CN101007745A - Pollution-reducing special fertilizer for leaf-kinds vegetable production - Google Patents
Pollution-reducing special fertilizer for leaf-kinds vegetable production Download PDFInfo
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Abstract
一种用于叶菜类蔬菜生产的降污专用肥,包括氮肥、磷肥和钾肥,其特征是在该专用肥中添加有作为硝化抑制剂的双氰胺或咪唑,以及添加有作为重金属钝化剂的废菌棒和(或)硫磺,其中硝化抑制剂双氰胺或咪唑的用量占氮肥有效养分含量的6~12%,重金属钝化剂废菌棒占专用肥实物重量的13~20%,硫磺的用量占专用肥实物重量的2~5%。所述氮肥、磷肥和钾肥中的有效成分N、P2O5和K2O的重量比可选为1∶0.36~0.72∶0.44~0.83。本发明添加有硝化抑制剂和重金属钝化剂,施用该肥料不仅对叶菜类蔬菜生长有较大促进作用,而且对降低菜体硝酸盐和重金属含量,改善蔬菜品质大有裨益。蔬菜地施用该专用肥,每公顷可增收3300元左右,同时可使菜体中铅、镉、汞、砷等重金属的含量降低10~40%,硝酸盐含量降低20~30%。A special fertilizer for reducing pollution used in the production of leafy vegetables, including nitrogen fertilizer, phosphorus fertilizer and potassium fertilizer, is characterized in that dicyandiamide or imidazole as a nitrification inhibitor is added to the special fertilizer, and dicyandiamide or imidazole as a heavy metal passivation agent is added in the special fertilizer. waste bacteria sticks and (or) sulfur, wherein the amount of nitrification inhibitor dicyandiamide or imidazole accounts for 6-12% of the effective nutrient content of nitrogen fertilizers, and the waste bacteria sticks of heavy metal passivators account for 13-20% of the weight of the special fertilizer , The consumption of sulfur accounts for 2~5% of special fertilizer kind weight. The weight ratio of the effective components N, P 2 O 5 and K 2 O in the nitrogen fertilizer, phosphorus fertilizer and potassium fertilizer can be selected as 1:0.36-0.72:0.44-0.83. The invention adds a nitrification inhibitor and a heavy metal passivator, and the application of the fertilizer not only greatly promotes the growth of leafy vegetables, but also is of great benefit to reducing the contents of nitrate and heavy metals in vegetables and improving the quality of vegetables. Applying the special fertilizer to the vegetable field can increase the income by about 3,300 yuan per hectare, and at the same time reduce the content of heavy metals such as lead, cadmium, mercury, and arsenic in vegetables by 10-40%, and reduce the content of nitrate by 20-30%.
Description
技术领域technical field
本发明涉及一种农业蔬菜肥料生产技术,特别是一种用于叶菜类蔬菜生产的降污专用肥(复合肥)。The invention relates to an agricultural vegetable fertilizer production technology, in particular to a pollution-reducing special fertilizer (composite fertilizer) used for the production of leafy vegetables.
背景技术Background technique
蔬菜是一种容易富集并残留硝酸盐和重金属的作物,加上环境污染或其他因素的影响,菜体中存在不同程度的硝酸盐(亚硝酸盐)和有害重金属的富集量增加,有的甚至严重超标,既影响广大人民群众的健康,也影响出口,食用卫生安全的无公害蔬菜已成为人们关注的焦点。另一方面,现有的蔬菜专用肥,一般都是以增产为目的,以氮磷钾为主,有的再添加些中微量元素,有些称为无公害或绿色肥料,其实质也只是有机无机复混肥或(生物)有机肥,并不是真正意义上能降低菜体硝酸盐和重金属富集量的专用肥。Vegetables are a kind of crops that are easy to accumulate and retain nitrate and heavy metals. Coupled with the influence of environmental pollution or other factors, there are different degrees of nitrate (nitrite) in vegetables and the accumulation of harmful heavy metals increases. Some even seriously exceed the standard, which not only affects the health of the masses, but also affects exports. Eating hygienic and safe pollution-free vegetables has become the focus of attention. On the other hand, the existing special fertilizers for vegetables are generally for the purpose of increasing production, mainly based on nitrogen, phosphorus and potassium, and some add some medium and trace elements. Some are called pollution-free or green fertilizers, and their essence is only organic and inorganic fertilizers. Compound fertilizers or (bio) organic fertilizers are not really special fertilizers that can reduce the accumulation of nitrate and heavy metals in vegetables.
发明内容Contents of the invention
本发明的目的在于克服上述之缺陷,从而提供一种用于叶菜类蔬菜生产的降污专用肥,使得用于叶菜类(或叶茎类)蔬菜的肥料施用时,不仅具有合理比例的充足养分,而且还可有效降低菜体硝酸盐的含量和有害重金属富集量,减轻蔬菜的污染,改善蔬菜的品质。The purpose of the present invention is to overcome above-mentioned defect, thereby provide a kind of pollution-reducing special-purpose fertilizer that is used for the production of leafy vegetables, make when being used for the fertilizer application of leafy vegetables (or leaf stems) vegetables, not only have reasonable proportion Sufficient nutrients, but also can effectively reduce the content of nitrate and the accumulation of harmful heavy metals in vegetables, reduce the pollution of vegetables, and improve the quality of vegetables.
本发明是以如下技术方案实现的:本发明的专用肥包括氮肥、磷肥和钾肥,其中有效养分为N、P2O5和K2O,其特征是在该专用肥中还添加有作为降低硝酸盐的硝化抑制剂双氰胺或咪唑,以及添加有作为重金属钝化剂的废菌棒和(或)硫磺,其中硝化抑制剂双氰胺或咪唑的用量占氮肥有效养分含量的6~12%,重金属钝化剂废菌棒占专用肥实物重量的13~20%,硫磺的用量占专用肥实物重量的2~5%。The present invention is realized by the following technical scheme: the special fertilizer of the present invention comprises nitrogen fertilizer, phosphorus fertilizer and potash fertilizer, and wherein effective nutrient is N, P 2 O 5 and K 2 O, it is characterized in that in this special fertilizer also adds as reducing Nitrate nitrification inhibitor dicyandiamide or imidazole, and waste bacteria sticks and (or) sulfur added as heavy metal passivator, wherein the amount of nitrification inhibitor dicyandiamide or imidazole accounts for 6-12% of the effective nutrient content of nitrogen fertilizer %, the heavy metal passivator waste bacteria stick accounts for 13-20% of the weight of the special fertilizer, and the amount of sulfur accounts for 2-5% of the weight of the special fertilizer.
具体实施时,在本发明的专用肥中,所述氮肥、磷肥和钾肥中的有效成分N、P2O5和K2O的重量比可选为1∶0.36~0.72∶0.44~0.83。During specific implementation, in the special fertilizer of the present invention, the weight ratio of the active components N, P 2 O 5 and K 2 O in the nitrogen fertilizer, phosphorus fertilizer and potassium fertilizer can be selected as 1:0.36-0.72:0.44-0.83.
具体实施时,在本发明中所述氮肥、磷肥和钾肥中的有效成分N、P2O5和K2O的优选重量比为1∶0.40~0.57∶0.50~0.69。During specific implementation, the preferred weight ratio of the effective components N, P 2 O 5 and K 2 O in the nitrogen fertilizer, phosphorus fertilizer and potassium fertilizer in the present invention is 1:0.40-0.57:0.50-0.69.
本发明之所以采用前述技术方案,是鉴于:硝化抑制剂是抑制铵态氮肥或尿素转化为硝态氮,从而减少氮肥的损失并提高肥料利用率的一类物质。由于其可以通过抑制硝化作用(2NH3+3O2→2HNO2+2H2O,2HNO2+O2→2HNO3),有效抑制硝态氮的形成,促进作物对铵态氮的吸收,从而达到降低蔬菜硝酸盐累积量的目的。重金属钝化剂主要是根据废菌棒(为食用菌生产中的废弃物)中的有机质与重金属发生螯合作用形成作物难于吸收的螯合物,以及硫化物很容易与土壤中重金属产生化学反应形成难溶的化合物(如:S2-+Cd2+→CdS↓,S2-+Pb2+→PbS↓),从而达到降低重金属的生物有效性来减少蔬菜对重金属的富集量的目的。本发明所使用的硝化抑制剂主要为双氰胺和/或咪唑,重金属钝化剂主要为废菌棒和(或)硫磺。The reason why the present invention adopts the aforementioned technical solution is that the nitrification inhibitor is a kind of substance that inhibits the conversion of ammonium nitrogen fertilizer or urea into nitrate nitrogen, thereby reducing the loss of nitrogen fertilizer and improving the utilization rate of fertilizer. Because it can effectively inhibit the formation of nitrate nitrogen by inhibiting nitrification (2NH 3 +3O 2 →2HNO 2 +2H 2 O, 2HNO 2 +O 2 →2HNO 3 ), and promote the absorption of ammonium nitrogen by crops, so as to achieve The purpose of reducing the accumulation of nitrate in vegetables. The heavy metal deactivator is mainly based on the chelation of organic matter in the waste fungus sticks (waste in the production of edible fungi) and heavy metals to form chelates that are difficult for crops to absorb, and sulfides are easy to chemically react with heavy metals in the soil Form insoluble compounds (such as: S 2- +Cd 2+ →CdS↓, S 2- +Pb 2+ →PbS↓), so as to reduce the bioavailability of heavy metals and reduce the accumulation of heavy metals in vegetables . The nitrification inhibitor used in the present invention is mainly dicyandiamide and/or imidazole, and the heavy metal deactivator is mainly waste bacteria sticks and (or) sulfur.
综上所述,本发明采用上述比例的原料生产的蔬菜(叶菜类)降污专用肥,是根据叶菜类蔬菜生长对氮、磷、钾的需求而定,而且还添加有硝化抑制剂和重金属钝化剂,因此施用该肥料不仅对叶菜类蔬菜生长有较大促进作用,而且对降低菜体硝酸盐、重金属(铅、镉、汞、砷等)含量,改善蔬菜品质大有裨益。蔬菜地施用该专用肥,每公顷可增收3300元左右,同时可使菜体中铅、镉、汞、砷等重金属的含量降低10~40%,硝酸盐含量降低20~30%。本发明尤其适合用作叶菜类蔬菜的降污专用肥,适宜于生产蔬菜的基肥或追肥。In summary, the vegetable (leafy vegetables) pollution-reducing special fertilizer that the present invention adopts the raw material production of above-mentioned proportion, is to decide according to the demand of leafy vegetable growth to nitrogen, phosphorus, potassium, and also adds nitrification inhibitor Therefore, the application of this fertilizer not only greatly promotes the growth of leafy vegetables, but also reduces the content of nitrate and heavy metals (lead, cadmium, mercury, arsenic, etc.) in the vegetables, and is of great benefit to improving the quality of vegetables. . Applying the special fertilizer to the vegetable field can increase the income by about 3,300 yuan per hectare, and at the same time reduce the content of heavy metals such as lead, cadmium, mercury, and arsenic in vegetables by 10-40%, and reduce the content of nitrate by 20-30%. The invention is especially suitable for being used as special pollution-reducing fertilizer for leafy vegetables, and suitable for producing vegetable base fertilizer or topdressing fertilizer.
具体实施方式Detailed ways
以下是本发明的二种实施例,以生产1000kg专用肥为例:Below are two kinds of embodiments of the present invention, take the production of 1000kg special fertilizer as example:
1)称取167.7kg的尿素,119.0kg的磷酸二铵和91.7kg的氯化钾,折合N、P2O5和K2O分别为95kg、50kg、55kg,另称取硝化抑制剂双氰胺9.5kg(为氮肥有效养分的10%左右)或5.7kg咪唑(为氮肥有效养分的6%左右),重金属钝化剂硫磺30kg(用量占专用肥实物重量的3%左右),废菌棒166.7kg,调节有机质用的草炭125kg,上述各原料经粉碎后混合均匀(可加入适量粘结用调理剂如高岭土等),配伍造粒,即成为本发明所提供的有机质含量≥20%的有机(质的)无机型蔬菜(叶菜类)降污专用肥。1) Weigh 167.7kg of urea, 119.0kg of diammonium phosphate and 91.7kg of potassium chloride, equivalent to 95kg, 50kg and 55kg of N, P 2 O 5 and K 2 O, and weigh the nitrification inhibitor dicyandiamide 9.5kg of amine (about 10% of the effective nutrient of nitrogen fertilizer) or 5.7kg of imidazole (about 6% of the effective nutrient of nitrogen fertilizer), 30kg of heavy metal passivator sulfur (the amount accounts for about 3% of the actual weight of special fertilizer), waste bacteria stick 166.7kg, adjust the peat 125kg that organic matter is used, above-mentioned each raw material mixes homogeneously after pulverizing (can add the conditioner such as kaolin etc. for bonding in right amount), compatibility granulation, promptly becomes the organic matter content ≥ 20% provided by the present invention. (Quality) Special fertilizer for pollution reduction of inorganic vegetables (leafy vegetables).
2)称取325.2kg的尿素,190.5kg的磷酸二铵和183.3kg的氯化钾,折合N、P2O5和K2O分别为160kg、80kg、110kg,另称取硝化抑制剂双氰胺16kg(为氮肥有效养分的10%左右)或10kg咪唑(为氮肥有效养分的6%左右),重金属钝化剂硫磺32kg(用量占专用肥实物重量的3%左右),上述各原料经粉碎后混合均匀(可加入适量粘结用调理剂如高岭土等),配伍造粒,即成为本发明所提供的无机型蔬菜(叶菜类)降污专用肥。2) Weigh 325.2kg of urea, 190.5kg of diammonium phosphate and 183.3kg of potassium chloride, equivalent to 160kg, 80kg and 110kg of N, P 2 O 5 and K 2 O, respectively, and weigh the nitrification inhibitor dicyandiamide 16kg of amine (about 10% of the available nutrient of nitrogen fertilizer) or 10kg of imidazole (about 6% of the available nutrient of nitrogen fertilizer), 32kg of heavy metal passivator sulfur (the amount accounts for about 3% of the actual weight of special fertilizer), and the above-mentioned raw materials are pulverized After mixing evenly (can add an appropriate amount of bonding conditioner such as kaolin, etc.), compatibility and granulation, it becomes the special fertilizer for pollution reduction of inorganic vegetables (leaf vegetables) provided by the present invention.
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| CN102180745A (en) * | 2011-02-18 | 2011-09-14 | 中国热带农业科学院分析测试中心 | Irrigation fertilizer special for sauropus androgynus |
| CN102826925A (en) * | 2012-08-30 | 2012-12-19 | 中国农业大学 | Rhizosphere regulating agent for promoting cadmium-contaminated soil phytoremediation and application method thereof |
| CN103012017A (en) * | 2012-12-31 | 2013-04-03 | 中国水稻研究所 | Fertilizer for controlling cadmium accumulation of dry-land crops and preparation method thereof |
| CN103086800A (en) * | 2013-02-05 | 2013-05-08 | 中国水稻研究所 | Fertilizer for controlling cadmium accumulation of crops, and its preparation method |
| CN103524250A (en) * | 2013-10-30 | 2014-01-22 | 安徽万利生态园林景观有限公司 | Green vegetable special-purpose fertilizer and preparation method thereof |
| CN104263374A (en) * | 2014-09-22 | 2015-01-07 | 广西大学 | Soil heavy metal compound stabilizer and application method thereof |
| CN105001020A (en) * | 2015-07-22 | 2015-10-28 | 沈阳化工研究院有限公司 | Compound mixing fertilizer having heavy metal passivation effect, preparation method and uses thereof |
| CN105272779A (en) * | 2015-11-18 | 2016-01-27 | 广东省农业科学院蔬菜研究所 | Long-acting and quick-acting combined special compound fertilizer for fruits and vegetables in South China |
| CN105969364A (en) * | 2016-06-06 | 2016-09-28 | 福建省农业科学院土壤肥料研究所 | Composite heavy metal passivator containing secondary reduction iron powder and use method of passivator |
| CN111763126A (en) * | 2020-07-02 | 2020-10-13 | 山东泉立方生物科技有限公司 | Soil conditioner for improving stress resistance of crops and preparation method thereof |
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| AU2006200528A1 (en) * | 2001-05-09 | 2006-03-02 | Summit-Quinphos (Nz) Limited | Fertiliser Compositions |
| CN1227978C (en) * | 2003-09-15 | 2005-11-23 | 王正银 | Leaf vegetable nitrate composite control agent |
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| CN102180745A (en) * | 2011-02-18 | 2011-09-14 | 中国热带农业科学院分析测试中心 | Irrigation fertilizer special for sauropus androgynus |
| CN102826925A (en) * | 2012-08-30 | 2012-12-19 | 中国农业大学 | Rhizosphere regulating agent for promoting cadmium-contaminated soil phytoremediation and application method thereof |
| CN103012017B (en) * | 2012-12-31 | 2014-07-23 | 中国水稻研究所 | Fertilizer for controlling cadmium accumulation of dry-land crops and preparation method thereof |
| CN103012017A (en) * | 2012-12-31 | 2013-04-03 | 中国水稻研究所 | Fertilizer for controlling cadmium accumulation of dry-land crops and preparation method thereof |
| CN103086800B (en) * | 2013-02-05 | 2014-12-03 | 中国水稻研究所 | Fertilizer for controlling cadmium accumulation of crops, and its preparation method |
| CN103086800A (en) * | 2013-02-05 | 2013-05-08 | 中国水稻研究所 | Fertilizer for controlling cadmium accumulation of crops, and its preparation method |
| CN103524250A (en) * | 2013-10-30 | 2014-01-22 | 安徽万利生态园林景观有限公司 | Green vegetable special-purpose fertilizer and preparation method thereof |
| CN104263374A (en) * | 2014-09-22 | 2015-01-07 | 广西大学 | Soil heavy metal compound stabilizer and application method thereof |
| CN104263374B (en) * | 2014-09-22 | 2017-09-01 | 广西大学 | A kind of soil heavy metal composite stabilizer and using method thereof |
| CN105001020A (en) * | 2015-07-22 | 2015-10-28 | 沈阳化工研究院有限公司 | Compound mixing fertilizer having heavy metal passivation effect, preparation method and uses thereof |
| CN105272779A (en) * | 2015-11-18 | 2016-01-27 | 广东省农业科学院蔬菜研究所 | Long-acting and quick-acting combined special compound fertilizer for fruits and vegetables in South China |
| CN105969364A (en) * | 2016-06-06 | 2016-09-28 | 福建省农业科学院土壤肥料研究所 | Composite heavy metal passivator containing secondary reduction iron powder and use method of passivator |
| CN111763126A (en) * | 2020-07-02 | 2020-10-13 | 山东泉立方生物科技有限公司 | Soil conditioner for improving stress resistance of crops and preparation method thereof |
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| CN100391909C (en) | 2008-06-04 |
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Effective date of registration: 20151111 Address after: 365104 West Village, west coast town, Youxi County, Sanming City, Fujian Patentee after: FUJIAN PROVINCE TIANBO BIOLOGICAL FERTILIZER CO.,LTD. Address before: The new PO Dang Village District Fuzhou Fujian province 350013 Patentee before: INSTITUTE OF SOIL AND FERTILIZER, FUJIAN ACADEMY OF AGRICULTURAL SCIENCES |
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Denomination of invention: Special fertilizer for pollution reduction in the production of leafy vegetables Effective date of registration: 20210709 Granted publication date: 20080604 Pledgee: Agricultural Bank of China Limited Youxi County sub branch Pledgor: FUJIAN PROVINCE TIANBO BIOLOGICAL FERTILIZER Co.,Ltd. Registration number: Y2021980005946 |
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Address after: 365104 Xiyang Village, Xibin Town, Youxi County, Sanming City, Fujian Province Patentee after: Fujian Tianbo Biotechnology Co.,Ltd. Address before: 365104 Xiyang Village, Xibin Town, Youxi County, Sanming City, Fujian Province Patentee before: FUJIAN PROVINCE TIANBO BIOLOGICAL FERTILIZER CO.,LTD. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080604 |