CN101007723A - Concrete water-permeable brick using steel slag as aggregate - Google Patents
Concrete water-permeable brick using steel slag as aggregate Download PDFInfo
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- CN101007723A CN101007723A CNA2007100049198A CN200710004919A CN101007723A CN 101007723 A CN101007723 A CN 101007723A CN A2007100049198 A CNA2007100049198 A CN A2007100049198A CN 200710004919 A CN200710004919 A CN 200710004919A CN 101007723 A CN101007723 A CN 101007723A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00284—Materials permeable to liquids
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
一种利用钢渣作骨料的混凝土透水砖,其特征在于:所述透水砖包含重量百分比计的如下组分:70-85%的压碎值小于5%同时游离氧化钙含量小于3%的钢渣;10-25%的C52.5低碱水泥;0.5-6%的增强剂;0-3%的着色粉;3.5-5%的水。钢渣、水泥、增强剂、着色粉、水、在两个搅拌机中分类混合后,采用二次布料工艺,最后成型得到该混凝土透水砖。本发明解决了现有的结型的陶瓷类透水砖成本高、耗能高;水泥透水砖的透水性和抗压强度不能兼顾的问题,还利用了冶金固体废弃物钢渣,解决了钢渣造成的资源浪费和环境污染的问题。本发明的全生态钢渣混凝土透水砖不仅透水性优异,而且抗压强度很高。A concrete permeable brick using steel slag as aggregate, characterized in that: the permeable brick contains the following components in weight percentage: 70-85% of steel slag with a crushing value of less than 5% and a free calcium oxide content of less than 3% ; 10-25% of C52.5 low-alkali cement; 0.5-6% of reinforcing agent; 0-3% of coloring powder; 3.5-5% of water. Steel slag, cement, reinforcing agent, coloring powder, and water are classified and mixed in two mixers, and then the secondary material distribution process is used to finally form the concrete permeable brick. The invention solves the problems of high cost and high energy consumption of the existing knot-type ceramic permeable bricks; the problem that the water permeability and compressive strength of the cement permeable bricks cannot be taken into account, and also utilizes metallurgical solid waste steel slag to solve the problems caused by steel slag Problems of waste of resources and environmental pollution. The all-ecological steel slag concrete permeable brick of the present invention not only has excellent water permeability, but also has high compressive strength.
Description
技术领域technical field
本发明属于建筑材料领域,特别涉及一种用废钢渣、水泥常温压制成型的透水性道路用砖。The invention belongs to the field of building materials, in particular to a permeable road brick formed by pressing waste steel slag and cement at normal temperature.
背景技术Background technique
目前常见的路面透水砖大致分烧结型的陶瓷类透水砖和水泥透水砖,但由烧结型陶瓷透水砖成本高、耗能高,目前无法大范围推广,而水泥透水砖要么透水率不高,要么透水性能可以,但抗压强度不高,这二方面性能难兼顾,钢渣是目前较难高附加值利用的一种冶金固体废弃物,我国目前各大钢铁厂炼钢产生的大量废渣无法处置,长期占地搁置,浪费资源并且引起一定的环境污染。At present, the common pavement permeable bricks are roughly divided into sintered ceramic permeable bricks and cement permeable bricks. However, sintered ceramic permeable bricks have high cost and high energy consumption, and cannot be widely promoted at present, while cement permeable bricks either have low water permeability. Either the water permeability is good, but the compressive strength is not high. It is difficult to balance the performance of these two aspects. Steel slag is a kind of metallurgical solid waste that is currently difficult to use with high added value. At present, a large amount of waste slag produced by steelmaking in major iron and steel plants in my country cannot be disposed of. , long-term land occupation, waste of resources and cause certain environmental pollution.
发明内容Contents of the invention
本发明的目的是通过对废钢渣的工艺处理,加入专用增强剂配合高强度水泥,采用二次布料振动加压成型工艺制成透水性优异、抗压强度很高的全生态钢渣混凝土透水砖。The purpose of the present invention is to process the waste steel slag, add a special reinforcing agent and high-strength cement, and adopt the secondary distribution vibration and pressure molding process to make a fully ecological steel slag concrete permeable brick with excellent water permeability and high compressive strength.
为实现上述目的本发明采用的技术手段为:一种利用钢渣作为骨料的混凝土透水砖,所述透水砖包含重量百分比计的如下组分:In order to achieve the above object, the technical means adopted by the present invention is: a concrete permeable brick using steel slag as aggregate, and the permeable brick contains the following components in weight percentage:
70-85%的 压碎值小于5%同时游离氧化钙含量小于3%的钢渣;70-85% of steel slags with a crushing value of less than 5% and a free calcium oxide content of less than 3%;
10-25%的C52.5低碱水泥;10-25% C52.5 low-alkali cement;
0.5-6%的增强剂;0.5-6% enhancer;
0-3%的着色粉;0-3% coloring powder;
3.5-5%的水。3.5-5% water.
钢渣的规格为粒径5-8mm的用于砖体,粒径为1-3mm的用于砖体上表面。增强剂选自乙烯醋酸乙烯乳液或聚乙烯醇乳液,乙烯醋酸乙烯乳液制成的透水砖强度较高,聚乙烯醇乳液制成透水砖强度一般,但掺量较低成本也低。The specifications of the steel slag are 5-8mm for the brick body, and 1-3mm for the upper surface of the brick body. The reinforcing agent is selected from ethylene vinyl acetate emulsion or polyvinyl alcohol emulsion. The permeable brick made of ethylene vinyl acetate emulsion has high strength, and the permeable brick made of polyvinyl alcohol emulsion has average strength, but the dosage is low and the cost is low.
着色粉选自氧化铁类无机颜料,市场销售的合格产品都可用,但为拜耳乐无机颜料产品最好。The coloring powder is selected from iron oxide inorganic pigments, and all qualified products sold in the market can be used, but Bayferrox inorganic pigment products are the best.
将上述权利要求所述的的钢渣、水泥、增强剂、着色粉、水、在两个搅拌机中分类混合后,采用二次布料工艺,最后成型而得,After the steel slag, cement, reinforcing agent, coloring powder, and water described in the above claims are classified and mixed in two mixers, the secondary distribution process is adopted, and finally formed,
将砖的主体料占砖体积的90%和面料占砖体积的10%按不同配比分开搅拌,将搅拌好的主体料先注入砖模中,再将搅拌好的面料注入砖模作为面层,再加压振动成型。The main material of the brick accounts for 90% of the brick volume and the fabric accounts for 10% of the brick volume and is mixed separately according to different proportions. The main material that has been mixed is first injected into the brick mold, and then the mixed fabric is injected into the brick mold as the surface layer , and then press vibration molding.
采用二次布料工艺,其中透水砖主体用5-8mm粒径钢渣作骨料,同时主体中不加着色剂,而厚6mm的面层采用1-3mm粒径钢渣作骨料同时加入着色剂。The secondary material distribution process is adopted, in which the main body of the permeable brick uses steel slag with a particle size of 5-8mm as aggregate, and no colorant is added to the main body, while the surface layer with a thickness of 6mm uses steel slag with a particle size of 1-3mm as aggregate and colorant is added at the same time.
使用加压带振动成型工艺才能保证成型的透水砖体有足够的结构强度,成型激振力大于2吨。Only by using the pressurized belt vibration forming process can the formed permeable brick body have sufficient structural strength, and the forming excitation force is greater than 2 tons.
将C52.5水泥300公斤、5-8MM钢渣1500公斤、增强剂1.5公斤和水80公斤,在强制式搅拌机中搅拌30-60秒后,摊铺在透水砖胚内作为主体;同时将C52.5水泥50公斤、1-3MM钢渣250公斤、增强剂0.25公斤、着色剂1.5公斤、水15公斤在强制式搅拌机中搅拌30-60秒后摊铺在透水砖主体上作为面层,即荷兰砖的二次布料工艺,同时加压振动成型,成型激振力大于2吨,然后脱模,24小时后浇水养护7天以上,一般规格是长20厘米,宽10厘米,厚6厘米,在砖体体积中含20%大量连通而分布均匀的透水孔,因为孔的孔隙较大,所以水份不会大量滞留砖内,所以本技术制成的砖在低温下不会冻坏,冬天砖内不含水不会结冰,所以有很好的抗冻性。Mix 300 kg of C52.5 cement, 1,500 kg of 5-8MM steel slag, 1.5 kg of reinforcing agent and 80 kg of water in a forced mixer for 30-60 seconds, and spread them in permeable brick embryos as the main body; at the same time, mix C52. 50 kg of cement, 250 kg of 1-3MM steel slag, 0.25 kg of reinforcing agent, 1.5 kg of colorant, and 15 kg of water are mixed in a forced mixer for 30-60 seconds and spread on the main body of the permeable brick as the surface layer, that is, Dutch brick The secondary fabric technology, pressurization and vibration molding at the same time, the molding excitation force is greater than 2 tons, then demoulding, watering and curing for more than 7 days after 24 hours, the general specification is 20 cm long, 10 cm wide, and 6 cm thick. The volume of the brick body contains 20% of a large number of connected and evenly distributed permeable holes. Because the pores are large, the water will not stay in the brick in large quantities, so the bricks made by this technology will not be damaged by freezing at low temperatures. It does not contain water and will not freeze, so it has good frost resistance.
使用本发明的有益效果为:本透水砖使用的原材料70%为废钢渣,是真正的变废为宝的全生态透水砖,本发明的透水砖透水系数达到5~10×10-2cm/s,用本品铺设的路面,大雨时无任何积水,耐压强,常温成型不需烧结,能耗少。The beneficial effects of using the present invention are: 70% of the raw materials used in this permeable brick are scrap steel slag, which is a real ecological permeable brick that turns waste into treasure . s, the pavement paved with this product has no water accumulation during heavy rain, strong pressure resistance, no sintering required for normal temperature molding, and less energy consumption.
具体实施方式Detailed ways
一种利用钢渣作为骨料的混凝土透水砖,以钢渣、水泥、增强剂、着色粉、水为原料,按以下配方制成。A concrete permeable brick using steel slag as an aggregate is made of steel slag, cement, reinforcing agent, coloring powder and water as raw materials according to the following formula.
原料 规格 用量(公斤)Raw material Specifications Consumption (kg)
硅酸盐水泥 C52.5海螺 350Portland cement C52.5 conch 350
优质无机颜料 拜耳 0~10.5High-quality inorganic pigments Bayer 0~10.5
乙烯聚合物高分子乳液 固含量40% 1.75~21Ethylene polymer polymer emulsion Solid content 40% 1.75~21
钢渣 1~3mm 150~300Steel slag 1~3mm 150~300
钢渣 5~8mm 1450~1600Steel slag 5~8mm 1450~1600
水 自来水 90~100Water Tap water 90~100
生产钢渣混凝土透水砖的方法依闪按下列步骤进行:The method for producing steel slag concrete permeable bricks is carried out according to the following steps:
选料material selection
对废钢渣进行热闷纯化调整使钢渣中游离氧化钙含量降低至3%以下,压碎值小于5%,接着将废钢渣块破碎后分级筛选成1~3mm和5~8mm两种规格待用;Thermally purify and adjust the waste steel slag to reduce the content of free calcium oxide in the steel slag to less than 3%, and the crushing value is less than 5%. Then, the scrap steel slag is crushed and classified into two specifications of 1-3mm and 5-8mm for use ;
水泥,采用C52.5低碱水泥,保证钢渣颗粒间的粘接强度,Cement, C52.5 low-alkali cement is used to ensure the bonding strength between steel slag particles,
增强剂选自乙烯醋酸乙烯乳液或聚乙烯醇乳液,乙烯醋酸乙烯乳液制成的透水砖强度较高作为优选选用,聚乙烯醇乳液制成透水砖强度一般,但掺量较低成本也低;The reinforcing agent is selected from ethylene vinyl acetate emulsion or polyvinyl alcohol emulsion. The permeable brick made of ethylene vinyl acetate emulsion has higher strength as the preferred choice. The permeable brick made of polyvinyl alcohol emulsion has average strength, but the dosage is low and the cost is low;
着色粉选自氧化铁类无机颜料。市场销售的合格产品都可用,但首选为拜耳乐无机颜料产品;The coloring powder is selected from iron oxide inorganic pigments. Qualified products sold in the market are all available, but the Bayferrox inorganic pigment products are the first choice;
水为自来水。Water is tap water.
工艺craft
将C52.5水泥300公斤、5-8MM钢渣1500公斤、增强剂1.5公斤和水85公斤左右,在强制式搅拌机中搅拌30-60秒后,摊铺入荷兰砖的模具中;将C52.5水泥50公斤、1-3mm钢渣250公斤、增强剂0.25公斤、无机颜料1.5公斤、水10公斤左右,在强制式搅拌机中搅拌30-60秒后,摊铺在上述5-8mm料的面层上,即荷兰砖的二次布料工艺,同时加压振动成型(大于2吨的激振力),然后脱模。24小时后浇水养护7天以上;Mix 300 kg of C52.5 cement, 1,500 kg of 5-8MM steel slag, 1.5 kg of reinforcing agent and about 85 kg of water in a forced mixer for 30-60 seconds, and spread it into the mold of the Dutch brick; 50 kg of cement, 250 kg of 1-3mm steel slag, 0.25 kg of reinforcing agent, 1.5 kg of inorganic pigment, and about 10 kg of water, after stirring in a forced mixer for 30-60 seconds, spread on the surface layer of the above-mentioned 5-8mm material , that is, the secondary distribution process of Dutch bricks, simultaneously pressurized and vibrated (greater than 2 tons of exciting force), and then demoulded. After 24 hours, water and maintain for more than 7 days;
即得到本产品钢渣混凝土透水砖,一般规格是长20厘米,宽10厘米,厚6厘米,在砖体体积中含20%大量连通而分布均匀的透水孔,因为孔的孔隙较大,所以水份不会大量滞留砖内,所以本技术制成的砖在低温下不会冻坏,冬天砖内不含水不会结冰,所以有很好的抗冻性。本产品的特点在增强剂、钢渣及选择配比和工艺上,正常的石子水泥制成的透水混凝土透水砖强度只能在25Mpa以下,而加了我们的增强剂可以提高到35Mpa,利用钢渣代替石子强度可以达到45Mpa以上。That is to say, the steel slag concrete permeable brick of this product is obtained. The general specification is 20 cm long, 10 cm wide, and 6 cm thick. The volume of the brick body contains 20% of a large number of connected and evenly distributed permeable holes. A large amount of water will not stay in the bricks, so the bricks made by this technology will not be damaged by freezing at low temperatures. In winter, the bricks will not freeze without water, so they have good frost resistance. The characteristics of this product are in terms of reinforcing agent, steel slag and selected ratio and process. The strength of permeable concrete permeable brick made of normal gravel cement can only be below 25Mpa, but it can be increased to 35Mpa with our reinforcing agent, and steel slag is used instead The stone strength can reach above 45Mpa.
本钢渣混凝土透水砖主要技术指示检测结果如下:The main technical indication test results of the steel slag concrete permeable brick are as follows:
本透水砖透水系数达到5~10×10-2cm/sThe water permeability coefficient of this permeable brick reaches 5~10×10 -2 cm/s
透水砖体最高强度达到35~45MPaThe highest strength of permeable bricks reaches 35-45MPa
工艺 本透水砖使用C52.5水泥常温成型不需烧结、能耗少。Process This permeable brick uses C52.5 cement to form at room temperature without sintering and less energy consumption.
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| CN102310462A (en) * | 2011-07-08 | 2012-01-11 | 山西太钢不锈钢股份有限公司 | Method for producing building standard brick by using stainless steel tailing and grain slag |
| CN102311252A (en) * | 2011-07-08 | 2012-01-11 | 山西太钢不锈钢股份有限公司 | Method for producing imitation stone from stainless steel slag |
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| CN104193300A (en) * | 2014-07-24 | 2014-12-10 | 天津市嘉禾弘基环保建材股份有限公司 | Water permeable brick formed by sintering steel slag and production method of water permeable brick |
| CN104341136A (en) * | 2014-10-16 | 2015-02-11 | 内江市恒世达建材有限公司 | Concrete pavior brick facing material with water permeability |
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| CN105016642A (en) * | 2015-08-14 | 2015-11-04 | 昆明钢铁控股有限公司 | Environment-friendly and energy-saving steel slag water permeable brick and preparation method thereof |
| CN105967753A (en) * | 2016-04-29 | 2016-09-28 | 中南大学 | Method for producing freeze thaw resisting ground water permeable bricks from gold and antimony mine tailings |
| CN106045416A (en) * | 2016-05-30 | 2016-10-26 | 山东金艺园林股份有限公司 | Environment-friendly high-strength permeable brick |
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2007
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