CH686439A5 - Verfahren zur Herstellung von farbigen Acrylatkunststoffen mit metallisch glaenzenden Oberflaechen. - Google Patents

Verfahren zur Herstellung von farbigen Acrylatkunststoffen mit metallisch glaenzenden Oberflaechen. Download PDF

Info

Publication number: CH686439A5
Authority: CH; Switzerland
Prior art keywords: polymerization; acrylic; methacrylic resin; objects; degrees
Prior art date: 1993-04-28

Application number

CH112094A

Other languages

German (de)

English (en)

Inventor

Klaus Dr Kabs

Hans Lichtenstein

Original Assignee

Roehm Gmbh

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-04-28

Filing date

1994-04-14

Publication date

1996-03-29

1994-04-14 Application filed by Roehm Gmbh filed Critical Roehm Gmbh

1996-03-29 Publication of CH686439A5 publication Critical patent/CH686439A5/de

Links

238000004519 manufacturing process Methods 0.000 title claims description 10
238000006116 polymerization reaction Methods 0.000 claims description 47
239000000049 pigment Substances 0.000 claims description 36
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 19
238000000034 method Methods 0.000 claims description 16
239000011347 resin Substances 0.000 claims description 14
229920005989 resin Polymers 0.000 claims description 14
239000000178 monomer Substances 0.000 claims description 12
239000003086 colorant Substances 0.000 claims description 11
125000005395 methacrylic acid group Chemical group 0.000 claims description 10
239000004033 plastic Substances 0.000 claims description 10
229920003023 plastic Polymers 0.000 claims description 10
239000004925 Acrylic resin Substances 0.000 claims description 9
239000003999 initiator Substances 0.000 claims description 8
239000000113 methacrylic resin Substances 0.000 claims description 7
238000007493 shaping process Methods 0.000 claims description 7
238000006243 chemical reaction Methods 0.000 claims description 5
229920000642 polymer Polymers 0.000 description 12
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
239000011159 matrix material Substances 0.000 description 6
239000002245 particle Substances 0.000 description 6
238000009826 distribution Methods 0.000 description 5
230000000694 effects Effects 0.000 description 5
239000011324 bead Substances 0.000 description 4
238000004040 coloring Methods 0.000 description 4
238000005516 engineering process Methods 0.000 description 4
239000000945 filler Substances 0.000 description 4
239000000203 mixture Substances 0.000 description 4
229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
239000004926 polymethyl methacrylate Substances 0.000 description 4
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
229920000193 polymethacrylate Polymers 0.000 description 3
238000003756 stirring Methods 0.000 description 3
239000006188 syrup Substances 0.000 description 3
235000020357 syrup Nutrition 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
229920000178 Acrylic resin Polymers 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
206010038743 Restlessness Diseases 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
238000010276 construction Methods 0.000 description 2
230000004069 differentiation Effects 0.000 description 2
239000000976 ink Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
239000002243 precursor Substances 0.000 description 2
238000007639 printing Methods 0.000 description 2
238000005496 tempering Methods 0.000 description 2
239000002966 varnish Substances 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 description 1
DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
238000000137 annealing Methods 0.000 description 1
239000001000 anthraquinone dye Substances 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
230000031700 light absorption Effects 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000002932 luster Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
239000010445 mica Substances 0.000 description 1
229910052618 mica group Inorganic materials 0.000 description 1
DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 description 1
150000002898 organic sulfur compounds Chemical class 0.000 description 1
239000003973 paint Substances 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
230000000750 progressive effect Effects 0.000 description 1
FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
238000005204 segregation Methods 0.000 description 1
238000007873 sieving Methods 0.000 description 1
239000005368 silicate glass Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000003017 thermal stabilizer Substances 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Graft Or Block Polymers (AREA)
Compositions Of Macromolecular Compounds (AREA)
Polymerisation Methods In General (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Treatments Of Macromolecular Shaped Articles (AREA)
Physical Vapour Deposition (AREA)
Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Wrappers (AREA)

CH112094A 1993-04-28 1994-04-14 Verfahren zur Herstellung von farbigen Acrylatkunststoffen mit metallisch glaenzenden Oberflaechen. CH686439A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE4313924A DE4313924C2 (de)	1993-04-28	1993-04-28	Verfahren zur Herstellung von farbigen Acrylatkunststoffen mit einer metallisch glänzenden Oberfläche

Publications (1)

Publication Number	Publication Date
CH686439A5 true CH686439A5 (de)	1996-03-29

Family

ID=6486608

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH112094A CH686439A5 (de)	1993-04-28	1994-04-14	Verfahren zur Herstellung von farbigen Acrylatkunststoffen mit metallisch glaenzenden Oberflaechen.

Country Status (8)

Country	Link
AT (1)	AT403920B (it)
CH (1)	CH686439A5 (it)
DE (1)	DE4313924C2 (it)
ES (1)	ES2094684B1 (it)
FR (1)	FR2704550B1 (it)
GB (1)	GB2277521B (it)
IT (1)	IT1273161B (it)
NL (1)	NL194673C (it)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4443355A1 (de) *	1994-12-06	1996-06-13	Roehm Gmbh	Flugzeugverglasung mit erhöhter Lichtstabilität, verbesserter chemischer Stabilität und verbesserter Wärmeformbeständigkeit
DE102015115769A1 (de)	2015-09-18	2017-03-23	Schock Gmbh	Gießformkörper

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1080549A (en) *	1964-12-29	1967-08-23	Ici Ltd	Improvements in or relating to light transmitting polymeric sheet
GB2007695A (en) *	1977-11-14	1979-05-23	Ici Ltd	Decorative acrylic sheet and articles
JPS60210B2 (ja) *	1978-09-19	1985-01-07	三菱レイヨン株式会社	パ−ル板の連続製造方法
DE3023964A1 (de) *	1980-06-26	1982-01-21	Röhm GmbH, 6100 Darmstadt	Verfahren zur erzeugung oberflaechennaher, farbmittelhaltiger zonen in acryl- und methacrylharzen
DE3323951A1 (de) *	1983-07-02	1985-01-03	Röhm GmbH, 6100 Darmstadt	Acrylatharze als bindemittel fuer farbmittelkonzentrate
JPS61108634A (ja) *	1984-11-01	1986-05-27	Kyowa Gas Chem Ind Co Ltd	表面が粗面化されたポリメチルメタクリレ−ト系成型品の製造方法
AT385511B (de) *	1986-06-05	1988-04-11	Pfeffer Wolfgang Mag Dr	Optisch dekorativer formkoerper mit glitzerndem oberflaecheneffekt
AU631782B2 (en) *	1987-12-04	1992-12-10	E.I. Du Pont De Nemours And Company	Cast polymeric sink with high thermal cycling resistance
US5025041A (en) *	1989-06-15	1991-06-18	Ciba-Geigy Corporation	Pearlescent coating compositions
US5049442A (en) *	1990-01-23	1991-09-17	Basf Corporation	Opalescent coatings containing foamed metal oxides
JP2567726B2 (ja) *	1990-09-04	1996-12-25	三菱レイヨン株式会社	メタクリル樹脂板の製造方法
DE4040602A1 (de) *	1990-12-19	1992-07-02	Schock & Co Gmbh	Gegossene kunststofformteile

1993
- 1993-04-28 DE DE4313924A patent/DE4313924C2/de not_active Expired - Fee Related
1994
- 1994-03-24 AT AT0062294A patent/AT403920B/de not_active IP Right Cessation
- 1994-04-14 CH CH112094A patent/CH686439A5/de not_active IP Right Cessation
- 1994-04-25 FR FR9404938A patent/FR2704550B1/fr not_active Expired - Fee Related
- 1994-04-26 ES ES09400873A patent/ES2094684B1/es not_active Expired - Fee Related
- 1994-04-27 IT ITTO940337A patent/IT1273161B/it active IP Right Grant
- 1994-04-28 NL NL9400690A patent/NL194673C/nl not_active IP Right Cessation
- 1994-04-28 GB GB9408427A patent/GB2277521B/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
GB9408427D0 (en)	1994-06-22
ITTO940337A1 (it)	1995-10-27
GB2277521B (en)	1996-09-25
GB2277521A (en)	1994-11-02
DE4313924A1 (de)	1994-11-03
ES2094684B1 (es)	1997-12-16
FR2704550B1 (fr)	1996-03-08
AT403920B (de)	1998-06-25
NL194673B (nl)	2002-07-01
ES2094684A1 (es)	1997-01-16
ATA62294A (de)	1997-11-15
NL194673C (nl)	2002-11-04
NL9400690A (nl)	1994-11-16
FR2704550A1 (fr)	1994-11-04
ITTO940337A0 (it)	1994-04-27
DE4313924C2 (de)	2002-07-18
IT1273161B (it)	1997-07-07

Legal Events

Date	Code	Title	Description
2004-12-15	PL	Patent ceased

Publication	Publication Date	Title
EP1812484B1 (de)	2008-12-03	Kern-mantel-partikel
EP2217658B1 (de)	2011-04-20	Formkörper mit matter und strukturierter oberflächenbeschaffenheit
EP0130576B1 (de)	1990-01-17	Farbmittelkonzentrate, Acrylatharze als Bindemittel enthaltend
EP0748818A2 (de)	1996-12-18	Hochgefüllte Kunststoffe mit Glitzereffekt
DE3528165C2 (de)	1994-07-07	Mittels vernetzter Perlen eingetrübte Kunststoffelemente
EP1469952A1 (de)	2004-10-27	Formkörper aus kern-mantel-partikeln
EP0731116A2 (de)	1996-09-11	Verfahren zur Herstellung hochgefüllter Kunststoffe
EP0491170B1 (de)	1996-05-08	Gegossene Kunststofformteile
EP0640651B1 (de)	1997-01-29	Hochgefüllte Kunststoff-Formkörper mit Graniteffekt
DE10357679A1 (de)	2005-07-07	Effektfarbmittel enthaltend Kern-Mantel-Partikel
DE4327610A1 (de)	1995-02-23	Verfahren zur Herstellung gegossener, hochgefüllter Polymethylmethacrylat-Formteile
DE69510531T2 (de)	2000-03-23	Thermoformbare Acrylplatte, deren Herstellungsverfahren sowie daraus thermogeformte granitähnliche Gegenstände
EP0659786B1 (de)	1998-03-18	Kunststoff-Sanitärobjekte mit verbesserten Eigenschaften
AT403920B (de)	1998-06-25	Verfahren zur herstellung von objekten aus kunststoffen auf acryl- und/oder methacrylharzbasis, die metallisch glänzende oberflächen aufweisen
EP1495297A2 (de)	2005-01-12	Dehnungs- und stauchungssensor
DE4343868A1 (de)	1995-06-29	Verfahren zur Herstellung von hochgefülltem Kunststoff-Plattenmaterial
EP0060935B1 (de)	1986-02-19	Verfahren zur Herstellung von Acrylatkunststoffen mit einer farblich differenzierten Oberfläche
DE3821116B4 (de)	2006-07-13	Verfahren zur Herstellung von eingefärbten Polyacrylatplatten
CH686498A5 (de)	1996-04-15	Polymerisatformstuecke mit metallisch glaenzenden, gegebenenfalls farbigen Oberflaechen.
DE3028484C2 (it)	1990-04-12
EP0346691A2 (de)	1989-12-20	Verfahren zum Färben thermoplastischer Kunststoffe in der Masse
EP2108463A1 (de)	2009-10-14	Verfahren zur Herstellung von Effektlacklerungen und ihre Verwendung