CH512554A - Verfahren zur Verbesserung der durch energiereiche, ionisierende Strahlung induzierten Pfropfpolymerisation oder Pfropfcopolymerisation einer oder mehrerer radikalisch polymerisierbarer Verbindungen auf aus synthetischen Hochpolymeren bestehende geformte Gebilde nicht textiler Art - Google Patents
Verfahren zur Verbesserung der durch energiereiche, ionisierende Strahlung induzierten Pfropfpolymerisation oder Pfropfcopolymerisation einer oder mehrerer radikalisch polymerisierbarer Verbindungen auf aus synthetischen Hochpolymeren bestehende geformte Gebilde nicht textiler ArtInfo
- Publication number
- CH512554A CH512554A CH1408669A CH1408669A CH512554A CH 512554 A CH512554 A CH 512554A CH 1408669 A CH1408669 A CH 1408669A CH 1408669 A CH1408669 A CH 1408669A CH 512554 A CH512554 A CH 512554A
- Authority
- CH
- Switzerland
- Prior art keywords
- graft
- cmpds
- polymerisation
- free radical
- glass transition
- Prior art date
Links
- 239000000758 substrate Substances 0.000 title abstract description 6
- 230000005855 radiation Effects 0.000 title description 3
- 150000003254 radicals Chemical class 0.000 title 1
- 229920000642 polymer Polymers 0.000 abstract description 20
- 230000009477 glass transition Effects 0.000 abstract description 11
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 19
- 238000000034 method Methods 0.000 description 16
- -1 polyethylene Polymers 0.000 description 10
- 230000005865 ionizing radiation Effects 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 238000007334 copolymerization reaction Methods 0.000 description 6
- 238000010559 graft polymerization reaction Methods 0.000 description 5
- 229920002239 polyacrylonitrile Polymers 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- 229920002302 Nylon 6,6 Polymers 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000000753 cycloalkyl group Chemical group 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920006267 polyester film Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920001567 vinyl ester resin Polymers 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical class C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 125000000547 substituted alkyl group Chemical class 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 231100000987 absorbed dose Toxicity 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 150000001253 acrylic acids Chemical class 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- 229960002684 aminocaproic acid Drugs 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000003609 aryl vinyl group Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical class C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 230000005251 gamma ray Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical class 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/18—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to irradiated or oxidised macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/16—Chemical modification with polymerisable compounds
- C08J7/18—Chemical modification with polymerisable compounds using wave energy or particle radiation
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
- D06M14/26—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Graft Or Block Polymers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Coloring (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1408669A CH512554A (de) | 1968-08-27 | 1968-08-27 | Verfahren zur Verbesserung der durch energiereiche, ionisierende Strahlung induzierten Pfropfpolymerisation oder Pfropfcopolymerisation einer oder mehrerer radikalisch polymerisierbarer Verbindungen auf aus synthetischen Hochpolymeren bestehende geformte Gebilde nicht textiler Art |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1283768 | 1968-08-27 | ||
| CH1408669A CH512554A (de) | 1968-08-27 | 1968-08-27 | Verfahren zur Verbesserung der durch energiereiche, ionisierende Strahlung induzierten Pfropfpolymerisation oder Pfropfcopolymerisation einer oder mehrerer radikalisch polymerisierbarer Verbindungen auf aus synthetischen Hochpolymeren bestehende geformte Gebilde nicht textiler Art |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH512554A true CH512554A (de) | 1971-09-15 |
Family
ID=4386837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH1408669A CH512554A (de) | 1968-08-27 | 1968-08-27 | Verfahren zur Verbesserung der durch energiereiche, ionisierende Strahlung induzierten Pfropfpolymerisation oder Pfropfcopolymerisation einer oder mehrerer radikalisch polymerisierbarer Verbindungen auf aus synthetischen Hochpolymeren bestehende geformte Gebilde nicht textiler Art |
Country Status (9)
| Country | Link |
|---|---|
| AT (1) | AT301175B (es) |
| BE (1) | BE736285A (es) |
| BR (1) | BR6911889D0 (es) |
| CH (1) | CH512554A (es) |
| DE (1) | DE1943061B2 (es) |
| ES (1) | ES369638A1 (es) |
| FR (1) | FR2016445A1 (es) |
| GB (1) | GB1279709A (es) |
| NL (1) | NL6910996A (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4743267A (en) * | 1982-06-21 | 1988-05-10 | International Yarn Corporation Of Tennessee | Process for improving polymer fiber properties and fibers produced thereby |
| CN101858121A (zh) * | 2010-06-23 | 2010-10-13 | 白建国 | 一种储热保温砌块及制造安装方法 |
-
1968
- 1968-08-27 CH CH1408669A patent/CH512554A/de not_active IP Right Cessation
-
1969
- 1969-07-10 AT AT662569A patent/AT301175B/de active
- 1969-07-17 NL NL6910996A patent/NL6910996A/xx unknown
- 1969-07-17 ES ES369638A patent/ES369638A1/es not_active Expired
- 1969-07-18 BE BE736285D patent/BE736285A/xx unknown
- 1969-08-21 GB GB4185669A patent/GB1279709A/en not_active Expired
- 1969-08-25 DE DE19691943061 patent/DE1943061B2/de active Pending
- 1969-08-26 FR FR6929169A patent/FR2016445A1/fr not_active Withdrawn
- 1969-08-27 BR BR21188969A patent/BR6911889D0/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR6911889D0 (pt) | 1973-01-11 |
| DE1943061A1 (de) | 1970-03-05 |
| GB1279709A (en) | 1972-06-28 |
| DE1943061B2 (de) | 1973-06-14 |
| BE736285A (es) | 1970-01-19 |
| FR2016445A1 (es) | 1970-05-08 |
| ES369638A1 (es) | 1971-06-01 |
| NL6910996A (es) | 1970-03-03 |
| AT301175B (de) | 1972-08-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased |