CN101048043A - A material for covering the appearance of a device and its manufacturing method - Google Patents

A material for covering the appearance of a device and its manufacturing method Download PDF

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CN101048043A
CN101048043A CN 200610067465 CN200610067465A CN101048043A CN 101048043 A CN101048043 A CN 101048043A CN 200610067465 CN200610067465 CN 200610067465 CN 200610067465 A CN200610067465 A CN 200610067465A CN 101048043 A CN101048043 A CN 101048043A
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layer
covering
exterior
coated
manufacturing
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冯崇智
姚伊蓬
黄培火
王格峰
林永松
康开丰
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San Fang Chemical Industry Co Ltd
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San Fang Chemical Industry Co Ltd
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Abstract

The invention relates to a material for covering the appearance of a device and a manufacturing method thereof, the manufacturing method of the material is that a PU fabric layer is coated on release paper, the fabric layer is dried after being coated, then a PU coating layer is coated on the PU fabric layer, a PU coating bottom layer is coated after the PU coating layer is dried, and the release paper is released through the steps of drying, reeling and ripening to obtain the electronic covering material with the PU appearance with surface color grains; the PU material is characterized in that the PU material has a surface grain color layer, so that the PU material is used for covering the appearance of an electronic product, can generate more diversified changes of the appearance, increases good touch feeling of a user, and enables the electronic product to be more integrated into the living space of the user.

Description

一种覆盖装置外表的材料及其制造方法A material for covering the appearance of a device and its manufacturing method

技术领域technical field

本发明为一种覆盖装置外表的材料及其制造方法,尤指一种利用PU材料表面具多样纹路色彩变化等材质特性,使用于电子产品外表覆盖,使其有类似真皮般柔软触感舒适、外观多样多元等特性。The invention relates to a material for covering the appearance of a device and a manufacturing method thereof, especially to a material characteristic such as a variety of textures and color changes on the surface of a PU material, which is used to cover the appearance of electronic products, so that it has a soft, comfortable touch, and an appearance similar to genuine leather. Diversity and other characteristics.

背景技术Background technique

市面上的电子产品外壳材质主要有ABS塑料、铝镁合金、碳纤维及钛合金四种,总体来说,目前市场较受欢迎的材质是铝镁合金与钛合金,上述各种材质的电子产品外壳均有其优缺点,以下就这些材质的特性做一比较:The housing materials of electronic products on the market mainly include ABS plastic, aluminum-magnesium alloy, carbon fiber and titanium alloy. Generally speaking, the most popular materials in the market are aluminum-magnesium alloy and titanium alloy. Both have their advantages and disadvantages. The following is a comparison of the characteristics of these materials:

第一类型:防火塑料-ABSType 1: Fireproof plastic-ABS

ABS由苯乙烯、丙烯腈和丁二烯乳浆共聚合而成,本身耐热性和耐溶剂均比HIPS为佳,且具有光泽性。由于丙烯腈的腈基极性较强,可以增强PS中分子链的相互作用,所以冲击强度、拉伸强度及塑件的表面硬度均较HIPS为佳。ABS is made of styrene, acrylonitrile and butadiene emulsion copolymerization. Its heat resistance and solvent resistance are better than HIPS, and it has gloss. Since the nitrile group of acrylonitrile has strong polarity, it can enhance the interaction of molecular chains in PS, so the impact strength, tensile strength and surface hardness of plastic parts are better than HIPS.

一般丙烯腈的比例含量越高,其耐热性佳、刚性及耐溶剂性越佳,但流动性越差,且塑料底色带黄,在射出成形(Injection Mold)时其机械性及尺寸安定性非常好,基于上述的优点,ABS树脂成为一种优秀的工程塑料。Generally, the higher the proportion of acrylonitrile, the better the heat resistance, rigidity and solvent resistance, but the worse the fluidity, and the plastic background color is yellowish, and its mechanical properties and dimensions are stable during injection molding (Injection Mold). The performance is very good, based on the above advantages, ABS resin has become an excellent engineering plastic.

具有高光泽、耐冲击、可电镀等特性的ABS树脂,一般用于家电、玩具等日常用品;具高流动特性的ABS,一般用于大型家电、摩托车外壳、薄肉成型品等成型用品;具低流动特性的ABS,适合射出板材及管件,一般用于冰箱内衬、手提皮箱、管材及大型容器等;具难燃特性的ABS,一般用于计算机外壳及配件、电子产品、事务机器等需符合UL94规范要求的产品;具耐热级的ABS,适合高温要求的产品,一般用于发热家电外壳、吹风机、暖风机及汽车零组件如仪表板等。ABS resin with high gloss, impact resistance, and electroplating properties is generally used in household appliances, toys and other daily necessities; ABS with high flow characteristics is generally used in molding products such as large household appliances, motorcycle shells, and thin-meat molded products; ABS with low flow characteristics is suitable for injection of plates and pipe fittings, generally used for refrigerator linings, suitcases, pipes and large containers, etc.; ABS with flame retardant characteristics, generally used for computer casings and accessories, electronic products, business machines, etc. Products that need to meet the requirements of UL94 specifications; heat-resistant ABS, products suitable for high temperature requirements, generally used for heating appliances, hair dryers, heaters and automotive components such as instrument panels, etc.

ABS塑料材质,其单片厚度与碳纤维产品差不多,约为1.2毫米;在热传导方面,效果一般,不如铝镁合金及钛合金,使用时机壳外部温度会让人感受到温热的感觉;而在材质的延展性上,则属平庸,因此不会有太大的造型变化;其主要优点是韧度高,抗震性好,整体而言,ABS塑料材质的最大好处便是其成本较低,制造快速,但达不到现今电子产品外壳强度的需求,且无法解决笔记型计算机电磁波外泄的问题。ABS plastic material, the thickness of a single piece is similar to that of carbon fiber products, about 1.2mm; in terms of heat conduction, the effect is average, not as good as aluminum-magnesium alloy and titanium alloy, the external temperature of the casing will make people feel warm when used; and In terms of material ductility, it is mediocre, so there will not be much shape change; its main advantages are high toughness and good shock resistance. Overall, the biggest advantage of ABS plastic material is its low cost. The manufacturing is fast, but it cannot meet the demand for the strength of the casing of today's electronic products, and it cannot solve the problem of electromagnetic wave leakage of notebook computers.

第二类型:镁铝合金材质(Magnesium Alloy)The second type: Magnesium Alloy material (Magnesium Alloy)

镁合金材料的应用使于1808年,最早用在航空工业,由于镁合金内构件具备坚固、散热佳和可以模块化的特性,加上近年来电子产品讲求轻、薄、短、小以及对于散热性的要求,镁合金逐渐取代铝、钢、塑料等金属,在各产业的产品应用上均有相当好的表现;也由于镁合金较其它材料来的轻,加上有散热、导电、防EMI、吸振、可回收、提升产品价值等特性,运用在电子信息产品的机壳构件应用逐渐扩大,首先大量应用于投影机机壳,之后迅速应用至笔记型计算机、手机、PDA、相机等产品,已成为3C产品机壳构件的首先考量的材料。The application of magnesium alloy materials started in 1808, and was first used in the aviation industry. Due to the characteristics of strong, good heat dissipation and modularization of magnesium alloy internal components, and in recent years, electronic products have emphasized lightness, thinness, shortness, and smallness. Magnesium alloys are gradually replacing metals such as aluminum, steel, and plastic, and have performed well in product applications in various industries; also because magnesium alloys are lighter than other materials, plus they have heat dissipation, electrical conductivity, and anti-EMI , vibration absorption, recyclability, and product value enhancement, the application of casing components used in electronic information products has gradually expanded. First, it was widely used in projector casings, and then quickly applied to notebook computers, mobile phones, PDAs, cameras and other products. It has become the first consideration material for the casing components of 3C products.

镁铝合金具有许多优点,EMI阻隔效果佳:镁合金为非磁性金属,电磁波噪声的遮蔽性佳,可有效防止电磁干扰;散热性优良:镁合金的热传导性佳,在CPU持续高速化,散热设计日益重要状况下,是一很好的选择;质坚量轻:镁的重量为铝的1/3、铁的1/4,且强度、刚性皆优于铝及铁;吸震性佳:镁合金的比阻尼容量为铝合金的10~25倍,锌合金的1.5倍,显示其吸震能力的优异,可减少噪音及震动,用在可携式设备上有助减少外界震动源对内部精密电子、光学组件的干扰;收缩率小:厚度可达20mm,收缩率小,不会产生收缩下陷现象,且外型安定性高,不受环境温度及时间影响产生变化;生产效率高:镁较铝的同容积热容量小,在模具内可迅速凝固,除铸造作业时间缩短,同一单位时间内提高外,铸件表面亦更为细致。Magnesium-aluminum alloy has many advantages, and it has good EMI barrier effect: Magnesium alloy is a non-magnetic metal, which has good shielding performance of electromagnetic wave noise and can effectively prevent electromagnetic interference; excellent heat dissipation: magnesium alloy has good thermal conductivity, and it can dissipate heat when the CPU continues to increase in speed. It is a good choice when the design is becoming more and more important; strong and light: the weight of magnesium is 1/3 of aluminum and 1/4 of iron, and its strength and rigidity are better than aluminum and iron; good shock absorption: magnesium The specific damping capacity of the alloy is 10 to 25 times that of aluminum alloy and 1.5 times that of zinc alloy, which shows its excellent shock absorption ability and can reduce noise and vibration. It is used in portable devices to help reduce the impact of external vibration sources on internal precision electronics. , Interference of optical components; small shrinkage rate: the thickness can reach 20mm, the shrinkage rate is small, there will be no shrinkage and sinking phenomenon, and the appearance is stable, and it will not change due to the influence of ambient temperature and time; high production efficiency: magnesium is better than aluminum The heat capacity of the same volume is small, and it can be solidified quickly in the mold. In addition to shortening the casting operation time and improving the same unit time, the surface of the casting is also more detailed.

镁合金除具备上述优点外,由于镁是地球上第8大元素,丰富蕴藏在菱镁矿、白云石及海水中,在原料来源方面亦不虞匮乏,因此未来仍有相当大的市场空间;镁合金之前已有应用在部分汽车、自行车及手工具上,目前3C产品则仍以工程塑料为主要的外壳材料,而为能符合3C产品持续往轻薄短小EMI散热及耐热等要求,镁合金机壳需求应运而生。In addition to the above-mentioned advantages, magnesium alloys still have considerable market space in the future because magnesium is the eighth largest element on the earth and is abundantly stored in magnesite, dolomite and seawater, and there is no shortage of raw material sources. Alloys have been used in some automobiles, bicycles and hand tools before. At present, 3C products still use engineering plastics as the main shell material. In order to meet the requirements of 3C products for continuous thinner and shorter EMI heat dissipation and heat resistance, magnesium alloy machine Shell demand came into being.

镁铝合金材质,其单片厚度约1.0毫米,其重量轻盈而且延展性佳,因此可以用于平面设计上,但缺点是其机壳本身所发出的热量较高,在生产时必须小心处理其散热方面的问题。Magnesium-aluminum alloy material, the thickness of a single piece is about 1.0 mm, it is light in weight and has good ductility, so it can be used in graphic design, but the disadvantage is that the heat emitted by the case itself is relatively high, so it must be handled carefully during production Problems with heat dissipation.

目前镁铝合金所遭遇到的问题不少,例如:在量产性方面,镁铝合金压铸的不良率高,二次加工的制程数多,还需要经过防锈的化成处理及涂装制程等,需要耗费大量的人力与成本。At present, there are many problems encountered by magnesium-aluminum alloys. For example, in terms of mass production, the defect rate of magnesium-aluminum alloy die-casting is high, the number of secondary processing processes is large, and anti-rust chemical treatment and coating processes are required. , requires a lot of manpower and cost.

第三类型:碳纤维(Carbon-Fiber)The third type: carbon fiber (Carbon-Fiber)

碳纤维合金的电子产品未来有可能取代已流行多年的铝镁合金,减轻电子产品的重量,提高电子产品的可移动性;近年来,在电子产品的外壳上,由于强度及刚性的需求,大都采用铝镁合金为电子产品材质,但铝镁合金本身存在一些问题,例如:在环保的考量下,铝美合金并没有确定的方法可做回收使用,而仅是标榜可回收使用。Electronic products made of carbon fiber alloys may replace the aluminum-magnesium alloys that have been popular for many years in the future, reduce the weight of electronic products, and improve the mobility of electronic products; Aluminum-magnesium alloy is a material for electronic products, but there are some problems in aluminum-magnesium alloy itself. For example, in consideration of environmental protection, there is no definite method for aluminum-magnesium alloy to be recycled, but it is only advertised as recyclable.

碳纤维合金依碳纤维添加量的增加,又可大幅提升弹性率,让强度增加,不易变形,又可以表现玻璃纤维所做不到的弹性率。Carbon fiber alloy can greatly increase the elastic rate by increasing the amount of carbon fiber added, so that the strength is increased, it is not easy to deform, and it can also express the elastic rate that glass fiber cannot do.

碳纤维合金除了可达到完全的轻量化设计目的之外,它更呈现出风格多样化的发丝纹,强度是镁合金的两倍,重量则只有镁合金的八成,对防制电磁波EMI的效应,有更好的表现。Carbon fiber alloy not only achieves the purpose of completely lightweight design, but also presents a variety of styles of hairlines. Its strength is twice that of magnesium alloy, and its weight is only 80% of that of magnesium alloy. It is effective in preventing electromagnetic waves and EMI. have better performance.

碳纤维材质,其单片厚度仅有1.2毫米,除了拥有ABS塑料材质很好的抗震性外,其韧性极佳,为铝镁合金的2倍;重量也很轻巧,耐腐蚀性好,不易变质;而碳纤维材质的最大特点是其较佳的散热效果,是所有现今电子产品中的笔记型计算机外壳材质中较好的一种,在总体上比ABS稍好,但在笔记型计算机外壳强度上仍属平庸,还是达不到现今笔记型计算机外壳的强度需求。Carbon fiber material, the thickness of a single piece is only 1.2 mm. In addition to the good shock resistance of ABS plastic material, its toughness is excellent, which is twice that of aluminum-magnesium alloy; the weight is also very light, good corrosion resistance, and not easy to deteriorate; The biggest feature of carbon fiber material is its better heat dissipation effect. It is the better material of notebook computer casings in all electronic products today. It is slightly better than ABS in general, but it is still strong in the strength of notebook computer casings. It is mediocre, and it still does not meet the strength requirements of today's notebook computer casings.

第四类型:钛合金(Titanium Alloy)The fourth type: Titanium Alloy

钛合金的应用非常广泛,最早是应用在航天工业;由于钛合金具有质轻、强韧、耐震、延展性佳、散热性佳,因而钛合金开始广泛应用在日常生活用品上;而且,由于钛合金具有耐热及耐蚀的特性,连人工骨骼也是使用钛合金。Titanium alloys are widely used, and were first used in the aerospace industry; due to their light weight, toughness, shock resistance, good ductility, and good heat dissipation, titanium alloys began to be widely used in daily necessities; and, because titanium Alloys are heat-resistant and corrosion-resistant, and even artificial bones use titanium alloys.

钛合金材质应用在电子产品中如笔记型计算机上,其单片厚度仅有0.5毫米,为铝镁合金的二分之一,此材质不仅散热速度最快,且因其延展性极佳,故无设计上的限制;再者也因为其散热效果佳,因此在使用机壳的温度比起其它材质来要低;钛合金的强韧性是铝镁合金的3至4倍,重量是现今笔记型计算机外壳材质中最轻的一种。Titanium alloy material is used in electronic products such as notebook computers. Its single-piece thickness is only 0.5 mm, which is one-half of aluminum-magnesium alloy. This material not only has the fastest heat dissipation speed, but also has excellent ductility. There is no design limitation; moreover, because of its good heat dissipation effect, the temperature of the casing is lower than other materials; the strength and toughness of titanium alloy is 3 to 4 times that of aluminum-magnesium alloy, and the weight is less than that of today's notebooks One of the lightest computer case materials.

虽然钛合金材质应用在笔记型计算机上具有上述优点,但钛合金制造笔记型计算机外壳是无法采用压铸制程,而只能采用冲压制程方式,由于钛金属的结晶结构为HCP,材料机械性质偏脆,因此以冲压的制程上亦有其困难性;以冲压制程方式制造钛合金笔记型计算机外壳时,只能采用分片式制造,在笔记型计算机外壳中有许多强肋、外壳与其它零件连接的连接部、外壳与外壳连接的连接部等,这些零件都需要分别制造再采用黏结与钣金结合的方式连接,二次加工的制程数过多,需要耗费大量的人力与成本。Although titanium alloy material has the above-mentioned advantages when applied to notebook computers, the die-casting process cannot be used to manufacture notebook computer casings from titanium alloys, but the stamping process can only be used. Since the crystal structure of titanium metal is HCP, the mechanical properties of the material are relatively brittle. Therefore, the stamping process also has its difficulties; when the titanium alloy notebook computer case is manufactured by the stamping process, it can only be manufactured in pieces. There are many strong ribs in the notebook computer case, and the case is connected with other parts. The connecting part of the shell, the connecting part of the shell and the shell, etc., these parts need to be manufactured separately and then connected by bonding and sheet metal bonding. The number of secondary processing processes is too many, which requires a lot of manpower and cost.

基于上述理由,市面上的电子产品中的外壳材质主要有ABS塑料、铝镁合金、碳纤维及钛合金四种,总体来说,虽然目前市场较受欢迎的材质是铝镁合金与钛合金,但是ABS塑料材质的最大好处便是以塑料射出制程,其成本较低,制造快速,在电子产品中的外壳中有许多加强肋、外壳与其它零件连接的连接部、外壳与外壳连接的连接部等,均可以塑料射出制程一次完成,但达不到现今电子产品中的外壳的强度需求,且无法解决电子产品中的电磁波外泄的问题;铝镁合金所遭遇到的问题也不少,在量产性方面,镁铝合金压铸的不良率极高,二次加工的制程数很多,还需要经过防锈的化成处理及涂装制程等,需要耗费大量的人力与成本;钛合金制造电子产品中的外壳是无法采用压铸制程一次成型,而只能采用分片冲压制程方式,以冲压的制程上亦有其困难性,以冲压制程方式制造钛合金电子产品中的外壳时,只能采用分片式制造,在电子产品中的外壳中有许多加强肋、外壳与其它零件连接的连接部、外壳与外壳连接的连接部等,这些零件都需要分别制造,再采用黏结与钣金结合的方式连接,后加工处理的制程数过多,需要耗费大量成本。Based on the above reasons, the shell materials of electronic products on the market mainly include ABS plastic, aluminum-magnesium alloy, carbon fiber and titanium alloy. Generally speaking, although the more popular materials in the market are aluminum-magnesium alloy and titanium alloy, but The biggest advantage of ABS plastic material is the plastic injection process, which has low cost and fast manufacturing. There are many reinforcing ribs in the housing of electronic products, the connection between the housing and other parts, the connection between the housing and the housing, etc. , can be completed at one time by the plastic injection process, but it cannot meet the strength requirements of the shells in today's electronic products, and cannot solve the problem of electromagnetic wave leakage in electronic products; there are also many problems encountered by aluminum-magnesium alloys. In terms of productivity, the defect rate of magnesium-aluminum alloy die-casting is extremely high, and the number of secondary processing processes is large. It also needs to go through anti-rust chemical conversion treatment and coating process, which requires a lot of manpower and cost; titanium alloy manufacturing electronic products The shell of the titanium alloy electronic product cannot be formed at one time by the die-casting process, but only the stamping process of pieces can be used. The stamping process is also difficult. When the shell of titanium alloy electronic products is manufactured by the stamping process, only slices can be used. In the case of electronic products, there are many reinforcing ribs, the connection between the case and other parts, the connection between the case and the case, etc. These parts need to be manufactured separately, and then connected by bonding and sheet metal , the number of post-processing processes is too many, which requires a lot of cost.

一般的电子产品壳体通常系以金属类的铁、铝或铝镁合金等所加工成型,或以塑化类的PC或ABS等材质,进行热压或射出成型所制成,故其壳体外表通常会有,在金属类中表面坚硬,使使用者手感冰冷触感,或以塑化类材质的表面仅具颜色变化,无法产生壳体表面的高低起伏的纹路变化,对现电子产品必须融入于使用者而言,实无法达成此目的。Ordinary electronic product shells are usually made of metallic iron, aluminum, or aluminum-magnesium alloys, or made of plasticized PC or ABS materials, which are hot-pressed or injection-molded. Watches usually have a hard surface in metals, which makes the user feel cold to the touch, or the surface of plasticized materials only changes in color, and cannot produce fluctuations in the texture of the shell surface. It must be integrated into modern electronic products. For users, it is impossible to achieve this purpose.

且采如铝镁合金,为其电子产品的外表覆盖,虽有材料的质轻,加上银白色的外观,对于本来价格就较昂贵的电子产品而言,又再增添了一份尊贵的表征材料,但在其制造的处理程序中,应用了物理、化学原理及电化学表面处理方式,为使其具就清洁力使用了极大量的溶剂如此才具就清洁力、且在金属表面置换的加工过程,因此其中所产生的废弃物均具高度污染性。And the aluminum-magnesium alloy is used to cover the appearance of its electronic products. Although the material is light in weight and the silver-white appearance, it adds a noble symbol to the relatively expensive electronic products. However, in the process of its manufacture, physical and chemical principles and electrochemical surface treatment methods are applied, and a very large amount of solvent is used to make it have cleaning power, so that it can have cleaning power and replace the processing on the metal surface process, so the waste generated therein is highly polluting.

发明内容Contents of the invention

本发明目的之一即在于提供一种使用于覆盖装置外表的材料结构,进而提供制造成本低廉,不需要耗费大量人力且具有丰富的颜色及纹路变化,触感更为柔软易握,使其能更融入使用者生活的电子产品覆盖材料。One of the objects of the present invention is to provide a material structure used to cover the appearance of the device, thereby providing low manufacturing cost, no need to consume a lot of manpower, rich color and texture changes, softer touch and easy grip, so that it can be used more Covering materials for electronic products that integrate into the lives of users.

在以聚胺基甲酸酯(Polyurethane,PU)作为电子产品的覆盖材料时,因为PU在表面易于加工形成花纹,再加上PU材质本身触感极佳,不像金属或是碳纤维的材质般触感较为冰冷光滑,而且若是金属或是碳纤维的材质形成表面有花纹的模样,则需要进行表面蚀刻的工作,此举较为花费时间与成本,而PU材质本身表面可利用离型纸来形成花纹或是纹路,故此PU材质在表面形成纹路及在触感上,比起金属材质或是碳纤维的材质上来的较为优异。When using polyurethane (Polyurethane, PU) as the covering material of electronic products, because PU is easy to process and form patterns on the surface, and the PU material itself has an excellent touch, unlike metal or carbon fiber materials. It is cold and smooth, and if the metal or carbon fiber material forms a pattern on the surface, it needs to be etched on the surface, which is time-consuming and costly. However, the surface of the PU material itself can be patterned with release paper or Textures, so the PU material has better surface texture and tactility than metal or carbon fiber materials.

本发明亦为了解决上述防火塑料ABS、镁铝合金材质、碳纤维及钛合金在制作成电子产品外壳时,所遇到的限制,故此以聚胺基甲酸酯(Polyurethane,PU)作为电子产品的装饰覆盖材质,来解决以上所述的问题,以下将PU简要概述:The present invention also aims to solve the limitations encountered when the above-mentioned fire-resistant plastic ABS, magnesium-aluminum alloy material, carbon fiber and titanium alloy are made into electronic product casings, so polyurethane (Polyurethane, PU) is used as the electronic product. Decorative covering materials are used to solve the above-mentioned problems. The following is a brief overview of PU:

聚胺基甲酸酯(Polyurethane,PU)是由二异氰酸酯(Diisocyanate)、聚二醇(Polyol)以及短链二醇合成所得的产物,由于具有优异的机械性能以及耐溶剂、抗油性,可达到耐磨、耐油、耐酸碱、耐冲击、消音避震、耐溶剂、高弹性、高负重、恢复佳等特性。Polyurethane (PU) is a product synthesized from diisocyanate (Diisocyanate), polyglycol (Polyol) and short-chain diol. Due to its excellent mechanical properties, solvent resistance and oil resistance, it can reach Wear resistance, oil resistance, acid and alkali resistance, impact resistance, noise reduction and shock absorption, solvent resistance, high elasticity, high load, good recovery and other characteristics.

PU树脂由于具有不兼容的软段(Soft Segment,由聚二醇而来)及硬段(Hard Segment,由二异氰酸酯及链延长剂而来),产生相分离,导致硬段在PU膜中呈现类似海岛的结晶相,使PU在室温下有物理交联(即假性交联)的现象,因此PU分子量虽仅有数万,但由于相分离所产生的物理交联,使得其机械性质十分优异。PU resin has incompatible soft segment (Soft Segment, derived from polyglycol) and hard segment (Hard Segment, derived from diisocyanate and chain extender), resulting in phase separation, resulting in the hard segment appearing in the PU film The crystalline phase similar to sea islands makes PU physically cross-linked (that is, pseudo-cross-linked) at room temperature. Therefore, although the molecular weight of PU is only tens of thousands, due to the physical cross-linking produced by phase separation, its mechanical properties are very good. .

聚胺基甲酸酯(Polyurethane,PU)处提供软质、硬质泡绵、结构材及半硬质自成皮泡绵、热固性弹性体及人造皮革工业的制造原料,它可以运用在以下的这些工业:Polyurethane (PU) provides soft and hard foam, structural materials and semi-rigid self-forming foam, thermosetting elastomers and raw materials for the artificial leather industry. It can be used in the following These industries:

A.汽车工业(汽车零件,例如座椅、保险杆、挡泥板、方向盘、仪表板及车顶板)A. Automobile industry (auto parts such as seats, bumpers, fenders, steering wheels, dashboards and roof panels)

B.建筑工业(屋顶板、隔热板)B. Construction industry (roof panels, insulation panels)

C.软质泡绵工业(床垫、家俱和寝具)C. Soft foam industry (mattresses, furniture and bedding)

D.自成皮及弹性树脂工业(鞋底、机器零件、混凝土保护层、跑道、电子设备、家俱、滑雪板及合成皮)D. Self-forming leather and elastic resin industry (shoe soles, machine parts, concrete coverings, running tracks, electronic equipment, furniture, snowboards and synthetic leather)

E.隔热绝缘体工业(电冰箱、冷冻货柜、屋顶防漏工程及油品或液态石油气保温输送管)E. Heat insulation and insulator industry (refrigerators, refrigerated containers, roof leak-proof projects and oil or liquid petroleum gas insulation delivery pipes)

F.软质泡绵(可应用在沙发制作上)F. Soft foam (can be used in sofa production)

等等多种民生工具的材质运用,已是成熟且较符合环保的材料选项之一。The use of materials for various livelihood tools is already one of the mature and environmentally friendly material options.

本发明在制造过程中,可以在PU涂料中直接加入染剂,来达到外表覆盖的材料结构的外观所需要的颜色,加上利用离型纸进行离型的过程,便可以使表面形成丰富的纹路变化,而且PU材质本身为亲肤性的材料,当皮肤接触PU材质所形成的外表覆盖的材料时,其触感甚佳,胜过于金属所带来冰冷的感受或ABS塑料外壳光亮平滑的感觉,加上添加于PU涂料中的发泡剂而形成的PU发泡层,可以使本发明较为厚实,而形成的PU发泡层可以达到防水、防裂、耐震、隔热、填实、隔音的功能。In the manufacturing process of the present invention, dyes can be directly added to the PU coating to achieve the color required for the appearance of the material structure covered by the outer surface, and the process of using release paper to release the type can make the surface form a rich color. The texture changes, and the PU material itself is a skin-friendly material. When the skin is in contact with the material covered by the PU material, the touch is very good, which is better than the cold feeling brought by metal or the bright and smooth feeling of the ABS plastic shell. , plus the PU foam layer formed by the foaming agent added to the PU paint, can make the present invention thicker, and the formed PU foam layer can achieve waterproof, crack-proof, shock resistance, heat insulation, filling, sound insulation function.

以上所述,以PU材料用于电子产品外表覆盖,本发明特别是可将以具表面含颜色及纹路变化的PU材质特性,运用并制成电子产品外表覆盖用材质,除可取代旧有的金属或ABS等类的外壳覆盖材质,更可使电子制品的外壳不但具有丰富的颜色及纹路变化且触感更为柔软易握,使其能更融入使用者生活。As mentioned above, the PU material is used to cover the surface of electronic products. In particular, the present invention can use and make the PU material with surface color and texture changes into a material for covering the surface of electronic products, in addition to replacing the old ones. The shell covering material such as metal or ABS can make the shell of electronic products not only have rich color and texture changes, but also softer and easier to hold, so that it can be more integrated into the life of users.

附图说明Description of drawings

图1为本发明的一剖视图(第一实施例);Fig. 1 is a sectional view (first embodiment) of the present invention;

图2为本发明的一剖视图(第二实施例);Fig. 2 is a sectional view (second embodiment) of the present invention;

图3为本发明的一剖视图(第三实施例);Fig. 3 is a sectional view (the third embodiment) of the present invention;

图4为本发明的一剖视图(第四实施例);Fig. 4 is a sectional view (the fourth embodiment) of the present invention;

图5为本发明的一剖视图(第五实施例)。Fig. 5 is a sectional view of the present invention (fifth embodiment).

【图号说明】【Description of figure number】

100 覆盖装置外表的材料        131 PU发泡结构层100 Material covering the exterior of the device 131 PU foam structure layer

120 表面层                    132 PU不发泡结构层120 Surface layer 132 PU non-foaming structure layer

130 结构层                    140 底层130 Structural layer 140 Bottom layer

具体实施方式Detailed ways

而以本发明的相关具体结构,如图1所示,为本发明覆盖装置外表的材料100剖视图,其上为具有颜色及高低起伏的PU纹路的表面层120,中间具有一结构层130,可由发泡PU或非发泡PU所构成的结构,而在结构层130的下则为一底层140。With the specific structure related to the present invention, as shown in Figure 1, it is a cross-sectional view of the material 100 covering the outer surface of the device of the present invention, on which there is a surface layer 120 with a color and undulating PU texture, and a structural layer 130 in the middle, which can be formed by The structure made of foamed PU or non-foamed PU, and under the structure layer 130 is a bottom layer 140 .

另,请如图2所示,本发明另一较佳实施例的结构,其上层亦为具有颜色及高低起伏的的PU纹路的表面层120外,而在表面层120之下的结构层130部分,则由发泡PU来构成PU发泡结构层131,而在PU发泡结构层131之下为一底层140作为底部;而图3所示,本发明另一较佳实施例的结构由下层的底层140部分由下而上,则分别由底层140、PU发泡结构层131及PU不发泡结构层132,最后为表面层120所构成的组合结构;图4所示,本发明另一较佳实施例的结构从下层的底层140部分由下而上,则分别由底层140、PU不发泡结构层132及PU发泡结构层131,最后为表面层120所构成的组合结构;如图5所示,本发明另一较佳实施例的结构,从下层的底层140,其上为表面层120所构成的组合结构。In addition, as shown in Figure 2, the structure of another preferred embodiment of the present invention, the upper layer is also a surface layer 120 with a color and undulating PU texture, and the structural layer 130 under the surface layer 120 Partly, the PU foam structure layer 131 is formed by foaming PU, and a bottom layer 140 is used as the bottom under the PU foam structure layer 131; and as shown in Fig. 3, the structure of another preferred embodiment of the present invention consists The bottom layer 140 part of lower floor is from bottom to top, then respectively by bottom layer 140, PU foam structure layer 131 and PU foam structure layer 132, finally is the combination structure that surface layer 120 forms; As shown in Figure 4, the present invention also The structure of a preferred embodiment starts from the bottom layer 140 part of the lower layer from bottom to top, then respectively consists of the bottom layer 140, the PU non-foamed structure layer 132 and the PU foamed structure layer 131, and finally the composite structure composed of the surface layer 120; As shown in FIG. 5 , the structure of another preferred embodiment of the present invention consists of a bottom layer 140 on which a surface layer 120 is formed.

本发明一种覆盖装置外表的材料及其制造方法,特将其各种结构制造方法实施描述如下:The present invention is a kind of material that covers the appearance of the device and its manufacturing method, and its various structural manufacturing methods are described as follows:

(实施例1)(Example 1)

将具有纹路的离型纸准备后,在离型纸上涂布具有颜色的PU面料层,面料层涂布完成之后将其烘干,之后再涂布PU涂料层,待其烘干形成一结构层130之后,涂布最后一道PU涂料底层来作为底层140,经过烘干、卷取及熟成的步骤,将离型纸离型的后形成表面层120,便可得一具有表面色彩纹路的PU外表的电子覆盖材,如图1所示,其规格为总厚度0.5mm;PU涂料层空孔率0%;软硬度ShoreA:60。After preparing the textured release paper, coat the colored PU fabric layer on the release paper. After the fabric layer is coated, dry it, and then apply the PU coating layer, and wait for it to dry to form a structure After the layer 130, apply the last PU paint primer as the primer layer 140. After the steps of drying, winding and aging, the release paper is released to form the surface layer 120, and a PU with surface color lines can be obtained. The surface electronic covering material, as shown in Figure 1, has a specification of total thickness of 0.5mm; PU coating layer porosity of 0%; softness and hardness ShoreA: 60.

(实施例2)(Example 2)

本发明的第二实施例,一开始先将具有纹路的离型纸准备后,在离型纸上涂布具有颜色的PU面料层,面料层涂布完成之后将其烘干,之后再涂布添加发泡剂的PU涂料层,待其烘干形成一PU发泡结构层131之后,涂布最后一道PU涂料底层来作为底层140,经过烘干、卷取及熟成的步骤,将离型纸离型之后形成表面层120,便可得一具有表面色彩纹路的PU外表的电子覆盖材,如图2所示,其规格为总厚度0.7mm;PU涂料层空孔率40%;软硬度ShoreA:30。In the second embodiment of the present invention, after preparing the release paper with texture at the beginning, coat the PU fabric layer with color on the release paper, dry it after the coating of the fabric layer is completed, and then coat it Add the PU paint layer of foaming agent, after it is dried to form a PU foam structure layer 131, coat the last PU paint bottom layer as the bottom layer 140, through the steps of drying, coiling and ripening, release paper Form the surface layer 120 after the mold is released, and then you can get an electronic covering material with a PU appearance with surface color lines, as shown in Figure 2, its specification is a total thickness of 0.7mm; the porosity of the PU coating layer is 40%; the hardness Shore A: 30.

(实施例3)(Example 3)

本发明的第三实施例,先将具有纹路的离型纸备妥后,在离型纸上涂布具有颜色的PU面料层,面料层涂布完成之后将其烘干,之后再涂布PU涂料层,待其烘干形成一PU不发泡结构层132之后,进行涂布添加发泡剂的PU涂料层,待其烘干形成一PU发泡结构层131之后,涂布最后一道PU涂料底层来作为底层140,经过烘干、卷取及熟成的步骤,将离型纸离型之后形成表面层120,便可得一具有表面色彩纹路的PU外表的电子覆盖材,且其中结构层130具有PU发泡结构层131及PU不发泡结构层132的结构,而且在表面层120紧邻的结构层为PU不发泡结构层132,如图3所示,其规格为总厚度0.6mm;PU涂料层空孔率0%;PU涂料层空孔率40%;软硬度ShoreA:40。In the third embodiment of the present invention, after the release paper with texture is prepared, the PU fabric layer with color is coated on the release paper. After the fabric layer is coated, it is dried, and then the PU is coated. Paint layer, after it is dried to form a PU non-foaming structure layer 132, coat the PU paint layer adding foaming agent, after it is dried to form a PU foaming structure layer 131, coat the last PU coating The bottom layer is used as the bottom layer 140. After the steps of drying, winding and aging, the release paper is released to form the surface layer 120, and an electronic covering material with a PU appearance with surface color lines can be obtained, and the structural layer 130 It has a structure of PU foamed structural layer 131 and PU non-foamed structural layer 132, and the structural layer next to the surface layer 120 is PU non-foamed structural layer 132, as shown in Figure 3, its specification is a total thickness of 0.6mm; The porosity of the PU coating layer is 0%; the porosity of the PU coating layer is 40%; the hardness ShoreA: 40.

(实施例4)(Example 4)

本发明的第四实施例,先将具有纹路的离型纸备妥后,在离型纸上涂布具有颜色的PU面料层,面料层涂布完成之后将其烘干,之后再进行涂布添加发泡剂的PU涂料层,待其烘干形成一PU发泡结构层131之后,涂布PU涂料层,待其烘干形成一PU不发泡结构层132之后,涂布最后一道PU涂料底层来作为底层140,经过烘干、卷取及熟成的步骤,将离型纸离型之后形成表面层120,便可得一具有表面色彩纹路的PU外表的电子覆盖材,且其中结构层130具有PU发泡结构层131及PU不发泡结构层132的结构,而且在表面层120紧邻的结构层为PU发泡结构层131,如图4所示,其规格为总厚度0.8mm;PU涂料层发空孔率0%;PU涂料层空孔率70%;软硬度ShoreA:35。In the fourth embodiment of the present invention, after the release paper with texture is prepared, the PU fabric layer with color is coated on the release paper, and after the coating of the fabric layer is completed, it is dried and then coated Add the PU coating layer of foaming agent, after it dries to form a PU foaming structure layer 131, coat the PU coating layer, treat that after it dries to form a PU non-foaming structure layer 132, coat the last PU coating The bottom layer is used as the bottom layer 140. After the steps of drying, winding and aging, the release paper is released to form the surface layer 120, and an electronic covering material with a PU appearance with surface color lines can be obtained, and the structural layer 130 Have the structure of PU foam structure layer 131 and PU non-foam structure layer 132, and the structure layer next to surface layer 120 is PU foam structure layer 131, as shown in Figure 4, its specification is total thickness 0.8mm; PU The porosity of the coating layer is 0%; the porosity of the PU coating layer is 70%; the hardness ShoreA: 35.

(实施例5)(Example 5)

本发明的第五实施例,先将离型布备妥后,将PU湿式涂料涂布之后,将其进入水中使PU湿式涂料凝固,待凝固后在用水冲洗,烘干后卷曲,经过表面研磨后撕去离型布,便可形成一具有绒毛感的PU外表电子覆盖材;其规格为总厚度0.4mm;PU层空孔率30%;软硬度ShoreA:15。In the fifth embodiment of the present invention, first prepare the release cloth, apply the PU wet paint, put it into water to solidify the PU wet paint, rinse with water after solidification, curl after drying, and grind the surface After tearing off the release cloth, a fuzzy PU surface electronic covering material can be formed; its specification is a total thickness of 0.4mm; the porosity of the PU layer is 30%; the hardness ShoreA: 15.

综上所述,本发明一种覆盖装置外表的材料及其制造方法不仅可达预期的实用功效外,并且为前所未见的设计,已符合专利法发明的要件,于是依法具文申请。为此,谨请贵审员详予审查,并祈早日赐请专利,至感德便。To sum up, the material for covering the surface of the device and its manufacturing method of the present invention not only achieve the expected practical effect, but also have an unprecedented design, which meets the requirements of the patent law invention, so the application is filed in accordance with the law. For this reason, I would like to ask your reviewers to review in detail, and pray for the patent application as soon as possible, so thank you for your convenience.

以上已将发明作详细说明,然而其上所述,仅为本发明的较佳实施例而已,当不能限定本发明实施的范围,即凡一本发明申请专利范围所作的均等变化与修饰等,皆应属本发明的专利涵盖范围意图保护的范畴。The invention has been described in detail above, but the above description is only a preferred embodiment of the present invention, when it can not limit the scope of the present invention, that is, all equivalent changes and modifications made in the scope of the patent application for the present invention, All should belong to the category that the patent scope of the present invention intends to protect.

Claims (15)

1、一种外表覆盖的结构,特指为一覆盖装置外表的材料,此材料位于电子产品外部构造之上,其中该材料包含:1. A surface-covering structure, specifically referring to a material covering the surface of a device. This material is located on the external structure of an electronic product, wherein the material includes: 一表面层,为离型纸所离型后产生纹路的表面,在整体覆盖结构的最外层;A surface layer, which is the surface of the textured surface after the release paper is released, and is the outermost layer of the overall covering structure; 一结构层,为PU材质所构成的结构,在整体覆盖结构的中间部位,其上有表面层连结,而下部有底层连接;A structure layer is a structure made of PU material, in the middle part of the overall covering structure, the surface layer is connected to it, and the bottom layer is connected to it; 一底层,为PU涂料底层,在整体覆盖结构的最底层。A bottom layer is the bottom layer of PU paint, which is the bottom layer of the overall covering structure. 2、如权利要求1所述的覆盖装置外表的材料,其中该结构层为PU发泡层。2. The material for covering the exterior of a device as claimed in claim 1, wherein the structural layer is a PU foam layer. 3、如权利要求2所述的覆盖装置外表的材料的结构层,其中该PU发泡层的空孔率在90%以下。3. The structural layer of material covering the exterior of the device as claimed in claim 2, wherein the porosity of the PU foam layer is below 90%. 4、如权利要求1所述的覆盖装置外表的材料,其中该结构层为PU不发泡层。4. The material for covering the exterior of a device as claimed in claim 1, wherein the structural layer is a PU non-foaming layer. 5、如权利要求1所述的覆盖装置外表的材料,其中该结构层为PU发泡层与PU不发泡层两者搭配组成。5. The material for covering the exterior of a device as claimed in claim 1, wherein the structural layer is composed of a PU foamed layer and a PU non-foamed layer. 6、如权利要求5所述的覆盖装置外表的材料的结构层,其中该PU发泡层与PU不发泡层两者搭配组成的PU发泡层空孔率在90%以下。6. The structural layer of material covering the exterior of the device as claimed in claim 5, wherein the PU foam layer composed of the PU foam layer and the PU non-foam layer has a porosity of less than 90%. 7、如权利要求1所述的覆盖装置外表的材料,其中该表面层可具有颜色。7. The material for covering the exterior of a device as claimed in claim 1, wherein the surface layer can have a color. 8、如权利要求1所述的覆盖装置外表的材料,其中该材料结构的厚度在0.1~1.0mm。8. The material for covering the exterior of a device as claimed in claim 1, wherein the thickness of the material structure is 0.1-1.0 mm. 9、如权利要求1所述的覆盖装置外表的材料,其中该材料结构的软硬度为ShoreA:10~90。9. The material for covering the exterior of a device as claimed in claim 1, wherein the hardness of the material structure is ShoreA: 10-90. 10、如权利要求1所述的覆盖装置外表的材料,其中该材料结构可应用于笔记型计算机外壳、手机、PDA、MP3随身听、薄型化电视机及数字相机等对象等装置外壳均可应用在内。10. The material for covering the appearance of a device as claimed in claim 1, wherein the material structure can be applied to the casing of notebook computers, mobile phones, PDAs, MP3 players, thin TV sets and digital cameras, etc. inside. 11、一种覆盖装置外表的材料的制造方法,至少包含下列步骤:11. A method of manufacturing a material covering the exterior of a device, at least comprising the following steps: 在离型纸上涂布PU面料层,面料层涂布完成之后将其烘干,之后在PU面料层上涂布PU涂料层,待其烘干之后,涂布PU涂料底层,再经过烘干、卷取及熟成的步骤,将离型纸离型。Coat the PU fabric layer on the release paper, dry it after the fabric layer is coated, and then coat the PU paint layer on the PU fabric layer, after it is dried, coat the PU paint bottom layer, and then dry it , coiling and aging steps, release the release paper. 12、如权利要求11所述的覆盖装置外表的材料的制造方法,其中该面料层可添加任意颜色。12. The method of manufacturing the material for covering the exterior of the device as claimed in claim 11, wherein any color can be added to the fabric layer. 13、如权利要求11所述的覆盖装置外表的材料的制造方法,其中该涂料层可涂布含有发泡剂的PU涂料。13. The manufacturing method of the material covering the exterior of the device as claimed in claim 11, wherein the paint layer can be coated with PU paint containing a foaming agent. 14、如权利要求11所述的覆盖装置外表的材料的制造方法,其中该涂料层重复涂布两层以上。14. The method of manufacturing the material for covering the exterior of a device as claimed in claim 11, wherein the coating layer is repeatedly coated for two or more layers. 15、一种覆盖装置外表的材料的制造方法,其中涂布PU结构层为湿式涂料,涂布于载体上,后将其进入水中使PU湿式涂料凝固,待凝固后在用水冲洗,烘干后卷曲,经过表面研磨后离型。15. A method for manufacturing a material covering the exterior of a device, wherein the coated PU structural layer is a wet paint, which is coated on a carrier, and then put into water to solidify the PU wet paint, rinsed with water after solidification, and dried Curl, release after surface grinding.
CN 200610067465 2006-03-29 2006-03-29 A material for covering the appearance of a device and its manufacturing method Pending CN101048043A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8044805B2 (en) 2008-03-12 2011-10-25 China Steel Corporation RFID tag using monopole antenna
CN101659097B (en) * 2008-08-26 2011-11-09 三芳化学工业股份有限公司 Thermoformable composites and methods of making the same and shells with textured surfaces
US8206538B2 (en) 2008-05-26 2012-06-26 San Fang Chemical Industry Co., Ltd. Composite with thermo-formability, method for making the same and method for making a casing with texture on surface thereof
CN102984881A (en) * 2012-11-21 2013-03-20 华为技术有限公司 Circuit board connection structure
CN103237428A (en) * 2013-04-18 2013-08-07 苏州市华瑞热控制技术有限公司 Cabinet and manufacturing method thereof
CN103522824A (en) * 2012-07-04 2014-01-22 锣洋科技股份有限公司 Curing process, method for producing decorative molded article, and decorative molded article
CN114106673A (en) * 2020-08-31 2022-03-01 Oppo广东移动通信有限公司 Shell, shell preparation method and electronic equipment
CN114454585A (en) * 2020-11-09 2022-05-10 Oppo广东移动通信有限公司 Leather diaphragm and preparation method thereof, shell assembly and electronic equipment

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8044805B2 (en) 2008-03-12 2011-10-25 China Steel Corporation RFID tag using monopole antenna
US8206538B2 (en) 2008-05-26 2012-06-26 San Fang Chemical Industry Co., Ltd. Composite with thermo-formability, method for making the same and method for making a casing with texture on surface thereof
CN101659097B (en) * 2008-08-26 2011-11-09 三芳化学工业股份有限公司 Thermoformable composites and methods of making the same and shells with textured surfaces
CN103522824A (en) * 2012-07-04 2014-01-22 锣洋科技股份有限公司 Curing process, method for producing decorative molded article, and decorative molded article
CN102984881A (en) * 2012-11-21 2013-03-20 华为技术有限公司 Circuit board connection structure
CN102984881B (en) * 2012-11-21 2015-07-08 华为技术有限公司 Circuit board connection structure
CN103237428A (en) * 2013-04-18 2013-08-07 苏州市华瑞热控制技术有限公司 Cabinet and manufacturing method thereof
CN114106673A (en) * 2020-08-31 2022-03-01 Oppo广东移动通信有限公司 Shell, shell preparation method and electronic equipment
CN114454585A (en) * 2020-11-09 2022-05-10 Oppo广东移动通信有限公司 Leather diaphragm and preparation method thereof, shell assembly and electronic equipment

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