such as. B. silica, clay or talc. The active ingredient can also be added to commercially available fertilizers and either applied to the surface of the soil or worked into the soil together with them. A mixture with other herbicides or other plant protection products, such as
B. chlorinated hydrocarbons, urea derivatives or urethanes or phosphoric acid esters are also possible.
In the following examples, parts mean parts by weight.
<I> Example 1 </I> 80 parts of 1-phenyl-3,5-dichloro-pyridazon- (6) who with 19.5 parts of solid inert carrier, z. B. kaolin, and 0.5 part adhesive, e.g. B. carboxymethyl cellulose, ground in a suitable ball mill to the greatest fineness. The mixture serves as a dusting agent. When treating a test field with this dust, where 1 kg of active substance per hectare was used, the growth of plantain was prevented in a highly selective manner or it was made to die.
<I> Example 2 </I> 5 parts of 1-phenyl-3,5-dichloro-pyridazon- (6) are dissolved in 90 parts of an organic solvent, e.g. B. xylene, dissolved and treated with 5 parts of a nonionic emulsifier, e.g. B. an alkylphenol-ethylene oxide condensation product, added. The solution is mixed with water in the desired ratio and forms a milky emulsion for weed control, especially for control of ribwort.
<I> Example 3 </I> A dust for weed control is produced, similar to that in Example 1, but instead of 80 parts 1-phenyl-3,5-dichloro-pyridazon- (6) one is used equal amount of 1-phenyl-3-chloropyridazon (6).
The agent acts preferably against dicotyledons and is suitable, for. B. when using 1-3 kg of active substance per hectare to destroy broad-leaf weeds, while oats and maize grow completely normally. The agent is also suitable e.g. B. to burn potato plants as desired.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH6904859A CH373919A (en) | 1959-02-02 | 1959-02-02 | Method of controlling weeds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH6904859A CH373919A (en) | 1959-02-02 | 1959-02-02 | Method of controlling weeds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH373919A true CH373919A (en) | 1963-12-15 |
Family
ID=4529192
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH6904859A CH373919A (en) | 1959-02-02 | 1959-02-02 | Method of controlling weeds |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH373919A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996039392A1 (en) * | 1995-06-06 | 1996-12-12 | Bayer Aktiengesellschaft | Phenylpyridazinones |
| WO1999052878A1 (en) * | 1998-04-09 | 1999-10-21 | Bayer Aktiengesellschaft | Substituted phenyl pyridazinones |
| CN1117083C (en) * | 1995-08-21 | 2003-08-06 | 住友化学工业株式会社 | Pyridazin-3-one derivatives, their applications, and intermediates for their preparation |
-
1959
- 1959-02-02 CH CH6904859A patent/CH373919A/en unknown
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996039392A1 (en) * | 1995-06-06 | 1996-12-12 | Bayer Aktiengesellschaft | Phenylpyridazinones |
| JPH11506112A (en) * | 1995-06-06 | 1999-06-02 | バイエル・アクチエンゲゼルシヤフト | Phenylpyridazinone |
| US6551963B1 (en) | 1995-06-06 | 2003-04-22 | Bayer Aktiengesellschaft | Phenylpyridazinones |
| US7012041B2 (en) | 1995-06-06 | 2006-03-14 | Bayer Ag | Phenylpyridazinones |
| CN1117083C (en) * | 1995-08-21 | 2003-08-06 | 住友化学工业株式会社 | Pyridazin-3-one derivatives, their applications, and intermediates for their preparation |
| WO1999052878A1 (en) * | 1998-04-09 | 1999-10-21 | Bayer Aktiengesellschaft | Substituted phenyl pyridazinones |
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