CH620598A5 - Method for increasing the exchange turnover in ion exchange processes - Google Patents

Method for increasing the exchange turnover in ion exchange processes Download PDF

Info

Publication number: CH620598A5
Authority: CH; Switzerland
Prior art keywords: fraction; solution; bed; reaction; exchange
Prior art date: 1975-04-01

Application number

CH400676A

Other languages

German (de)

English (en)

Inventor

Sandor Dr Vajna

Original Assignee

Vajna Sandor

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-04-01

Filing date

1976-03-31

Publication date

1980-12-15

1975-04-01 Priority claimed from DE19752514222 external-priority patent/DE2514222A1/de

1975-09-30 Priority claimed from DE19752543573 external-priority patent/DE2543573A1/de

1976-03-31 Application filed by Vajna Sandor filed Critical Vajna Sandor

1980-12-15 Publication of CH620598A5 publication Critical patent/CH620598A5/de

Links

238000000034 method Methods 0.000 title claims description 91
238000005342 ion exchange Methods 0.000 title claims description 22
230000007306 turnover Effects 0.000 title claims description 14
238000006243 chemical reaction Methods 0.000 claims description 134
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 77
150000002500 ions Chemical class 0.000 claims description 51
238000006073 displacement reaction Methods 0.000 claims description 49
239000007788 liquid Substances 0.000 claims description 45
230000008569 process Effects 0.000 claims description 44
239000000203 mixture Substances 0.000 claims description 13
239000002245 particle Substances 0.000 claims description 8
238000002156 mixing Methods 0.000 claims description 6
230000007423 decrease Effects 0.000 claims description 4
238000011084 recovery Methods 0.000 claims 1
239000000243 solution Substances 0.000 description 160
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 37
239000002351 wastewater Substances 0.000 description 34
230000008929 regeneration Effects 0.000 description 24
238000011069 regeneration method Methods 0.000 description 24
-1 hydrogen ions Chemical class 0.000 description 17
150000001768 cations Chemical class 0.000 description 16
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 14
229910052739 hydrogen Inorganic materials 0.000 description 14
239000001257 hydrogen Substances 0.000 description 14
238000000926 separation method Methods 0.000 description 13
229910001415 sodium ion Inorganic materials 0.000 description 13
229910001424 calcium ion Inorganic materials 0.000 description 12
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 11
150000001450 anions Chemical class 0.000 description 10
230000000694 effects Effects 0.000 description 9
150000003839 salts Chemical class 0.000 description 9
241000792859 Enema Species 0.000 description 8
230000008901 benefit Effects 0.000 description 8
239000007920 enema Substances 0.000 description 8
229940095399 enema Drugs 0.000 description 8
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 7
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 7
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 7
230000001172 regenerating effect Effects 0.000 description 7
238000005406 washing Methods 0.000 description 7
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 6
230000002378 acidificating effect Effects 0.000 description 6
230000008859 change Effects 0.000 description 6
238000010612 desalination reaction Methods 0.000 description 6
230000009467 reduction Effects 0.000 description 6
239000004793 Polystyrene Substances 0.000 description 5
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
239000011975 tartaric acid Substances 0.000 description 5
235000002906 tartaric acid Nutrition 0.000 description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
239000002253 acid Substances 0.000 description 4
230000006872 improvement Effects 0.000 description 4
229920000831 ionic polymer Polymers 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
239000011734 sodium Substances 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
239000011780 sodium chloride Substances 0.000 description 4
239000001509 sodium citrate Substances 0.000 description 4
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 4
239000000126 substance Substances 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
238000010790 dilution Methods 0.000 description 3
239000012895 dilution Substances 0.000 description 3
230000007613 environmental effect Effects 0.000 description 3
238000005259 measurement Methods 0.000 description 3
238000003860 storage Methods 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
229910002651 NO3 Inorganic materials 0.000 description 2
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
230000002411 adverse Effects 0.000 description 2
238000010276 construction Methods 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
DKAGJZJALZXOOV-UHFFFAOYSA-N hydrate;hydrochloride Chemical compound O.Cl DKAGJZJALZXOOV-UHFFFAOYSA-N 0.000 description 2
230000036571 hydration Effects 0.000 description 2
238000006703 hydration reaction Methods 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
238000012856 packing Methods 0.000 description 2
229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 2
229940005642 polystyrene sulfonic acid Drugs 0.000 description 2
239000011347 resin Substances 0.000 description 2
229920005989 resin Polymers 0.000 description 2
HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 2
239000001433 sodium tartrate Substances 0.000 description 2
229960002167 sodium tartrate Drugs 0.000 description 2
235000011004 sodium tartrates Nutrition 0.000 description 2
230000008961 swelling Effects 0.000 description 2
238000012360 testing method Methods 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
238000013459 approach Methods 0.000 description 1
230000033228 biological regulation Effects 0.000 description 1
238000005341 cation exchange Methods 0.000 description 1
239000002131 composite material Substances 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
230000000254 damaging effect Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
238000011549 displacement method Methods 0.000 description 1
238000010494 dissociation reaction Methods 0.000 description 1
230000005593 dissociations Effects 0.000 description 1
238000000909 electrodialysis Methods 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
230000007774 longterm Effects 0.000 description 1
238000010327 methods by industry Methods 0.000 description 1
239000011259 mixed solution Substances 0.000 description 1
230000000149 penetrating effect Effects 0.000 description 1
238000000053 physical method Methods 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
230000007096 poisonous effect Effects 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000012492 regenerant Substances 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
230000010076 replication Effects 0.000 description 1
238000001223 reverse osmosis Methods 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
229940095064 tartrate Drugs 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Treatment Of Water By Ion Exchange (AREA)
Physical Or Chemical Processes And Apparatus (AREA)

CH400676A 1975-04-01 1976-03-31 Method for increasing the exchange turnover in ion exchange processes CH620598A5 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19752514222 DE2514222A1 (de)	1975-04-01	1975-04-01	Verfahren zur verbesserung von ionenaustauschreaktionen
DE19752543573 DE2543573A1 (de)	1975-09-30	1975-09-30	Verfahren zur verbesserung der mit gelagerten loesungsfraktionen arbeitenden ionenaustauschverfahren

Publications (1)

Publication Number	Publication Date
CH620598A5 true CH620598A5 (en)	1980-12-15

Family

ID=25768710

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH400676A CH620598A5 (en)	1975-04-01	1976-03-31	Method for increasing the exchange turnover in ion exchange processes

Country Status (10)

Country	Link
JP (1)	JPS51122675A (it)
AT (1)	AT347363B (it)
AU (1)	AU506525B2 (it)
CA (1)	CA1071778A (it)
CH (1)	CH620598A5 (it)
FR (1)	FR2306009A1 (it)
GB (1)	GB1540481A (it)
IT (1)	IT1091101B (it)
NL (1)	NL7603346A (it)
SE (1)	SE426655B (it)

1976
- 1976-03-25 IT IT48727/76A patent/IT1091101B/it active
- 1976-03-30 AU AU12495/76A patent/AU506525B2/en not_active Expired
- 1976-03-31 CA CA249,294A patent/CA1071778A/en not_active Expired
- 1976-03-31 NL NL7603346A patent/NL7603346A/xx not_active Application Discontinuation
- 1976-03-31 AT AT232176A patent/AT347363B/de not_active IP Right Cessation
- 1976-03-31 FR FR7609399A patent/FR2306009A1/fr active Granted
- 1976-03-31 SE SE7603832A patent/SE426655B/xx unknown
- 1976-03-31 GB GB13111/76A patent/GB1540481A/en not_active Expired
- 1976-03-31 CH CH400676A patent/CH620598A5/de not_active IP Right Cessation
- 1976-03-31 JP JP51035896A patent/JPS51122675A/ja active Pending

Also Published As

Publication number	Publication date
SE426655B (sv)	1983-02-07
JPS51122675A (en)	1976-10-26
IT1091101B (it)	1985-06-26
AT347363B (de)	1978-12-27
SE7603832L (sv)	1976-10-02
FR2306009B3 (it)	1978-12-22
GB1540481A (en)	1979-02-14
CA1071778A (en)	1980-02-12
ATA232176A (de)	1978-04-15
AU1249576A (en)	1977-10-13
AU506525B2 (en)	1980-01-10
NL7603346A (nl)	1976-10-05
FR2306009A1 (fr)	1976-10-29

Legal Events

Date	Code	Title	Description
1985-11-29	PL	Patent ceased
2024-10-31	PL	Patent ceased

Publication	Publication Date	Title
DE3446573C2 (it)	1993-08-12
EP0030697B1 (de)	1983-04-20	Gegenstrom-Verfahren zur Behandlung von Flüssigkeiten mit einem Ionenaustauscher und Ionenaustauschfilter zur Durchführung des Verfahrens
DE4238532A1 (de)	1994-05-19	Verfahren und Vorrichtung zum Entsalzen wäßriger Lösungen mittels Ionenaustauschermassen
DE1293698B (de)	1969-04-24	Verfahren und Vorrichtung zum Enthärten von Wasser
EP0166282B1 (de)	1988-11-30	Verfahren und Vorrichtung zur Behandlung von Flüssigkeiten mit Kationenaustauschern und Anionenaustauschern
DE60032983T2 (de)	2007-09-06	Verfahren zur Entfernung von radioaktivem Thorium aus Lösungsmittelextraktionsausflüssen
DE2210450A1 (de)	1972-09-21	Verfahren zum Regenerieren von Ionen austauschern
DE2002196C3 (de)	1979-02-15	Kondensatreinigungsverfahren mit Mischbettaustauschern
DE2439303C2 (de)	1984-07-19	Vorrichtung zum Abtrennen von feinverteilten emulgierten und/oder gelösten Stoffen sowie Feststoffen aus Flüssigkeiten
DE2221561A1 (de)	1973-11-15	Verfahren zur durchfuehrung von ionenaustausch- und adsorptionsvorgaengen unter verwendung eines gegenstromfilters
CH682639A5 (de)	1993-10-29	Feinreinigung von Wasser und Behandlung von Kondensaten in einer Ionenaustauscheranlage.
DE2708321A1 (de)	1977-09-01	Verfahren zur entfernung von jod
EP0125463B1 (de)	1987-11-25	Verfahren zur internen Regeneration von Ionenaustauscherharzen in Mischbettfiltern und Mischbettfilter zur Durchführung des Verfahrens
CH620598A5 (en)	1980-12-15	Method for increasing the exchange turnover in ion exchange processes
DE4019900C2 (de)	1999-04-08	Vorrichtung für Ionenaustauscher
DE2613971A1 (de)	1977-10-06	Verfahren zum erhoehen des austauschumsatzes in ionenaustauschverfahren
DE2723297A1 (de)	1978-12-14	Verfahren zur herstellung von vollentsalztem prozesswasser
EP0487455B1 (de)	1995-10-25	Verfahren und Einrichtung zur Entsalzung von wässrigen Flüssigkeiten
DE2022571A1 (de)	1970-11-12	Verfahren und Vorrichtung zur UEbertragung von Stoffen zwischen einer Fluessigkeit und einem koernigen Material
DE2029720C3 (de)	1981-04-02	Ionenaustauschanlage zur Behandlung von Flüssigkeit
CH675371A5 (it)	1990-09-28
DE2334695A1 (de)	1975-01-23	Verfahren und vorrichtung zur regeneration von ionenaustauschern
EP4612262B1 (de)	2026-04-29	Herstellungsverfahren für quaternäre ammonium-carboxylat-verbindungen und dadurch erhältliches additiv für kühlschmierstoff-emulsionen
DE2540020A1 (de)	1976-04-08	Verfahren zur durchfuehrung von festbett-ionenaustauschprozessen
DE4042633C2 (de)	1999-07-01	Ionenaustauschanlage, Verwendung der Ionenaustauschanlage und Verfahren zum Aufbereiten von Wasser