CN100370077C - Safety high efficient compound mildew-proof paper and preparation method thereof - Google Patents
Safety high efficient compound mildew-proof paper and preparation method thereof Download PDFInfo
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- CN100370077C CN100370077C CNB2005100323988A CN200510032398A CN100370077C CN 100370077 C CN100370077 C CN 100370077C CN B2005100323988 A CNB2005100323988 A CN B2005100323988A CN 200510032398 A CN200510032398 A CN 200510032398A CN 100370077 C CN100370077 C CN 100370077C
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- mildew
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- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 150000001875 compounds Chemical class 0.000 title claims description 18
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002131 composite material Substances 0.000 claims abstract description 21
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000853 adhesive Substances 0.000 claims abstract description 17
- 230000001070 adhesive effect Effects 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 235000019260 propionic acid Nutrition 0.000 claims abstract description 11
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims abstract description 11
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims abstract description 10
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 10
- 239000005711 Benzoic acid Substances 0.000 claims abstract description 9
- 235000010233 benzoic acid Nutrition 0.000 claims abstract description 9
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000010199 sorbic acid Nutrition 0.000 claims abstract description 9
- 239000004334 sorbic acid Substances 0.000 claims abstract description 9
- 229940075582 sorbic acid Drugs 0.000 claims abstract description 9
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000006013 carbendazim Substances 0.000 claims abstract description 7
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 6
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229930003268 Vitamin C Natural products 0.000 claims abstract description 5
- 229930003427 Vitamin E Natural products 0.000 claims abstract description 5
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 5
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 5
- 235000006708 antioxidants Nutrition 0.000 claims abstract description 5
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims abstract description 5
- 235000019154 vitamin C Nutrition 0.000 claims abstract description 5
- 239000011718 vitamin C Substances 0.000 claims abstract description 5
- 235000019165 vitamin E Nutrition 0.000 claims abstract description 5
- 229940046009 vitamin E Drugs 0.000 claims abstract description 5
- 239000011709 vitamin E Substances 0.000 claims abstract description 5
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 claims description 16
- 239000003112 inhibitor Substances 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000011265 semifinished product Substances 0.000 claims description 10
- 238000005303 weighing Methods 0.000 claims description 10
- 235000010292 orthophenyl phenol Nutrition 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 claims description 7
- 235000010331 calcium propionate Nutrition 0.000 claims description 7
- 239000004330 calcium propionate Substances 0.000 claims description 7
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 claims description 7
- 235000010334 sodium propionate Nutrition 0.000 claims description 7
- 239000004324 sodium propionate Substances 0.000 claims description 7
- 229960003212 sodium propionate Drugs 0.000 claims description 7
- 235000019504 cigarettes Nutrition 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 claims description 5
- MITFXPHMIHQXPI-UHFFFAOYSA-N benzoxaprofen Natural products N=1C2=CC(C(C(O)=O)C)=CC=C2OC=1C1=CC=C(Cl)C=C1 MITFXPHMIHQXPI-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- -1 propylben Chemical compound 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000000123 paper Substances 0.000 abstract description 35
- 241000208125 Nicotiana Species 0.000 abstract description 20
- 235000002637 Nicotiana tabacum Nutrition 0.000 abstract description 20
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 3
- 210000000056 organ Anatomy 0.000 abstract description 2
- 230000000638 stimulation Effects 0.000 abstract description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- 230000002265 prevention Effects 0.000 abstract 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 abstract 2
- 241001465754 Metazoa Species 0.000 abstract 1
- 229960004365 benzoic acid Drugs 0.000 abstract 1
- 239000002655 kraft paper Substances 0.000 abstract 1
- 229960003742 phenol Drugs 0.000 abstract 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 abstract 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 abstract 1
- 229960003415 propylparaben Drugs 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 8
- 238000012856 packing Methods 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000011111 cardboard Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 241000131314 Aspergillus candidus Species 0.000 description 1
- 241001225321 Aspergillus fumigatus Species 0.000 description 1
- 206010011409 Cross infection Diseases 0.000 description 1
- 244000168141 Geotrichum candidum Species 0.000 description 1
- 235000017388 Geotrichum candidum Nutrition 0.000 description 1
- 206010029803 Nosocomial infection Diseases 0.000 description 1
- 241000228150 Penicillium chrysogenum Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 150000003797 alkaloid derivatives Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003230 hygroscopic agent Substances 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paper (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention discloses safe, high efficiency and composite mildew proof paper and a preparation method thereof. The mildew proof paper of the present invention uses common kraft paper, etc. as base paper; one layer of composite mildew proof agent prepared from enyl phenol, benzoic acid, propylparaben and sorbic acid is coated or sprayed at one surface of the base paper; one layer of composite adhesive containing mildew proof agents of propionic acid, carbendazim, vitamin E or vitamin C, etc. and antioxidant is covered on the layer of composite mildew proof agent. The manufacturing method comprises the following steps: the base paper is selected; the composite mildew proof agent is prepared, coated or sprayed; the composite adhesive containing the mildew proof agents and the antioxidant is prepared, coated or sprayed. The mildew proof paper of the present invention has the advantages of no odor and no special foreign odor; the mildew proof paper completely eliminates stimulation to human organs and pollution on working environment; the antibacterial effect is free from the influence of the temperature and the humidity of environment, chemical compositions of tobacco leaves are coordinated, the natural alcoholization of the tobacco leaves can be promoted; the present invention is harmless to humans and animals; the present invention not only can be used for the mildew prevention of tobacco and products thereof but also can be used for the mildew prevention of grain, fodder, etc.
Description
Technical field
The present invention relates to a kind of compound mildew-resistant goods and preparation method thereof, especially relate to a kind of safety high efficient compound mildew-proof paper and preparation method thereof.
Background technology
At present, the blade after the tobacco leaf economy-combat leaf redrying of tobacco enterprise generally adopts carton or glued board packing.The conventional fungus-proof measure of storing smoked sheet mainly contains three kinds: the moisture content of (one) control storage smoked sheet is in less than 13% scope, and uniformity.Require to carry out two aspect work, 1. tobacco leaf warehouse-in and regular moisture content detect for this reason; 2. improve storage requirement: should there be good sealing, protection against the tide and ventilation, the facility that dries (adopting hygroscopic agent or dehumidifier to dry usually) in the tobacco barn storehouse.(2) in time the humiture in tobacco barn storehouse is controlled according to detection case; (3) strengthening tobacco leaf checks in the storehouse.Above conventional storage cigarette fungus-proof measure is mildew-resistant cost height not only, and anti-mold effect is undesirable.In recent years, tobacco enterprise uses the sheet cigarette generally to adopt packed in cases or wooden splint packing, uses the brown paper protection against the tide, takes formaldehyde to discharge measures such as mildew-resistant before the plank packing, and certain effect is arranged within a short period of time.Because smoked sheet reaches more than 1 year at storage alcoholization process time, plank, cardboard absorb the moisture content in the nature air, cause package panel cigarette moisture content to increase, and absorb airborne mould simultaneously.These factors are under the suitable situation of environment temperature, multiple moulds such as plank carton medial surface self-sow aspergillus candidus, these moulds have very strong repellence to the single mould inhibitor of general action, be difficult to eradicate, and can cause cross infection to go mouldy to smoked sheet, produce mould acid smell, cause negative effect, cause enormous economic loss to tobacco business to tobacco natural alcoholization.
Summary of the invention
At the above-mentioned shortcoming of prior art, it is easy and simple to handle that the present invention aims to provide a kind of use, in use non-stimulated, the compound mildew-proof paper of non-residual toxicity and manufacture method thereof.
The objective of the invention is to realize by the following technical solutions.
The present invention's anti-fungicide paper is basic paper with common brown paper or other similar paper or cardboard, applies or sprays composite type mouldproof agent, coated weight or sprinkling amount 〉=10g/m in the one side of basic paper
2(preferred version is 20-50g/m
2, I haven't seen you for ages excessively influences the effect and the timeliness of mildew-resistant; Too much can cause the waste of mould inhibitor, increase production cost), on described composite type mouldproof agent layer, be coated with the compound adhesive that one deck is added with mould inhibitor and antioxidant, coated weight 20-90g/m
2(preferred version is 40-70g/m
2).
The component of described composite type mouldproof agent and proportioning are: o-phenyl phenol 10～50 weight portions, benzoic acid 5～20 weight portions, propylben 2～20 weight portions, sorbic acid 10～30 weight portions;
The component of described compound adhesive and proportioning are: high speed cigarette adhesive or starch adhesive 20-70 weight portion, be selected from one or both mixture 5～15 weight portions in propionic acid, calcium propionate, the sodium propionate, carbendazim or benomyl 2～10 weight portions, vitamin E or C3～10 weight portions.
The manufacture method of anti-fungicide paper of the present invention may further comprise the steps: (1) selectes basic paper; (2) composite type mouldproof agent preparation, coating or sprinkling take by weighing o-phenyl phenol by preset blending ratio, benzoic acid, propylben, sorbic acid is dissolved in the ethanol of 2～3 times of weight under the greenhouse, treats to dissolve fully (to be accelerate dissolution, can suitably heat) after, apply or be sprayed on surface one side of basic paper, place the greenhouse oven dry again, promptly get semi-finished product; (3) contain mould inhibitor and antioxidant the preparation of compound adhesive, apply or spray take by weighing 1 by preset blending ratio) adhesive, 2) one or both in propionic acid, calcium propionate, the sodium propionate, 3) carbendazim or benomyl, 4) vitamin E or C mix, and stir, apply or be sprayed at (2) and go on foot the side that the semi-finished product that make have mould inhibitor, oven dry packs again, gets product.
The mould inhibitor raw material that the present invention uses is commercially available chemicals commonly used, as o-phenyl phenol, benzoic acid, propylben, sorbic acid etc., and wide material sources, and production technology is simple, and production process can not produce the three wastes.
The mould inhibitor that the present invention uses belongs to low toxicity compounds, and its toxicity is about about 3 times of salt, and is to the person poultry harmless, safe and reliable.
Product odorless of the present invention does not have specific peculiar smell, has eliminated fully to the stimulation of human organ and mucous membrane and to the contamination hazard that working environment causes, and does not influence the work situation that the workman operates in the warehouse.
Product of the present invention has the dual-use function that smoked, sterilization, anti-mildew fresh-keeping are steamed in contact.Antibacterial effect is not subjected to the influence of ambient temperature and humidity, and can make the chemical composition of tobacco leaf more become to coordinating, and can promote tobacco natural alcoholization,
Product of the present invention not only can be used for tobacco and goods mildew-resistant thereof, also can be used for mildew-resistant such as grain, feed.
The specific embodiment
The invention will be further described below in conjunction with embodiment, but they can not be interpreted as the restriction of scope that the present invention is asked for protection.
Embodiment 1
(1) chooses basic paper (brown paper); (2) take by weighing o-phenyl phenol 40kg, benzoic acid 20kg, propylben 15kg, sorbic acid 30kg, put into the reactor that has agitator, add 300kg ethanol, be heated to 60 ℃ and stir by the programming rate of 1 ℃ of per minute, after treating to dissolve fully, be sprayed on the one side of brown paper, advance the greenhouse oven dry, get semi-finished product, the mould inhibitor of having on the brown paper is 50g/m
2(3) take by weighing high speed cigarette adhesive 140kg, propionic acid 24kg, carbendazim 16kg, vitamin e1 0kg, mixing and stirring is coated in the side of semi-finished product with mould inhibitor again, and coated weight is 40-70g/m
2, place greenhouse oven dry again after, pack, be finished product.
The present embodiment compound mildew-proof paper the results are shown in following table to the bacteriostatic test of multiple mould:
| Project | Geotrichum candidum | Penicillium chrysogenum | Head mold | Lignin wood is mould | Aspergillus fumigatus |
| Control group antibacterial circle diameter mm | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 |
| Antibacterial circle diameter mm of the present invention | 10.2 | 10.1 | 20.2 | 21.5 | 21.6 |
More than test shows, the composite mildewproof paper of present embodiment has the very strong antibacterial mould effect of killing.
Show by in some warehouses, making tobacco leaf storage mildew-resistant application test, compound mildew-proof paper of the present invention, surpass under 13% the situation at tobacco leaf moisture content, still the growth of can powerful control mildew-resistant going mouldy, the mildew-resistant special efficacy reaches 12 months, tobacco leaf send national tobacco quality supervision center detect to confirm in packing, and water-soluble total reducing sugar, total ammonia, total alkaloid, aesthetic quality etc. have reached every technical indicator, is used for the mildew-resistant of tobacco leaf inner packing, moistureproof aspect has possessed domestic and international advanced level.
Embodiment 2
(1) takes by weighing o-phenyl phenol 15kg, benzoic acid 15kg, propylben 10kg, sorbic acid 20kg, put into the reactor that has agitator, add 180kg ethanol, at room temperature stir, after treating to dissolve fully, be coated in the brown paper one side, advance the greenhouse oven dry, get semi-finished product, the mould inhibitor of having on the brown paper is 30g/m
2(3) take by weighing common starch adhesive 60kg, calcium propionate 10kg, benomyl 5kg, vitamin C 10kg mixes, and stirs, and is sprayed at the side of semi-finished product with mould inhibitor, and the sprinkling amount is 40g/m
2
All the other are with embodiment 1.
It is approaching that the composite mildewproof paper of present embodiment antibacterial kills the composite mildewproof paper of mould effect and embodiment 1.
Embodiment 3
(1) takes by weighing o-phenyl phenol 10kg, benzoic acid 15kg, propylben 5kg, sorbic acid 10kg, put into the reactor that has agitator, add 150kg ethanol, at room temperature stir, after treating to dissolve fully, be coated in the brown paper one side, put the greenhouse oven dry, get semi-finished product, the mould inhibitor of having on the brown paper is 25g/m
2(3) take by weighing common starch adhesive 50kg, sodium propionate 10kg, carbendazim 8kg, vitamin C 8kg mixes, and stirs, and is sprayed at the side of semi-finished product with mould inhibitor, and the sprinkling amount is 35g/m
2
All the other are with embodiment 1.
The composite mildewproof paper of present embodiment antibacterial kills the composite mildewproof paper that mould effect is inferior to embodiment 1.
Embodiment 4
" propionic acid 24kg " among the embodiment 1 changed into " propionic acid 10kg, calcium propionate 14kg ", and all the other are with embodiment 1.
Embodiment 5
" propionic acid 24kg " among the embodiment 1 changed into " propionic acid 10kg, sodium propionate 14kg ", and all the other are with embodiment 1.
Embodiment 6.
" propionic acid 24kg " among the embodiment 1 changed into " calcium propionate 14kg, sodium propionate 10kg ", and all the other are with embodiment 1.
The composite mildewproof paper that the composite mildewproof paper of embodiment 4,5,6 antibacterial kills mould effect and embodiment 1 is suitable.
Claims (4)
1. a compound mildew-proof paper is characterized in that, applying or spray in the one side of basic paper has one deck composite type mouldproof agent, coated weight or sprinkling amount 〉=10g/m
2, on described composite mildew inhibitor layer, cover the compound adhesive that one deck contains mould inhibitor and antioxidant, coated weight 20-90g/m
2
The component of described composite type mouldproof agent and proportioning are: o-phenyl phenol 10～50 weight portions, benzoic acid 5～20 weight portions, propylben 2～20 weight portions, sorbic acid 10～30 weight portions;
The component of described compound adhesive and proportioning are: high speed cigarette adhesive or starch adhesive 20-70 weight portion, be selected from one or both mixture 5～15 weight portions in propionic acid, calcium propionate, the sodium propionate, carbendazim or benomyl 2～10 weight portions, vitamin E or C3～10 weight portions.
2. compound mildew-proof paper according to claim 1 is characterized in that, described composite type mouldproof agent coated weight or sprinkling amount are 20-50g/m
2
3. compound mildew-proof paper according to claim 1 and 2 is characterized in that, the overlay capacity of described compound adhesive is 40-70g/m
2
4. according to the preparation method of claim 1 or 2 or 3 described compound mildew-proof papers, it is characterized in that, may further comprise the steps: (1) selectes basic paper; (2) take by weighing o-phenyl phenol by preset blending ratio, benzoic acid, propylben, sorbic acid is dissolved in the ethanol of 2～3 times of weight under the greenhouse, after treating to dissolve fully, applies or be sprayed on surface one side of basic paper, places the greenhouse oven dry again, promptly gets semi-finished product; (3) take by weighing 1 by preset blending ratio) adhesive, 2) one or both in propionic acid, calcium propionate, the sodium propionate, 3) carbendazim or benomyl, 4) vitamin E or C mix, and stir, apply or be sprayed at (2) and go on foot the side that the semi-finished product that make have mould inhibitor, oven dry packs again, gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100323988A CN100370077C (en) | 2005-11-18 | 2005-11-18 | Safety high efficient compound mildew-proof paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100323988A CN100370077C (en) | 2005-11-18 | 2005-11-18 | Safety high efficient compound mildew-proof paper and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1793502A CN1793502A (en) | 2006-06-28 |
| CN100370077C true CN100370077C (en) | 2008-02-20 |
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|---|---|---|---|
| CNB2005100323988A Expired - Fee Related CN100370077C (en) | 2005-11-18 | 2005-11-18 | Safety high efficient compound mildew-proof paper and preparation method thereof |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105000244A (en) * | 2015-05-18 | 2015-10-28 | 达成包装制品（苏州）有限公司 | Mold-proof packaging corrugated case |
| CN105350302A (en) * | 2015-12-16 | 2016-02-24 | 常熟市中宏针织厂 | Finishing process for home textile fabric |
| CN106894285A (en) * | 2017-02-23 | 2017-06-27 | 东莞市隆威实业有限公司 | A kind of essential oil composition of antibacterial and mouldproof and the wrapping paper using its preparation |
| CN108193554A (en) * | 2017-12-29 | 2018-06-22 | 上海海洋大学 | A kind of preparation method of antibacterial and mouldproof fluid film |
| CN108660858A (en) * | 2018-03-30 | 2018-10-16 | 句容市茂源织造厂 | A kind of preparation method of antibacterial brown paper |
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|---|---|---|---|---|
| JPH10251995A (en) * | 1997-03-06 | 1998-09-22 | Tokyo Seishi Kk | Paper for food and drink liquid container and method for producing the same |
| JP2000248495A (en) * | 1999-03-03 | 2000-09-12 | Rengo Co Ltd | Production of antimicrobial paper, antimicrobial paper and production of antimicrobial corrugated board |
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-
2005
- 2005-11-18 CN CNB2005100323988A patent/CN100370077C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10251995A (en) * | 1997-03-06 | 1998-09-22 | Tokyo Seishi Kk | Paper for food and drink liquid container and method for producing the same |
| JP2000248495A (en) * | 1999-03-03 | 2000-09-12 | Rengo Co Ltd | Production of antimicrobial paper, antimicrobial paper and production of antimicrobial corrugated board |
| CN1371604A (en) * | 2002-03-22 | 2002-10-02 | 唐建文 | Compound mildew and rot resistant freshness-retaining agent |
| CN1596777A (en) * | 2004-09-27 | 2005-03-23 | 唐建文 | Safety broad spectrum high efficiency compound type gas phase mildew proof antiseptic antistaling agent and its manufacturing method and application |
Non-Patent Citations (2)
| Title |
|---|
| 大枣晒前防腐保鲜. 唐雪蓉，李国涛，祖农红.食品科学，第6期. 1991 * |
| 鲜果采收后的防腐与保鲜技术(续). 吕荣欣，黄维南.亚热带植物科学，第1期. 1983 * |
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| CN1793502A (en) | 2006-06-28 |
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