CL2017000975A1 - Process to produce liquid hydrogen - Google Patents

Process to produce liquid hydrogen

Info

Publication number
CL2017000975A1
CL2017000975A1 CL2017000975A CL2017000975A CL2017000975A1 CL 2017000975 A1 CL2017000975 A1 CL 2017000975A1 CL 2017000975 A CL2017000975 A CL 2017000975A CL 2017000975 A CL2017000975 A CL 2017000975A CL 2017000975 A1 CL2017000975 A1 CL 2017000975A1
Authority
CL
Chile
Prior art keywords
metal
hydrogen
gaseous hydrogen
stage
licuefaction
Prior art date
Application number
CL2017000975A
Other languages
Spanish (es)
Inventor
Nikunj Gupta
Thomas Pasfield
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of CL2017000975A1 publication Critical patent/CL2017000975A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/08—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of inorganic compounds with metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B5/00—Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/22—Inorganic acids
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/50—Processes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/087—Recycling of electrolyte to electrochemical cell
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0005—Light or noble gases
    • F25J1/001—Hydrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0244—Operation; Control and regulation; Instrumentation
    • F25J1/0245—Different modes, i.e. 'runs', of operation; Process control
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F25J1/0281—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc. characterised by the type of prime driver, e.g. hot gas expander
    • F25J1/0284—Electrical motor as the prime mechanical driver
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2260/00—Coupling of processes or apparatus to other units; Integrated schemes
    • F25J2260/30—Integration in an installation using renewable energy
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/62—Details of storing a fluid in a tank
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

<p>LA INVENCIÓN SE REFIERE A UN PROCESO INTEGRADO PARA LA PRODUCCIÓN CONTINUA DE HIDROGENO LIQUIDO, QUE COMPRENDE (A) PRODUCIR HIDROGENO GASEOSO POR ELECTROLISIS; Y (B) LICUAR DICHO HIDROGENO GASEOSO EN UNA UNIDAD DE LICUEFACCIÓN DE HIDROGENO, CUYA UNIDAD DE LICUEFACCIÓN ES ALIMENTADA POR ENERGÍA QUE PROVIENE DE MANERA ESENCIAL DE FUENTES RENOVABLES; Y (C) CUANDO SE NECESITA ENERGÍA ADICIONAL, USAR ENERGÍA ELÉCTRICA GENERADA EN UN PROCESO EN EL QUE SE COGENERAN ENERGÍA ELÉCTRICA E HIDROGENO PAR MEDIA DE UN PROCESO INTEGRADO DE ELECTRÓLISIS QUE COMPRENDE: (D) ELECTROLIZAR UNA SAL DE METAL O MEZCLA DE SALES DE METAL Y AGUA EN EL CORRESPONDIENTE METAL O METALES, ÁCIDO O ÁCIDOS Y OXIGENO (FASE DE ALMACENAMIENTO DE ELECTRICIDAD) Y (E) PRODUCIR HIDROGENO GASEOSO Y RECUPERAR ELECTRICIDAD EN UNA REACCIÓN DE REGENERACIÓN DE LOS METAL(ES) Y ÁCIDO(S) DE LA ETAPA (D) (FASE DE REGENERACIÓN); EN DONDE AL MENOS PARTE DEL HIDROGENO GASEOSO GENERADO EN IA ETAPA (E) SE USA EN LA ETAPA (B) DEL PROCESO.</p><p> THE INVENTION REFERS TO AN INTEGRATED PROCESS FOR THE CONTINUOUS PRODUCTION OF LIQUID HYDROGEN, WHICH INCLUDES (A) PRODUCING GASEOUS HYDROGEN BY ELECTROLYSIS; AND (B) LICUAR SUCH GASEOUS HYDROGEN IN A HYDROGEN LICUEFACTION UNIT, WHOSE LICUEFACTION UNIT IS POWERED BY ENERGY THAT COMES ESSENTIALLY FROM RENEWABLE SOURCES; AND (C) WHEN ADDITIONAL ENERGY IS NEEDED, USE ELECTRICAL ENERGY GENERATED IN A PROCESS IN WHICH ELECTRICAL ENERGY AND HYDROGEN WILL BE COGENED THROUGH AN INTEGRATED ELECTROLISIS PROCESS THAT INCLUDES: (D) ELECTROLLING A METAL SALT OR METAL SALT METAL AND WATER IN THE CORRESPONDING METAL OR METAL, ACID OR ACIDS AND OXYGEN (ELECTRICITY STORAGE PHASE) AND (E) PRODUCE GASEOUS HYDROGEN AND RECOVER ELECTRICITY IN A METAL (S) AND ACID (A) REGENERATION REACTION STAGE (D) (REGENERATION PHASE); WHERE AT LEAST PART OF THE GASEOUS HYDROGEN GENERATED IN THE STAGE (E) IS USED IN STAGE (B) OF THE PROCESS. </p>

CL2017000975A 2014-10-28 2017-04-20 Process to produce liquid hydrogen CL2017000975A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP14190677 2014-10-28

Publications (1)

Publication Number Publication Date
CL2017000975A1 true CL2017000975A1 (en) 2018-01-12

Family

ID=51795564

Family Applications (1)

Application Number Title Priority Date Filing Date
CL2017000975A CL2017000975A1 (en) 2014-10-28 2017-04-20 Process to produce liquid hydrogen

Country Status (7)

Country Link
US (1) US20170321332A1 (en)
CN (1) CN107074538A (en)
AU (1) AU2015340752B2 (en)
BR (1) BR112017007390A2 (en)
CL (1) CL2017000975A1 (en)
ES (1) ES2643558B1 (en)
WO (1) WO2016066571A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SI25573A (en) * 2017-12-13 2019-06-28 Univerza V Novi Gorici Procedure for storing electrical energy in solid matter
WO2019190305A1 (en) * 2018-03-27 2019-10-03 Harit Ecotech Sdn. Bhd. A hydroxygen generator for reducing carbon emission and increasing fuel efficieny
GB201811785D0 (en) * 2018-07-19 2018-09-05 Univ Surrey A continuous process for sustainable production of hydrogen
FR3098576B1 (en) * 2019-07-08 2022-04-29 Air Liquide Process and installation for the production of liquid hydrogen
EP4067533B1 (en) * 2021-03-30 2026-03-18 Linde GmbH Method and installation for the production of liquid hydrogen by means of electrolysis
US12535268B2 (en) * 2021-04-09 2026-01-27 Honda Motor Co., Ltd. Fuel cell power-supply management device and fuel cell power-supply management method
CN114909871B (en) * 2022-04-22 2023-05-09 湖南大学 A method and device for preparing liquid hydrogen by offshore off-grid superconducting wind power

Family Cites Families (13)

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Publication number Priority date Publication date Assignee Title
DE3036805A1 (en) * 1980-09-30 1982-05-06 Karlheinz 7321 Zell Hanzlik Electrolytic hydrogen generated from sunlight via solar cells - is liquefied and then used as motor vehicle fuel
US4910963A (en) * 1988-11-21 1990-03-27 Vanzo Gordon F Solar energy process
CN1352323A (en) * 2000-11-03 2002-06-05 穆瑞力 Method and apparatus for producing hydrogen by utilizing solar energy and/or wind energy
CN1854063A (en) * 2005-04-28 2006-11-01 黄潮 Electrochemical zinc-water hydrogen making and storing method
US20080127646A1 (en) * 2005-10-11 2008-06-05 Doland George J System and Method for Energy and Hydrogen Production
EP2132820A4 (en) * 2007-04-03 2014-12-24 New Sky Energy Inc Electrochemical system, apparatus, and method to generate renewable hydrogen and sequester carbon dioxide
CN101492825A (en) * 2009-01-05 2009-07-29 陈有孝 Process for producing hydrogen gas by using solar energy
FR2948654B1 (en) * 2009-07-30 2015-01-16 Gerkaro COGENERATION OF ELECTRIC ENERGY AND HYDROGEN
CN101892491A (en) * 2010-07-28 2010-11-24 张建洲 Comprehensive application system for generating electricity by natural energy and electrolyzing seawater or brackish water
CN102453922A (en) * 2010-11-03 2012-05-16 尹华文 Solar hydrogen production system engineering
WO2012159818A1 (en) * 2011-04-11 2012-11-29 Antecy B.V. Self-contained solar-powered energy supply and storage system
EP2751307B1 (en) * 2011-08-29 2015-09-09 Karl-Hermann Busse Power supply system, in particular for the field of building technology
AU2014100315A4 (en) * 2014-04-01 2014-05-01 Cooper, Bretton MR Liquid air facilitating renewable hydrogen exports

Also Published As

Publication number Publication date
ES2643558B1 (en) 2018-09-19
CN107074538A (en) 2017-08-18
AU2015340752B2 (en) 2018-02-01
BR112017007390A2 (en) 2018-02-14
US20170321332A1 (en) 2017-11-09
WO2016066571A1 (en) 2016-05-06
AU2015340752A1 (en) 2017-04-20
ES2643558A2 (en) 2017-11-23
ES2643558R1 (en) 2017-12-13

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