CH652416A5 - Freifliessende spruehgetrocknete hohlkuegelchen. - Google Patents

Freifliessende spruehgetrocknete hohlkuegelchen. Download PDF

Info

Publication number: CH652416A5
Authority: CH; Switzerland
Prior art keywords: zeolite; water; weight; sodium; hollow spheres
Prior art date: 1981-02-26

Application number

CH1136/82A

Other languages

German (de)

English (en)

Inventor

John Jerome Grecsek

Sue Wilson Giordano

Seymour Grey

Original Assignee

Colgate Palmolive Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-02-26

Filing date

1982-02-24

Publication date

1985-11-15

1982-02-24 Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co

1985-11-15 Publication of CH652416A5 publication Critical patent/CH652416A5/de

Links

239000003599 detergent Substances 0.000 claims description 173
239000010457 zeolite Substances 0.000 claims description 132
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 116
229910021536 Zeolite Inorganic materials 0.000 claims description 111
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 95
229910001868 water Inorganic materials 0.000 claims description 90
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 84
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 57
229920000058 polyacrylate Polymers 0.000 claims description 57
239000000440 bentonite Substances 0.000 claims description 53
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 53
229910000278 bentonite Inorganic materials 0.000 claims description 52
229910000029 sodium carbonate Inorganic materials 0.000 claims description 41
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 34
239000004115 Sodium Silicate Substances 0.000 claims description 32
229910052911 sodium silicate Inorganic materials 0.000 claims description 32
235000017557 sodium bicarbonate Nutrition 0.000 claims description 28
229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 28
239000002245 particle Substances 0.000 claims description 22
230000036571 hydration Effects 0.000 claims description 21
238000006703 hydration reaction Methods 0.000 claims description 21
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 16
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 14
229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 14
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 13
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 12
239000011324 bead Substances 0.000 claims description 12
229910001424 calcium ion Inorganic materials 0.000 claims description 12
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
239000011734 sodium Substances 0.000 claims description 11
229910052708 sodium Inorganic materials 0.000 claims description 10
239000004927 clay Substances 0.000 claims description 8
229910000019 calcium carbonate Inorganic materials 0.000 claims description 7
238000005342 ion exchange Methods 0.000 claims description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
230000008961 swelling Effects 0.000 claims description 5
239000000203 mixture Substances 0.000 description 137
239000000047 product Substances 0.000 description 64
235000012216 bentonite Nutrition 0.000 description 48
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 45
229940092782 bentonite Drugs 0.000 description 43
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 40
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 35
239000000463 material Substances 0.000 description 33
235000017550 sodium carbonate Nutrition 0.000 description 33
238000001694 spray drying Methods 0.000 description 33
238000002156 mixing Methods 0.000 description 28
239000000126 substance Substances 0.000 description 24
239000007788 liquid Substances 0.000 description 23
235000019341 magnesium sulphate Nutrition 0.000 description 21
239000007787 solid Substances 0.000 description 21
102000004190 Enzymes Human genes 0.000 description 19
108090000790 Enzymes Proteins 0.000 description 19
229940088598 enzyme Drugs 0.000 description 19
238000005406 washing Methods 0.000 description 19
239000002304 perfume Substances 0.000 description 18
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 17
238000004519 manufacturing process Methods 0.000 description 17
229920002125 Sokalan® Polymers 0.000 description 16
238000007792 addition Methods 0.000 description 16
229910052943 magnesium sulfate Inorganic materials 0.000 description 16
238000000034 method Methods 0.000 description 16
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 15
238000009472 formulation Methods 0.000 description 15
239000000843 powder Substances 0.000 description 14
239000002002 slurry Substances 0.000 description 14
239000007864 aqueous solution Substances 0.000 description 13
238000012545 processing Methods 0.000 description 13
238000012360 testing method Methods 0.000 description 13
IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 12
230000015572 biosynthetic process Effects 0.000 description 12
235000013799 ultramarine blue Nutrition 0.000 description 12
239000000499 gel Substances 0.000 description 11
230000008569 process Effects 0.000 description 11
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 9
239000007795 chemical reaction product Substances 0.000 description 9
239000003795 chemical substances by application Substances 0.000 description 9
238000004140 cleaning Methods 0.000 description 9
239000011521 glass Substances 0.000 description 9
239000002609 medium Substances 0.000 description 9
229920000742 Cotton Polymers 0.000 description 8
-1 aluminum silicates Chemical class 0.000 description 8
230000008021 deposition Effects 0.000 description 8
238000001035 drying Methods 0.000 description 8
230000000694 effects Effects 0.000 description 8
239000000049 pigment Substances 0.000 description 8
239000000975 dye Substances 0.000 description 7
229910010272 inorganic material Inorganic materials 0.000 description 7
239000011147 inorganic material Substances 0.000 description 7
239000002808 molecular sieve Substances 0.000 description 7
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 7
239000000654 additive Substances 0.000 description 6
239000013078 crystal Substances 0.000 description 6
238000000354 decomposition reaction Methods 0.000 description 6
239000004744 fabric Substances 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000001509 sodium citrate Substances 0.000 description 6
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 6
239000000243 solution Substances 0.000 description 6
239000007921 spray Substances 0.000 description 6
YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical group C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 5
CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 5
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
239000006057 Non-nutritive feed additive Substances 0.000 description 5
229910019142 PO4 Inorganic materials 0.000 description 5
108010056079 Subtilisins Proteins 0.000 description 5
102000005158 Subtilisins Human genes 0.000 description 5
239000002250 absorbent Substances 0.000 description 5
230000002745 absorbent Effects 0.000 description 5
229910052783 alkali metal Inorganic materials 0.000 description 5
238000002425 crystallisation Methods 0.000 description 5
230000008025 crystallization Effects 0.000 description 5
239000008367 deionised water Substances 0.000 description 5
229910021641 deionized water Inorganic materials 0.000 description 5
150000002500 ions Chemical class 0.000 description 5
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 5
235000021317 phosphate Nutrition 0.000 description 5
108091005804 Peptidases Proteins 0.000 description 4
102000035195 Peptidases Human genes 0.000 description 4
239000004902 Softening Agent Substances 0.000 description 4
238000010521 absorption reaction Methods 0.000 description 4
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 4
239000012736 aqueous medium Substances 0.000 description 4
150000001768 cations Chemical class 0.000 description 4
239000000428 dust Substances 0.000 description 4
150000002191 fatty alcohols Chemical class 0.000 description 4
239000011368 organic material Substances 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
239000010452 phosphate Substances 0.000 description 4
239000004014 plasticizer Substances 0.000 description 4
229920000728 polyester Polymers 0.000 description 4
238000005507 spraying Methods 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
240000007313 Tilia cordata Species 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 3
230000000996 additive effect Effects 0.000 description 3
230000002411 adverse Effects 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
230000008901 benefit Effects 0.000 description 3
239000011575 calcium Substances 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
239000007859 condensation product Substances 0.000 description 3
238000001704 evaporation Methods 0.000 description 3
230000008020 evaporation Effects 0.000 description 3
239000000945 filler Substances 0.000 description 3
239000012467 final product Substances 0.000 description 3
239000006081 fluorescent whitening agent Substances 0.000 description 3
238000001879 gelation Methods 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
230000006872 improvement Effects 0.000 description 3
239000000395 magnesium oxide Substances 0.000 description 3
229910052700 potassium Inorganic materials 0.000 description 3
239000011591 potassium Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
150000004760 silicates Chemical class 0.000 description 3
238000007711 solidification Methods 0.000 description 3
230000008023 solidification Effects 0.000 description 3
239000000725 suspension Substances 0.000 description 3
108091005658 Basic proteases Proteins 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
241000872931 Myoporum sandwicense Species 0.000 description 2
239000004677 Nylon Substances 0.000 description 2
230000035508 accumulation Effects 0.000 description 2
238000009825 accumulation Methods 0.000 description 2
230000009471 action Effects 0.000 description 2
239000004480 active ingredient Substances 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
230000000844 anti-bacterial effect Effects 0.000 description 2
239000007844 bleaching agent Substances 0.000 description 2
229940043430 calcium compound Drugs 0.000 description 2
150000001674 calcium compounds Chemical class 0.000 description 2
239000000292 calcium oxide Substances 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
150000001860 citric acid derivatives Chemical class 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000013068 control sample Substances 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000007423 decrease Effects 0.000 description 2
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical group [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 2
150000004677 hydrates Chemical class 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
229910001425 magnesium ion Inorganic materials 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
229910052901 montmorillonite Inorganic materials 0.000 description 2
229920001778 nylon Polymers 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
239000011148 porous material Substances 0.000 description 2
239000000523 sample Substances 0.000 description 2
239000004576 sand Substances 0.000 description 2
229940080314 sodium bentonite Drugs 0.000 description 2
229910000280 sodium bentonite Inorganic materials 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
XCMDVRAWAIYDEE-UHFFFAOYSA-N 1,2-diphenyl-3h-pyrazole Chemical class C1C=CN(C=2C=CC=CC=2)N1C1=CC=CC=C1 XCMDVRAWAIYDEE-UHFFFAOYSA-N 0.000 description 1
QWZHDKGQKYEBKK-UHFFFAOYSA-N 3-aminochromen-2-one Chemical compound C1=CC=C2OC(=O)C(N)=CC2=C1 QWZHDKGQKYEBKK-UHFFFAOYSA-N 0.000 description 1
REJHVSOVQBJEBF-OWOJBTEDSA-N 5-azaniumyl-2-[(e)-2-(4-azaniumyl-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical compound OS(=O)(=O)C1=CC(N)=CC=C1\C=C\C1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-OWOJBTEDSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
239000004382 Amylase Substances 0.000 description 1
229920004934 Dacron® Polymers 0.000 description 1
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
108090000787 Subtilisin Proteins 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
239000002671 adjuvant Substances 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
230000003625 amylolytic effect Effects 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
238000013459 approach Methods 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000002585 base Substances 0.000 description 1
150000003842 bromide salts Chemical class 0.000 description 1
238000001354 calcination Methods 0.000 description 1
ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
HFNQLYDPNAZRCH-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O.OC(O)=O HFNQLYDPNAZRCH-UHFFFAOYSA-N 0.000 description 1
JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical class O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
150000001767 cationic compounds Chemical class 0.000 description 1
230000008859 change Effects 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003086 colorant Substances 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
239000002537 cosmetic Substances 0.000 description 1
238000005336 cracking Methods 0.000 description 1
MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
239000011363 dried mixture Substances 0.000 description 1
238000010410 dusting Methods 0.000 description 1
229910052675 erionite Inorganic materials 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
239000000834 fixative Substances 0.000 description 1
230000009969 flowable effect Effects 0.000 description 1
239000007850 fluorescent dye Substances 0.000 description 1
239000006260 foam Substances 0.000 description 1
230000006870 function Effects 0.000 description 1
239000007789 gas Substances 0.000 description 1
JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
239000008233 hard water Substances 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
230000003165 hydrotropic effect Effects 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
230000003993 interaction Effects 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
229910052680 mordenite Inorganic materials 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
239000003973 paint Substances 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000867 polyelectrolyte Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
230000002028 premature Effects 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000012958 reprocessing Methods 0.000 description 1
210000002374 sebum Anatomy 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000000344 soap Substances 0.000 description 1
229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
235000021286 stilbenes Nutrition 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
235000007586 terpenes Nutrition 0.000 description 1
230000009974 thixotropic effect Effects 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1
238000005303 weighing Methods 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
229910001845 yogo sapphire Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Biochemistry (AREA)
Detergent Compositions (AREA)

CH1136/82A 1981-02-26 1982-02-24 Freifliessende spruehgetrocknete hohlkuegelchen. CH652416A5 (de)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date
US23862081A	1981-02-26	1981-02-26
US23861981A	1981-02-26	1981-02-26
US27955081A	1981-07-01	1981-07-01

Publications (1)

Publication Number	Publication Date
CH652416A5 true CH652416A5 (de)	1985-11-15

Family

ID=27399126

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH1136/82A CH652416A5 (de)	1981-02-26	1982-02-24	Freifliessende spruehgetrocknete hohlkuegelchen.

Country Status (22)

Country	Link
AT (1)	AT388172B (da)
AU (1)	AU549000B2 (da)
BR (1)	BR8200996A (da)
CA (1)	CA1188953A (da)
CH (1)	CH652416A5 (da)
DE (1)	DE3206265C2 (da)
DK (1)	DK160885C (da)
DO (1)	DOP1982003096A (da)
ES (1)	ES509904A0 (da)
FR (1)	FR2500475B1 (da)
GB (1)	GB2097419B (da)
GR (1)	GR76028B (da)
HK (1)	HK36190A (da)
IE (1)	IE52739B1 (da)
IT (1)	IT1147643B (da)
MX (1)	MX158565A (da)
NL (1)	NL8200804A (da)
NO (1)	NO153736C (da)
NZ (1)	NZ199773A (da)
PT (1)	PT74486B (da)
SE (2)	SE452773B (da)
ZW (2)	ZW3382A1 (da)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU549122B2 (en) *	1981-02-26	1986-01-16	Colgate-Palmolive Pty. Ltd.	Spray dried base beads and detergent compositions
ATE20476T1 (de) *	1983-04-08	1986-07-15	Procter & Gamble	Granulierte detergenszusammensetzungen, welche ein gemischtes polymerzusatzsystem enthalten.
US4490271A (en) *	1983-06-30	1984-12-25	The Procter & Gamble Company	Detergent compositions containing polyethylene glycol and polyacrylate
US4510066A (en) *	1983-07-06	1985-04-09	Colgate-Palmolive Company	Retarding setting of crutcher slurry for manufacturing base beads for detergent compositions
FR2568790B1 (fr) *	1984-08-10	1990-01-12	Rhone Poulenc Chim Base	Procede d'obtention d'une suspension aqueuse stable et pompable de zeolite et suspension ainsi obtenue
DE3444960A1 (de) *	1984-12-10	1986-06-12	Henkel KGaA, 4000 Düsseldorf	Koerniges adsorptionsmittel
SE466963B (sv) *	1984-12-24	1992-05-04	Colgate Palmolive Co	Textilmjukgoerande hoegverkande flytande detergent med stabil viskositet
CA1297376C (en) *	1985-11-01	1992-03-17	David Philip Jones	Detergent compositions, components therefor, and processes for theirpreparation
GB8526999D0 (en) *	1985-11-01	1985-12-04	Unilever Plc	Detergent compositions
DE3545947A1 (de) *	1985-12-23	1987-07-02	Henkel Kgaa	Phosphatfreies, granulares waschmittel
GB8607388D0 (en) *	1986-03-25	1986-04-30	Unilever Plc	Activator compositions
CA1286563C (en) *	1986-04-04	1991-07-23	Jan Hendrik Eertink	Detergent powders and processes for preparing them
GB8609044D0 (en) *	1986-04-14	1986-05-21	Unilever Plc	Detergent powders
DE3641314A1 (de) *	1986-12-03	1988-06-09	Henkel Kgaa	Waeschenachbehandlungsmittel auf der basis von schichtsilikat
GB8709057D0 (en) *	1987-04-15	1987-05-20	Unilever Plc	Composition for softening fabrics
DE3715052A1 (de) *	1987-05-06	1988-11-17	Degussa	Koerniges adsorptionsmittel
DE3717227A1 (de) *	1987-05-21	1988-12-01	Henkel Kgaa	Phosphatfreies waschmittel mit reduzierter inkrustierungstendenz
DE3818660A1 (de) *	1987-06-05	1988-12-15	Colgate Palmolive Co	Freifliessendes, pulvriges geschirrwaschmittel und verfahren zur herstellung desselben
GB2194793A (en) *	1987-10-15	1988-03-16	Unilever Plc	Mottled liquid detergents
GB8823008D0 (en) *	1988-09-30	1988-11-09	Unilever Plc	Composition for softening fabrics
DE3835918A1 (de)	1988-10-21	1990-04-26	Henkel Kgaa	Verfahren zur herstellung von tensidhaltigen granulaten
GB8918984D0 (en) *	1989-08-21	1989-10-04	Unilever Plc	Detergent compositions
DE3943019A1 (de) *	1989-12-27	1991-07-04	Henkel Kgaa	Granulares, avivierend wirkendes waschmitteladditiv und verfahren zu seiner herstellung
GB9008462D0 (en) *	1990-04-12	1990-06-13	Ecc Int Ltd	Granules for detergent compositions
DE69112970T2 (de) *	1990-09-28	1996-03-21	Kao Corp	Nichtionische pulverförmige Detergentzusammensetzung.
AU649504B2 (en) *	1991-07-03	1994-05-26	Kao Corporation	Nonionic powder detergent composition
AU3524093A (en) *	1992-03-27	1993-09-30	Kao Corporation	Nonionic powdery detergent composition and process for producing the same
AU4324693A (en) *	1992-06-18	1994-01-04	Unilever Plc	Machine dishwashing composition
AU660101B2 (en) *	1992-08-07	1995-06-08	Colgate-Palmolive Company, The	Heavy duty laundry detergent compositions of reduced dye transfer properties
TR27896A (tr) *	1993-08-05	1995-10-11	Colgate Palmolive Co	Boya transferi özellikleri düsürülmüs agir is camasir deterjani bilesimleri.
DE19538028A1 (de) *	1995-10-12	1997-04-17	Sued Chemie Ag	Waschmittelzusatz
DE19538029A1 (de) *	1995-10-12	1997-04-17	Sued Chemie Ag	Waschmittelzusatz
US5962389A (en) *	1995-11-17	1999-10-05	The Dial Corporation	Detergent having improved color retention properties
US5726142A (en) *	1995-11-17	1998-03-10	The Dial Corp	Detergent having improved properties and method of preparing the detergent
DE19858888A1 (de) *	1998-12-19	2000-06-21	Henkel Kgaa	Verhinderung von Ablagerungen
WO2000039265A1 (fr) *	1998-12-28	2000-07-06	Kao Corporation	Procede de fabrication de granules pour surfactant de support
GB2348435A (en) *	1999-04-01	2000-10-04	Procter & Gamble	Softening compositions
GB2348434A (en) *	1999-04-01	2000-10-04	Procter & Gamble	Detergent compositions
CN1170921C (zh) *	1999-06-14	2004-10-13	花王株式会社	基本颗粒物和颗粒状洗涤剂
ID28222A (id) *	1999-06-14	2001-05-10	Kao Corp	Butiran untuk menampung surfaktan dan metode untuk menghasilkan butiran tersebut
DE60040462D1 (de) *	1999-06-16	2008-11-20	Kao Corp	Teilchenförmiges waschmitteladditiv
US6333005B1 (en) *	1999-06-16	2001-12-25	Hercules Incorporated	Methods of preventing scaling involving inorganic compositions in combination with copolymers of maleic anhydride and isobutylene, and compositions therefor
DE19938640A1 (de) *	1999-08-14	2001-02-15	Henkel Kgaa	Verhinderung von Ablagerungen
DE10032127A1 (de) *	2000-07-05	2002-01-24	Henkel Kgaa	Mechanisch stabile Soda-Partikel
DE10040631A1 (de) *	2000-08-16	2002-03-07	Wolfram Koch	Vergilbungshemmer für Blue Denim Textilien
EP1987120B2 (en) *	2006-02-24	2013-09-11	Unilever PLC	Fast release granules
CN101868526B (zh) *	2007-11-16	2014-07-16	花王株式会社	洗净剂助剂颗粒
US20240156100A1 (en) *	2022-11-11	2024-05-16	Ken W Donovan	Odor and microbial mitigation solution
WO2024240517A1 (en) *	2023-05-22	2024-11-28	Basf Se	Solid composition comprising at least one organic chemical compound and at least one ceramic oxide

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4166039A (en) *	1973-10-15	1979-08-28	The Proctor & Gamble Company	Detergent composition and process
DE2547389A1 (de) *	1975-10-23	1977-05-05	Henkel & Cie Gmbh	Phosphatfreies waschmittel
NZ188469A (en) *	1977-10-06	1980-12-19	Colgate Palmolive Co	Detergent composition comprising a univalent cation-exchanging zeolite a nonionic detergent and builder salts
US4303556A (en) *	1977-11-02	1981-12-01	The Procter & Gamble Company	Spray-dried detergent compositions
GB2063289B (en) *	1979-11-13	1984-02-22	Unilever Ltd	Low phosphate spray-dried powders

1982
- 1982-02-09 AU AU80283/82A patent/AU549000B2/en not_active Ceased
- 1982-02-10 DO DO1982003096A patent/DOP1982003096A/es unknown
- 1982-02-17 GR GR67338A patent/GR76028B/el unknown
- 1982-02-18 NZ NZ199773A patent/NZ199773A/en unknown
- 1982-02-20 DE DE3206265A patent/DE3206265C2/de not_active Expired
- 1982-02-23 ZW ZW33/82A patent/ZW3382A1/xx unknown
- 1982-02-23 ZW ZW32/82A patent/ZW3282A1/xx unknown
- 1982-02-24 CH CH1136/82A patent/CH652416A5/de not_active IP Right Cessation
- 1982-02-24 AT AT0069082A patent/AT388172B/de not_active IP Right Cessation
- 1982-02-25 PT PT74486A patent/PT74486B/pt not_active IP Right Cessation
- 1982-02-25 BR BR8200996A patent/BR8200996A/pt not_active IP Right Cessation
- 1982-02-25 IT IT47865/82A patent/IT1147643B/it active
- 1982-02-25 ES ES509904A patent/ES509904A0/es active Granted
- 1982-02-25 CA CA000397017A patent/CA1188953A/en not_active Expired
- 1982-02-25 DK DK083382A patent/DK160885C/da active
- 1982-02-25 SE SE8201170A patent/SE452773B/sv not_active IP Right Cessation
- 1982-02-25 FR FR8203113A patent/FR2500475B1/fr not_active Expired
- 1982-02-25 NO NO820589A patent/NO153736C/no unknown
- 1982-02-26 IE IE433/82A patent/IE52739B1/en not_active IP Right Cessation
- 1982-02-26 MX MX191612A patent/MX158565A/es unknown
- 1982-02-26 GB GB8205685A patent/GB2097419B/en not_active Expired
- 1982-02-26 NL NL8200804A patent/NL8200804A/nl active Search and Examination
1987
- 1987-09-08 SE SE8703474A patent/SE502089C2/sv not_active IP Right Cessation
1990
- 1990-05-10 HK HK361/90A patent/HK36190A/xx unknown

Also Published As

Publication number	Publication date
NZ199773A (en)	1984-11-09
DE3206265A1 (de)	1982-11-04
AU8028382A (en)	1982-09-02
IT1147643B (it)	1986-11-19
ES8305412A1 (es)	1983-04-01
ATA69082A (de)	1988-10-15
ZW3382A1 (en)	1982-06-16
SE8703474L (sv)	1987-09-08
DK160885C (da)	1991-10-21
IE820433L (en)	1982-08-26
MX158565A (es)	1989-02-15
SE8201170L (sv)	1982-08-27
FR2500475A1 (fr)	1982-08-27
IE52739B1 (en)	1988-02-03
ES509904A0 (es)	1983-04-01
GB2097419B (en)	1985-04-17
SE452773B (sv)	1987-12-14
DE3206265C2 (de)	1987-04-09
DK160885B (da)	1991-04-29
NO153736B (no)	1986-02-03
DK83382A (da)	1982-08-27
AT388172B (de)	1989-05-10
HK36190A (en)	1990-05-18
AU549000B2 (en)	1986-01-09
GR76028B (da)	1984-08-03
SE8703474D0 (sv)	1987-09-08
DOP1982003096A (es)	1987-11-17
NL8200804A (nl)	1982-09-16
FR2500475B1 (fr)	1985-06-28
IT8247865A0 (it)	1982-02-25
SE502089C2 (sv)	1995-08-14
NO153736C (no)	1986-05-14
BR8200996A (pt)	1983-01-04
GB2097419A (en)	1982-11-03
PT74486B (en)	1983-09-01
NO820589L (no)	1982-08-27
CA1188953A (en)	1985-06-18
ZW3282A1 (en)	1982-07-21

Legal Events

Date	Code	Title	Description
2024-10-31	PL	Patent ceased

Publication	Publication Date	Title
CH652416A5 (de)	1985-11-15	Freifliessende spruehgetrocknete hohlkuegelchen.
DE3206379C2 (da)	1991-03-07
DE3141136C2 (da)	1989-03-23
DE2753026C2 (da)	1990-04-19
DE3727727A1 (de)	1988-03-03	Schmutzfreisetzungsfoerderndes pet-poet copolymeres verfahren zum herstellen und anwendung desselben in waschmitteln
DE2843390C2 (da)	1987-06-25
DE3344098A1 (de)	1984-06-14	Teilchenfoermiger, als waschmittelzusatz geeigneter textilweichmacher
DE3518100A1 (de)	1985-12-05	Gewebeweichmachendes builderhaltiges waschmittel
AT394380B (de)	1992-03-25	Teilchenfoermiges und weichmachendes grobwaschmittel fuer textilien, verfahren zu seiner herstellung, agglomerierte bentonitteilchen fuer das waschmittel und verfahren zu ihrer herstellung
CH636124A5 (en)	1983-05-13	Easily disintegrating, water-insoluble detergent-builder agglomerate in particle form
AT397810B (de)	1994-07-25	Stabilisiertes, textilweichmachendes, flüssiges waschmittel
DE2843709A1 (de)	1979-04-26	Waschmittelgemische, die silan-zeolith-geruestsubstanzen enthalten
AT394863B (de)	1992-07-10	Textilweichmachendes fluessiges vollwaschmittel
DE2538680A1 (de)	1976-03-18	Freifliessende waschmittelpulver
JPS60262897A (ja)	1985-12-26	ビルダー入り粒状非イオン性洗剤組成物
EP0544670B1 (de)	1994-07-20	Sprühgetrocknetes, avivierend wirkendes waschmitteladditiv
DE2656009A1 (de)	1977-06-23	Phosphatfreies grobwaschmittel
DE3516548A1 (de)	1985-12-05	Teilchenfoermiges waschmittelprodukt mit einem gehalt an builder und nichtionischem tensid
DE2539429A1 (de)	1976-03-18	Verfahren zur herstellung von reinigungsmittelzusammensetzungen und nach dem verfahren hergestellte produkte
DE2655578A1 (de)	1977-06-16	Verfahren zur wiederaufbereitung von waschmittelpulvern
DE3943019A1 (de)	1991-07-04	Granulares, avivierend wirkendes waschmitteladditiv und verfahren zu seiner herstellung
DE2656251A1 (de)	1977-06-16	Waschmittel
AT384436B (de)	1987-11-10	Frei fliessfaehige, koernige, phosphatfreie waschmittelzusammensetzung und verfahren zu ihrer herstellung
AT394381B (de)	1992-03-25	Weichmachendes waschmittel fuer textilien und verfahren zu seiner herstellung
DE3542080A1 (de)	1986-06-05	Antistatische, teilchenfoermige, builder enthaltende waschmittelzusammensetzung