CL2016001422A1 - Proceso para la producción de gas de síntesis. - Google Patents
Proceso para la producción de gas de síntesis.Info
- Publication number
- CL2016001422A1 CL2016001422A1 CL2016001422A CL2016001422A CL2016001422A1 CL 2016001422 A1 CL2016001422 A1 CL 2016001422A1 CL 2016001422 A CL2016001422 A CL 2016001422A CL 2016001422 A CL2016001422 A CL 2016001422A CL 2016001422 A1 CL2016001422 A1 CL 2016001422A1
- Authority
- CL
- Chile
- Prior art keywords
- stream
- hydrocarbon feedstock
- production
- synthesis gas
- hydrogen
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/102—Removal of contaminants of acid contaminants
- C10L3/103—Sulfur containing contaminants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0495—Composition of the impurity the impurity being water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1247—Higher hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1258—Pre-treatment of the feed
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1258—Pre-treatment of the feed
- C01B2203/1264—Catalytic pre-treatment of the feed
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1258—Pre-treatment of the feed
- C01B2203/1264—Catalytic pre-treatment of the feed
- C01B2203/127—Catalytic desulfurisation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
- C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/16—Controlling the process
- C01B2203/169—Controlling the feed
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
- C10L2290/541—Absorption of impurities during preparation or upgrading of a fuel
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Un proceso para la producción de un gas de síntesis para su uso en la producción de compuestos químicos a partir de una materia prima de hidrocarburo que contiene hidrocarburos superiores, que comprende los pasos que consisten en: (a) dividir la materia prima de hidrocarburo en por lo menos dos corrientes, la primera corriente en la forma de una corriente principal de materia prima de hidrocarburo y la segunda corriente en la forma de una corriente de derivación de materia prima de hidrocarburo; (b) agregar vapor a la corriente principal de materia prima de hidrocarburo y prereformar esta corriente a un gas pre-reformado que contiene metano, hidrógeno, monóxido de carbono, dióxido do carbono e hidrocarburos superiores; (c) combinar la corriente derivada de materia prima de hidrocarburo del peso (a) con el gas prereformado del paso (b) y pre-reformar el gas combinado de esta manera a un gas pre-reformado que contiene metano, hidrógeno, monóxido de carbono y dióxido de carbono; (d) reformar en una etapa de reformado el gas pre-reformado del paso (c) en un gas de síntesis que contiene hidrógeno, monóxido de carbono y dióxido de carbono.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA201370764 | 2013-12-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CL2016001422A1 true CL2016001422A1 (es) | 2017-01-06 |
Family
ID=52021215
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CL2016001422A CL2016001422A1 (es) | 2013-12-12 | 2016-06-09 | Proceso para la producción de gas de síntesis. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9890041B2 (es) |
| KR (2) | KR102492899B1 (es) |
| AU (1) | AU2014363523B2 (es) |
| BR (1) | BR112016013624A2 (es) |
| CA (1) | CA2933420C (es) |
| CL (1) | CL2016001422A1 (es) |
| EA (1) | EA031571B1 (es) |
| MX (1) | MX375875B (es) |
| SA (1) | SA516371275B1 (es) |
| UA (1) | UA120173C2 (es) |
| WO (1) | WO2015086752A1 (es) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102764053B1 (ko) * | 2016-02-26 | 2025-02-07 | 토프쉐 에이/에스 | Soec에 의해 최적화된 일산화탄소 생산 과정 |
| FR3053034A1 (fr) * | 2016-06-22 | 2017-12-29 | Gauchi Georges Martino | Procede de fabrication d'hydrogene de schiste |
| KR102517055B1 (ko) * | 2016-12-13 | 2023-04-04 | 토프쉐 에이/에스 | 합성 가스 제조를 위한 시스템 및 방법 |
| US10370248B2 (en) | 2017-01-27 | 2019-08-06 | L'air Liquide Societe Anonyme Pour L'etude | Maximizing steam methane reformer combustion efficiency by pre-heating pre-reformed fuel gas |
| US10870810B2 (en) * | 2017-07-20 | 2020-12-22 | Proteum Energy, Llc | Method and system for converting associated gas |
| ES2982501T3 (es) * | 2017-07-25 | 2024-10-16 | Topsoe As | Método para mejorar la eficiencia de una planta de gas de síntesis para la producción de amoniaco |
| AU2018305877B2 (en) * | 2017-07-25 | 2024-04-18 | Haldor Topsøe A/S | Method for the preparation of synthesis gas |
| UA127414C2 (uk) * | 2017-07-25 | 2023-08-16 | Хальдор Топсьое А/С | Спосіб отримання синтез-газу |
| EP3658494B1 (en) * | 2017-07-25 | 2022-01-19 | Haldor Topsøe A/S | Method for the preparation of synthesis gas |
| UA127164C2 (uk) * | 2017-07-25 | 2023-05-24 | Хальдор Топсьое А/С | Спосіб отримання газу для синтезу аміаку |
| AU2021226977A1 (en) | 2020-02-28 | 2022-07-28 | Topsoe A/S | Method for the preparation of synthesis gas |
| US12565423B2 (en) | 2023-01-26 | 2026-03-03 | Valero Services, Inc. | Process for producing hydrogen from natural gas |
| US20240400908A1 (en) | 2023-05-30 | 2024-12-05 | Arcadia eFuels US Inc. | Production of synthetic hydrocarbons |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3278452A (en) * | 1959-12-24 | 1966-10-11 | Pullman Inc | Production of hydrogen-containing gases |
| FR2560866B1 (fr) | 1984-03-09 | 1988-05-20 | Inst Francais Du Petrole | Nouveau procede de fabrication de gaz de synthese par oxydation indirecte d'hydrocarbures |
| CA1263671A (en) * | 1986-02-10 | 1989-12-05 | David Leon Banquy | Process for the production of synthesis gas |
| US6833126B2 (en) * | 2001-03-30 | 2004-12-21 | Industries Co., Ltd. | Method and apparatus for reforming fuel |
| US7967878B2 (en) | 2002-01-04 | 2011-06-28 | Meggitt (Uk) Limited | Reformer apparatus and method |
| GB0504755D0 (en) * | 2005-03-08 | 2005-04-13 | Rolls Royce Fuel Cell Systems | A fuel processor for a fuel cell arrangement and a method of operating a fuel processor for a fuel cell arrangement |
| MY145000A (en) * | 2005-03-14 | 2011-12-15 | Shell Int Research | Process to prepare a mixture of carbon monoxide and hydrogen |
| DE102006023248C5 (de) | 2006-05-18 | 2018-01-25 | Air Liquide Global E&C Solutions Germany Gmbh | Verfahren und Anlage zur Herstellung von Synthesegas |
| EP1927577A1 (en) | 2006-12-01 | 2008-06-04 | Casale Chemicals S.A. | Process for producing synthesis gas and related apparatus |
| DE102008039014A1 (de) | 2008-08-21 | 2010-02-25 | Uhde Gmbh | Mehrstufige Reaktorkaskade zur rußfreien Herstellung von Systhesegas |
| DK2419375T3 (en) | 2009-04-15 | 2016-07-25 | Air Prod & Chem | A process for producing a hydrogen-containing product gas |
-
2014
- 2014-12-11 AU AU2014363523A patent/AU2014363523B2/en active Active
- 2014-12-11 CA CA2933420A patent/CA2933420C/en active Active
- 2014-12-11 MX MX2016007322A patent/MX375875B/es active IP Right Grant
- 2014-12-11 BR BR112016013624-1A patent/BR112016013624A2/pt active Search and Examination
- 2014-12-11 US US15/039,242 patent/US9890041B2/en active Active
- 2014-12-11 KR KR1020227000494A patent/KR102492899B1/ko active Active
- 2014-12-11 WO PCT/EP2014/077394 patent/WO2015086752A1/en not_active Ceased
- 2014-12-11 UA UAA201607604A patent/UA120173C2/uk unknown
- 2014-12-11 KR KR1020167018129A patent/KR102349885B1/ko active Active
- 2014-12-11 EA EA201691228A patent/EA031571B1/ru not_active IP Right Cessation
-
2016
- 2016-06-09 SA SA516371275A patent/SA516371275B1/ar unknown
- 2016-06-09 CL CL2016001422A patent/CL2016001422A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US9890041B2 (en) | 2018-02-13 |
| KR20160097266A (ko) | 2016-08-17 |
| CA2933420A1 (en) | 2015-06-18 |
| KR20220008389A (ko) | 2022-01-20 |
| SA516371275B1 (ar) | 2019-07-01 |
| BR112016013624A2 (pt) | 2018-05-22 |
| AU2014363523B2 (en) | 2018-02-15 |
| UA120173C2 (uk) | 2019-10-25 |
| CA2933420C (en) | 2021-09-28 |
| KR102492899B1 (ko) | 2023-01-31 |
| MX2016007322A (es) | 2016-08-19 |
| EA031571B1 (ru) | 2019-01-31 |
| US20170022056A1 (en) | 2017-01-26 |
| AU2014363523A1 (en) | 2016-06-23 |
| EA201691228A1 (ru) | 2016-09-30 |
| MX375875B (es) | 2025-03-07 |
| KR102349885B1 (ko) | 2022-01-11 |
| WO2015086752A1 (en) | 2015-06-18 |
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