CH644598A5 - Process for the preparation of 1-(triphenylmethyl)imidazoles - Google Patents

Process for the preparation of 1-(triphenylmethyl)imidazoles Download PDF

Info

Publication number: CH644598A5
Authority: CH; Switzerland
Prior art keywords: derivatives; compounds; tritylcarbinol; preparation; imidazole
Prior art date: 1978-06-01

Application number

CH509479A

Other languages

German (de)

English (en)

Inventor

Hideo Agui

Ikutaro Saji

Mitsuo Nakashita

Original Assignee

Sumitomo Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-06-01

Filing date

1979-05-31

Publication date

1984-08-15

1979-05-31 Application filed by Sumitomo Chemical Co filed Critical Sumitomo Chemical Co

1984-08-15 Publication of CH644598A5 publication Critical patent/CH644598A5/de

Links

NPZDCTUDQYGYQD-UHFFFAOYSA-N 1-tritylimidazole Chemical class C1=NC=CN1C(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 NPZDCTUDQYGYQD-UHFFFAOYSA-N 0.000 title claims abstract description 18
238000000034 method Methods 0.000 title claims description 22
238000002360 preparation method Methods 0.000 title claims description 21
HWOZVQNBUIBZMZ-UHFFFAOYSA-N tri(imidazol-1-yl)phosphane Chemical class C1=NC=CN1P(N1C=NC=C1)N1C=NC=C1 HWOZVQNBUIBZMZ-UHFFFAOYSA-N 0.000 claims abstract description 16
KTVAHLGKTSPDOG-UHFFFAOYSA-N TRAM-3 Chemical compound C=1C=CC=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=CC=C1 KTVAHLGKTSPDOG-UHFFFAOYSA-N 0.000 claims description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
125000004432 carbon atom Chemical group C* 0.000 claims description 11
238000006243 chemical reaction Methods 0.000 claims description 11
239000002904 solvent Substances 0.000 claims description 9
150000001875 compounds Chemical class 0.000 claims description 8
125000003545 alkoxy group Chemical group 0.000 claims description 7
125000004414 alkyl thio group Chemical group 0.000 claims description 7
125000005843 halogen group Chemical group 0.000 claims description 7
150000002460 imidazoles Chemical class 0.000 claims description 7
125000004093 cyano group Chemical group *C#N 0.000 claims description 6
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 claims description 6
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 6
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 6
VNFPBHJOKIVQEB-UHFFFAOYSA-N clotrimazole Chemical compound ClC1=CC=CC=C1C(N1C=NC=C1)(C=1C=CC=CC=1)C1=CC=CC=C1 VNFPBHJOKIVQEB-UHFFFAOYSA-N 0.000 claims description 5
-1 alkyl radicals Chemical class 0.000 claims description 4
150000004820 halides Chemical class 0.000 claims description 4
238000004519 manufacturing process Methods 0.000 claims description 4
150000003839 salts Chemical class 0.000 claims description 4
239000007858 starting material Substances 0.000 claims description 4
239000003242 anti bacterial agent Substances 0.000 claims description 2
230000000843 anti-fungal effect Effects 0.000 claims description 2
229940121375 antifungal agent Drugs 0.000 claims description 2
239000003429 antifungal agent Substances 0.000 claims description 2
150000003851 azoles Chemical class 0.000 claims description 2
239000004332 silver Substances 0.000 claims description 2
229910052709 silver Inorganic materials 0.000 claims description 2
159000000000 sodium salts Chemical class 0.000 claims description 2
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 27
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 21
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 20
239000000203 mixture Substances 0.000 description 17
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 15
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 12
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 6
238000010992 reflux Methods 0.000 description 6
238000009835 boiling Methods 0.000 description 5
239000011541 reaction mixture Substances 0.000 description 5
MFHPYLFZSCSNST-UHFFFAOYSA-N 1-chloro-2-(trichloromethyl)benzene Chemical compound ClC1=CC=CC=C1C(Cl)(Cl)Cl MFHPYLFZSCSNST-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
238000000921 elemental analysis Methods 0.000 description 3
239000000706 filtrate Substances 0.000 description 3
229910052943 magnesium sulfate Inorganic materials 0.000 description 3
235000019341 magnesium sulphate Nutrition 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
238000001953 recrystallisation Methods 0.000 description 3
LZTRCELOJRDYMQ-UHFFFAOYSA-N triphenylmethanol Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(O)C1=CC=CC=C1 LZTRCELOJRDYMQ-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
239000003610 charcoal Substances 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
239000012044 organic layer Substances 0.000 description 2
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 2
QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
IWUWHGXBCVDMST-UHFFFAOYSA-N 1-benzhydryl-2-chlorobenzene Chemical compound ClC1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 IWUWHGXBCVDMST-UHFFFAOYSA-N 0.000 description 1
JDIIGWSSTNUWGK-UHFFFAOYSA-N 1h-imidazol-3-ium;chloride Chemical compound [Cl-].[NH2+]1C=CN=C1 JDIIGWSSTNUWGK-UHFFFAOYSA-N 0.000 description 1
HDNFMKOSKDGYQQ-UHFFFAOYSA-N 2-[(2-chlorophenyl)-diphenylmethyl]-1h-imidazole Chemical compound ClC1=CC=CC=C1C(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=NC=CN1 HDNFMKOSKDGYQQ-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
238000005727 Friedel-Crafts reaction Methods 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
229960004022 clotrimazole Drugs 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000000498 cooling water Substances 0.000 description 1
239000012043 crude product Substances 0.000 description 1
MYTMXVHNEWBFAL-UHFFFAOYSA-L dipotassium;carbonate;hydrate Chemical compound O.[K+].[K+].[O-]C([O-])=O MYTMXVHNEWBFAL-UHFFFAOYSA-L 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
230000000855 fungicidal effect Effects 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
238000002955 isolation Methods 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
238000000746 purification Methods 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
239000012258 stirred mixture Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Plural Heterocyclic Compounds (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

CH509479A 1978-06-01 1979-05-31 Process for the preparation of 1-(triphenylmethyl)imidazoles CH644598A5 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP6634178A JPS5938949B2 (ja)	1978-06-01	1978-06-01	Ｎ↓−置換イミダゾ−ル誘導体の製法

Publications (1)

Publication Number	Publication Date
CH644598A5 true CH644598A5 (en)	1984-08-15

Family

ID=13313050

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH509479A CH644598A5 (en)	1978-06-01	1979-05-31	Process for the preparation of 1-(triphenylmethyl)imidazoles

Country Status (11)

Country	Link
JP (1)	JPS5938949B2 (da)
AR (1)	AR220392A1 (da)
AT (1)	AT373244B (da)
CA (1)	CA1119179A (da)
CH (1)	CH644598A5 (da)
DK (1)	DK228379A (da)
ES (1)	ES481166A1 (da)
HU (1)	HU180088B (da)
NL (1)	NL7904329A (da)
PT (1)	PT69691A (da)
SE (1)	SE7904739L (da)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0433813A3 (en) *	1989-12-21	1991-11-06	Bayer Ag	Triarylmethane colour formers
US5233048A (en) *	1989-12-21	1993-08-03	Bayer Aktiengesellschaft	Triarylmethane color formers

1978
- 1978-06-01 JP JP6634178A patent/JPS5938949B2/ja not_active Expired
1979
- 1979-05-29 PT PT6969179A patent/PT69691A/pt unknown
- 1979-05-30 AR AR27672679A patent/AR220392A1/es active
- 1979-05-30 SE SE7904739A patent/SE7904739L/xx not_active Application Discontinuation
- 1979-05-30 HU HUSU001017 patent/HU180088B/hu unknown
- 1979-05-31 ES ES481166A patent/ES481166A1/es not_active Expired
- 1979-05-31 CA CA000328849A patent/CA1119179A/en not_active Expired
- 1979-05-31 CH CH509479A patent/CH644598A5/de not_active IP Right Cessation
- 1979-05-31 DK DK228379A patent/DK228379A/da not_active Application Discontinuation
- 1979-06-01 AT AT400679A patent/AT373244B/de not_active IP Right Cessation
- 1979-06-01 NL NL7904329A patent/NL7904329A/xx not_active Application Discontinuation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0433813A3 (en) *	1989-12-21	1991-11-06	Bayer Ag	Triarylmethane colour formers
US5233048A (en) *	1989-12-21	1993-08-03	Bayer Aktiengesellschaft	Triarylmethane color formers

Also Published As

Publication number	Publication date
DK228379A (da)	1979-12-02
JPS5938949B2 (ja)	1984-09-20
HU180088B (en)	1983-01-28
JPS54157561A (en)	1979-12-12
CA1119179A (en)	1982-03-02
PT69691A (en)	1979-06-01
NL7904329A (nl)	1979-12-04
ES481166A1 (es)	1980-02-01
SE7904739L (sv)	1979-12-02
AR220392A1 (es)	1980-10-31
ATA400679A (de)	1983-05-15
AT373244B (de)	1983-12-27

Legal Events

Date	Code	Title	Description
1988-01-29	PL	Patent ceased
2024-10-31	PL	Patent ceased

Publication	Publication Date	Title
DD148055A5 (de)	1981-05-06	Verfahren zur herstellung von o-substituierten derivaten des(+)-cyanidan-3-ols
AT349029B (de)	1979-03-12	Verfahren zur herstellung von neuen 1,2- dithiolderivaten
DE2147023B2 (de)	1981-07-23	Verfahren zur Herstellung von 1H- Tetrazol-Verbindungen
CH597199A5 (en)	1978-03-31	3-Phenyl pyridaz-6-ones prodn.
DE2462011A1 (de)	1975-06-26	Cyanamidderivate
DE2835157A1 (de)	1980-02-21	Verfahren zur herstellung von n-substituierten alpha -halogenacetaniliden
DE3019069C2 (da)	1989-11-30
DE2810267A1 (de)	1978-09-14	Verfahren zur herstellung von phenylpyridazinonderivaten
CH644598A5 (en)	1984-08-15	Process for the preparation of 1-(triphenylmethyl)imidazoles
DE2434378C3 (de)	1978-06-15	Pyrazolin-thiono-phosphorsäureester, Verfahren zu deren Herstellung und diese enthaltende Mittel
DE3750587T2 (de)	1995-01-26	Verfahren zur Herstellung von Eicosatetraynsäure.
DE1931061A1 (de)	1970-01-08	Pyrazolverbindungen,Verfahren zu ihrer Herstellung und ihre Verwendung
EP0169439A2 (de)	1986-01-29	Verfahren und Zwischenprodukte zur Synthese von diastereomeren Triazolyl-O,N-acetalen
EP0043024B1 (de)	1984-03-28	Verfahren zur Herstellung von 5-Aminoisoxazolen
DE60114889T2 (de)	2006-07-20	Verfahren zur herstellung von fluconazole und kristallmodifikationen davon
DE2640616C3 (de)	1980-11-27	Verfahren zur Herstellung von N-Acyl-2-aiylglycinen
AT364836B (de)	1981-11-25	Verfahren zur herstellung von neuen o-substituierten derivaten des (+)-cyanidan-3-ols und deren salzen
EP0110116B1 (de)	1989-01-04	Verfahren zur Herstellung von Keten-O,N-acetalen
DE3538873A1 (de)	1987-05-07	Verfahren zur herstellung von imidazolyl-methan-derivaten
DE3231449A1 (de)	1983-03-10	Imidazolderivate und verfahren zu ihrer herstellung
AT331804B (de)	1976-08-25	Verfahren zur herstellung von neuen 6-aza-3h-1,4-benzodiazepinen, deren optischen isomeren und deren salzen
AT258264B (de)	1967-11-10	Verfahren zur Herstellung von 5-(3'-Methylaminopropyl)-5H-dibenzo[a,d] cyclohepten
AT394800B (de)	1992-06-25	Mittel zur wachstumshemmung von pilzen und bakterien
DE2619321C2 (de)	1984-05-17	Oxalsäurederivate, ihre Herstellung und ihre Verwendung
AT326101B (de)	1975-11-25	Verfahren zur herstellung von neuen substituierten formylazapentadiennitrilen sowie von deren säureadditionssalzen

CH644598A5 - Process for the preparation of 1-(triphenylmethyl)imidazoles - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (1)

Publications (1)

Family

ID=13313050

Family Applications (1)

Country Status (11)

Cited By (2)

Cited By (2)

Also Published As

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Legal Events