CN101372528B - 含有可光化固化基团的低粘度脲基甲酸酯的制备方法 - Google Patents

含有可光化固化基团的低粘度脲基甲酸酯的制备方法 Download PDF

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CN101372528B
CN101372528B CN2008101463255A CN200810146325A CN101372528B CN 101372528 B CN101372528 B CN 101372528B CN 2008101463255 A CN2008101463255 A CN 2008101463255A CN 200810146325 A CN200810146325 A CN 200810146325A CN 101372528 B CN101372528 B CN 101372528B
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groups
radiation
compounds
nco
curing
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CN101372528A (zh
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M·路德威格
W·费希尔
H·库泽夫斯基
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Zhanxin Holdings International Co ltd
Zhanxin Holland Co ltd
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Bayer MaterialScience AG
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7837—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/227—Catalysts containing metal compounds of antimony, bismuth or arsenic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/002—Priming paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Paints Or Removers (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Sealing Material Composition (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN2008101463255A 2007-08-25 2008-08-25 含有可光化固化基团的低粘度脲基甲酸酯的制备方法 Active CN101372528B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007040240.8 2007-08-25
DE200710040240 DE102007040240A1 (de) 2007-08-25 2007-08-25 Verfahren zur Herstellung von niedrigviskosen Allophanaten mit aktinisch härtbaren Gruppen

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CN101372528A CN101372528A (zh) 2009-02-25
CN101372528B true CN101372528B (zh) 2012-11-14

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Country Status (13)

Country Link
US (1) US8071659B2 (2)
EP (1) EP2031005B1 (2)
JP (1) JP5591457B2 (2)
KR (2) KR101504356B1 (2)
CN (1) CN101372528B (2)
AT (1) ATE496953T1 (2)
AU (1) AU2008203814B2 (2)
BR (1) BRPI0803675A2 (2)
CA (1) CA2639063C (2)
DE (2) DE102007040240A1 (2)
ES (1) ES2358301T3 (2)
PL (1) PL2031005T3 (2)
TW (1) TWI433861B (2)

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DE102004048873A1 (de) * 2004-10-07 2006-04-13 Bayer Materialscience Ag Verfahren zur Herstellung von niedrigviskosen Allophanaten mit aktinisch härtbaren Gruppen
DE102009008569A1 (de) 2009-02-12 2010-08-19 Bayer Materialscience Ag Verfahren zur Herstellung von besonders reaktiven und niedrigviskosen Allophanaten mit aktinisch härtbaren Gruppen und deren Verwendung zur Herstellung besonders kratzfester Beschichtungen
JP5873083B2 (ja) 2010-06-30 2016-03-01 ダウ グローバル テクノロジーズ エルエルシー 低粘度シリル変性ポリマー
US9023916B2 (en) 2010-09-30 2015-05-05 Voco Gmbh Composite material comprising a monomer with a polyalicyclic structure element
EP2436366B1 (de) 2010-09-30 2015-07-29 VOCO GmbH Kompositmaterial umfassend ein Monomer mit einem polyalicyclischen Strukturelement als Versiegelungsmaterial
US9079828B2 (en) 2010-09-30 2015-07-14 Voco Gmbh Polymerizable compounds comprising a polyalicylic structure element
EP2436364B1 (de) 2010-09-30 2017-05-31 VOCO GmbH Lackzusammensetzung umfassend ein Monomer mit einem polyalicyclischen Strukturelement
EP2436363B1 (de) 2010-09-30 2017-01-18 VOCO GmbH Zusammensetzung umfassend ein Monomer mit einem polyalicyclischen Strukturelement zum Füllen und/oder Versiegeln eines Wurzelkanals
EP2726525B1 (en) 2011-06-30 2020-12-30 Dow Global Technologies LLC Improved process for making low viscosity, fast curing silane terminated polymers
ES2523277T3 (es) * 2011-10-14 2014-11-24 Allnex Ip S.À.R.L. Procedimiento para la preparación de alofanatos emulsionables en agua, de baja viscosidad, que contienen grupos endurecibles por radiaciones
EP2581397B1 (de) 2011-10-14 2014-12-10 Allnex IP S.à.r.l. Verfahren zur herstellung von niedrigviskosen, wasserverdünnbaren urethan(meth)acrylaten
FR3003255B1 (fr) 2013-03-14 2015-10-02 Vencorex France Allophanate polyacrylate
JP6281188B2 (ja) * 2013-03-28 2018-02-21 日油株式会社 ウレタン（メタ）アクリレート及びこれを含有する光硬化型樹脂組成物
US20160168397A1 (en) * 2013-07-17 2016-06-16 Jun Liu Substrate coating compositions and methods
JP6241727B2 (ja) * 2013-10-31 2017-12-06 日油株式会社 ウレタン（メタ）アクリレート組成物
BR112016029755A2 (pt) 2014-06-23 2017-08-22 Carbon Inc métodos de produção de objetos tridimensionais a partir de materiais tendo múltiplos mecanismos de endurecimento
US10316213B1 (en) 2017-05-01 2019-06-11 Formlabs, Inc. Dual-cure resins and related methods
EP3424971A1 (de) * 2017-07-03 2019-01-09 HILTI Aktiengesellschaft Urethanmethacrylat-verbindungen enthaltende reaktivharze, reaktivharzkomponenten sowie reaktivharz-systeme und deren verwendung
WO2025192236A1 (ja) * 2024-03-14 2025-09-18 三井化学株式会社 （メタ）アクリレート化合物の製造方法

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US20090137750A1 (en) 2009-05-28
TWI433861B (zh) 2014-04-11
DE102007040240A1 (de) 2009-02-26
CN101372528A (zh) 2009-02-25
JP5591457B2 (ja) 2014-09-17
DE502008002449D1 (de) 2011-03-10
AU2008203814A1 (en) 2009-03-12
JP2009074070A (ja) 2009-04-09
EP2031005B1 (de) 2011-01-26
PL2031005T3 (pl) 2011-06-30
AU2008203814B2 (en) 2014-07-10
ATE496953T1 (de) 2011-02-15
ES2358301T3 (es) 2011-05-09
TW200920759A (en) 2009-05-16
CA2639063A1 (en) 2009-02-25
KR20090021247A (ko) 2009-03-02
KR20140143733A (ko) 2014-12-17
EP2031005A2 (de) 2009-03-04
BRPI0803675A2 (pt) 2009-05-05
CA2639063C (en) 2015-10-13
EP2031005A3 (de) 2009-11-25
US8071659B2 (en) 2011-12-06
KR101504356B1 (ko) 2015-03-19

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