CL2017001753A1 - Proceso para obtener un gcc con altas propiedades de dispersión luminosas y alto contenido de sólidos - Google Patents
Proceso para obtener un gcc con altas propiedades de dispersión luminosas y alto contenido de sólidosInfo
- Publication number
- CL2017001753A1 CL2017001753A1 CL2017001753A CL2017001753A CL2017001753A1 CL 2017001753 A1 CL2017001753 A1 CL 2017001753A1 CL 2017001753 A CL2017001753 A CL 2017001753A CL 2017001753 A CL2017001753 A CL 2017001753A CL 2017001753 A1 CL2017001753 A1 CL 2017001753A1
- Authority
- CL
- Chile
- Prior art keywords
- gcc
- solids content
- dispersion properties
- calcium carbonate
- applications
- Prior art date
Links
- 239000006185 dispersion Substances 0.000 title 1
- 239000007787 solid Substances 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
- C09C1/021—Calcium carbonates
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K33/00—Medicinal preparations containing inorganic active ingredients
- A61K33/06—Aluminium, calcium or magnesium; Compounds thereof, e.g. clay
- A61K33/10—Carbonates; Bicarbonates
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
- C01F11/185—After-treatment, e.g. grinding, purification, conversion of crystal morphology
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/26—Carbonates
- C04B14/28—Carbonates of calcium
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
- C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Ceramic Engineering (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Civil Engineering (AREA)
- Pharmacology & Pharmacy (AREA)
- Epidemiology (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
<p>LA PRESENTE INVENCIÓN, TIENE RELACIÓN CON UN PROCESO PARA LA ELABORACIÓN DE UN MATERIAL QUE COMPRENDE CARBONATO DE CALCIO, UN MATERIAL QUE COMPRENDE CARBONATO DE CALCIO OBTENIDO MEDIANTE UN PROCESO, ASÍ COMO TAMBIÉN EL USO DEL MATERIAL QUE COMPRENDE CARBONATO DE CALCIO PARA APLICACIONES DE RELLENO DE PAPEL Y RECUBRIMIENTO DE PAPEL, APLICACIONES DE PAPEL PARA CIGARRILLOS, PARA APLICACIONES DE PLÁSTICOS O EN PINTURAS, RECUBRIMIENTOS, ADHESIVOS, REEMPLAZO DE DIÓXIDO DE TITANIO, PREFERENTEMENTE EN PINTURAS, SELLADORES, ALIMENTOS, PIENSOS, FARMACIA, HORMIGÓN, CEMENTOS, COSMÉTICOS, TRATAMIENTO DEL AGUA Y/O APLICACIONES PARA LA AGRICULTURA.</p>
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15150367.9A EP3042878B1 (en) | 2015-01-07 | 2015-01-07 | Process to obtain an ultrafine GCC with high light scattering properties and high solid content |
| US201562103095P | 2015-01-14 | 2015-01-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CL2017001753A1 true CL2017001753A1 (es) | 2018-03-16 |
Family
ID=52292781
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CL2017001753A CL2017001753A1 (es) | 2015-01-07 | 2017-06-30 | Proceso para obtener un gcc con altas propiedades de dispersión luminosas y alto contenido de sólidos |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US10619049B2 (es) |
| EP (2) | EP3042878B1 (es) |
| JP (1) | JP6499764B2 (es) |
| KR (1) | KR101964537B1 (es) |
| CN (1) | CN107109078A (es) |
| AR (1) | AR103358A1 (es) |
| AU (1) | AU2016206099B2 (es) |
| BR (1) | BR112017014566B1 (es) |
| CA (1) | CA2971773C (es) |
| CL (1) | CL2017001753A1 (es) |
| ES (1) | ES2728380T3 (es) |
| HR (1) | HRP20190885T1 (es) |
| MX (1) | MX2017008892A (es) |
| RU (1) | RU2663765C1 (es) |
| SI (1) | SI3042878T1 (es) |
| TW (1) | TWI627134B (es) |
| WO (1) | WO2016110459A1 (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3318599A1 (en) | 2016-11-07 | 2018-05-09 | Omya International AG | Use of mono-substituted succinic anhydride |
| EP3354622A1 (en) * | 2017-01-26 | 2018-08-01 | Omya International AG | Process for the preparation of fragmented natural calcium carbonate with a reduced content of impurities and products obtained thereof |
| EP3400810A1 (en) | 2017-05-11 | 2018-11-14 | Omya International AG | Surface-reacted calcium carbonate in food |
| RU2652031C1 (ru) * | 2017-07-11 | 2018-04-24 | Юлия Алексеевна Щепочкина | Способ подготовки полиакрилата натрия для введения в состав бетонной смеси (варианты) |
| EP3467050A1 (en) | 2017-10-04 | 2019-04-10 | Omya International AG | Coating compositions comprising ground natural calcium carbonate (gcc) |
| CN107935012B (zh) * | 2017-11-20 | 2020-03-31 | 广西河池华泰新材料科技有限公司 | 一种重质碳酸钙浆料脱水烘干方法 |
| US11905189B2 (en) * | 2018-05-10 | 2024-02-20 | Chad Daloia | Method of refining and recovering barium sulfate from contaminated water sources |
| EP3693339A1 (en) | 2019-02-01 | 2020-08-12 | Omya International AG | Production of surface-reacted calcium salts by grinding induced conversion |
| KR102849861B1 (ko) * | 2019-02-26 | 2025-08-26 | 옴야 인터내셔널 아게 | 분쇄된 탄산칼슘-포함 물질을 포함하는 수성 현탁액을 제조하는 방법 |
| FR3093011B1 (fr) * | 2019-02-26 | 2021-02-19 | Coatex Sas | Réduction de l’hygroscopicité d’un matériau minéral |
| KR102858549B1 (ko) | 2019-02-26 | 2025-09-12 | 옴야 인터내셔널 아게 | 표면-처리된 탄산칼슘 물질을 제조하는 방법 |
| EP3931265B1 (en) * | 2019-02-26 | 2025-06-25 | Omya International AG | Process for preparing a surface treated calcium carbonate material |
| EP3725851A1 (en) | 2019-04-16 | 2020-10-21 | Omya International AG | Process for preparing surface-reacted calcium carbonate |
| AR119243A1 (es) * | 2019-07-08 | 2021-12-01 | Omya Int Ag | Composición seca cosmética y/o para el cuidado de la piel |
| EP4225840A1 (en) | 2020-10-05 | 2023-08-16 | Omya International AG | Kit comprising surface-treated calcium carbonate and a peroxide agent for improving the mechanical properties of polyethylene/polypropylene compositions |
| WO2023187059A1 (en) | 2022-03-31 | 2023-10-05 | Omya International Ag | Calcium carbonate for improving the mechanical properties of thermoplastic polymer compositions |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1599632A (en) * | 1977-01-19 | 1981-10-07 | English Clays Lovering Pochin | Comminution of solid materials |
| US4793985A (en) | 1982-08-23 | 1988-12-27 | J. M. Huber Corporation | Method of producing ultrafine ground calcium carbonate |
| US5558850A (en) | 1990-07-27 | 1996-09-24 | Ecc International Limited | Precipitated calcium carbonate |
| US5533678A (en) | 1993-01-19 | 1996-07-09 | Pluess-Staufer Ag | Method for the production of carbonates by wet grinding |
| GB2275876B (en) | 1993-03-12 | 1996-07-17 | Ecc Int Ltd | Grinding alkaline earth metal pigments |
| GB9520703D0 (en) * | 1995-10-10 | 1995-12-13 | Ecc Int Ltd | Paper coating pigments and their production and use |
| ATE203261T1 (de) | 1996-03-13 | 2001-08-15 | Omya Ag | Streichfarbe |
| GB9627002D0 (en) * | 1996-12-27 | 1997-02-12 | Ecc Int Ltd | Dispersed aqueous suspensions |
| ES2194255T3 (es) | 1997-07-28 | 2003-11-16 | Omya Ag | Suspension que contiene un pigmento a partir de un carbonato aglomerado. |
| JPH1150068A (ja) | 1997-07-30 | 1999-02-23 | Tonen Corp | 燃料油添加剤及び該添加剤を含有する燃料油組成物 |
| WO2000039029A2 (en) | 1998-12-23 | 2000-07-06 | Imerys Minerals Ltd. | Production of concentrated carbonate suspensions |
| RU2172329C1 (ru) * | 2000-11-10 | 2001-08-20 | Открытое акционерное общество "Стройматериалы" | Способ получения наполнителя на основе карбоната кальция |
| FR2818165B1 (fr) | 2000-12-20 | 2003-10-31 | Coatex Sas | Agent d'aide au broyage de materiaux mineraux en suspension aqueuse. suspensions aqueuses obtenues et leurs utilisations |
| CN101090949B (zh) * | 2004-12-22 | 2013-06-05 | 索尔维公司 | 碱土金属碳酸盐的耐酸粒子 |
| WO2006120694A1 (en) | 2005-05-13 | 2006-11-16 | Anil Kelkar | Organic compound and process for inhibiting corrosion on metals |
| DK2143688T3 (en) * | 2008-07-07 | 2017-01-09 | Omya Int Ag | A process for the preparation of aqueous suspensions of calcium carbonate, and the resulting suspensions as well as uses thereof |
| EP2194103A1 (en) * | 2008-12-04 | 2010-06-09 | Omya Development Ag | Process for manufacturing calcium carbonate materials having a particle surface with improved adsorption properties |
| ES2438278T5 (es) * | 2009-07-01 | 2017-07-11 | Omya International Ag | Método de mejora de la opacidad |
| PT2546410E (pt) * | 2011-07-11 | 2014-02-17 | Omya Int Ag | Partículas de carbonato de cálcio hidrofobizado |
| DK2722368T3 (en) | 2012-10-16 | 2016-10-24 | Omya Int Ag | A method for the controlled chemical reaction of a solid filler material surface and additives to produce a surface treated filler material product |
| HUE026774T2 (en) | 2013-02-22 | 2016-08-29 | Omya Int Ag | New surface treatment of white minerals for use in plastics |
-
2015
- 2015-01-07 ES ES15150367T patent/ES2728380T3/es active Active
- 2015-01-07 EP EP15150367.9A patent/EP3042878B1/en active Active
- 2015-01-07 SI SI201530763T patent/SI3042878T1/sl unknown
- 2015-12-11 TW TW104141694A patent/TWI627134B/zh not_active IP Right Cessation
-
2016
- 2016-01-04 KR KR1020177021328A patent/KR101964537B1/ko active Active
- 2016-01-04 CN CN201680005190.3A patent/CN107109078A/zh active Pending
- 2016-01-04 US US15/538,373 patent/US10619049B2/en active Active
- 2016-01-04 CA CA2971773A patent/CA2971773C/en active Active
- 2016-01-04 BR BR112017014566-9A patent/BR112017014566B1/pt active IP Right Grant
- 2016-01-04 RU RU2017127902A patent/RU2663765C1/ru active
- 2016-01-04 MX MX2017008892A patent/MX2017008892A/es unknown
- 2016-01-04 AR ARP160100004A patent/AR103358A1/es unknown
- 2016-01-04 JP JP2017536022A patent/JP6499764B2/ja active Active
- 2016-01-04 WO PCT/EP2016/050006 patent/WO2016110459A1/en not_active Ceased
- 2016-01-04 AU AU2016206099A patent/AU2016206099B2/en active Active
- 2016-01-04 EP EP16700005.8A patent/EP3242856A1/en not_active Withdrawn
-
2017
- 2017-06-30 CL CL2017001753A patent/CL2017001753A1/es unknown
-
2019
- 2019-05-14 HR HRP20190885TT patent/HRP20190885T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2663765C1 (ru) | 2018-08-09 |
| MX2017008892A (es) | 2017-10-25 |
| KR20170102176A (ko) | 2017-09-07 |
| TWI627134B (zh) | 2018-06-21 |
| US20180009991A1 (en) | 2018-01-11 |
| CN107109078A (zh) | 2017-08-29 |
| BR112017014566A2 (pt) | 2018-03-27 |
| EP3042878A1 (en) | 2016-07-13 |
| AU2016206099B2 (en) | 2018-08-02 |
| AR103358A1 (es) | 2017-05-03 |
| CA2971773C (en) | 2020-11-10 |
| WO2016110459A1 (en) | 2016-07-14 |
| EP3042878B1 (en) | 2019-03-06 |
| EP3242856A1 (en) | 2017-11-15 |
| TW201630815A (zh) | 2016-09-01 |
| CA2971773A1 (en) | 2016-07-14 |
| BR112017014566B1 (pt) | 2022-01-25 |
| AU2016206099A1 (en) | 2017-08-24 |
| US10619049B2 (en) | 2020-04-14 |
| JP2018501185A (ja) | 2018-01-18 |
| KR101964537B1 (ko) | 2019-04-01 |
| JP6499764B2 (ja) | 2019-04-10 |
| HRP20190885T1 (hr) | 2019-09-20 |
| ES2728380T3 (es) | 2019-10-24 |
| SI3042878T1 (sl) | 2019-07-31 |
| AU2016206099A8 (en) | 2018-08-02 |
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