CN100381492C - 有机硅烷母炼胶 - Google Patents

有机硅烷母炼胶 Download PDF

Info

Publication number: CN100381492C
Authority: CN; China
Prior art keywords: tetrasulfide; organosilane; propyl; propyl group; rubber
Prior art date: 2003-05-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CNB2004100420377A

Other languages

English (en)

Chinese (zh)

Other versions

CN1542038A (zh

Inventor

吴卢亮

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Evonik Operations GmbH

Evermore Trading Corp

Original Assignee

Changmao Trade Ltd By Share Ltd

Degussa GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2003-05-02

Filing date

2004-04-29

Publication date

2008-04-16

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=33305765&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN100381492(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2004-04-29 Application filed by Changmao Trade Ltd By Share Ltd, Degussa GmbH filed Critical Changmao Trade Ltd By Share Ltd

2004-11-03 Publication of CN1542038A publication Critical patent/CN1542038A/zh

2008-04-16 Application granted granted Critical

2008-04-16 Publication of CN100381492C publication Critical patent/CN100381492C/zh

2024-04-29 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

150000001282 organosilanes Chemical class 0.000 title claims abstract description 50
239000004594 Masterbatch (MB) Substances 0.000 title claims abstract description 25
229920001971 elastomer Polymers 0.000 claims abstract description 38
239000005060 rubber Substances 0.000 claims abstract description 34
239000000945 filler Substances 0.000 claims abstract description 11
-1 methoxyl group Chemical group 0.000 claims description 24
239000006229 carbon black Substances 0.000 claims description 12
239000003795 chemical substances by application Substances 0.000 claims description 12
229910052736 halogen Inorganic materials 0.000 claims description 6
229920003048 styrene butadiene rubber Polymers 0.000 claims description 6
150000001721 carbon Chemical group 0.000 claims description 5
239000006185 dispersion Substances 0.000 claims description 5
150000002367 halogens Chemical class 0.000 claims description 5
125000001931 aliphatic group Chemical group 0.000 claims description 4
239000004215 Carbon black (E152) Substances 0.000 claims description 3
239000002253 acid Substances 0.000 claims description 3
125000003545 alkoxy group Chemical group 0.000 claims description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
229930195733 hydrocarbon Natural products 0.000 claims description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
238000000034 method Methods 0.000 claims description 3
238000002360 preparation method Methods 0.000 claims description 3
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
125000000217 alkyl group Chemical group 0.000 claims description 2
125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims description 2
125000000000 cycloalkoxy group Chemical group 0.000 claims description 2
125000000753 cycloalkyl group Chemical group 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
238000007761 roller coating Methods 0.000 claims description 2
JSBCRJBLPVDUIC-UHFFFAOYSA-N triethoxy-[(triethoxysilylmethyltetrasulfanyl)methyl]silane Chemical compound CCO[Si](OCC)(OCC)CSSSSC[Si](OCC)(OCC)OCC JSBCRJBLPVDUIC-UHFFFAOYSA-N 0.000 claims description 2
XQCNPXMIHJAHGO-UHFFFAOYSA-N trimethoxy-[(trimethoxysilylmethyltetrasulfanyl)methyl]silane Chemical compound CO[Si](OC)(OC)CSSSSC[Si](OC)(OC)OC XQCNPXMIHJAHGO-UHFFFAOYSA-N 0.000 claims description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 8
238000006884 silylation reaction Methods 0.000 claims 6
229910052799 carbon Inorganic materials 0.000 claims 4
WQDRMFCRLUCWRV-UHFFFAOYSA-N 3-triethoxysilylpropyl carbamodithioate Chemical compound CCO[Si](OCC)(OCC)CCCSC(N)=S WQDRMFCRLUCWRV-UHFFFAOYSA-N 0.000 claims 2
VUJAGXVTGFFECW-UHFFFAOYSA-N 3-trimethoxysilylpropyl carbamodithioate Chemical compound C(N)(SCCC[Si](OC)(OC)OC)=S VUJAGXVTGFFECW-UHFFFAOYSA-N 0.000 claims 2
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 2
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims 2
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims 2
125000001183 hydrocarbyl group Chemical group 0.000 claims 2
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
NESLVXDUKMNMOG-UHFFFAOYSA-N triethoxy-(propyltetrasulfanyl)silane Chemical compound CCCSSSS[Si](OCC)(OCC)OCC NESLVXDUKMNMOG-UHFFFAOYSA-N 0.000 claims 2
ZCDXUDHKMTUIHQ-UHFFFAOYSA-N C(CCCCCCC)(=O)O.C(N)(SCCC[Si](OC)(OC)OC)=S Chemical compound C(CCCCCCC)(=O)O.C(N)(SCCC[Si](OC)(OC)OC)=S ZCDXUDHKMTUIHQ-UHFFFAOYSA-N 0.000 claims 1
UMFVPDTWZQNVLK-UHFFFAOYSA-N C(CCCCCCC)(=O)O.C(N)(SCCC[Si](OCC)(OCC)OCC)=S Chemical compound C(CCCCCCC)(=O)O.C(N)(SCCC[Si](OCC)(OCC)OCC)=S UMFVPDTWZQNVLK-UHFFFAOYSA-N 0.000 claims 1
ABTGGVQYJQKMME-UHFFFAOYSA-N CC(CSSSSCC(C)(OCCCOCC)[SiH3])([SiH3])OCCCOCC Chemical compound CC(CSSSSCC(C)(OCCCOCC)[SiH3])([SiH3])OCCCOCC ABTGGVQYJQKMME-UHFFFAOYSA-N 0.000 claims 1
SXSGKPIKBFCWJT-UHFFFAOYSA-N COC(CC([SiH3])(OC)OC)SSSC(CC(OC)(OC)[SiH3])OC Chemical compound COC(CC([SiH3])(OC)OC)SSSC(CC(OC)(OC)[SiH3])OC SXSGKPIKBFCWJT-UHFFFAOYSA-N 0.000 claims 1
GHCSOVVTQWYFIM-UHFFFAOYSA-N [1,1,3-trimethoxy-3-[(1,3,3-trimethoxy-3-silylpropyl)disulfanyl]propyl]silane Chemical compound COC(CC([SiH3])(OC)OC)SSC(CC(OC)(OC)[SiH3])OC GHCSOVVTQWYFIM-UHFFFAOYSA-N 0.000 claims 1
VNNGGZLEHCTJMS-UHFFFAOYSA-N [1,1,3-trimethoxy-3-[(1,3,3-trimethoxy-3-silylpropyl)hexasulfanyl]propyl]silane Chemical compound COC(CC([SiH3])(OC)OC)SSSSSSC(CC(OC)(OC)[SiH3])OC VNNGGZLEHCTJMS-UHFFFAOYSA-N 0.000 claims 1
UQYXGXMHZJMWGH-UHFFFAOYSA-N [1,1,3-trimethoxy-3-[(1,3,3-trimethoxy-3-silylpropyl)tetrasulfanyl]propyl]silane Chemical compound COC(CC([SiH3])(OC)OC)SSSSC(CC(OC)(OC)[SiH3])OC UQYXGXMHZJMWGH-UHFFFAOYSA-N 0.000 claims 1
238000010528 free radical solution polymerization reaction Methods 0.000 claims 1
125000005843 halogen group Chemical group 0.000 claims 1
YACCECLVHQLZQK-UHFFFAOYSA-N methoxyperoxyethane Chemical compound CCOOOC YACCECLVHQLZQK-UHFFFAOYSA-N 0.000 claims 1
238000012856 packing Methods 0.000 claims 1
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims 1
238000006116 polymerization reaction Methods 0.000 claims 1
ASAOXGWSIOQTDI-UHFFFAOYSA-N triethoxy-[2-(2-triethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCSSSSCC[Si](OCC)(OCC)OCC ASAOXGWSIOQTDI-UHFFFAOYSA-N 0.000 claims 1
NOPBHRUFGGDSAD-UHFFFAOYSA-N triethoxy-[4-(4-triethoxysilylbutyltetrasulfanyl)butyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCCSSSSCCCC[Si](OCC)(OCC)OCC NOPBHRUFGGDSAD-UHFFFAOYSA-N 0.000 claims 1
MMJVGDWGJGFPAM-UHFFFAOYSA-N trimethoxy-[2-methoxy-3-[(2-methoxy-3-trimethoxysilylpropyl)tetrasulfanyl]propyl]silane Chemical compound CO[Si](OC)(OC)CC(OC)CSSSSCC(C[Si](OC)(OC)OC)OC MMJVGDWGJGFPAM-UHFFFAOYSA-N 0.000 claims 1
150000001875 compounds Chemical class 0.000 abstract description 8
239000002270 dispersing agent Substances 0.000 abstract description 6
238000002156 mixing Methods 0.000 abstract description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 46
239000000203 mixture Substances 0.000 description 15
235000019241 carbon black Nutrition 0.000 description 11
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 7
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
239000011593 sulfur Substances 0.000 description 7
229910052717 sulfur Inorganic materials 0.000 description 7
244000043261 Hevea brasiliensis Species 0.000 description 5
229920003052 natural elastomer Polymers 0.000 description 5
229920001194 natural rubber Polymers 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
239000000806 elastomer Substances 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
125000003118 aryl group Chemical group 0.000 description 3
239000011324 bead Substances 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
229920001577 copolymer Polymers 0.000 description 3
239000000049 pigment Substances 0.000 description 3
OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
239000005062 Polybutadiene Substances 0.000 description 2
238000005299 abrasion Methods 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
230000003078 antioxidant effect Effects 0.000 description 2
229940125782 compound 2 Drugs 0.000 description 2
239000003431 cross linking reagent Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000003365 glass fiber Substances 0.000 description 2
230000005484 gravity Effects 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
IUJLOAKJZQBENM-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-2-methylpropan-2-amine Chemical compound C1=CC=C2SC(SNC(C)(C)C)=NC2=C1 IUJLOAKJZQBENM-UHFFFAOYSA-N 0.000 description 2
229920002857 polybutadiene Polymers 0.000 description 2
MRFMYANPSJUQPW-UHFFFAOYSA-N 1-propyl-5-triethoxysilylcyclohexa-2,4-diene-1-carbothioic S-acid Chemical compound CCCC1(C(S)=O)CC([Si](OCC)(OCC)OCC)=CC=C1 MRFMYANPSJUQPW-UHFFFAOYSA-N 0.000 description 1
BOOFKIWEVSNEQL-UHFFFAOYSA-N 1-propyl-5-trimethoxysilylcyclohexa-2,4-diene-1-carbothioic S-acid Chemical compound CCCC1(C(S)=O)CC([Si](OC)(OC)OC)=CC=C1 BOOFKIWEVSNEQL-UHFFFAOYSA-N 0.000 description 1
ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 description 1
HKMVWLQFAYGKSI-UHFFFAOYSA-N 3-triethoxysilylpropyl thiocyanate Chemical compound CCO[Si](OCC)(OCC)CCCSC#N HKMVWLQFAYGKSI-UHFFFAOYSA-N 0.000 description 1
UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
241001441571 Hiodontidae Species 0.000 description 1
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
101001077374 Oryza sativa subsp. japonica UMP-CMP kinase 3 Proteins 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
125000004423 acyloxy group Chemical group 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
239000010692 aromatic oil Substances 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
239000006231 channel black Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
229940125904 compound 1 Drugs 0.000 description 1
229940126214 compound 3 Drugs 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
238000013016 damping Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000006232 furnace black Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
230000020169 heat generation Effects 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
238000003754 machining Methods 0.000 description 1
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
239000004005 microsphere Substances 0.000 description 1
238000000465 moulding Methods 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
125000003544 oxime group Chemical group 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
125000004115 pentoxy group Chemical group [*]OC([H])([H])C([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
239000000047 product Substances 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
125000000547 substituted alkyl group Chemical group 0.000 description 1
229920003051 synthetic elastomer Polymers 0.000 description 1
239000005061 synthetic rubber Substances 0.000 description 1
238000009864 tensile test Methods 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
238000010998 test method Methods 0.000 description 1
125000004001 thioalkyl group Chemical group 0.000 description 1
NELNNGOFUZQQGL-UHFFFAOYSA-N triethoxy-[1-(1-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)C(CC)SSSSC(CC)[Si](OCC)(OCC)OCC NELNNGOFUZQQGL-UHFFFAOYSA-N 0.000 description 1
VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
238000004073 vulcanization Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03F—SEWERS; CESSPOOLS
- E03F3/00—Sewer pipe-line systems
- E03F3/04—Pipes or fittings specially adapted to sewers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
- F16L11/11—Hoses, i.e. flexible pipes made of rubber or flexible plastics with corrugated wall
- F16L11/112—Hoses, i.e. flexible pipes made of rubber or flexible plastics with corrugated wall having reinforcements embedded in the wall

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Hydrology & Water Resources (AREA)
Public Health (AREA)
Water Supply & Treatment (AREA)
Compositions Of Macromolecular Compounds (AREA)
Processes Of Treating Macromolecular Substances (AREA)

CNB2004100420377A 2003-05-02 2004-04-29 有机硅烷母炼胶 Expired - Lifetime CN100381492C (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP03010018A EP1514892B2 (de)	2003-05-02	2003-05-02	Organosilankonzentrat
EP03010018.4		2003-05-02

Publications (2)

Publication Number	Publication Date
CN1542038A CN1542038A (zh)	2004-11-03
CN100381492C true CN100381492C (zh)	2008-04-16

Family

ID=33305765

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CNB2004100420377A Expired - Lifetime CN100381492C (zh)	2003-05-02	2004-04-29	有机硅烷母炼胶

Country Status (15)

Country	Link
US (1)	US7666933B2 (de)
EP (1)	EP1514892B2 (de)
JP (1)	JP4587278B2 (de)
KR (1)	KR20040094376A (de)
CN (1)	CN100381492C (de)
AT (1)	ATE332930T1 (de)
BR (1)	BRPI0401673A (de)
CA (1)	CA2465739A1 (de)
DE (1)	DE60306779T3 (de)
ES (1)	ES2268210T5 (de)
MX (1)	MXPA04004077A (de)
MY (1)	MY138853A (de)
PL (1)	PL367573A1 (de)
RU (1)	RU2345102C2 (de)
TW (1)	TWI272281B (de)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US9105382B2 (en)	2003-11-14	2015-08-11	Tundra Composites, LLC	Magnetic composite
US8841358B2 (en)	2009-04-29	2014-09-23	Tundra Composites, LLC	Ceramic composite
FR2886305B1 (fr) *	2005-05-26	2007-08-10	Michelin Soc Tech	Composition de caoutchouc pour pneumatique comportant un agent de couplage organosilicique et un agent de recouvrement de charge inorganique
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Publication number	Publication date
EP1514892B1 (de)	2006-07-12
RU2345102C2 (ru)	2009-01-27
CN1542038A (zh)	2004-11-03
KR20040094376A (ko)	2004-11-09
ATE332930T1 (de)	2006-08-15
ES2268210T3 (es)	2007-03-16
US20040220307A1 (en)	2004-11-04
DE60306779D1 (de)	2006-08-24
ES2268210T5 (es)	2010-05-19
CA2465739A1 (en)	2004-11-02
MY138853A (en)	2009-08-28
MXPA04004077A (es)	2005-01-25
US7666933B2 (en)	2010-02-23
JP2004339507A (ja)	2004-12-02
DE60306779T2 (de)	2007-07-12
TW200424240A (en)	2004-11-16
EP1514892A1 (de)	2005-03-16
RU2004113386A (ru)	2005-10-20
JP4587278B2 (ja)	2010-11-24
BRPI0401673A (pt)	2005-01-18
TWI272281B (en)	2007-02-01
PL367573A1 (pl)	2004-11-15
DE60306779T3 (de)	2010-07-29
EP1514892B2 (de)	2010-01-06

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2008-04-16	C14	Grant of patent or utility model
2008-04-16	GR01	Patent grant
2010-06-30	C56	Change in the name or address of the patentee	Owner name: EVONIK DEGUSSA CO., LTD. Free format text: FORMER NAME: DECOUCHY STOCK COMPANY
2010-06-30	CP03	Change of name, title or address	Address after: essen Co-patentee after: EVERMORE TRADING CORPORATION Patentee after: EVONIK DEGUSSA GmbH Address before: Dusseldorf, the Federal Republic of Germany Co-patentee before: EVERMORE TRADING CORPORATION Patentee before: Degussa AG
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2020-02-18	CP01	Change in the name or title of a patent holder	Address after: Essen, Germany Co-patentee after: EVERMORE TRADING CORPORATION Patentee after: Evonik Operations Ltd. Address before: Essen, Germany Co-patentee before: EVERMORE TRADING CORPORATION Patentee before: EVONIK DEGUSSA GmbH
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