CN101501271A - Surface coverings and methods - Google Patents

Surface coverings and methods Download PDF

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Publication number
CN101501271A
CN101501271A CNA2007800300678A CN200780030067A CN101501271A CN 101501271 A CN101501271 A CN 101501271A CN A2007800300678 A CNA2007800300678 A CN A2007800300678A CN 200780030067 A CN200780030067 A CN 200780030067A CN 101501271 A CN101501271 A CN 101501271A
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backing
layer
foam
textile
adhesive
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肯尼思·B·希金斯
彼得·C·布雷热
朱莉·A·O·斯莫尔费尔德
丹尼斯·L·里德尔
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Milliken and Co
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Abstract

A surface covering comprises a show surface, decorative layer, or face and an optional backing layer. The show surface, decorative layer, or face can comprise a decorative textile or fabric layer that is optionally saturated, covered, and/or coated with a protective film or film-forming composition. The backing can optionally comprise an agglomerated mass of particles, a foam, foam and particles, a felt, or a combination thereof. Methods for producing such surface coverings are also disclosed.

Description

表面覆盖物和方法 Surface Coverings and Methods

相关申请related application

本申请要求于2006年6月12日递交的美国专利申请第60/812,718号的优先权和权利。This application claims priority and rights to US Patent Application Serial No. 60/812,718, filed June 12,2006.

技术领域 technical field

本发明可涉及工艺、方法、用途、装置和/或产品,例如具有纺织品或织物显露表面、装饰层或面及选择性的背衬的表面覆盖物,如地板覆盖物、墙壁覆盖物、家俱覆盖物等。这样的纺织品显露表面、层或面是选择性地浸透、覆盖和/或涂覆的,或者包括保护性涂层组合物或磨损表面,如透明树脂或聚合材料。在至少一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬由结团的邻接颗粒部件构成或者包括结团的邻接颗粒部件。在至少另一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬由泡沫垫层构成或者包括泡沫垫层。在又一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬是颗粒和泡沫的掺合或组合背衬。具体地说,但非排他性地,至少某些本发明的实施方式可涉及表面覆盖物,例如地板覆盖物,其包括但不限于地毯、地毯砖(carpet tile)、地板、地砖、小块地毯、区块地毯、长条地毯、垫子、地板垫、稳定宽幅地毯、组合地板、卷材(roll goods)等。表面覆盖物中可加入簇绒、粘绒、针织、机织、非织造、针刺、植绒等纺织品或织物显露表面、表面材料、装饰纺织品层等。纺织品层可用膜或成膜组合物来浸透、覆盖和/或涂覆,所述膜或成膜组合物在固化时理想地为透明的或者半透明的。或者或另外地,面纱(face yarn)或纤维可包括一种或多种涂层或层,例如透明的、半透明的和/或有色的涂层或层。例如,面纱可包括涂覆有一层或多层涂层、覆层、外壳、层、磨损层、膜和/或类似物质的芯纱或芯纤维或芯丝或芯材料。另外,理想的是膜或成膜组合物或者一种或多种涂层或层是耐磨、耐脏、耐污、美学上令人愉悦、可熔合和/或类似的。在一个实施方式中,纺织品面可以以覆盖关系设置在由结团颗粒块构成的弹性和/或柔性的背衬上,所述颗粒的例子是不规则颗粒,如新的、回收的、可回收的、可再生的、天然的、生物类的、可生物降解的和/或其它环保或可靠的材料,如回收地毯、泡沫、橡胶和/或软木。纺织品面和颗粒背衬通常以邻接关系粘合在一起。选择性的胶粘剂层、胶粘膜、稳定层、纺织品背衬和/或类似物质可设置在颗粒背衬之上、之中或之下。增大摩擦、胶粘或有助于安装的材料或涂层可加入到颗粒背衬中和/或加到颗粒背衬的底侧上。例如,颗粒背衬可包括增加横向握持、减少滑动等的空隙。或者或另外地,具有增大摩擦的涂层的纺织品或织物背衬可添加到颗粒背衬之下、泡沫背衬之下、或者颗粒和泡沫的掺合或组合背衬之下。还提供了这些表面覆盖物的制造和回收方法。The present invention may relate to processes, methods, uses, devices and/or products, such as surface coverings, such as floor coverings, wall coverings, furniture coverings, having a textile or fabric exposed surface, a decorative layer or face and optionally a backing things etc. Such textile exposed surfaces, layers or faces are selectively impregnated, covered and/or coated, or include protective coating compositions or abrasive surfaces, such as transparent resins or polymeric materials. In at least one exemplary embodiment, the textile exposed surface is in overlying relationship with a backing consisting of or comprising agglomerated contiguous particle components. In at least another exemplary embodiment, the textile exposed surface is in covering relationship with a backing that is comprised of or includes a foam cushion. In yet another exemplary embodiment, the textile exposed surface is in covering relationship with a backing that is a blend or combination of particles and foam. Specifically, but not exclusively, at least some embodiments of the present invention may relate to surface coverings, such as floor coverings, including but not limited to carpets, carpet tiles, floors, floor tiles, rugs, Carpet tiles, carpet strips, rugs, floor mats, stable broadloom, floor tiles, roll goods, etc. Tufted, viscose, knitted, woven, non-woven, needle punched, flocked and other textiles or fabric exposed surfaces, surface materials, decorative textile layers, etc. can be added to the surface covering. The textile layer may be impregnated, covered and/or coated with a film or film-forming composition that is desirably transparent or translucent when cured. Alternatively or additionally, the face yarn or fibers may include one or more coatings or layers, such as transparent, translucent and/or colored coatings or layers. For example, a face yarn may comprise a core yarn or core fiber or core filament or core material coated with one or more coatings, sheaths, sheaths, layers, wear layers, films, and/or the like. Additionally, it is desirable that the film or film-forming composition or one or more coatings or layers be abrasion resistant, stain resistant, stain resistant, aesthetically pleasing, fusible, and/or the like. In one embodiment, the textile face may be disposed in covering relation on an elastic and/or flexible backing composed of agglomerated masses of particles, examples of which are irregular particles such as new, recycled, recyclable renewable, natural, bio-based, biodegradable and/or other environmentally friendly or reliable materials such as recycled carpet, foam, rubber and/or cork. The textile face and the particulate backing are usually bonded together in contiguous relationship. Optional adhesive layers, adhesive films, stabilizing layers, textile backings and/or the like may be disposed on, in or below the particulate backing. Materials or coatings that increase friction, stickiness, or aid in fit may be added to the particle backing and/or to the underside of the particle backing. For example, the particle backing can include voids to increase lateral grip, reduce slippage, and the like. Alternatively or additionally, a textile or fabric backing with a friction increasing coating may be added under the particle backing, under the foam backing, or under a blend or combination of particles and foam. Methods of manufacture and recycling of these surface coverings are also provided.

背景技术 Background technique

已知提供具有簇绒或粘绒地毯面并具有背衬层的地毯或地毯砖,所述背衬层由所谓的“新”或“填充”泡沫或者由其中回收泡沫碎片的不规则片通过粘合剂固定在一起的“再生粘接(rebond)”泡沫形成。这些新或填充泡沫地毯结构如,例如,美国专利5,545,276、5,948,500、6,203,881和6,468,623中所述,上述每篇专利在此以引用的方式引入,如同其在此完全阐述一般。这些再生粘接地毯结构在例如美国专利申请09/721,871和09/993,158(美国申请公开号US 2002/0132085)和10/209,050(美国申请公开号US 2004/0022991)和授权给Higgins等的英国专利GB 2369294中公开,上述每篇专利和专利申请在此以引用的方式引入,如同在此完全阐述一般。It is known to provide carpets or carpet tiles with a tufted or bonded pile carpet surface and with a backing layer made of so-called "fresh" or "filled" foam or irregular sheets of recycled foam fragments by bonding. A "rebond" foam is formed that holds the mixture together. These new or filled foam carpet structures are described, for example, in US Patent Nos. 5,545,276, 5,948,500, 6,203,881 and 6,468,623, each of which is hereby incorporated by reference as if fully set forth herein. These regenerated bonded carpet structures are described, for example, in U.S. Patent Application Nos. 09/721,871 and 09/993,158 (U.S. Application Publication No. US 2002/0132085) and 10/209,050 (U.S. Application Publication No. US 2004/0022991) and British Patent to Higgins et al. Disclosed in GB 2369294, each of the above patents and patent applications is hereby incorporated by reference as if fully set forth herein.

此外,还已知具有纺织品表面和橡胶背衬的垫子或地板垫形式的地板覆盖物。通常,这些垫子包括与橡胶背衬片粘合的簇绒纺织品表面,例如,聚酰胺(如尼龙)、棉、聚丙烯或这些纤维的混合物。这样的垫子通常通过在热压制(heated press)中将纺织品表面层与未固化的橡胶片粘合而制成。压制产生的热使橡胶硫化(固化),同时将其与纺织品层粘合。这些垫子具有非常好的控尘特性,可高效地从行人脚底除去灰尘和湿气,并且具有良好的脚感和外观。这种垫子中的某些还是可清洗、耐用、柔软的,并且可在光滑地面上平整放置。Furthermore, floor coverings in the form of mats or floor mats with a textile surface and a rubber backing are also known. Typically, these mats comprise a tufted textile surface bonded to a rubber backing sheet, eg polyamide (eg nylon), cotton, polypropylene or a blend of these fibers. Such mats are usually made by bonding a textile surface layer to an uncured rubber sheet in a heated press. The heat from the pressing vulcanizes (cures) the rubber, bonding it to the textile layers at the same time. These mats have very good dust control properties, efficiently remove dirt and moisture from the soles of pedestrians' feet, and have a good feel and appearance. Some of these mats are also washable, durable, soft, and lay flat on slippery floors.

以上描述的许多结构的一个缺点是其往往因新背衬材料的相对高成本而相当昂贵,它们在结构上可能是复杂的,尤其是地毯砖,它们可能不易回收和/或它们不能包含回收材料。此外,制造商和使用者通常希望提高制作成品的回收含量。A disadvantage of many of the structures described above is that they tend to be quite expensive due to the relatively high cost of new backing materials, they can be structurally complex, especially carpet tiles, they may not be easily recycled and/or they cannot contain recycled materials . Additionally, manufacturers and users often wish to increase the recycled content of finished products.

发明内容 Contents of the invention

本发明可以涉及工艺、方法、用途、装置和/或产品,例如具有纺织品或织物显露表面、装饰层或面和选择性的背衬的表面覆盖物,如地板覆盖物、墙壁覆盖物、家俱覆盖物等。这样的纺织品显露表面、装饰层或面是选择性地浸透、覆盖和/或涂覆的,或者包括保护性涂层组合物或磨损表面,如透明树脂或聚合材料。在至少一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬由结团的邻接颗粒部件构成或者包括结团的邻接颗粒部件。在至少另一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬由泡沫垫层构成或者包括泡沫垫层。在至少又一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬是颗粒和泡沫的掺合或组合背衬。具体的说,但非排他性地,至少某些本发明的实施方式可以涉及表面覆盖物,例如地板覆盖物,包括但不限于地毯、地毯砖、地板、地砖、小块地毯、区块地毯、长条地毯、垫子、地板垫、稳定宽幅地毯、组合地板、卷材等。表面覆盖物中可加入簇绒、粘绒、针织、机织、非织造、针刺、植绒等纺织品或织物显露表面、面材、装饰纺织品层等。纺织品层可用膜或成膜组合物来浸透、覆盖和/或涂覆,所述膜或成膜组合物在固化时理想地为透明的或者半透明的。或者或另外地,面纱或纤维可包括一种或多种涂层或层,例如透明的、半透明的和/或有色的涂层或层。例如,面纱可包括芯纱或芯纤维或芯丝或涂覆有一层或多层涂层、覆层、外壳、层、磨损层、膜等的芯材料。另外,还希望膜或成膜组合物或一种或多种涂层或层具有耐磨、耐脏、耐污、美学上令人愉悦、可熔合和/或类似的性质。在一个实施方式中,纺织品表面可以以覆盖关系设置在由结团颗粒块构成的弹性和/或柔性的背衬上,所述颗粒的例子是不规则颗粒,如新的、回收的、可回收的、可再生的、天然的、生物类的、可生物降解的和/或其它环保或可靠的材料,如泡沫和/或橡胶和/或软木。纺织品表面和颗粒背衬通常以邻接关系粘合在一起。选择性的胶粘剂层、胶粘剂膜、稳定层、纺织品背衬和/或类似物质可设置在颗粒背衬之上、之中或之下。增大摩擦、胶粘或有助于安装的材料或涂层可添加到颗粒背衬中和/或加到颗粒背衬的底侧上。例如,颗粒背衬可包括增加横向握持、减少滑动等的空隙。或者或另外地,带有增大摩擦的涂层的纺织品或织物背衬(如非织造毡或稀松布)可添加到颗粒背衬之下、泡沫背衬之下或者颗粒和泡沫的掺合或组合背衬之下。还提供了这些表面覆盖物的制造和回收方法。The present invention may relate to processes, methods, uses, devices and/or products, such as surface coverings, such as floor coverings, wall coverings, furniture coverings, having a textile or fabric exposed surface, a decorative layer or face and optionally a backing things etc. Such textile exposed surfaces, decorative layers or faces are selectively impregnated, covered and/or coated, or include protective coating compositions or abrasive surfaces, such as transparent resins or polymeric materials. In at least one exemplary embodiment, the textile exposed surface is in overlying relationship with a backing consisting of or comprising agglomerated contiguous particle components. In at least another exemplary embodiment, the textile exposed surface is in covering relationship with a backing that is comprised of or includes a foam cushion. In at least one further exemplary embodiment, the textile exposed surface is in covering relationship with a backing that is a blend or combination of particles and foam. In particular, but not exclusively, at least some embodiments of the present invention may relate to surface coverings, such as floor coverings, including but not limited to carpets, carpet tiles, floors, floor tiles, rugs, carpet tiles, long Carpets, rugs, floor mats, stable broadloom, floor tiles, rolls and more. Tufted, viscose, knitted, woven, non-woven, needle-punched, flocked and other textiles or fabric exposed surfaces, surface materials, decorative textile layers, etc. can be added to the surface covering. The textile layer may be impregnated, covered and/or coated with a film or film-forming composition that is desirably transparent or translucent when cured. Alternatively or additionally, the veil or fibers may include one or more coatings or layers, such as transparent, translucent and/or colored coatings or layers. For example, the face yarn may comprise a core yarn or core fiber or filament or core material coated with one or more coatings, sheaths, sheaths, layers, wear layers, films, and the like. In addition, it is also desirable for the film or film-forming composition or one or more coatings or layers to be abrasion-resistant, stain-resistant, stain-resistant, aesthetically pleasing, fusible, and/or similar. In one embodiment, the textile surface may be disposed in overlying relationship on an elastic and/or flexible backing composed of agglomerated clumps of particles, examples of which are irregular particles such as new, recycled, recyclable renewable, natural, bio-based, biodegradable and/or other environmentally friendly or reliable materials such as foam and/or rubber and/or cork. The textile surface and the particulate backing are usually bonded together in contiguous relationship. Optional adhesive layers, adhesive films, stabilization layers, textile backings, and/or the like may be disposed on, in, or below the particulate backing. Materials or coatings that increase friction, stickiness, or facilitate installation can be added to the particle backing and/or onto the underside of the particle backing. For example, the particle backing can include voids to increase lateral grip, reduce slippage, and the like. Alternatively or additionally, a textile or fabric backing (such as a nonwoven felt or scrim) with a friction-enhancing coating can be added under a particle backing, under a foam backing, or a blend of particles and foam or Under the combined backing. Methods of manufacture and recycling of these surface coverings are also provided.

在至少所选的实施方式中,本发明通过提供以下表面覆盖物而提出、提供了优于现有结构的优势,或提供了优于现有结构的替代性方案,所述表面覆盖物的例子是地板覆盖物,包括但不限于地毯、地毯砖、地板、地砖、小块地毯、区块地毯、长条地毯、垫子、稳定宽幅地毯、组合地板、卷材等,所述表面覆盖物包括例如界定了显露表面的装饰纺织品或织物面和选择性的背衬,所述背衬的例子是泡沫和/或颗粒背衬,如由例如新的、回收的、可回收的、天然的、生物类的、可生物降解的和/或可再生的材料构成的泡沫和/或颗粒背衬,例如天然和/或合成材料,例如新的、天然的或回收的表面覆盖物、橡胶、泡沫、软木和/或等等的颗粒或碎屑。根据一种可能优选的实施方式,背衬包括至少一些回收物,该回收物的至少一部分是例如回收的装饰纺织品或表面织物、回收的背衬、回收的表面覆盖物或其掺合或组合的颗粒、碎片、小块、材料等等。根据一个具体例子,将使用过的本发明至少一些所选的实施方式的表面覆盖物磨碎为背衬或填充材料或颗粒,并使用在新表面覆盖物的背衬之中。这些使用过的表面覆盖物的装饰面优选由相对平整的例如机织、针织或非织造结构的织物或纺织品形成。In at least selected embodiments, the present invention addresses, provides advantages over, or provides an alternative to existing structures by providing surface coverings, examples of which are are floor coverings, including but not limited to carpets, carpet tiles, floors, tiles, rugs, carpet tiles, carpet strips, rugs, stable broadloom, floor tiles, rolls, etc., said surface coverings including For example, an upholstery textile or fabric face that defines the exposed surface and an optional backing, examples of which are foam and/or particle backings, such as made of, for example, new, recycled, recyclable, natural, biological Foam and/or particle backings of organic, biodegradable and/or renewable materials, such as natural and/or synthetic materials, such as new, natural or recycled surface coverings, rubber, foam, cork and/or particles or debris of the like. According to a possibly preferred embodiment, the backing comprises at least some recycled content, at least a portion of which is, for example, recycled upholstery textiles or surface fabrics, recycled backings, recycled surface coverings, or blends or combinations thereof Granules, chips, nubs, materials, etc. According to a specific example, used surface coverings of at least some selected embodiments of the present invention are ground into a backing or filler material or particles and used in the backing of a new surface covering. The decorative side of these used surface coverings is preferably formed from a relatively flat fabric or textile such as a woven, knitted or nonwoven structure.

装饰面可由具有或不具有透明或半透明涂层或层的有色纱线或纤维或丝形成。或者或另外地,例如文字、图案、色彩、图像和/或图形等装饰性图像可通过印花或染色而施加到纺织品面上。如果需要,选择性地在印花或染色之后,装饰面织物可以用膜或有效成膜量的保护性成膜组合物来浸透、覆盖和/或涂覆,所述保护性成膜组合物的例子是透明或半透明的耐磨、耐污或耐脏组合物,如透明树脂或聚合物,例如聚氨酯、丙烯酸系聚合物、聚酯、聚烯烃、聚酰胺、高密度聚烯烃、高密度聚丙烯(HDPP)及其掺合物或组合等。如果需要,例如由玻璃(如玻璃纤维、玻璃垫、玻璃稀松布、机织玻璃等)构成的稳定层可以应用在背衬上方、之上、之中和/或之下,或者可用作背衬。在一个可能的优选结构中,稳定层可嵌入颗粒和/或泡沫背衬之中。纺织品背衬层也可应用在背衬下侧。增大摩擦的涂层或材料可添加到颗粒和/或泡沫背衬的下侧或纺织品背衬的下侧上。The decorative surface may be formed from colored yarns or fibers or filaments with or without a transparent or translucent coating or layer. Alternatively or additionally, decorative images such as text, patterns, colours, images and/or graphics may be applied to the textile face by printing or dyeing. If desired, optionally after printing or dyeing, the upholstery fabric can be impregnated, covered and/or coated with a film or an effective film-forming amount of a protective film-forming composition, examples of which are are transparent or translucent abrasion, stain or stain resistant compositions such as transparent resins or polymers such as polyurethanes, acrylic polymers, polyesters, polyolefins, polyamides, high density polyolefins, high density polypropylene (HDPP) and blends or combinations thereof, etc. If desired, a stabilizing layer, for example, composed of glass (such as fiberglass, glass mat, glass scrim, woven glass, etc.) can be applied over, on, in and/or under the backing, or can be used as a backing. lining. In one possible preferred configuration, the stabilizing layer may be embedded in a particle and/or foam backing. A textile backing layer may also be applied on the underside of the backing. Friction increasing coatings or materials may be added to the underside of the particle and/or foam backing or on the underside of the textile backing.

虽然根据至少所选的实施方式,表面覆盖物具有颗粒背衬,但可设想表面覆盖物可具有胶粘剂、树脂、聚合物、织物、纺织品、泡沫和/或类似背衬或背衬层。例如,至少某些可能优选的实施方式的地砖可具有硬底或衬背颗粒、泡沫、胶粘剂、树脂、聚合物、织物、纺织品、挤压物、膜和/或类似背衬或背衬层,以及一层或多层选择性的胶粘剂层、胶粘剂膜、稳定层、纺织品背衬、涂层或材料。Although according to at least selected embodiments, the surface covering has a particle backing, it is contemplated that the surface covering may have an adhesive, resin, polymer, fabric, textile, foam, and/or similar backing or backing layer. For example, floor tiles of at least some potentially preferred embodiments may have a hard base or backing particle, foam, adhesive, resin, polymer, fabric, textile, extrusion, film, and/or similar backing or backing layer, and one or more optional adhesive layers, adhesive films, stabilizing layers, textile backings, coatings or materials.

根据本发明的一个可能方面,提供了一种制造具有纺织品或织物表面以及弹性和/或柔性背衬的表面覆盖物的方法,所述弹性和/或柔性背衬含有相当大百分比的回收材料。在一种可能优选的实践中,所述方法包括将回收材料的颗粒(如回收的表面覆盖物、橡胶、泡沫、软木和/或类似物质的颗粒)与粘合剂相混合,并选择性地加入一种或多种填料、试剂或化合物;将该颗粒/粘合剂混合物淀积成层;将浸透、覆盖和/或涂覆的纺织品表面材料放置在所述层上,形成多层结构;压制该多层结构,同时用例如热使粘合剂固化,从而使颗粒固结形成弹性和/或柔性的背衬。通常,弹性背衬将在压制颗粒之间包括空隙,而涂覆的纺织品表面材料将与背衬粘合。涂覆的纺织品表面材料可由有色纱线或纤维或丝或材料制成,和/或在其被涂覆或覆盖之前经过印花或染色。可将一种或多种其它保护性、耐污渍性、耐脏性或磨损层或膜添加到涂覆的纺织品表面材料上。或者或另外地,表面材料的纱线或纤维或丝或材料可用这些材料进行涂覆。例如,面纱可以是涂覆纱线,例如用有色聚烯烃聚合物材料挤压涂覆的聚烯烃纱线,在有色聚烯烃聚合物材料上再涂覆澄清聚合物磨损层。如果涂覆面纱由单一聚合物或材料制成,则更易于回收。例如,具有聚烯烃芯和聚烯烃涂层的纱线比多种聚合物或多种材料的纱线更易于回收。在具体例子中,优选的纱线可以具有聚丙烯芯和聚丙烯涂层。According to one possible aspect of the invention, there is provided a method of manufacturing a surface covering with a textile or fabric surface and an elastic and/or flexible backing containing a substantial percentage of recycled material. In a possibly preferred practice, the method comprises mixing particles of recycled material (such as particles of recycled surface coverings, rubber, foam, cork, and/or similar substances) with a binder and optionally adding one or more fillers, agents or compounds; depositing the particle/binder mixture as a layer; placing the impregnated, covered and/or coated textile surface material on said layer to form a multilayer structure; The multilayer structure is pressed while the binder is cured, eg with heat, thereby consolidating the particles to form an elastic and/or flexible backing. Typically, the elastic backing will include voids between the compressed particles, and the coated textile face material will be bonded to the backing. A coated textile surface material may be made of colored yarn or fiber or filament or material, and/or printed or dyed before it is coated or covered. One or more other protective, stain-resistant, stain-resistant or abrasion-resistant layers or films may be added to the coated textile surface material. Alternatively or additionally, yarns or fibers or filaments or materials of the surface material may be coated with these materials. For example, the face yarn may be a coated yarn, such as a polyolefin yarn extrusion coated with a colored polyolefin polymer material over which is coated a clear polymer wear layer. Coated veils are easier to recycle if they are made from a single polymer or material. For example, yarns with polyolefin cores and polyolefin coatings are easier to recycle than multi-polymer or multi-material yarns. In a particular example, preferred yarns may have a polypropylene core and a polypropylene coating.

在本说明书的全文中,术语“颗粒”、“粉末”、“细粒”、“碎片”或“碎屑”用于指代新的、可再生的、回收的、可回收的、天然的、生物类的、可生物降解的和/或其它环保或可靠的材料的小块,例如通过本领域技术人员公知的切碎、机械研磨、低温研磨或其它已知技术或合适的组合技术来“破坏”的玻璃、软木、泡沫、橡胶、地板、装饰面、背衬和/或类似物质的小块。因此,在预期实践中采用的软木、泡沫或橡胶的颗粒或碎屑可以具有任何尺寸,包括粉末、颗粒和碎片。为描述至少所选的本文实施方式,术语“粉末”表示如文中所要求的能穿过2mm网眼或者在至少一个维度上的最大尺寸为2mm的颗粒或碎屑。“细粒”表示如文中所要求的能穿过6mm网眼或者在至少一个维度上的最大尺寸为6mm的颗粒或碎屑。细粒通常包括一些粉末但普遍比粉末大,且其重均尺寸接近细粒尺寸规格的最大值。“碎片”表示比细粒大的颗粒或碎屑。即,如文中所要求的,在至少一个维度上大于6mm。不考虑实际尺寸,可以设想,颗粒或碎屑优选特征在于基本上不规则的表面结构,尽管也可以使用其它形状或结构,如圆柱形、小球、椭圆形、碟形、棒形、球形等。Throughout this specification, the terms "granules", "powder", "fines", "chips" or "crumbs" are used to refer to new, renewable, recovered, recoverable, natural, Small pieces of biological, biodegradable and/or other environmentally friendly or reliable materials, such as by shredding, mechanical grinding, cryogenic grinding or other known techniques or suitable combinations of techniques known to those skilled in the art to "destroy "Small pieces of glass, cork, foam, rubber, flooring, trim, backing and/or similar substances. Thus, particles or chips of cork, foam or rubber employed in contemplated practice may be of any size, including powders, granules and chips. For purposes of describing at least selected embodiments herein, the term "powder" means particles or debris that, as required herein, pass through a 2mm mesh or have a maximum dimension of 2mm in at least one dimension. "Fines" means particles or debris which, as required herein, pass through a 6mm mesh or have a maximum dimension of 6mm in at least one dimension. Fines generally include some powder but are generally larger than powder and have a weight average size close to the maximum value of the fine particle size specification. "Fragments" means particles or debris that are larger than granules. That is, greater than 6 mm in at least one dimension, as required herein. Regardless of actual size, it is envisaged that the particles or debris are preferably characterized by a substantially irregular surface structure, although other shapes or structures such as cylinders, pellets, ovals, discs, rods, spheres, etc. may also be used .

应当注意任何批次的颗粒通常含有小于标称粒径的部分。因此,例如,已经发现,通过使用标准“Endecott”测试筛(ISO3310-1:2200,BE410-1:2000,ASTM E11:95)测量,使用具有1.5mm筛(即具有直径1.5mm的孔)的造粒机制成的橡胶颗粒具有以下尺寸分布,其包括:72.82重量%的粒径为1.0-2.0mm,17.45重量%的粒径为0.71-1.0mm,6.90重量%的粒径为0.5-0.71mm,2.65重量%的粒径为0.25-0.5mm,且0.18重量%的粒径为0-0.25mm。因此,在本说明书中,当我们提及1.5mm的碎屑或粒径时,是指使用具有1.5mm筛的造粒机形成的颗粒。同样,可以理解的是当提及使粘合剂“固化”时,我们是指任何合适的使粘合剂固化的方法,例如使用例如使粘合剂固化、硬化、凝固或热固化之类的技术。本领域技术人员知道根据粘合剂的性质使用何种技术进行固化。粘合剂可选自热固化型和水固化型聚合材料、胶粘剂或其混合物。或者,粘合剂可选自热塑性聚合材料、热熔粘合剂、胶粘剂、可挤出材料及其混合物。It should be noted that any batch of particles will generally contain fractions smaller than the nominal particle size. Thus, for example, it has been found that, as measured by using standard "Endecott" test sieves (ISO3310-1:2200, BE410-1:2000, ASTM E11:95), using an The rubber granules produced by the granulator had the following size distribution comprising: 72.82% by weight of particles with a diameter of 1.0-2.0mm, 17.45% by weight of particles with a diameter of 0.71-1.0mm, and 6.90% by weight of particles with a diameter of 0.5-0.71mm , 2.65% by weight has a particle size of 0.25-0.5mm, and 0.18% by weight has a particle size of 0-0.25mm. Therefore, in this specification when we refer to a crumb or particle size of 1.5mm, we mean granules formed using a granulator with a 1.5mm screen. Likewise, it will be understood that when referring to "curing" an adhesive we mean any suitable method of curing the adhesive, for example using a method such as curing, hardening, setting or heat curing the adhesive. technology. Those skilled in the art know which technique to use for curing depending on the nature of the adhesive. The binder may be selected from heat-curing and water-curing polymeric materials, adhesives or mixtures thereof. Alternatively, the adhesive may be selected from thermoplastic polymeric materials, hot melt adhesives, adhesives, extrudable materials and mixtures thereof.

根据另一预期实践,将组装层(assembled layer)在约50℃至约200℃、优选约110℃至约180℃、最优选约约125℃至177℃的温度进行压制。According to another contemplated practice, the assembled layer is pressed at a temperature of from about 50°C to about 200°C, preferably from about 110°C to about 180°C, most preferably from about 125°C to 177°C.

组装体(assembly)可在包括低温阶段和高温阶段在内的多个阶段中进行压制。根据需要,可以首先采用低温阶段然后采用高温阶段,反之亦然。例如,如果粘合剂选自热固化型或水固化型聚合材料及其混合物,则组装体优选在包括至少一个低温阶段及随后的至少一个高温阶段在内的多个阶段中进行压制。或者,例如,如果粘合剂选自热塑性聚合材料、热熔粘合剂及其混合物,则组装体优选在包括至少一个高温阶段以及随后的至少一个低温阶段或冷却阶段在内的多个阶段中进行压制。The assembly can be pressed in multiple stages including a low temperature stage and a high temperature stage. A low temperature stage can be used first and then a high temperature stage, or vice versa, as desired. For example, if the binder is selected from heat-curing or water-curing polymeric materials and mixtures thereof, the assembly is preferably pressed in stages comprising at least one low temperature stage followed by at least one high temperature stage. Or, for example, if the adhesive is selected from thermoplastic polymeric materials, hot-melt adhesives and mixtures thereof, the assembly is preferably in multiple stages comprising at least one high temperature stage followed by at least one low temperature stage or cooling stage to suppress.

组装体可在一对相对的加压带(双带层压机)之间进行压制,尽管当需要在压力下使组装体固化时,也可以使用其它设备,如在辊和组装体之间选择性地具有膜或织物的一个或多个辊,或者具有可膨胀隔板的压机。Assemblies can be pressed between a pair of opposing press belts (two-belt laminator), although other equipment such as a choice between rollers and assemblies can be used when it is desired to cure the assembly under pressure One or more rolls, optionally with film or fabric, or a press with expandable diaphragms.

纺织品材料连续片材可放置在颗粒/粘合剂层上。所放置的纺织品材料是选择性地浸透、覆盖或涂覆的纺织品材料。作为连续片材的替代或者除连续片材之外,可将分离的纺织品部件连续地放置在颗粒/粘合剂层上。如果需要,胶粘剂层如胶粘剂膜、干胶粘剂或其它弹性胶粘剂可以放置在纺织品面和颗粒/粘合剂层之间、纺织品面和稳定层或材料之间、稳定层或材料和颗粒/粘合剂背衬之间、和/或颗粒/粘合剂背衬之下,以促进层间的粘合。A continuous sheet of textile material may be placed on the particle/binder layer. The placed textile material is a selectively impregnated, covered or coated textile material. Instead of or in addition to the continuous sheet, separate textile components may be placed continuously on the particle/binder layer. If desired, adhesive layers such as adhesive films, dry adhesives or other elastic adhesives can be placed between the textile face and the particle/adhesive layer, between the textile face and the stabilizing layer or material, between the stabilizing layer or material and the granule/adhesive between backings, and/or under particle/adhesive backings, to facilitate interlayer adhesion.

在使用橡胶颗粒的情况下,这些橡胶优选为回收的EPDM或丁腈橡胶。EPDM是用于指代其主要聚合成分是乙烯-丙烯-二烯橡胶单体的橡胶混合物的术语。其还可以含有填料、增塑剂和其它在橡胶合成工业中已知的辅助成分。EPDM颗粒可以是泡沫或固体颗粒。丁腈橡胶是用于描述其主要聚合成分是丙烯腈-丁二烯共聚物的混合橡胶混合物的术语。其还可以含有一种或多种填料,如碳黑、固化系统、增塑剂和其它辅助成分。也可以使用其它橡胶材料,如SBR橡胶颗粒、回收轮胎碎屑、回收垫子碎屑、回收垫子背衬碎屑、橡胶掺合物及其组合。Where rubber particles are used, these rubbers are preferably recycled EPDM or nitrile rubber. EPDM is the term used to refer to rubber compounds whose main polymerized component is ethylene-propylene-diene rubber monomer. It may also contain fillers, plasticizers and other auxiliary ingredients known in the rubber synthesis industry. EPDM particles can be foam or solid particles. Nitrile rubber is the term used to describe hybrid rubber compounds whose main polymeric component is acrylonitrile-butadiene copolymer. It may also contain one or more fillers such as carbon black, curing systems, plasticizers and other auxiliary ingredients. Other rubber materials may also be used, such as SBR rubber granules, recycled tire crumbs, recycled mat crumbs, recycled mat backing crumbs, rubber blends, and combinations thereof.

在使用泡沫颗粒的情况下,这种泡沫优选为回收的聚氨酯泡沫或EPDM泡沫。这种泡沫,尤其是聚氨酯泡沫,可经过机械发泡和/或化学吹泡,并且可以具有开孔结构或闭孔结构。也可以使用其它泡沫,如再生粘接泡沫、废物再生粘接泡沫、腈泡沫、SBR泡沫、回收垫子碎屑、回收泡沫垫子背衬、回收的衬有泡沫的地板、回收的地板泡沫背衬、其它回收泡沫材料、其掺合物、其组合等。Where foam particles are used, this foam is preferably recycled polyurethane foam or EPDM foam. Such foams, especially polyurethane foams, can be mechanically and/or chemically blown and can have an open-cell or closed-cell structure. Other foams can also be used such as recycled bonded foam, waste recycled bonded foam, nitrile foam, SBR foam, recycled cushion scraps, recycled foam cushion backing, recycled foam lined flooring, recycled floor foam backing, Other recycled foam materials, blends thereof, combinations thereof, and the like.

在至少一个实施方式中,颗粒/粘合剂背衬的密度小于约1g/cm3。在至少一个实施方式中,颗粒/粘合剂背衬的密度为约0.5至约0.9g/cm3,更优选约0.7至约0.9g/cm3In at least one embodiment, the particle/binder backing has a density of less than about 1 g/cm 3 . In at least one embodiment, the particle/binder backing has a density of about 0.5 to about 0.9 g/cm 3 , more preferably about 0.7 to about 0.9 g/cm 3 .

在至少一个实施方式中,颗粒/粘合剂背衬表现出至少约0.8N/mm2的耐撕裂强度,更优选颗粒/粘合剂背衬的耐撕裂强度为约1.5N/mm2或者更高。In at least one embodiment, the particle/adhesive backing exhibits a tear strength of at least about 0.8 N/mm 2 , more preferably the particle/adhesive backing has a tear strength of about 1.5 N/mm 2 or higher.

有利地,根据至少所选的实施方式,纺织品表面或面包括相对平整的纺织品或织物结构,如簇绒、植绒、针刺、非织造、针织或机织纺织品结构。如果需要,这些材料可形成、机织、针织、印花和/或喷染有装饰性表面图案。这些纺织品材料优选用至少一种澄清的保护膜或成膜组合物[如聚氨酯、丙烯酸系聚合物、聚酯等(优选在固化后至少为透明或半透明的)]来浸透、覆盖或涂覆。纺织品材料可以在印花、染色、制造、加背衬等之前或之后被浸透。在至少一个实施方式中,纺织品材料优选在浸透之前印花或染色。采用一种或多种升华印花技术,纺织品材料可在例如用透明材料浸透、覆盖或涂覆之后印花。完全浸透或进行完全浸透是指浸透、渗透或浸泡纺织品并充分覆盖以形成保护性的外膜、涂层等。纺织品表面或面可通过例如浸涂机来一次性完全浸透或涂覆,或者可通过先涂布一侧然后涂布另一侧(上侧和下侧)来涂布和浸透,例如在每侧上使用辊涂机,然后使用夹辊。可经过多步或一步来完成完全浸透。此外,可在纺织品的底部涂覆一种材料如不透明热熔体、胶粘剂、乳胶材料或二苯甲烷二异氰酸酯(MDI)粘合剂,并且在纺织品的顶部使用另一种材料如透明的聚氨酯、聚酯、丙烯酸等。或者,可将一层或多层膜放置在纺织品表面或面材料的顶部和/或底部。例如,在所选实施方式中,优选澄清、透明或半透明的树脂或聚合物膜或多层膜,如聚酯、聚氨酯、聚烯烃、其掺合物、其组合等。例如,第一聚氨酯膜可以放置或挤出在纺织品顶部,然后聚酯膜可放置或者挤出在聚氨酯膜之上。在其它所选实施方式中,可使用一层或多层有色、白色图案、印花或其它不透明膜。例如,将白色膜放置或挤出在纺织品上,印花,然后用一层或多层透明膜覆盖。当固化或加热时,多个膜层将熔合形成单一结构。作为另一个例子,纺织品的顶部可用第一薄膜胶粘剂、第二不透明膜和第三透明膜或磨损层来覆盖。同样,纺织品面材料的底部也可以在其底部上具有一层或多层膜或涂层,如一层或多层胶粘剂膜、稳定膜及其组合等。根据所使用的膜或涂层,其中一层或多层可用作例如磨损层、覆盖层、美化层、图形或印花层、防潮层、粘合剂层、稳定层、背衬等。因此,可经一步或多步用一种或多种材料来涂覆、覆盖或浸透纺织品面或表面材料。可在涂覆的纺织品表面材料上加上一层或多层其它优选透明防污渍、防污和/或耐磨层。或者或另外地,纺织品或织物表面材料的纱线或纤维可用这些材料涂覆。例如,面纱可以是涂覆的天然和/或合成纤维或纱线,例如用透明的无色或有色聚烯烃或PVC聚合材料来挤压涂覆的聚酯或聚烯烃单纤维或多纤维白色或有色纱线,在所述透明的无色或有色聚烯烃或PVC聚合材料上涂覆有透明的聚合物磨损层或膜,如高密度聚丙烯、聚酯、丙烯酸系聚合物、聚氨酯、其掺合物、其组合等。Advantageously, according to at least selected embodiments, the textile surface or face comprises a relatively flat textile or fabric structure, such as a tufted, flocked, needle punched, nonwoven, knitted or woven textile structure. These materials may, if desired, be formed, woven, knitted, printed and/or spray dyed with a decorative surface pattern. These textile materials are preferably impregnated, covered or coated with at least one clear protective film or film-forming composition [such as polyurethane, acrylic polymer, polyester, etc. (preferably at least transparent or translucent after curing)] . Textile materials may be saturated before or after printing, dyeing, manufacturing, backing, etc. In at least one embodiment, the textile material is preferably printed or dyed prior to impregnation. Using one or more sublimation printing techniques, the textile material can be printed, for example after being saturated, covered or coated with a transparent material. To saturate or to saturate completely means to saturate, penetrate or soak the textile and cover it sufficiently to form a protective outer film, coating, etc. The textile surface or face can be completely saturated or coated in one go by, for example, a dip coater, or it can be coated and saturated by coating one side first and then the other side (upper and lower), for example on each side Use a roller coater on top, then use a pinch roller. Complete impregnation can be accomplished in multiple steps or in one step. In addition, one material such as opaque hot melt, adhesive, latex material or methylene diphenyl diisocyanate (MDI) adhesive can be applied on the bottom of the textile and another material such as clear polyurethane, Polyester, Acrylic etc. Alternatively, one or more films may be placed on top and/or bottom of the textile surface or facing material. For example, clear, transparent or translucent resinous or polymeric films or multilayer films such as polyesters, polyurethanes, polyolefins, blends thereof, combinations thereof, and the like are preferred in selected embodiments. For example, a first polyurethane film can be placed or extruded on top of the textile and then a polyester film can be placed or extruded over the polyurethane film. In other selected embodiments, one or more layers of colored, white graphic, printed or other opaque films may be used. For example, a white film is placed or extruded onto a textile, printed and then covered with one or more layers of transparent film. When cured or heated, the multiple film layers will fuse to form a single structure. As another example, the top of the textile may be covered with a first film adhesive, a second opaque film, and a third transparent film or wear layer. Likewise, the bottom of the textile facing material may also have one or more films or coatings on its bottom, such as one or more layers of adhesive films, stabilizing films, combinations thereof, and the like. Depending on the film or coating used, one or more of these can be used, for example, as a wear layer, cover layer, aesthetic layer, graphic or print layer, moisture barrier layer, adhesive layer, stabilization layer, backing, and the like. Thus, a textile face or surface material may be coated, covered or saturated with one or more materials in one or more steps. One or more further, preferably transparent, stain-resistant, stain-resistant and/or abrasion-resistant layers may be added to the coated textile surface material. Alternatively or additionally, the yarns or fibers of textile or fabric surface materials may be coated with these materials. For example, the veil may be coated natural and/or synthetic fibers or yarns, such as polyester or polyolefin monofilament or multifiber white or polyolefin extrusion coated with clear colorless or colored polyolefin or PVC polymeric material Colored yarn coated with a clear polymer wear layer or film such as high density polypropylene, polyester, acrylic, polyurethane, blends thereof, on said clear colorless or colored polyolefin or PVC polymeric material Compounds, combinations thereof, etc.

根据至少一个实施方式,本发明可涉及具有涂覆纱线纺织品显露表面或面和选择性的背衬的表面覆盖物,如地板覆盖物、墙壁覆盖物、家俱覆盖物等。涂覆纱线纺织品显露表面或面是选择性地浸透、覆盖、涂覆的,或者包括保护性涂层组合物或磨损表面,如至少一种透明树脂或聚合材料。在至少一个示例性实施方式中,涂覆纱线纺织品显露表面与背衬成覆盖关系,所述背衬由结团的邻接颗粒部件构成或包括结团的邻接颗粒部件。在至少另一个示例性实施方式中,涂覆纱线纺织品显露表面与背衬成覆盖关系,所述背衬由泡沫垫层构成或包括泡沫垫层。具体但非排他性地,涂覆纱线纺织品表面覆盖物优选为地板覆盖物,包括但不限于地毯、地毯砖、地板、地砖、区块地毯、小块地毯、长条地毯、垫子、地板垫、稳定宽幅地毯、组合地板、卷材等。表面覆盖物中可包括簇绒、粘绒、针织、机织、非织造、针刺、植绒等装饰性涂覆纱线纺织品层。涂覆纱线纺织品层可用至少一种膜或成膜组合物来浸透、覆盖和/或涂覆,所述膜或成膜组合物在固化时理想地为透明或半透明的。或者或另外地,表面涂覆纱线或纤维可包括一层或多层涂层或层,如透明、半透明和/或有色的涂层或层。例如,面纱可以包括单或多纤维(短纤维或连续纱)、丝(包括长丝和单丝)或材料带,其是白色、透明或有色的,并形成芯纱或芯丝(如单丝)或涂覆有一层或多层涂层、覆层、外壳、磨损层等的芯材料。另外,还希望所述膜或成膜组合物或一种或者多种涂层或层具有耐磨、耐脏、耐污渍、美学上令人愉悦、可熔合和/或类似性质。在一个实施方式中,涂覆纱线纺织品表面可以以覆盖关系设置在由结团颗粒块构成的弹性和/或柔性的背衬上,所述颗粒的例子是不规则颗粒,如新的、回收的、可回收的、可再生的、天然的、和/或其它环保或可靠的材料,如新的和/或回收的地毯、地砖、垫子、轮胎、挡风雨条、涂覆纱线表面覆盖物、泡沫、橡胶、软木、玻璃、其掺合物、其组合等。纺织品表面和颗粒背衬通常以邻接关系粘合在一起。选择性的胶粘剂膜或层、稳定层、纺织品背衬和/或类似物质可放置在弹性背衬之上、之中或之下。增大摩擦、胶粘或有助于安装的材料或涂层可加入到背衬之中和/或加到背衬的底侧上。例如,颗粒背衬可包括增加横向握持、减少滑动等的空隙。或者或另外地,具有增大摩擦的涂层、材料、花纹等的毡背衬可加到颗粒背衬之下或泡沫背衬之下。涂覆面纱可以是涂覆的天然和/或合成纤维或丝或材料纱线,例如用透明的无色、白色或有色聚烯烃或PVC聚合材料挤压涂覆的单或多纤维、丝或聚酯或聚烯烃材料的透明的无色、白色或有色纱线,在所述透明的无色、白色或有色聚烯烃或PVC聚合材料上涂覆有透明的无色聚合物磨损层或膜,如高密度聚丙烯。还提供了这些表面覆盖物的制造和回收方法。According to at least one embodiment, the present invention may relate to surface coverings, such as floor coverings, wall coverings, furniture coverings, etc., having a coated yarn textile exposed surface or face and an optional backing. The coated yarn textile exposed surface or face is selectively impregnated, covered, coated, or includes a protective coating composition or abrasive surface, such as at least one transparent resin or polymeric material. In at least one exemplary embodiment, the coated yarn textile exposed surface is in overlying relationship with a backing that consists of or includes agglomerated contiguous particle components. In at least another exemplary embodiment, the coated yarn textile exposed surface is in covering relationship with a backing that is comprised of or includes a foam cushion. Specifically, but not exclusively, the coated yarn textile surface covering is preferably a floor covering including but not limited to carpets, carpet tiles, floors, floor tiles, carpet tiles, rugs, carpet strips, mats, floor mats, Stabilizes broadloom carpet, laminate flooring, rolls and more. Tufted, visored, knitted, woven, nonwoven, needle punched, flocked, etc. decorative coated yarn textile layers may be included in the surface covering. The coated yarn textile layer can be impregnated, covered and/or coated with at least one film or film-forming composition that is desirably transparent or translucent when cured. Alternatively or additionally, surface-coated yarns or fibers may include one or more coatings or layers, such as transparent, translucent and/or colored coatings or layers. For example, a veil may comprise single or multiple fibers (staple or continuous), filaments (including filaments and ) or core material coated with one or more coatings, claddings, shells, wear layers, etc. Additionally, it is also desirable that the film or film-forming composition or one or more coatings or layers be abrasion resistant, stain resistant, stain resistant, aesthetically pleasing, fusible, and/or the like. In one embodiment, the coated yarn textile surface may be disposed in overlying relationship on an elastic and/or flexible backing composed of agglomerated clumps of particles, examples of which are irregular particles such as new, recycled recycled, renewable, natural, and/or other environmentally friendly or reliable materials such as new and/or recycled carpet, floor tiles, rugs, tires, weatherstripping, coated yarn surface coverings , foam, rubber, cork, glass, blends thereof, combinations thereof, etc. The textile surface and the particulate backing are usually bonded together in contiguous relationship. Optional adhesive films or layers, stabilizing layers, textile backings and/or the like may be placed on, in or under the elastic backing. Materials or coatings that increase friction, stickiness, or facilitate installation can be incorporated into the backing and/or onto the underside of the backing. For example, the particle backing can include voids to increase lateral grip, reduce slippage, and the like. Alternatively or additionally, a felt backing with a friction increasing coating, material, pattern, etc. may be added under the particle backing or under the foam backing. The coated veil may be a coated natural and/or synthetic fiber or silk or material yarn, such as single or multi-fiber, silk or poly Transparent colorless, white or colored yarns of ester or polyolefin material coated with a transparent colorless polymeric wear layer or film such as High density polypropylene. Methods of manufacture and recycling of these surface coverings are also provided.

附图说明 Description of drawings

通过实施例的方式并参考附图来描述本发明的至少某些示例性实施方式或方面,这些附图简要说明如下:At least some exemplary embodiments or aspects of the invention are described, by way of example, with reference to the accompanying drawings, which are briefly described as follows:

图1是具有纤维显露表面的示例性表面覆盖物部件的侧视截面图,其描绘了分层组成部件和选择性的附加上侧膜或层(如保护层)和选择性的下侧膜或层(如增大摩擦的层或胶粘剂层);Figure 1 is a side cross-sectional view of an exemplary surface covering component having a fiber-exposing surface, depicting a layered component component and an optional additional upper side film or layer (such as a protective layer) and an optional lower side film or layers (such as friction-enhancing layers or adhesive layers);

图2是用于制造表面覆盖物(如图1的表面覆盖物等)的示例性生产线的侧视图,所述表面覆盖物包括例如织物显露表面和颗粒背衬(如橡胶颗粒和粘合剂的背衬);Figure 2 is a side view of an exemplary production line for the manufacture of a surface covering (such as that of Figure 1, etc.) comprising, for example, a fabric exposed surface and a particle backing (such as rubber particles and adhesive) backing);

图2A是类似于图2的侧视图,其描述了用于制造表面覆盖物(例如带有或不带有纺织品背衬452的图7的表面覆盖物等)的示例性生产线,所述表面覆盖物包括例如织物显露表面、选择性的胶粘剂层和预成型的颗粒背衬(如再生粘接泡沫);FIG. 2A is a side view similar to FIG. 2 depicting an exemplary production line for manufacturing a surface covering, such as the surface covering of FIG. 7 with or without a textile backing 452, etc. Materials include, for example, fabric exposed surfaces, optional adhesive layers, and preformed particle backings (e.g., recycled adhesive foam);

图2B是类似于图2的侧视图,其描述了用于制造表面覆盖物(如图1的表面覆盖物等)的另一种示例性生产线,所述表面覆盖物具有织物显露表面和颗粒背衬;2B is a side view similar to FIG. 2 depicting another exemplary production line for manufacturing a surface covering, such as that of FIG. 1 , etc., having a fabric exposed surface and a particle backing. lining;

图3是类似于图1的截面侧视图,其描述了另一种示例性表面覆盖物部件,所述示例性表面覆盖物部件具有与稳定颗粒背衬胶粘结合的织物表面,所述稳定颗粒背衬带有底层背衬片和选择性的其它上和/或下层;3 is a cross-sectional side view similar to FIG. 1 depicting another exemplary surface covering component having a fabric surface adhesively bonded to a backing of stabilizing particles, the stabilizing particles Backing with a bottom backing sheet and optionally other upper and/or lower layers;

图4是用于制造表面覆盖物(如图11或图3中所示的具有分层结构的表面覆盖物等)的示例性生产线的侧视图,所述表面覆盖物包括织物显露表面和颗粒背衬,或者包括与带有选择性的上下层的稳定颗粒背衬(如橡胶颗粒和粘合剂的背衬)胶粘结合的织物表面;4 is a side view of an exemplary production line for manufacturing a surface covering (such as a surface covering having a layered structure as shown in FIG. 11 or FIG. 3 , etc.) comprising a fabric exposed surface and a particle backing Lining, or comprising a fabric surface adhesively bonded to a stable particle backing (such as a backing of rubber particles and adhesive) with optional upper and lower layers;

图4A是类似于图4的侧视图,其描述了用于制造例如具有如图3所示的分层结构等的表面覆盖物的示例性生产线,所述表面覆盖物包括与预成型的稳定颗粒背衬(例如,具有例如两个预成型的再生粘接泡沫层和选择性的附加层的再生粘接泡沫背衬)胶粘结合的织物显露表面;4A is a side view similar to FIG. 4 depicting an exemplary production line for manufacturing a surface covering, such as having a layered structure as shown in FIG. 3 , comprising preformed stabilizing particles a fabric exposed surface adhesively bonded to the backing (e.g., a recycled adhesive foam backing having, for example, two preformed recycled adhesive foam layers and optionally additional layers);

图5是与图1相类似的示例性表面覆盖物的截面侧视图,其包括纺织品背衬如纤维背衬片;Figure 5 is a cross-sectional side view similar to Figure 1 of an exemplary surface covering comprising a textile backing such as a fibrous backing sheet;

图6是与图3、图5或图7相类似的示例性表面覆盖物部件的截面侧视图,其描绘了具有与稳定颗粒背衬胶粘结合的织物显露表面的另一种结构,所述稳定颗粒背衬带有底层背衬片和选择性的附加层;Figure 6 is a cross-sectional side view of an exemplary surface covering component similar to Figure 3, Figure 5, or Figure 7, depicting another structure having a fabric exposed surface adhesively bonded to a stabilizing particle backing, said Stabilized particle backing with an underlying backing sheet and optional additional layers;

图7是与图3、图5或图6相类似的示例性表面覆盖物部件的截面侧视图,其描绘了具有与颗粒背衬胶粘结合的织物显露表面的示例性结构,所述颗粒背衬带有底层背衬片和选择性的附加层;Figure 7 is a cross-sectional side view of an exemplary surface covering component similar to Figure 3, Figure 5, or Figure 6, depicting an exemplary structure having a fabric exposed surface adhesively bonded to a particle backing Backing with an underlying backing sheet and optional additional layers;

图8是与图1、图5或图7相类似的示例性表面覆盖物部件的截面侧视图,所述示例性表面覆盖物部件包括粘合纤维背衬片的胶粘层;Figure 8 is a cross-sectional side view similar to Figure 1 , Figure 5, or Figure 7 of an exemplary surface covering component comprising an adhesive layer bonding a fibrous backing sheet;

图9是与图8或图7相类似的示例性表面覆盖物部件的截面侧视图,所述示例性表面覆盖物部件在颗粒背衬层的任一侧上包括胶粘剂层;9 is a cross-sectional side view similar to FIG. 8 or FIG. 7 of an exemplary surface covering component including an adhesive layer on either side of a particle backing layer;

图10是描述具有与图6相类似的结构的示例性表面覆盖物部件的截面侧视图,所述示例性表面覆盖物部件中包括稳定层(如玻璃垫和稀松布稳定层)的组合;10 is a cross-sectional side view depicting an exemplary surface covering component having a structure similar to that of FIG. 6 including a combination of stabilizing layers such as a glass mat and a scrim stabilizing layer therein;

图11是与图3相类似的示例性表面覆盖物部件的截面侧视图,但不包括至少某些胶粘剂附加层;Figure 11 is a cross-sectional side view of an exemplary surface covering component similar to Figure 3, but excluding at least some of the additional layer of adhesive;

图12是示例性表面覆盖物部件(如地砖产品)的顶视图,所述示例性表面覆盖物部件包括装饰性显露表面和选择性的上层[如一层或多层其它保护层及纹理(如压花)]);12 is a top view of an exemplary surface covering component (such as a floor tile product) including a decorative exposed surface and an optional upper layer [such as one or more other protective layers and texture (such as embossed flower)]);

图13是沿图12中直线13-13截取的侧视图,其描述了具有背衬和选择性的底层的图12的表面覆盖物部件;Figure 13 is a side view taken along line 13-13 in Figure 12, which depicts the surface covering component of Figure 12 with a backing and an optional bottom layer;

图14是示例性表面覆盖物部件(如地砖产品)的顶视图,所述示例性表面覆盖物部件包括具有外边际区的装饰性显露表面和选择性的上层[一层或多层其它保护层及纹理(如压花)];14 is a top view of an exemplary surface covering component, such as a floor tile product, including a decorative exposed surface with an outer margin region and an optional upper layer [one or more other protective layers and texture (such as embossing)];

图15是沿图14中直线15-15截取的侧视图,其描述了具有背衬和选择性的底层的图14的表面覆盖物部件;Figure 15 is a side view taken along line 15-15 in Figure 14, which depicts the surface covering component of Figure 14 with a backing and an optional bottom layer;

图16是放大的截面端视图,其描述了根据本发明的面结构的一个实施方式的示例性涂覆纱线;Figure 16 is an enlarged cross-sectional end view illustrating an exemplary coated yarn according to one embodiment of a face structure of the present invention;

图17A是放大的截面端视图,其描述了根据面结构的另一个实施方式的示例性涂覆纱线;Figure 17A is an enlarged cross-sectional end view illustrating an exemplary coated yarn according to another embodiment of a face structure;

图17B是沿图17A中直线17B-17B截取的放大的截面侧视图,其描述了一段图17A的涂覆纱线;Figure 17B is an enlarged cross-sectional side view taken along line 17B-17B in Figure 17A, which depicts a section of the coated yarn of Figure 17A;

图18是放大的截面端视图,其描述了根据面结构的再一个实施方式的再一种示例性涂覆纱线、纤维、丝或材料;Figure 18 is an enlarged cross-sectional end view illustrating yet another exemplary coated yarn, fiber, filament or material according to yet another embodiment of a face structure;

图19是放大的截面端视图,其描述了根据面结构的另一个实施方式的另一种示例性涂覆纱线、纤维、丝或材料;Figure 19 is an enlarged cross-sectional end view illustrating another exemplary coated yarn, fiber, filament or material according to another embodiment of a face structure;

图20是放大的截面端视图,其描述了根据面结构的再一个实施方式的具有多根芯纱的另一种示例性涂覆纱线(或多种纱线);Figure 20 is an enlarged cross-sectional end view illustrating another exemplary coated yarn (or yarns) having a plurality of core yarns according to yet another embodiment of a face structure;

图21A-21D分别是放大的截面端视图,它们分别描述了根据相应面结构的实施方式的示例性面纤维、丝或材料形状;21A-21D are enlarged cross-sectional end views, each depicting an exemplary face fiber, filament, or material shape according to an embodiment of a corresponding face structure;

图22是机织面表面覆盖物如机织面地板结构的示例性实施方式的剖面侧视图;Figure 22 is a cutaway side view of an exemplary embodiment of a woven surface covering, such as a woven flooring structure;

图23是包含可能优选的泡沫背衬结构的示例性机织面表面覆盖物的剖面侧视图;Figure 23 is a cutaway side view of an exemplary woven face surface covering comprising a possibly preferred foam backing structure;

图24是包含可能优选的泡沫背衬结构的示例性簇绒面表面覆盖物的剖面侧视图;Figure 24 is a cutaway side view of an exemplary tufted face surface covering comprising a possibly preferred foam backing structure;

图25是与图24相类似的具有短割绒的另一种簇绒面表面覆盖物的剖面侧视图;Figure 25 is a cutaway side view of another tufted surface covering similar to Figure 24 with short cut pile;

图26是与图24相类似的具有短或紧的起圈绒头的另一种簇绒面表面覆盖物的剖面侧视图;Figure 26 is a cutaway side view of another tufted face surface covering similar to Figure 24 with short or tight loop piles;

图27是与图22相类似的另一种非织造面表面覆盖物的剖面侧视图;且Figure 27 is a cross-sectional side view of another nonwoven surface covering similar to Figure 22; and

图28是与图22相类似的另一种针刺或针冲压面表面覆盖物的剖面侧视图。FIG. 28 is a cross-sectional side view similar to FIG. 22 of an alternative needled or needle punched face surface covering.

具体实施方式 Detailed ways

本发明可涉及工艺、方法、用途、装置和/或产品,例如具有纺织品或织物显露表面、装饰层或面和选择性的背衬的表面覆盖物,如地板覆盖物、墙壁覆盖物、家俱覆盖物等。所述纺织品显露表面、层或面是选择性地浸透、覆盖和/或涂覆的,或者包括保护性涂层组合物或磨损表面,如透明树脂或聚合材料。在至少一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬由结团的邻接颗粒部件构成或包括结团的邻接颗粒部件。在至少另一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬由泡沫垫层构成或包括泡沫垫层。在另一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬是颗粒和泡沫的掺合或组合背衬。具体但非排他性地,本发明的至少一个实施方式涉及表面覆盖物,例如地板覆盖物,包括但不限于地毯、地毯砖、地板、地砖、小块地毯、区块地毯、长条地毯、垫子、地板垫、稳定宽幅地毯、组合地板、卷材等。表面覆盖物中可加入簇绒、粘绒、针织、机织、非织造、针刺、植绒等纺织品或织物显露表面、表面材料、装饰纺织品层等。所述纺织品层可用膜或成膜组合物来浸透、覆盖和/或涂覆,所述膜或成膜组合物在固化时理想地为透明或者半透明的。或者或另外地,面纱或纤维可包括一种或多种涂层或层,如透明、半透明和/或有色的涂层或层。例如,面纱可包括芯纱或芯纤维或芯丝或涂覆有一层或多层涂层、覆层、外壳、层、磨损层、膜等的芯材料。另外还希望所述膜或成膜组合物或一种或多种涂层或层具有耐磨、耐脏、耐污渍、美学上令人愉悦、可熔合和/或类似性质。在一个实施方式中,纺织品表面可以以覆盖关系设置在由结团颗粒块构成的弹性和/或柔性的背衬上,所述颗粒的例子是不规则颗粒,如新的、回收的、可回收的、可再生的、天然的、生物类的、可生物降解的和/或其它环保或可靠的材料,如新的或回收的表面材料、背衬材料、表面覆盖物、泡沫、橡胶、软木、其掺合物、其组合等。纺织品表面和颗粒背衬通常以邻接关系粘合在一起。选择性的胶粘剂层、胶粘剂膜、稳定层、纺织品背衬和/或类似物质可设置在弹性背衬之上、之中或之下。增大摩擦、粘合或有助于安装的材料或涂层可加入到颗粒背衬中和/或加到颗粒背衬的底侧上。例如,颗粒背衬可包括增加横向握持、减少滑动等的空隙。或者或另外地,具有增大摩擦的涂层的纺织品或织物背衬可附加在颗粒背衬之下、泡沫背衬之下或者颗粒和泡沫的混合或组合背衬之下。还提供了这些表面覆盖物的制造和回收方法。The present invention may relate to processes, methods, uses, devices and/or products, such as surface coverings, such as floor coverings, wall coverings, furniture coverings, having a textile or fabric exposed surface, a decorative layer or face and optionally a backing things etc. The textile exposed surface, layer or face is selectively impregnated, covered and/or coated, or includes a protective coating composition or an abrasive surface, such as a transparent resin or polymeric material. In at least one exemplary embodiment, the textile exposed surface is in overlying relationship with a backing that consists of or includes agglomerated contiguous particle components. In at least another exemplary embodiment, the textile exposed surface is in covering relationship with a backing that is comprised of or includes a foam cushion. In another exemplary embodiment, the textile exposed surface is in covering relationship with a backing that is a blend or combination of particles and foam. Specifically, but not exclusively, at least one embodiment of the present invention relates to surface coverings, such as floor coverings, including but not limited to carpets, carpet tiles, floors, floor tiles, rugs, carpet tiles, carpet strips, mats, Floor mats, stable broadloom carpets, floor tiles, rolls, etc. Tufted, viscose, knitted, woven, non-woven, needle punched, flocked and other textiles or fabric exposed surfaces, surface materials, decorative textile layers, etc. can be added to the surface covering. The textile layer may be impregnated, covered and/or coated with a film or film-forming composition which is desirably transparent or translucent when cured. Alternatively or additionally, the veil or fibers may include one or more coatings or layers, such as transparent, translucent and/or colored coatings or layers. For example, the face yarn may comprise a core yarn or core fiber or filament or core material coated with one or more coatings, sheaths, sheaths, layers, wear layers, films, and the like. It is also desirable that the film or film-forming composition or one or more coatings or layers be abrasion resistant, stain resistant, stain resistant, aesthetically pleasing, fusible, and/or the like. In one embodiment, the textile surface may be disposed in overlying relationship on an elastic and/or flexible backing composed of agglomerated clumps of particles, examples of which are irregular particles such as new, recycled, recyclable renewable, natural, bio-based, biodegradable and/or other environmentally friendly or reliable materials such as new or recycled surface materials, backing materials, surface coverings, foam, rubber, cork, Blends thereof, combinations thereof, and the like. The textile surface and the particulate backing are usually bonded together in contiguous relationship. Optional adhesive layers, adhesive films, stabilizing layers, textile backings and/or the like may be disposed on, in or under the elastic backing. Materials or coatings that increase friction, adhesion, or aid in fit may be added to the particle backing and/or to the underside of the particle backing. For example, the particle backing can include voids to increase lateral grip, reduce slippage, and the like. Alternatively or additionally, a textile or fabric backing with a friction-enhancing coating may be affixed under the particle backing, under the foam backing, or under a mix or combination of particles and foam. Methods of manufacture and recycling of these surface coverings are also provided.

在至少所选的实施方式中,本发明通过提供以下表面覆盖物而提出、提供了优于现有结构的优势,或者提供了优于现有结构的替代性方案,所述表面覆盖物的例子是地板覆盖物,包括但不限于地毯、地毯砖、地板、地砖、小块地毯、区块地毯、长条地毯、垫子、稳定宽幅地毯、组合地板、卷材等,所述表面覆盖物包括例如界定显露表面的装饰纺织品或织物面和硬底或衬垫背衬,所述背衬的例子是由例如新的、回收的、可回收的、天然的、和/或可再生材料构成的泡沫和/或颗粒背衬,所述可再生材料的例子是天然和/或合成材料,例如优选回收材料和填料(例如回收的表面覆盖物、地板、表面织物、背衬、橡胶、泡沫、软木、其掺合物、其组合和/或类似物质)的颗粒(粉末、小粒和/或碎屑)。这些表面覆盖物的装饰表面优选由机织、针织或非织造结构的平整织物或纺织品形成,但也可使用簇绒、植绒或针刺结构。装饰面可由具有或不具有透明或半透明涂层或层的有色纱线或纤维或丝或材料形成,或者或另外地,如印刷文字、图案、色彩、图像或图形等装饰图案可印花或染色到纺织品表面。如需要,选择性地在印花或染色之后,用膜或有效成膜量的保护性成膜组合物来将装饰面织物浸透、覆盖和/或涂覆,所述保护性成膜组合物的例子是透明或半透明的耐磨、耐污渍或耐脏组合物如透明树脂或聚合物,例如聚氨酯、丙烯酸系聚合物、聚酯、聚烯烃、聚酰胺、高密度聚烯烃、高密度聚丙烯等。如需要,例如由玻璃(如纤维玻璃、玻璃纤维、玻璃垫、玻璃稀松布等)构成的稳定层可应用在背衬之上或之中,或者可用作背衬。。在一个可能的优选结构中,稳定层可嵌入颗粒背衬之中。纺织品背衬层也可施加在泡沫或颗粒背衬的下侧。可将增大摩擦的涂层或材料加在颗粒和/或泡沫背衬的下侧或纺织品背衬的下侧。In at least selected embodiments, the present invention addresses, provides advantages over, or provides an alternative to existing structures by providing surface coverings, examples of which are are floor coverings, including but not limited to carpets, carpet tiles, floors, tiles, rugs, carpet tiles, carpet strips, rugs, stable broadloom, floor tiles, rolls, etc., said surface coverings including Such as an upholstery textile or fabric face defining a revealing surface and a rigid or padded backing, examples of which are foams constructed of, for example, new, recycled, recyclable, natural, and/or renewable materials and/or particle backing, examples of said renewable materials are natural and/or synthetic materials such as preferably recycled materials and fillers (e.g. recycled surface coverings, floors, surface fabrics, backings, rubber, foam, cork, blends thereof, combinations thereof and/or the like) particles (powders, granules and/or crumbs). The decorative surfaces of these surface coverings are preferably formed from flat fabrics or textiles of woven, knitted or nonwoven construction, but tufted, flocked or needled constructions may also be used. The decorative surface may be formed from colored yarns or fibers or filaments or materials with or without a transparent or translucent coating or layer, or, or in addition, decorative motifs such as printed text, patterns, colours, images or graphics may be printed or dyed onto the textile surface. If desired, optionally after printing or dyeing, the decorative fabric is impregnated, covered and/or coated with a film or an effective film-forming amount of a protective film-forming composition, examples of which are Abrasion-, stain- or stain-resistant compositions that are transparent or translucent such as transparent resins or polymers, such as polyurethanes, acrylic polymers, polyesters, polyolefins, polyamides, high-density polyolefins, high-density polypropylene, etc. . If desired, a stabilizing layer, eg, composed of glass (eg, fiberglass, fiberglass, glass mat, glass scrim, etc.) can be applied on or in the backing, or can be used as the backing. . In one possible preferred configuration, the stabilizing layer can be embedded in the particulate backing. A textile backing layer may also be applied on the underside of a foam or particle backing. A friction increasing coating or material may be added to the underside of the particle and/or foam backing or the underside of the textile backing.

虽然根据至少所选的实施方式,表面覆盖物具有颗粒背衬,优选弹性或柔性颗粒背衬,但可设想表面覆盖物可具有其它胶粘剂、树脂、聚合物、织物、纺织品、泡沫和/或类似的背衬或背衬层。例如,至少某些可能的优选实施方式的地砖具有硬底或衬垫背衬、颗粒、泡沫、胶粘剂、树脂、聚合物、织物、纺织品和/或类似背衬或背衬层,以及一层或多层选择性的稳定层、背衬层或增大摩擦的层。Although according to at least selected embodiments, the surface covering has a particle backing, preferably an elastic or flexible particle backing, it is contemplated that the surface covering may have other adhesives, resins, polymers, fabrics, textiles, foams, and/or the like backing or backing layer. For example, at least some of the possible preferred embodiment floor tiles have a hard substrate or cushion backing, particles, foams, adhesives, resins, polymers, fabrics, textiles, and/or similar backings or backing layers, and a layer or Multiple optional stabilizing, backing or friction increasing layers.

参考图1,以截面方式描述了表面覆盖物10的示例性实施方式,例如地板覆盖物,如地毯、地毯砖、地板、地砖、组合地板、区块地毯、小块地毯、长条地毯、垫子、地板垫、卷材、稳定宽幅地毯等。应当理解,为便于理解,将以放大的尺度对各层进行描述。因此,所描述的尺度并非必须对应于在层或最终结构中的最终相对厚度水平。Referring to FIG. 1 , an exemplary embodiment of a surface covering 10 , such as a floor covering, such as carpet, carpet tile, floor, floor tile, floor tile, carpet tile, rug, carpet strip, mat, is depicted in cross-section. , floor mats, rolls, stable broadloom carpets, etc. It should be understood that the various layers will be depicted on an exaggerated scale for ease of understanding. Thus, the dimensions described do not necessarily correspond to final relative thickness levels in layers or in the final structure.

如所示,在图1所示的示例性实施方式中,表面覆盖物10包括外复合层18,该外复合层18包括优选基本上平整的机织、非织造或针织织物或纺织品结构的纺织品显露表面12,所述纺织品显露表面12优选用选择性的耐磨性成膜组合物16来浸透或涂覆,这在纺织品显露表面12上界定了封闭的保护屏障。复合层18可包括一层或多层选择性的保护、耐磨、耐污渍、耐脏和/或类似的附加层、膜、涂层或类似物17。外复合层18以覆盖关系设置在单层或多层选择性的背衬结构14上,正如在下文中所进一步描述的,例如,所述背衬结构14包括例如新的、回收的、可回收的、天然的、生物类的、可生物降解的和/或其它环保或可靠的材料,例如回收地板、泡沫、橡胶、软木和/或玻璃颗粒的结团颗粒块。正如可以理解的,在提到纺织品显露表面时使用的术语“平整”意指显露表面12上优选无绒头或低绒头的表面轮廓,而不是指任何具体的成型技术。在此方面,应当理解,平整织物可包括相对低表面绒头水平的织物,例如长毛绒、绒面或磨砂面表面织物。纺织品或织物12可以是砂眼、网眼、稀松编织、紧密编织、短环、短密环、短绒、超短绒、针刺、粘绒、簇绒、植绒、机织、非织造、针织、簇绒、多水平、织纹、花纹和/或类似的。通过举例而非限制的方式,在美国专利5,916,273中公开了形成编织或针织长毛绒织物的工艺,其内容在此以引用的方式引入。在美国专利5,916,273中公开的该类型织物适用于本发明的表面覆盖物的至少某些实施方式。当需要使用棱纹织物时,优选基本平整的表面,例如平纹、单层机织、非织造、针刺和经编织物。当然,由于例如纱线交叉点、花纹等,这些织物在其表面上必然有一定程度的不规则。显露表面12优选为透过透明或半透明膜可见,所述透明或不透明膜是由浸透性成膜组合物16及任何其它层17形成的,因此,所述显露表面12对于产品使用者或购买者而言是可见的。As shown, in the exemplary embodiment shown in FIG. 1 , the surface covering 10 includes an outer composite layer 18 comprising a preferably substantially flat woven, nonwoven, or knitted fabric or textile construction. The exposed surface 12, which is preferably impregnated or coated with an optional abrasion resistant film-forming composition 16, defines an enclosed protective barrier on the textile exposed surface 12. Composite layer 18 may include one or more optional protective, abrasion, stain, stain and/or similar additional layers, films, coatings or the like 17 . The outer composite layer 18 is disposed in overlying relationship on a single or multi-layer optional backing structure 14, as further described hereinafter, comprising, for example, new, recycled, recyclable , natural, bio-based, biodegradable and/or other environmentally friendly or reliable materials such as recycled flooring, foam, rubber, cork and/or agglomerated particle blocks of glass particles. As will be appreciated, the term "flat" as used in reference to the textile exposure surface is intended to refer to the preferably nap-free or low-pile surface profile on the exposure surface 12, rather than to any particular shaping technique. In this regard, it should be understood that flat fabrics may include fabrics with a relatively low surface pile level, such as plush, pile, or frosted surface fabrics. The textile or fabric 12 may be eyelet, mesh, open weave, close weave, short loop, short dense loop, short pile, super short pile, needle punched, viscoeled, tufted, flocked, woven, nonwoven, knitted, Tufted, multi-level, weave, pattern and/or the like. By way of example and not limitation, a process for forming a woven or knitted plush fabric is disclosed in US Pat. No. 5,916,273, the contents of which are incorporated herein by reference. The type of fabric disclosed in US Pat. No. 5,916,273 is suitable for use in at least some embodiments of the surface coverings of the present invention. When it is desired to use a ribbed fabric, a substantially flat surface is preferred, such as plain weave, single layer woven, nonwoven, needle punched and warp knitted fabrics. Of course, these fabrics necessarily have a certain degree of irregularity in their surface due to, for example, yarn intersections, patterns, and the like. The exposed surface 12 is preferably visible through the transparent or translucent film formed by the penetrable film-forming composition 16 and any other layers 17, so that the exposed surface 12 is invisible to the product user or purchaser. are visible to those.

在至少所选的实施方式中,纺织品显露表面12优选为机织或编织材料,例如天然和/或合成纱线、纤维、丝或材料,例如,复丝段纤纱结构的聚酯,更理想的是其中纱线的特征在于线性密度水平为约50至约2500旦尼尔的类型。例如,一种设想的纺织品显露表面是具有由150旦尼尔的变形聚酯形成的提花结构的办公室嵌板织物(office panelfabric),其形成结构为每英寸(2.54cm)约128根经纱和每英寸(2.54cm)约42根纬纱,浸透前单位面积质量为约6.1盎司/平方码(205.88g/m2)。另一种设想的纺织品显露表面是具有由150旦尼尔的变形聚酯(texturedpolyester)形成的提花结构的办公室嵌板织物,其形成结构为每英寸(2.54cm)约132根经纱和每英寸(2.54cm)约51根纬纱,浸透前单位面积质量为约5.4盎司/平方码(182.25g/m2)。又一个设想的纺织品显露表面是由1/800/1弹性聚酯和3/150/36变形聚酯形成的针织结构的密封织物,其形成结构为每英寸(2.54cm)约14条纵行和每英寸约20条横行,浸透前单位面积质量为约13.5盎司/平方码(455.53g/m2)。纺织品显露表面12可以是整体染色的,或者具有通过在其上机织、簇绒、成型、印花或染色的装饰色、图像、图案或图形。例如,图像、图案、色彩、图形等可如下形成:通过使用例如纱线染色或溶液染色的有色纤维或纱线形成,通过匹布染色形成,通过在由白色或淡色或浅色纱线或纤维或丝或材料制成的纺织品显露表面上印花或喷染形成。任何印花、染色或其它着色都希望在浸透前进行。或者,在浸透后采用一种或多种升华印花技术对纺织品显露表面印花或染色。In at least selected embodiments, the textile revealing surface 12 is preferably a woven or knitted material, such as a natural and/or synthetic yarn, fiber, filament or material, such as polyester of multifilament segment yarn construction, more desirably is the type wherein the yarn is characterized by a linear density level of from about 50 to about 2500 denier. For example, one contemplated textile revealing surface is an office panel fabric having a jacquard structure formed from 150 denier textured polyester with a structure of about 128 ends per inch (2.54 cm) and About 42 picks per inch (2.54 cm), with a mass per unit area of about 6.1 ounces per square yard (205.88 g/m 2 ) before soaking. Another contemplated textile revealing surface is an office panel fabric having a jacquard structure formed from a textured polyester of 150 denier with a structure of about 132 ends per inch (2.54 cm) and a per inch ( 2.54 cm) about 51 weft yarns, with a mass per unit area of about 5.4 ounces per square yard (182.25 g/m 2 ) before soaking. Yet another contemplated textile revealing surface is an airtight fabric of knit construction formed of 1/800/1 elastic polyester and 3/150/36 textured polyester with a formation of approximately 14 wales per inch (2.54 cm) and About 20 rows per inch, with a mass per unit area of about 13.5 ounces per square yard (455.53 g/m 2 ) before soaking. The textile revealing surface 12 may be integrally dyed, or have decorative colors, images, patterns or graphics woven, tufted, molded, printed or dyed thereon. For example, images, patterns, colours, graphics, etc. may be formed by using colored fibers or yarns such as yarn dyed or solution dyed, by dyeing pieces of cloth, by dyeing yarns or fibers made of white or pastel or light colored Textiles made of silk or materials are exposed on the surface by printing or spraying. Any printing, dyeing or other coloring is desirably done before soaking. Alternatively, the exposed surface of the textile is printed or dyed after soaking using one or more sublimation printing techniques.

如之前所指出的,显露表面12优选用优选耐磨的透明膜浸透、渗透、密封、涂覆或覆盖,所述耐磨的透明膜由合适的成膜组合物16和一层或多层选择性的附加层、膜、涂层或类似结构17形成,所述一层或多层选择性的附加层、膜、涂层或类似结构在纺织品显露表面12上界定了密闭的保护性屏障。在本文中提及所描述的实施方式时所使用的术语“完全浸透”或“完全被浸透”用于指代使用有效地浸透、渗透或浸泡纺织品或织物12并在其两侧形成膜的量的成膜组合物。为形成有效的屏障,优选将成膜组合物16以足以完全浸透的程度施用,从而至少在织物两侧(正面和背面)上形成薄膜,,从而形成纺织品显露表面12。优选完全浸透和渗透,因为其可防止色差、加固表面、提高耐用性、提高尺寸稳定性和/或类似优点。成膜组合物16和任何其它层17优选在最终固化状态中足够透明,以避免干扰纺织品显露表面的装饰特征。附加层和成膜组合物优选可挤出或者为液体,如聚酯、聚氨酯或丙烯酸系聚合物等,例如容易用于涂覆硬木地板等,尽管如需要也可以采用其它合适的透明或半透明保护膜或成膜组合物如聚酯等。组合物或材料16的添加重量应优选足以完全浸透和渗透纺织品显露表面12,从而包围和密闭该纺织品显露表面。As previously indicated, exposed surface 12 is preferably saturated, permeated, sealed, coated or covered with a preferably abrasion resistant transparent film selected from a suitable film forming composition 16 and one or more layers Optional additional layers, films, coatings or similar structures 17 are formed which define an airtight protective barrier on the textile exposed surface 12. The terms "fully saturated" or "fully saturated" as used herein in reference to the described embodiments are used to refer to the use of an amount effective to saturate, penetrate or soak the textile or fabric 12 and form a film on both sides thereof. film-forming composition. To form an effective barrier, the film-forming composition 16 is preferably applied to an extent sufficient to fully saturate to form a film on at least both sides (front and back) of the fabric, thereby forming the textile-exposing surface 12 . Full saturation and penetration is preferred because it prevents color shifts, strengthens the surface, increases durability, increases dimensional stability, and/or similar benefits. The film-forming composition 16 and any other layers 17 are preferably sufficiently transparent in the final cured state to avoid interfering with the decorative features of the exposed surface of the textile. The additional layer and film-forming composition is preferably extrudable or liquid, such as polyester, polyurethane or acrylic polymers, etc., such as are readily used to coat hardwood floors, etc., although other suitable transparent or translucent materials can also be used if desired. Protective films or film-forming compositions such as polyesters and the like. The added weight of composition or material 16 should preferably be sufficient to fully saturate and penetrate the textile-exposing surface 12, thereby surrounding and sealing the textile-exposing surface.

如前所述,背衬结构14优选为由颗粒物质构成,例如可再生、可回收和/或回收的固体或泡沫颗粒,例如新的、天然的或回收的软木、泡沫、橡胶和/或其它颗粒或其掺合物或其组合,这些颗粒物质使用至少一种粘合剂材料(如弹性或硬性粘合剂)来粘附在一起,所述至少一种粘合剂材料单独或与其它物质、试剂、填料、添加剂和/或类似物质一起将每颗颗粒与邻接颗粒粘合。颗粒优选具有基本上不规则的碎片表面几何形状,以提供用于粘合的高表面积。然而,如果需要,也可使用球形、小球形、柱形、碟形、棒形、椭圆形和/或其它相对光滑的表面几何形状。例如,可采用可压缩和/或不可压缩的球形颗粒,如橡胶或陶瓷球体。在所描述的实施方式中,粘合剂也可在外复合层18的底侧将背衬结构14粘合到保护性或成膜组合物16上。应理解,在背衬结构中,在颗粒之间可存在空隙,这些空隙中的一些可部分或完全地用粘合剂、填料、添加剂等填充。如需要,保留空隙和/或使用弹性粘合剂能提供相当大的弹性和缓冲。一定数量的空隙也可减轻质量、降低成本、提高柔韧性、增强横向握持、减少滑动和/或类似作用。至少在使用液体粘合剂时,优选每一颗背衬颗粒被包封在至少一层粘合剂薄层中。这有助于将颗粒粘合在一起,并有助于将背衬14粘合到面复合层18上。As previously mentioned, the backing structure 14 is preferably constructed of particulate matter, such as renewable, recyclable and/or recycled solid or foam particles, such as virgin, natural or recycled cork, foam, rubber and/or other Granules or blends or combinations thereof that are adhered together using at least one binder material, such as an elastic or hard binder, alone or with other substances , reagents, fillers, additives and/or the like together bind each particle to adjacent particles. The particles preferably have a substantially irregular chip surface geometry to provide a high surface area for binding. However, spheres, pellets, cylinders, disks, rods, ellipses, and/or other relatively smooth surface geometries may also be used, if desired. For example, compressible and/or incompressible spherical particles such as rubber or ceramic spheres may be used. In the depicted embodiment, the adhesive may also bond backing structure 14 to protective or film-forming composition 16 on the bottom side of outer composite layer 18 . It should be understood that in the backing structure there may be voids between the particles and some of these voids may be partially or completely filled with binders, fillers, additives, and the like. Leaving voids and/or using elastic adhesives can provide considerable elasticity and cushioning, if desired. A certain amount of clearance may also reduce mass, reduce cost, increase flexibility, enhance lateral grip, reduce slippage, and/or the like. Preferably, at least when a liquid adhesive is used, each backing particle is encapsulated in at least one thin layer of adhesive. This helps to bind the particles together and to bond the backing 14 to the facing composite 18 .

在背衬结构颗粒是橡胶的情况下,优选腈橡胶或EPDM。举例说明,一种可设想的EPDM来源是回收的挡风雨条。这些EPDM可以具有硬质或者弹性(泡沫)特点。仅仅是举例,一种设想的腈橡胶来源来自工业垫子。出租工业链段(rental industrial segment)也是橡胶颗粒原材料的理想来源,因为这确保了低褪色、低着色的腈橡胶被用作表面覆盖物生产的起始点。如需要,也可使用来自回收轮胎的橡胶。也可以使用回收的SBR橡胶。在背衬结构颗粒是泡沫的情况下,优选蜂窝状聚氨酯泡沫。也可以使用其它橡胶材料(实心或发泡)。而且,也可以使用其它回收的填料或材料,例如磨碎或回收的表面覆盖物、显露表面、背衬、地板、玻璃、粉煤灰、石膏、骨粉、使用过的铸造用沙、及其掺合物及其组合。根据至少一个实施方式,填料优选研磨至小于50目的尺寸,更优选小于100目,最优选小于350目。In case the backing structural particle is rubber, nitrile rubber or EPDM is preferred. By way of example, one conceivable source of EPDM is recycled weatherstripping. These EPDMs can be of rigid or elastic (foam) character. By way of example only, one contemplated source of nitrile rubber comes from industrial mats. The rental industrial segment is also an ideal source of rubber granulate raw material, as this ensures that low-fading, low-pigmented nitrile rubber is used as a starting point for the production of surface coverings. Rubber from recycled tires can also be used if desired. Recycled SBR rubber can also be used. Where the backing structural particles are foams, cellular polyurethane foams are preferred. Other rubber materials (solid or foamed) may also be used. Also, other recycled fillers or materials may be used, such as ground or recycled surface coverings, exposed surfaces, backings, flooring, glass, fly ash, gypsum, bone meal, used foundry sand, and blends thereof. Compounds and combinations thereof. According to at least one embodiment, the filler is preferably ground to a size of less than 50 mesh, more preferably less than 100 mesh, most preferably less than 350 mesh.

可设想的是,所采用的背衬结构颗粒如泡沫、橡胶或软木颗粒的尺寸优选为约0.01至约15mm。然而,如需要,也可使用更大或更小的粒径。It is contemplated that the size of the backing structure particles employed, such as foam, rubber or cork particles, is preferably from about 0.01 to about 15 mm. However, larger or smaller particle sizes can also be used if desired.

通常,选择尽可能大的尺寸以满足所要求的用途和性质。已发现可对粒径进行选择以便在产品中得到不同程度的弹性。较大的颗粒通常提供更高的弹性。理想尺寸的颗粒可与相同材料或者不同材料的粉末相混合以得到更好的撕裂强度。对于给定的粘合剂水平,粉末可提高撕裂强度。其它粉末或液体形式的添加剂的使用可提供相同的或不同的优势。合适的添加剂包括但不限于磁性或可磁化颗粒、抗微生物材料、阻燃添加剂、增味剂、着色剂或色素如氧化铁粉末、抗静电添加剂如碳纤维、填料和/或其它常见添加剂。In general, the largest possible size is chosen to suit the desired use and properties. It has been found that the particle size can be selected to obtain varying degrees of elasticity in the product. Larger particles generally provide higher elasticity. Granules of the desired size can be mixed with powders of the same material or a different material for better tear strength. Powder increases tear strength for a given level of binder. The use of other additives in powder or liquid form may provide the same or different advantages. Suitable additives include, but are not limited to, magnetic or magnetizable particles, antimicrobial materials, flame retardant additives, flavor enhancers, colorants or pigments such as iron oxide powder, antistatic additives such as carbon fibers, fillers, and/or other common additives.

同样,可以将相同材料或不同材料的硬质和弹性碎片、颗粒或碎屑相结合。例如,可以将EPDM颗粒与实心填料颗粒和粘合剂混合。Likewise, hard and elastic chips, granules or chips of the same material or of different materials may be combined. For example, EPDM particles can be mixed with solid filler particles and a binder.

用于连接背衬14颗粒的粘合剂可以是例如水固化型、热固化型和/或热塑型之一。根据所采用的背衬制造工艺,粘合剂可以是液体或粉末形式。优选粘合剂选自以下类型之一:聚氨酯反应性热熔体、共聚酯或共聚酰胺反应性热塑性热熔体和4,4-亚甲基二对亚苯基异氰酸酯(MDI)聚氨酯单组分和双组分胶粘剂。粘合剂可以位于背衬中所使用的颗粒或填料等之上或之中,或者作为上述颗粒或填料等的一部分。例如,在地毯砖中具有至少一层热熔体层的回收地毯砖的结团颗粒可形成颗粒和粘合剂(自粘合颗粒)。The adhesive used to attach the particles of the backing 14 may be, for example, one of the water-curable, heat-curable, and/or thermoplastic types. Depending on the backing manufacturing process employed, the binder can be in liquid or powder form. Preferably the adhesive is selected from one of the following types: polyurethane reactive hotmelts, copolyester or copolyamide reactive thermoplastic hotmelts and 4,4-methylene di-p-phenylene isocyanate (MDI) polyurethane monogroups One-part and two-component adhesives. The binder may be on or in the particles or fillers or the like used in the backing, or as part of such particles or fillers or the like. For example, agglomerated particles of recycled carpet tile having at least one layer of hot melt in the carpet tile can form granules and binders (self-bonding particles).

重要的是粘合剂具有良好的粘合性质以确保颗粒很好地结合在一起,另外还希望提供足够的游离粘合剂从而能够与例如面复合层18、稳定层142、背衬152等的外表面形成物理或化学结合。粘合剂也应当理想地表现出足够的粘着强度从而为背衬提供足够的强度。粘合剂可含有任何已知的交联剂或固化加速剂以适合所制造的产品和所使用的微粒的工艺和所需特征。It is important that the binder has good binding properties to ensure that the particles are well bonded together, and it is also desirable to provide sufficient free binder to be able to bond with, for example, the face composite layer 18, stabilizing layer 142, backing 152, etc. The outer surface forms a physical or chemical bond. The adhesive should also ideally exhibit sufficient cohesive strength to provide sufficient strength to the backing. The adhesive may contain any known crosslinkers or cure accelerators to suit the process and desired characteristics of the product being manufactured and the microparticles used.

根据一个可能的优选实施方式,通过将颗粒、碎片、填料和/或类似物质加入到聚合物泡沫中形成组合物或泥浆(puddle),从而形成颗粒背衬或杂混颗粒/泡沫背衬。例如,采用形成泡沫的组合物(其通常形成泡沫缓冲层)作为所加入的颗粒的粘合剂或者载体,将回收地毯砖、地板和/或其它表面覆盖物的颗粒加入到液体聚氨酯形成泡沫的组合物中,从而形成杂混背衬。According to a possible preferred embodiment, the particle backing or hybrid particle/foam backing is formed by adding particles, chips, fillers and/or similar substances to a polymer foam to form a composition or puddle. For example, adding particles of recycled carpet tile, flooring, and/or other surface coverings to a liquid polyurethane foam-forming base employs a foam-forming composition (which typically forms a foam cushion) as a binder or carrier for the added particles. composition, thereby forming a hybrid backing.

在图1所示的实施方式中(并参考例如图2和2B),粘合剂发挥了将颗粒维持在一起形成背衬14和将背衬14与外复合层18的底部粘合的双重作用。为发挥这两种作用,粘合剂水平优选为颗粒重量的约2%~约20%。使用较小粒径可表示使用更高百分比的粘合剂,因为其具有更大的表面积。具体而言,使用尺寸小于约0.5mm的细粉可以需要约20%或更多的粘合剂。In the embodiment shown in FIG. 1 (and with reference to, for example, FIGS. 2 and 2B ), the binder performs the dual function of holding the particles together to form the backing 14 and bonding the backing 14 to the bottom of the outer composite layer 18. . To perform both functions, the binder level is preferably from about 2% to about 20% by weight of the granules. Using a smaller particle size can mean using a higher percentage of binder because it has a greater surface area. In particular, use of fine powders with a size of less than about 0.5 mm may require about 20% or more binder.

通常,在粘合剂含量和粒径之间以及在粘合剂含量和在形成背衬结构14时向粘合剂/颗粒混合物施加的压力之间存在反比关系。因此,当粒径和压力增加时,粘合剂含量通常会降低。最佳粘合剂含量也取决于其它因素,例如粘合剂类型、所使用的颗粒材料和织物类型,并且能够通过常规试验进行确定。Generally, there is an inverse relationship between binder content and particle size, and between binder content and the pressure applied to the binder/particle mixture in forming backing structure 14 . Therefore, binder content generally decreases as particle size and pressure increase. The optimum binder level also depends on other factors, such as binder type, particulate material used and fabric type, and can be determined by routine experimentation.

例如,粘合剂可以是液体聚氨酯MDI粘合剂,例如,其中如果背衬主要由碎片或小粒构成,则粘合剂优选以约4重量%~约12重量%的水平存在。粘合剂可进一步含有理想地为液体形式并与粘合剂相容的添加剂,例如着色剂、增塑剂和香味剂。粘合剂也可以含有其它添加剂,只要它们适于加入液体介质之中。For example, the binder may be a liquid polyurethane MDI binder, for example, wherein if the backing consists primarily of chips or pellets, the binder is preferably present at a level of from about 4% to about 12% by weight. The adhesive may further contain additives, desirably in liquid form and compatible with the adhesive, such as colorants, plasticizers and fragrances. The binder may also contain other additives as long as they are suitable for incorporation into the liquid medium.

或者,粘合剂可以是热塑性或热固性热熔粉末,在该情况下,例如如果背衬主要由碎屑或颗粒构成,则粘合剂优选以约3重量%~10重量%的水平存在。粉末粘合剂也可以含有其它添加剂,只要它们适合于加入粉末介质之中。Alternatively, the binder may be a thermoplastic or thermosetting hot melt powder, in which case the binder is preferably present at a level of about 3% to 10% by weight, for example if the backing consists essentially of chips or particles. The powder binder may also contain other additives as long as they are suitable for incorporation into the powder medium.

根据至少所选的实施方式,粘合剂含量的优选范围可总结如下:According to at least selected embodiments, the preferred range of binder content can be summarized as follows:

碎屑/颗粒背衬:粘合剂含量为约2重量%至约20重量%,优选约4重量%至约12重量%,例如用MDI粘合剂时为约3重量%至约10重量%,或者例如用热熔粘合剂时为约3重量%至约10重量%。Chip/Particle Backing: Binder content from about 2% to about 20% by weight, preferably from about 4% to about 12% by weight, for example from about 3% to about 10% by weight with MDI binder , or, for example, from about 3% to about 10% by weight when using a hot melt adhesive.

具有约10%粉末的背衬:粘合剂含量为约9重量%至约20重量%,优选约14重量%或更多。Backing with about 10% powder: binder content from about 9% to about 20% by weight, preferably about 14% by weight or more.

在特别情况下,可采用约25重量%或更多的粘合剂含量,尽管这可能导致形成外皮(skin)。In particular cases, a binder content of about 25% by weight or more may be employed, although this may result in skin formation.

现在参考图2来描述图1的表面覆盖物10的制造过程,所述表面覆盖物10具有例如泡沫、软木或橡胶的粒状颗粒的背衬结构,图2是一体化生产线的示意图。在所描述的过程中,将颗粒或碎屑P(如具有掺合关系的泡沫、橡胶或软木颗粒)与所需粘合剂B的混合物从掺合颗粒与粘合剂的储配器中输送到电动机驱动的传送带22上。为有助于在传送带22上形成均匀淀积的颗粒和粘合剂,可将刮刀23或其它合适的调平装置放置于储配器20的下游。The manufacturing process of the surface covering 10 of FIG. 1 having a backing structure of granular particles such as foam, cork or rubber will now be described with reference to FIG. 2 , which is a schematic view of an integrated production line. In the described process, a mixture of granules or crumbs P (such as foam, rubber or cork granules in blending relationship) and the desired binder B is conveyed from a tank for blending granules and binders to Motor-driven conveyor belt 22. To help form an even deposit of particles and binder on the conveyor belt 22 , a scraper 23 or other suitable leveling device may be placed downstream of the dispenser 20 .

传送带22由不沾性表面如涂覆有聚四氟乙烯(PTFE)的机织玻璃纤维制成,从而防止淀积的材料粘附其上。或者,传送带22可用释放层涂覆或者用衬板覆盖,从而有助于从背衬上释放。例如,可以将背衬片夹在传送带22和背衬14之间。在使用中,传送带沿所示箭头方向前进。根据所形成的产品的性质,移动可以是步进或连续的。如所示,传送带22与电动机驱动的加压带24相对放置,所述加压带24相对于传送带以相反角度移动,从而在加热(或冷却)部件或压盘26附近的带之间形成压料区。由此使淀积在传送带上的材料在传送带22和加压带24之间经受一定程度的压制,同时可加热或冷却。The conveyor belt 22 is made of a non-stick surface such as woven fiberglass coated with polytetrafluoroethylene (PTFE) to prevent deposited material from adhering thereto. Alternatively, the conveyor belt 22 may be coated with a release layer or covered with a liner to facilitate release from the backing. For example, the backing sheet may be sandwiched between the conveyor belt 22 and the backing 14 . In use, the conveyor belt advances in the direction of the arrows shown. Depending on the nature of the product being formed, the movement can be stepped or continuous. As shown, a conveyor belt 22 is positioned opposite a motor-driven pressurized belt 24 that moves at an opposite angle relative to the conveyor belt to create a pressure between the belts near a heated (or cooled) member or platen 26. material area. The material deposited on the conveyor belt is thereby subjected to a certain degree of compression between the conveyor belt 22 and the pressure belt 24, and may be heated or cooled at the same time.

在所示过程中,形成显露表面12的织物由辊30传送经过涂布机32(如浸辊式涂布机等),其中成膜组合物16优选以浸透纺织品显露表面织物的方式施用。成膜组合物16优选为例如容易用于涂覆硬木地板等的液体聚氨酯,尽管如果需要也可采用聚酯、丙烯酸系聚合物和其它合适的保护性涂层或成膜组合物。例如但不限于,一种适宜的成膜保护性组合物可以是以商品名STREETSHOE SUPER MATTE由Matrix Coatings销售的聚氨酯,该产品由公司位于Des Moines,Iowa的Matrix Coatings公司出售。这样的组合物含有20重量%的固体含量,并优选为以约2至约100盎司/平方码(约67.5至约3375g/m2)的水平以湿态涂覆,从而在固化后形成约0.4至约20盎司/平方码(约13.5至约675g/m2)的干增重,由此形成优选需要的浸透和成膜特性。当然,这样的水平仅是示例性的,并且取决于被浸透或者被涂覆的织物的性质。仅举例说明,对于由150旦尼尔的变形聚酯纱线形成的提花结构,其形成结构为每英寸(2.54cm)约132根经纱和每英寸(2.54cm)约51根纬纱,浸透前单位面积质量为约5.4盎司/平方码(182.25g/m2)。已发现理想的是约8盎司/平方码(270g/m2)的湿涂覆在干燥后形成约1.0盎司/平方码(54g/m2)的干增重。In the process shown, the fabric forming the exposed surface 12 is conveyed by a roll 30 through a coater 32 (eg, a dip roll coater, etc.), wherein the film-forming composition 16 is applied preferably in a manner that saturates the fabric of the textile exposed surface. The film-forming composition 16 is preferably, for example, a liquid polyurethane that is readily used to coat hardwood floors and the like, although polyesters, acrylic polymers, and other suitable protective coating or film-forming compositions can also be used if desired. For example and without limitation, a suitable film-forming protective composition may be polyurethane sold under the tradename STREETSHOE SUPER MATTE by Matrix Coatings, Inc. of Des Moines, Iowa. Such compositions contain 20% solids by weight and are preferably applied wet at a level of from about 2 to about 100 oz/square yard (about 67.5 to about 3375 g/m 2 ) to form about 0.4 Dry gain to about 20 oz/square yard (about 13.5 to about 675 g/m 2 ), thereby developing the preferred requisite wet-out and film-forming characteristics. Of course, such levels are exemplary only and depend on the nature of the fabric being impregnated or coated. By way of example only, for a jacquard structure formed from a textured polyester yarn of 150 denier, which forms a structure of about 132 warp yarns per inch (2.54 cm) and about 51 weft yarns per inch (2.54 cm), the front unit of saturation The areal mass is about 5.4 ounces per square yard (182.25 g/m 2 ). It has been found desirable that a wet coating of about 8 oz/yd2 (270 g/ m2 ) dry to give a dry gain of about 1.0 oz/yd2 (54 g/ m2 ).

在离开涂覆机32之后,浸透的织物然后经过固化器34(如加热器、烘箱、风扇等)以使所涂覆的成膜组合物16固化形成如前所述的外复合层18。然后,将具有固化涂层的织物以覆盖的关系输送至传送带上的颗粒/粘合剂组合物上以进行随后在传送带22和加压带24之间的压制。当然,可理解的是显露表面织物的涂覆并不需要与热压制在同一生产线上进行,实际上,这些步骤可以在不同的生产线上进行,从而有助于加工自由度。例如,浸透的织物18的辊30可输送至图2中所示的生产线(范围)。After exiting the coater 32, the saturated fabric then passes through a curing device 34 (eg, heater, oven, fan, etc.) to cure the applied film-forming composition 16 to form the outer composite layer 18 as previously described. The fabric with cured coating is then conveyed in overlay relation onto the granulate/binder composition on the conveyor belt for subsequent compression between conveyor belt 22 and pressure belt 24 . Of course, it will be appreciated that the coating of the surface-revealing fabric need not be performed on the same line as the hot pressing, in fact these steps could be performed on a different line, thereby facilitating process freedom. For example, a roll 30 of saturated fabric 18 may be conveyed to a production line (range) shown in FIG. 2 .

继续参考附图中的图2,辊涂机60(如反转辊涂机)或其它涂覆装置如挤压机或膜传送系统等也可用于将胶粘剂或涂层或膜50添加到织物12或浸透织物18的背面。而且,辊涂机19(如反式辊涂机)或其它涂覆装置如挤压机或膜传送系统等也可用于将一层或多层附加层或膜17添加到复合层18上或将材料16添加到织物12的顶面等。根据所需的结构,辊涂机60和/或19或者辊涂机32可以使用或不使用。此外,材料16可在一步或多步中加入,或者以一层或多层添加。例如,涂布机32可添加第一涂层16,而涂布机19可添加材料16的第二涂层。类似地,辊涂机60可将材料16的第二涂层添加至织物12的底部。因此,根据需要,涂布机32、60和19中的每一个可使用或不使用,并且可用于添加材料16、50或17。材料16、50和17可以是相同或不相同的材料。例如,材料50和17可以与材料16相同,或者例如材料17可以是聚酯磨损层,而材料16是聚氨酯涂层。可以设想的是,必要时可在涂布机60和19的下游添置其它烘箱、加热器、风扇、固化装置等。如果材料17是膜,则来自加热压盘26的热足以将膜17与涂层16熔合。此外,必要时可在带24和材料16或17之间加入释放衬板或释放膜。With continued reference to FIG. 2 of the drawings, a roll coater 60 (such as a reverse roll coater) or other coating device such as an extruder or film delivery system, etc., may also be used to add the adhesive or coating or film 50 to the fabric 12 Or saturate the back of the fabric 18. Also, a roll coater 19 (such as a reverse roll coater) or other coating apparatus such as an extruder or film delivery system, etc. may also be used to add one or more additional layers or films 17 to the composite layer 18 or to Material 16 is added to the top surface of fabric 12 and the like. Depending on the desired configuration, roll coaters 60 and/or 19 or roll coater 32 may or may not be used. Additionally, material 16 may be added in one or more steps, or in one or more layers. For example, coater 32 may add first coating 16 while coater 19 may add a second coat of material 16 . Similarly, roll coater 60 may add a second coat of material 16 to the bottom of fabric 12 . Thus, each of applicators 32, 60, and 19 may be used or not, and may be used to add material 16, 50, or 17, as desired. Materials 16, 50 and 17 may be the same or different materials. For example, materials 50 and 17 may be the same as material 16, or, for example, material 17 may be a polyester wear layer while material 16 is a polyurethane coating. It is contemplated that other ovens, heaters, fans, curing devices, etc. may be added downstream of the coaters 60 and 19 as necessary. If material 17 is a film, the heat from heated platen 26 is sufficient to fuse film 17 to coating 16 . In addition, a release liner or film may be interposed between the belt 24 and the material 16 or 17 if desired.

在使外复合层18在颗粒粘合剂组合物顶部定向以后,相对的带22、24之间施加的压力和热(或者当需要时进行冷却)使粘合剂与颗粒粘合或熔合在一起,从而形成具有所需厚度和弹性的稳定背衬结构14。在者方面,所施加的压力优选为约0.01至约50磅/平方英寸或者更高(约0.06895kpa至约344.75kPa),而温度优选为约300℉至约375℉(约148.9℃至约190.6℃),尽管根据所采用的材料结构和压力可以使用更高或更低的温度。背衬结构14中的浸透性成膜组合物16或胶粘剂50与粘合剂B的组合共同将外复合层18与背衬结构14粘合。所形成的分层结构优选具有如图1中所示的结构。可以理解的是,如果需要,一定百分比的外复合层18可以被压入并低于背衬结构14的表面。在成型后,如果在标准件安装中使用(或者作为小地毯、长条地毯或小垫子),所得结构将输送至切砖机31(或者小地毯、长条地毯或小垫子切砖机),如果以较长长度的片段如卷材、长条地毯、宽幅地毯如6英尺宽宽幅地毯使用或以后再切割,则将所得结构卷绕在辊上。After orienting the outer composite layer 18 on top of the particulate binder composition, pressure and heat (or cooling when required) applied between the opposing belts 22, 24 causes the binder to bond or fuse the particulate binder together. , thereby forming a stable backing structure 14 with desired thickness and elasticity. In these aspects, the applied pressure is preferably from about 0.01 to about 50 psig or greater (about 0.06895 kPa to about 344.75 kPa), and the temperature is preferably from about 300°F to about 375°F (about 148.9°C to about 190.6 °C), although higher or lower temperatures may be used depending on the material structure and pressure employed. The combination of soakable film-forming composition 16 or adhesive 50 in backing structure 14 and adhesive B together bond outer composite layer 18 to backing structure 14 . The formed layered structure preferably has a structure as shown in FIG. 1 . It will be appreciated that a percentage of the outer composite layer 18 may be pressed into and below the surface of the backing structure 14 if desired. After forming, the resulting structure is conveyed to a tile cutter 31 (or a tile cutter, tile cutter, or tile cutter) if used in a modular installation (or as a rug, strip or rug), If used in longer length segments such as rolls, strips, broadlooms such as 6 foot widelooms or cut later, the resulting structure is wound on rolls.

当然,如果需要,胶粘剂50如热熔聚氨酯、聚酯、聚酰胺等或者底漆或溶剂的附加层可插入到颗粒/粘合剂组合物和外复合层18之间。这种胶粘剂可进一步稳定结构并提供增强的抗分层保护。如果使用,则使用例如辊涂机60或其它涂布或涂覆技术例如喷涂、挤出、薄膜胶粘剂输送、粉末胶粘剂输送等来将这样的胶粘剂层依次涂覆在例如外复合层18的底部。如果需要,也可以通过喷涂机、空气刮刀或其它涂布或涂覆方法来将其涂覆在背衬结构14的顶部。图2的生产线或层压范围也可用于制造其它结构,例如在图7、12和14中所示的结构等。Of course, an additional layer of adhesive 50 such as hot melt polyurethane, polyester, polyamide, etc. or primer or solvent may be interposed between the particle/adhesive composition and outer composite layer 18 if desired. This adhesive further stabilizes the structure and provides enhanced protection against delamination. If used, such adhesive layers are sequentially applied, for example, to the bottom of the outer composite layer 18 using, for example, a roll coater 60 or other coating or application techniques such as spraying, extrusion, film adhesive delivery, powder adhesive delivery, etc. It can also be applied on top of the backing structure 14 if desired by a sprayer, air knife, or other coating or application methods. The production line or lamination range of Figure 2 can also be used to manufacture other structures such as those shown in Figures 7, 12 and 14, etc.

除了例如橡胶、泡沫与粘合剂的原地熔合颗粒之外,还可以设想至少本发明的所选实施方式的表面覆盖物包含所谓“再生粘接(rebond)”泡沫的背衬结构,在“再生粘接”泡沫中,使用泡沫块之间的弹性粘合剂来将相对较小块或较小片的碎屑泡沫成型为片材。图2A描述了用于向如图1所示的分层结构中加入例如这种预成型的再生粘接泡沫或其它预成型的背衬的生产线。在图2A中,对应于图2中所描述的那些部件的部件将用相应的带单引号的编号来标识。In addition to in situ fused particles such as rubber, foam and adhesives, it is also contemplated that at least selected embodiments of the surface coverings of the present invention comprise a backing structure of so-called "rebond" foam, described in " In "recycled bonded" foam, relatively small pieces or pieces of crumb foam are formed into sheets using an elastic adhesive between foam blocks. FIG. 2A depicts a production line for adding such pre-formed recycled adhesive foam or other pre-formed backings to the layered structure as shown in FIG. 1 . In FIG. 2A , components corresponding to those described in FIG. 2 will be identified by corresponding single-quoted numerals.

图2A所述过程基本上与图2所述过程相同,不同之处在于颗粒和粘合剂的淀积块替换为颗粒和粘合剂的预成型片14′,例如再生粘接泡沫或其它粘合颗粒或颗粒混合物或泡沫或弹性材料。为将外复合层18′固定在预成型片14′上,可在与片14′相结合之前,使用涂布机6′将一层胶粘剂50′(如聚氨酯、聚酯、聚酰胺等)涂覆在外复合层18′的底面上。在进入相对的带22′、24′之间的压料区时,所施加的压力和热导致泡沫块被部分压缩。泡沫颗粒之间的粘合剂可在部分压缩状态下将颗粒熔合在一起,从而形成具有所需厚度和弹性的稳定背衬结构。在此方面,更大的压缩将导致缓冲弹性水平的降低。通过中间的胶粘剂层50′来同时将外复合层18′与背衬结构粘合。在成型后,如果在标准件安装中使用,所得结构将输送至切砖机31′,或者,如果以较长长度的片段使用或以后再进行切割,则将所得结构卷绕在辊上。由图2A的过程制造的表面覆盖物如地板、地砖或地板覆盖物可看起来类似具有或不具有背衬片452的图7的产品。The process described in FIG. 2A is essentially the same as that described in FIG. 2, except that the deposited mass of particles and binder is replaced by a preformed sheet 14' of particles and binder, such as recycled adhesive foam or other adhesive. granules or mixtures of granules or foams or elastomeric materials. In order to fix the outer composite layer 18' on the preformed sheet 14', a layer of adhesive 50' (such as polyurethane, polyester, polyamide, etc.) Overlies the bottom surface of the outer composite layer 18'. Upon entering the nip between the opposing belts 22', 24', the applied pressure and heat cause the foam block to be partially compressed. The binder between the foam particles fuses the particles together in a partially compressed state to form a stable backing structure with the desired thickness and elasticity. In this regard, greater compression will result in a lower level of cushioning elasticity. The outer composite layer 18' is simultaneously bonded to the backing structure by an intermediate layer of adhesive 50'. After forming, the resulting structure is conveyed to a brick cutter 31' if used in a standard piece installation, or wound on rollers if used in longer length segments or cut later. A surface covering such as a floor, tile or floor covering manufactured by the process of FIG. 2A may look similar to the product of FIG. 7 with or without backing sheet 452 .

可用于形成所描绘和描述的结构的另一种过程显示在图2B中。在图2B中,对应于图2中所描述的那些部件的部件将用相应的带双引号的编号进行标识。在此过程中,颗粒/粘合剂组合物P、B由位于坝体下游的储配器20"输送到传送带20"上,在刮刀辊或加压辊37"与传送带22"之间的压料区形成颗粒/粘合剂组合物的淀积体或胶泥(puddle)。加压辊37"将带有或不带有层17"的外复合层18"压制成颗粒/粘合剂块,同时控制颗粒/粘合剂材料的厚度。在此压制过程中,优选加热部件26"的下半部分使层温升高以引发熔合结合。所形成的结构随后在传送带22"和下游加压带24"之间通过从而完成结合。在形成后,如果在标准件安装中使用,则将所得结构输送至切砖机31′,或者如果以较长长度的片段或以后再进行切割,则将所得结构卷绕在辊(未示出)上。Another process that can be used to form the depicted and described structures is shown in Figure 2B. In FIG. 2B, components corresponding to those described in FIG. 2 will be identified with corresponding double-quoted numbers. During this process, the granule/adhesive composition P, B is transported from the reservoir 20" located downstream of the dam body to the conveyor belt 20", and the pressing material between the scraper roller or pressure roller 37" and the conveyor belt 22" The zone forms a deposit or puddle of particle/binder composition. The pressure rollers 37" press the outer composite layer 18" with or without the layer 17" into a pellet/binder mass while controlling the thickness of the pellet/binder material. During this pressing, the components are preferably heated The bottom half of the 26" raises the layer temperature to initiate fusion bonding. The formed structure is then passed between the conveyor belt 22" and the downstream pressure belt 24" to complete the bond. After forming, the resulting structure is conveyed to a brick cutter 31' if used in a standard piece installation, or wound on rollers (not shown) if cut in longer length pieces or later. )superior.

可以设想的是选择性地将一种或多种增大摩擦的材料或层15添加到图1的表面覆盖部件10的背衬14的底部。这些增大摩擦的材料在例如美国专利申请10/209,050(美国申请公开号US2004/0022991)中描述,该专利申请在此以引用的方式引入。优选这些增大摩擦的材料提供了额外的横向握持和一些垂直附着。同样,背衬14和/或材料15可包括磁性或可磁化颗粒或材料,从而提供对例如金属地板或金属凸起通道地板(metal raised access flooring)的吸引。此外,材料15可用可释放、可移除的覆盖片来覆盖,从而提供即时贴型(peel-n-stick)表面覆盖产品。可在颗粒/粘合剂输送的上游、带24和切砖机31之间、切砖机31的下游、在进行产品包装时、或者在卷绕形成的复合层时,在例如图2或图2A的范围内施加选择性的下层、涂层或膜15。It is contemplated to selectively add one or more friction increasing materials or layers 15 to the bottom of the backing 14 of the surface covering member 10 of FIG. 1 . These friction increasing materials are described, for example, in US Patent Application 10/209,050 (US Application Publication No. US 2004/0022991 ), which is hereby incorporated by reference. Preferably these friction increasing materials provide additional lateral grip and some vertical attachment. Likewise, the backing 14 and/or material 15 may include magnetic or magnetisable particles or materials to provide attraction to, for example, metal floors or metal raised access floors. Additionally, material 15 may be covered with a releasable, removable cover sheet, thereby providing a peel-n-stick surface covering product. It can be upstream of the granulate/binder conveying, between the belt 24 and the brick cutter 31, downstream of the brick cutter 31, when packaging the product, or when winding the formed composite layer, for example in FIG. 2 or FIG. An optional underlayer, coating or membrane 15 is applied within the scope of 2A.

至少某些实施方式也容易适用于需要相当高水平的内部尺寸稳定性的结构。意图具有这种内部尺寸稳定性的表面覆盖物110的一个示例性结构在图3中描述,其中对应于图1中所描述的那些部件的部件将用相应的编号增加100来标识。如图所示,在图3的实施方式中,表面覆盖物110包含多层稳定背衬结构114,该多层稳定背衬结构114具有位于相对的颗粒和粘合剂层140之间的稳定层142(如机织或非织造玻璃或玻璃纤维材料),所述颗粒和粘合剂层的例子是如前文所述的用一种或多种粘合剂结合在一起的回收表面覆盖物、软木、泡沫、橡胶、其掺合物、其组合或类似颗粒。此外,例如热熔聚氨酯、聚酯、聚酰胺等的胶粘剂150的附加层可位于外复合层118和背衬结构114的上表面之间。如需要,例如机织或非织造结构之类的选择性的背衬片、纺织品或材料152可位于具有或不具有中间胶粘剂层和下部增大摩擦材料层115的底面上。背衬材料如非织造毡不仅用作释放层,还可为产品提供水分芯吸、蒸发或蒸汽传输特性。毡152倾向于将水或湿气从地板产品底部芯吸至接缝处。同样,毡152也能将蒸汽从地板底部输送至接缝处。At least some embodiments are also readily adaptable to structures requiring a relatively high level of internal dimensional stability. One exemplary construction of a surface covering 110 intended to have such internal dimensional stability is depicted in FIG. 3 , where components corresponding to those depicted in FIG. 1 will be identified with corresponding numbers incremented by 100 . As shown, in the embodiment of FIG. 142 (such as woven or nonwoven glass or fiberglass material), examples of said particle and binder layer are recycled surface coverings, cork, as previously described, bound together with one or more binders , foam, rubber, blends thereof, combinations thereof or similar particles. Additionally, an additional layer of adhesive 150 , such as hot melt polyurethane, polyester, polyamide, etc., may be positioned between outer composite layer 118 and the upper surface of backing structure 114 . An optional backing sheet, textile or material 152 such as a woven or nonwoven structure may be located on the bottom surface with or without an intermediate adhesive layer and lower friction increasing material layer 115 if desired. Backing materials such as nonwoven felts not only serve as a release layer but also provide moisture wicking, evaporation or vapor transport properties to the product. Felt 152 tends to wick water or moisture from the bottom of the flooring product to the seams. Likewise, the felt 152 can also transport steam from the bottom of the floor to the seams.

现在参考图4来描述图3的表面覆盖物110的制造过程,所述表面覆盖物110具有面118和包含例如回收表面覆盖物、泡沫、软木、玻璃、粉煤灰和/或橡胶的粒状颗粒的背衬结构114,所述图4是完整生产线(类似于图2)的示意图。在所述过程中,例如机织或非织造纺织品材料之类的背衬片152以覆盖关系输送到传送带122上。仅举例说明,背衬片优选包含具有从100%聚酯到100%聚丙烯之间的任何所需比例的聚酯和/或聚丙烯纤维的非织造毡材料。增大摩擦的材料115可以在产品成型之后、在产品形成之前或类似时刻添加到背衬152上。在下游位置,将由颗粒P与所需粘合剂B掺合的第一混合物从掺合并淀积颗粒与粘合剂的第一储配器120输送到背衬152上。为有助于在背衬152上形成颗粒和粘合剂的均匀淀积物,在第一储配器120的下游设置刮刀123或其它合适的调平装置。然后将例如机织或非织造玻璃之类的稳定材料层142毗邻施加到第一颗粒和粘合剂层上。一旦稳定层142就位,将由颗粒P与所需粘合剂B掺合的第二混合物从掺合并淀积颗粒与粘合剂的第二储配器121输送到稳定层142上。为有助于形成颗粒和粘合剂的均匀淀积物,在第二储配器121的下游设置刮刀125或其它合适的调平装置。图4的储配器120、121和图2的储配器20的淀积头(deposit head)可例如分别在传送带122和22上来回移动,从而将颗粒和粘合剂混合物涂敷在传送带上。Reference is now made to FIG. 4 to describe the manufacturing process of the surface covering 110 of FIG. 3 having a face 118 and granular particles comprising, for example, recycled surface covering, foam, cork, glass, fly ash, and/or rubber. The backing structure 114 of FIG. 4 is a schematic diagram of a complete production line (similar to FIG. 2 ). In the process, a backing sheet 152 , such as a woven or nonwoven textile material, is conveyed in covering relation onto the conveyor belt 122 . By way of example only, the backing sheet preferably comprises a nonwoven felt material having polyester and/or polypropylene fibers in any desired proportion from 100% polyester to 100% polypropylene. The friction increasing material 115 may be added to the backing 152 after the product is formed, before the product is formed, or the like. At a downstream location, a first mixture of particles P blended with the desired binder B is delivered from a first reservoir 120 where the particles and binder are blended and deposited onto the backing 152 . Downstream of the first reservoir 120, a doctor blade 123 or other suitable leveling device is provided to aid in the formation of a uniform deposit of particles and binder on the backing 152. A layer 142 of stabilizing material such as woven or nonwoven glass is then applied adjacent to the first particle and binder layer. Once the stabilizing layer 142 is in place, a second mixture of particles P blended with the desired binder B is delivered onto the stabilizing layer 142 from the second reservoir 121 where the particles and binder are blended and deposited. Downstream of the second reservoir 121, a scraper 125 or other suitable leveling device is provided to aid in the formation of a uniform deposit of particles and binder. The deposit heads of the dispensers 120, 121 of FIG. 4 and the dispenser 20 of FIG. 2 may, for example, be moved back and forth on the conveyor belts 122 and 22, respectively, thereby coating the particle and binder mixture on the conveyor belts.

与传动带22相似,传送带122由不沾性表面如涂覆有聚四氟乙烯(PTFE)的机织玻璃织物制成,从而防止淀积的材料粘附其上。在运转时,传送带沿所示的箭头方向前进。根据所形成的产品的性质,移动可以是步进或连续的。如所示,传送带122以与电动机驱动的加压带124相对放置,所述加压带124相对于传送带以相反角度运行,从而在加热(或冷却)部件126附近的带之间形成压料区。由此使淀积在传送带上的材料在传送带122和加压带124之间经受一定程度的压制,同时进行加热或冷却。Like the drive belt 22, the conveyor belt 122 is made of a non-stick surface such as woven glass fabric coated with polytetrafluoroethylene (PTFE) to prevent deposited material from adhering thereto. In operation, the belt advances in the direction of the arrows shown. Depending on the nature of the product being formed, the movement can be stepped or continuous. As shown, a conveyor belt 122 is positioned opposite a motor-driven pressurized belt 124 that runs at an opposite angle relative to the conveyor belt, thereby forming a nip between the belts near a heating (or cooling) element 126 . The material deposited on the conveyor belt is thereby subjected to a degree of compression between the conveyor belt 122 and the pressure belt 124, while being heated or cooled.

在所示过程中,形成显露表面112的织物由辊130传送经过第一涂布机132(如浸辊式涂布机等),其中成膜组合物116以浸透关系施加到纺织品显露表面织物上。成膜组合物优选为液体聚氨酯,例如容易地可用于涂覆硬木地板等的液体聚氨酯,尽管如果需要同样可以使用丙烯酸系聚合物、聚酯、聚酰胺及其它合适的保护性成膜组合物。在离开涂布机132之后,被浸透的织物优选随后经过固化器134(如加热器、烘箱、风扇等),以便将所施加的成膜组合物116固化,从而形成如前所述的外复合层118。然后将外复合层118输送到第二涂布机160(如反式辊涂机等),以便将胶粘剂层150施加在底面上。表面复合层118随后通过涂布机119(如反式辊涂机)以施加例如其它磨损层、防污层、防污渍层、其它复合层116等。具有固化涂层116和施加的胶粘剂150及选择性的层117的织物随后以覆盖关系施加在颗粒/粘合剂组合物的上层上,从而随后在传送带和加压带之间进行压缩和加热和/或冷却。当然,可理解的是显露表面织物的涂覆并非需要在进行热压制的同一生产线上进行,实际上,这些步骤可以在不同的生产线上进行,从而有助于加工自由度。例如,已浸透的织物18的辊30可输送至图2中所示的生产线(范围)。因此,可以以具有或不具有层150、117和/或类似物的卷(roll)的形式提供外复合层118。可设想的是一个或多个涂布机132、160和119可用于或未用于具体结构中,并且每一个可涂布不同的材料。In the process shown, the fabric forming the exposed surface 112 is conveyed by a roll 130 through a first coater 132 (e.g., a dip roll coater, etc.), wherein the film-forming composition 116 is applied to the textile exposed surface fabric in a saturated relationship. . The film-forming composition is preferably a liquid polyurethane such as is readily available for coating hardwood floors and the like, although acrylics, polyesters, polyamides and other suitable protective film-forming compositions may likewise be used if desired. After exiting the coater 132, the saturated fabric preferably then passes through a curing device 134 (e.g., heater, oven, fan, etc.) to cure the applied film-forming composition 116 to form the outer composite as previously described. Layer 118. The outer composite layer 118 is then conveyed to a second coater 160 (eg, a reverse roll coater, etc.) to apply the adhesive layer 150 to the bottom surface. The surface composite layer 118 is then passed through a coater 119, such as a reverse roll coater, to apply, for example, additional wear layers, anti-fouling layers, anti-stain layers, other composite layers 116, and the like. The fabric with cured coating 116 and applied adhesive 150 and optional layer 117 is then applied in covering relation over the upper layer of particle/adhesive composition for subsequent compression and heating and / or cooling. Of course, it will be appreciated that the coating of the surface-revealing fabric need not be performed on the same line as the hot pressing, and in fact these steps could be performed on a different line, thereby facilitating process freedom. For example, a roll 30 of saturated fabric 18 may be conveyed to a production line (area) shown in FIG. 2 . Thus, outer composite layer 118 may be provided in roll form with or without layers 150, 117, and/or the like. It is contemplated that one or more coaters 132, 160, and 119 may or may not be used in a particular configuration, and that each may coat different materials.

外复合层118在颗粒粘合剂组合物顶部定向以后,施加在相对的带122、124之间的压力和热(和/或冷却)使粘合剂与颗粒熔合在一起,粘附到稳定层142两侧的稳定背衬结构14。在此方面,所施加的压力优选为约0.01至约50磅/平方英寸,优选约0.1至约20磅/平方英寸,温度优选为约300℉至约375℉。外复合层118、117通过与选择性施加的胶粘剂150组合的粘合剂而同时粘合到背衬结构114上。在成型之后,如果在标准件安装中使用,则将所得结构输送至切砖机131,或者如果以较长长度的片段使用或以后再进行切割,则将所得结构卷绕在辊(未示出)上。After the outer composite layer 118 is oriented on top of the particulate binder composition, pressure and heat (and/or cooling) applied between the opposing belts 122, 124 fuse the binder and particulate together, adhering to the stabilizing layer 142 stabilizing backing structure 14 on both sides. In this regard, the pressure applied is preferably from about 0.01 to about 50 psig, preferably from about 0.1 to about 20 psig, and the temperature is preferably from about 300°F to about 375°F. The outer composite layers 118 , 117 are simultaneously bonded to the backing structure 114 by an adhesive in combination with an optionally applied adhesive 150 . After forming, the resulting structure is conveyed to the brick cutter 131 if used in a modular installation, or wound on rollers (not shown) if used in longer length pieces or cut later. )superior.

除回收的、可回收的、可再生的、天然的、生物类的、可生物降解的或其它材料例如回收的表面覆盖物、软木、橡胶和/或泡沫的熔合颗粒之外,还可以设想至少所选的本发明的实施方式的表面覆盖物包含由例如所谓“再生粘接”泡沫形成的背衬结构,其中相对小块或小片的碎屑泡沫通过泡沫块之间的弹性粘合剂而定型为片材。图4A描述了用于将例如这样的预成型再生粘接泡沫或其它颗粒或其它预成型材料加入到如图3、2A和11所示的分层结构中的生产线。在图4A中,对应于图4中所描述的那些部件的部件将用相应的带单引号的编号进行标识。In addition to fused particles of recycled, recyclable, renewable, natural, bio-based, biodegradable or other materials such as recycled surface coverings, cork, rubber and/or foam, at least The surface coverings of selected embodiments of the invention comprise a backing structure formed of, for example, so-called "regenerated bonded" foam, wherein relatively small pieces or pieces of crumb foam are held in place by an elastic adhesive between foam pieces. for the sheet. FIG. 4A depicts a production line for adding preformed recycled adhesive foam such as this or other granules or other preformed material into the layered structure shown in FIGS. 3 , 2A and 11 . In FIG. 4A, components corresponding to those described in FIG. 4 will be identified by corresponding single-quoted numerals.

图4A中描述的过程基本上与根据图4描述的过程相同,不同之处在于颗粒和粘合剂的淀积层替换为颗粒和粘合剂的预成型片140’,例如再生粘接泡沫。在所述过程中,通过涂布机161’和160’将胶粘剂层如聚氨酯胶粘剂、热熔胶粘剂等涂覆在预成型再生粘接泡沫片材140’和邻接层之间,以便促进粘合。在进入相对的带之间的压料区时,所施加的压力和热(和/或冷却)导致泡沫块被部分压缩。泡沫颗粒之间的粘合剂可在部分压缩状态下将颗粒熔合在一起,从而形成具有所需厚度和弹性的稳定背衬结构。在此方面,更大的压缩将导致缓冲弹性水平的降低。同时,外复合层118"通过再生粘接片材的粘合剂及所施加的胶粘剂150′粘合到背衬结构上。在形成后,如果在标准件安装中使用,则将所得结构输送至切砖机31′,或者如果以较长长度的片段使用或以后再进行切割,则将所得结构卷绕在辊(未示出)上。选择性的下层(例如,由增大摩擦的材料形成的层)可以被添加到背衬152’的上游、带124’之后、切砖机131’之后、或在产品110的包装或卷绕时加入。The process depicted in Figure 4A is essentially the same as that described with respect to Figure 4, except that the deposited layer of particles and binder is replaced by a preformed sheet 140' of particles and binder, such as recycled adhesive foam. In the process, a layer of adhesive, such as polyurethane adhesive, hot melt adhesive, etc., is applied between the preformed recycled adhesive foam sheet 140' and the adjacent layer by applicators 161' and 160' to promote adhesion. Upon entering the nip between opposing belts, the applied pressure and heat (and/or cooling) cause the foam block to be partially compressed. The binder between the foam particles fuses the particles together in a partially compressed state to form a stable backing structure with the desired thickness and elasticity. In this regard, greater compression will result in a lower level of cushioning elasticity. Simultaneously, the outer composite layer 118" is bonded to the backing structure by the adhesive of the recycled bonding sheet and the applied adhesive 150'. After formation, the resulting structure is transported to Brick cutter 31', or if used in longer length segments or cut later, the resulting structure is wound on rollers (not shown). An optional lower layer (e.g., formed of a friction-increasing material layer) can be added upstream of the backing 152', after the belt 124', after the brick cutter 131', or at the time of packaging or winding of the product 110.

当然,可理解的是,根据所设想的用途和性能要求,可采用任何数目或其它的表面覆盖物的实施方式。仅举例说明,一种设想的替代性结构在图5中进行了描述,其中与之前所描述的相对应的部件用200序列之内的相似编号进行标示。可理解的是,图5中的表面覆盖物210具有与图1的表面覆盖物10基本相同的结构,但增加了位于下侧上的由例如纺织品或织物(如机织或非织造纤维材料)组成的背衬片252。在此结构中,优选通过背衬层214中将颗粒固定在一起的粘合剂来将背衬片252固定就位。然而,如果需要可使用其它胶粘剂层。可设想的是,如果背衬结构214是原位形成的颗粒和粘合剂背衬(例如磨碎的材料如碎屑泡沫、橡胶或软木),则可以通过在图2或图4中所描绘和描述的过程形成这样的结构,如果所述背衬结构是预成型片(例如颗粒和粘合剂的预成型片,如再生粘接泡沫等),则可以通过图2A或图4A中描述的过程来形成这种结构。在这样的实践中,图4或图4A中供给稳定材料的辊和储配器之一(或供给再生粘接片材的辊之一)未运转。Of course, it is understood that any number or other embodiments of surface coverings may be employed depending on the intended use and performance requirements. By way of example only, a contemplated alternative structure is depicted in FIG. 5 , where parts corresponding to those previously described are labeled with like numerals within the 200 series. It will be appreciated that the surface covering 210 in FIG. 5 has substantially the same structure as the surface covering 10 of FIG. Composed backing sheet 252. In this construction, the backing sheet 252 is preferably held in place by an adhesive in the backing layer 214 that holds the particles together. However, other adhesive layers may be used if desired. It is contemplated that if the backing structure 214 is an in-situ formed particle and adhesive backing (e.g., ground material such as crumb foam, rubber, or cork), then the and the described process to form such a structure, if the backing structure is a preformed sheet (e.g., a preformed sheet of particles and binder, such as recycled adhesive foam, etc.), it can be obtained by the process described in Figure 2A or Figure 4A process to form this structure. In such a practice, one of the rolls feeding the stabilizing material and the reservoir in Figure 4 or Figure 4A (or one of the rolls feeding the recycled adhesive sheet material) is not operating.

在图6中描述了另一个设想的表面覆盖结构310,其中与之前所描述的相对应的部件用300序列之内的相似编号进行标示。在此结构中,通过例如热熔聚氨酯等胶粘剂层350将例如机织或非织造玻璃等的稳定层342胶粘连接在浸透的显露表面材料318下方。可以设想的是,如果使用磨碎的材料如碎屑泡沫、橡胶或软木,则可以通过在图4中描绘和描述的过程形成这样的结构,如果使用预成型再生粘接泡沫等,则可以通过图4A中描述的过程形成这样的结构。在这样的实践中,第二储配器(或下游供给再生粘接片材的辊)完全未运转。所得结构提供了相当大的内部尺寸稳定性,且特别适用于例如地毯砖、地砖、稳定卷材等。Another contemplated surface covering structure 310 is depicted in FIG. 6 , where parts corresponding to those previously described are labeled with like numerals within the 300 series. In this construction, a stabilizing layer 342, such as woven or non-woven glass, is adhesively attached beneath the saturated exposed surface material 318 by an adhesive layer 350, such as hot melt polyurethane. It is conceivable that such a structure could be formed by the process depicted and described in Figure 4 if using ground materials such as crumb foam, rubber or cork, or by The process described in Figure 4A forms such a structure. In such a practice, the second accumulator (or the roll downstream feeding the recycled adhesive sheet) is not running at all. The resulting structure provides considerable internal dimensional stability and is particularly suitable for applications such as carpet tiles, floor tiles, stabilizing membranes and the like.

在图7中描述了又一个设想的表面覆盖结构410,其中与之前所描述的相对应的部件用400序列之内的相似编号进行标示。在此结构中,通过例如热熔聚氨酯等胶粘剂层450将磨碎颗粒的颗粒/粘合剂层440或预成型片结构如再生粘接泡沫片材结构胶粘连接在被浸透的显露表面材料418下方。可设想的是,可以由图2、4或4A中描绘或描述的过程形成这样的结构。例如,如果使用原位磨碎的背衬材料如碎屑泡沫或软木,则可以通过在图4中的过程形成这样的结构,如果使用预成型的例如再生粘接泡沫片材则可以通过图4A所述的过程。在这样的实践中,提供再生粘接片材的辊和第二储配器(或下游提供再生粘接片材的辊)完全未运转。Yet another contemplated surface covering structure 410 is depicted in FIG. 7 , where components corresponding to those previously described are labeled with like numerals within the 400 series. In this construction, a particle/adhesive layer 440 of ground particles or a preformed sheet structure such as a recycled bonded foam sheet structure is adhesively joined to a saturated exposed surface material 418 by an adhesive layer 450 such as hot melt polyurethane. below. It is contemplated that such structures may be formed by the processes depicted or described in Figures 2, 4 or 4A. For example, such a structure can be formed by the process in Figure 4 if using an in-situ milled backing material such as crumb foam or cork, or by the process in Figure 4A if using a pre-formed, e.g. recycled bonded foam sheet. the process described. In such a practice, the roll supplying the recycled adhesive sheet and the second accumulator (or the roll downstream supplying the recycled adhesive sheet) are not running at all.

在图8中描述了再一个设想的表面覆盖结构510,其中与之前所描述的相对应的部件用500序列之内的相似编号进行标示。可以理解的是,该结构是图7中的结构的改进,其中去掉了胶粘剂层550并将胶粘剂层554放置于背衬结构514和纤维背衬片552之间。可以设想的是,可以由图2、4或4A中所描绘或描述的过程形成这样的结构。例如,如果使用原位磨碎的背衬材料(如碎屑泡沫或软木),则可以通过略微修改图4中描绘和描述的过程形成这样的结构,或者如果使用例如再生粘接泡沫的预成型片,则可以通过图4A所述的过程形成这样的结构。在这样的实践中,胶粘剂涂布机设置在第一储配器(或第一个供应再生粘接片材的辊)的上游,从而在与更上层结合之前在纤维背衬层552的顶部施加胶粘剂层。处理外复合层的胶粘剂涂布机、供给稳定材料的辊和第二储配器(或下游的供给再生粘接片材的辊)完全未运转。或者,图4中的储配器120可变更为用于将胶粘剂554施加到背衬552上的辊涂机。胶粘剂层554有助于将背衬514与例如聚酯或聚丙烯非织造物或毡背衬552粘合。可添加选择性的附加层517。Yet another contemplated surface covering structure 510 is depicted in FIG. 8 , where components corresponding to those previously described are labeled with like numerals within the 500 series. It will be appreciated that this structure is a modification of that of FIG. 7 in that adhesive layer 550 is removed and adhesive layer 554 is placed between backing structure 514 and fibrous backing sheet 552 . It is contemplated that such structures may be formed by the processes depicted or described in Figures 2, 4 or 4A. For example, such a structure can be formed by slightly modifying the process depicted and described in Figure 4 if using an in situ milled backing material such as detritus foam or cork, or if using a preform such as recycled bonded foam sheet, such a structure can be formed by the process described in Figure 4A. In such a practice, the adhesive applicator is positioned upstream of the first reservoir (or first roll supplying recycled adhesive sheet material) to apply the adhesive on top of the fibrous backing layer 552 prior to bonding with the upper layer layer. The adhesive applicator handling the outer composite layer, the roll feeding the stabilizing material, and the second accumulator (or the downstream roll feeding the recycled adhesive sheet) were not running at all. Alternatively, the dispenser 120 in FIG. 4 could be replaced with a roll coater for applying the adhesive 554 to the backing 552 . Adhesive layer 554 helps bond backing 514 to, for example, polyester or polypropylene nonwoven or felt backing 552 . Optional additional layers 517 may be added.

在图9中描述了再一个设想的表面覆盖结构610,其中与之前所描述的相对应的部件用600序列之内的相似编号进行标示。可理解的是,该结构是图7或图8中结构的改进,其中胶粘剂层650设置在表面层618和背衬640之间,且胶粘剂层654设置在背衬层640和纤维背衬片652之间。可设想的是,可以由图2、4或4A中描绘或描述的过程来形成这样的结构。例如,如果使用原位磨碎的背衬材料(如碎屑泡沫或软木),则可以通过略微修改图4中描绘和描述的过程形成这样的结构,如果使用例如再生粘接泡沫的预成型片,则可以通过图4A所述的过程来形成这样的结构。在这样的实践中,胶粘剂涂布机设置在第一储配器(或第一个供给再生粘接片材的辊)的上游,从而在与更上层结合之前在纤维背衬层652的顶部涂覆胶粘剂层。供给稳定材料的辊和第二储配器(或下游的供应再生粘接片材的辊)完全未运转。或者,图4中的储配器120可变更为用于将胶粘剂654施加到背衬652上的辊涂机。图9的结构610特别适用使用例如颗粒和粘合剂的预成型片作为背衬层640。Yet another contemplated surface covering structure 610 is depicted in FIG. 9 , where components corresponding to those previously described are labeled with like numerals within the 600 series. It will be appreciated that this structure is a modification of the structure in Figure 7 or Figure 8, wherein the adhesive layer 650 is disposed between the surface layer 618 and the backing 640, and the adhesive layer 654 is disposed between the backing layer 640 and the fibrous backing sheet 652 between. It is contemplated that such structures may be formed by the processes depicted or described in Figures 2, 4 or 4A. For example, if using an in situ milled backing material such as crumb foam or cork, such a structure can be formed by slightly modifying the process depicted and described in Figure 4, if using preformed sheets of e.g. recycled bonded foam , then such a structure can be formed through the process described in FIG. 4A. In such a practice, the adhesive applicator is positioned upstream of the first reservoir (or first roll feeding the recycled adhesive sheet) to coat the top of the fibrous backing layer 652 prior to bonding with the upper layer. Adhesive layer. The roll feeding the stabilizing material and the second accumulator (or the downstream roll feeding the recycled adhesive sheet) were not running at all. Alternatively, the dispenser 120 in FIG. 4 could be replaced with a roll coater for applying the adhesive 654 to the backing 652 . The structure 610 of FIG. 9 is particularly suitable for use as a backing layer 640 of a preformed sheet, such as particles and binder.

在图10中描述了再一个设想的表面覆盖结构710,其中与之前所描述的相对应的部件用700序列之内的相似编号进行标示。可理解的是,该结构是图6中结构的改进,其中稀松布层757[如聚酯、聚丙烯、玻璃等机织或非织造网或网状材料(稀松布)]设置为与玻璃层742邻接。可设想的是,如果使用原位磨碎的背衬材料(如碎屑泡沫或软木)及粘合剂,则可以通过图4中描绘和描述的过程形成这样的结构,或者,如果使用例如再生粘接泡沫的预成型片,则可通过图4A所述的过程来形成这样的结构。在这样的实践中,稀松布输送辊位于输送稳定材料的辊的上游,而第二储配器(或下游的供给再生粘接片材的辊)未运转。所得结构提供了相当大的内部尺寸稳定性,并且特别适用于例如地毯砖、地砖、模块化产品等物品。例如,稀松布757可抵消表面材料712中的任何收缩,从而提供平整或略微穹形的产品。附加的稳定层757可有助于去掉或去除纺织品背衬752,使用更轻的表面织物712,使用更少的组合物716或717,提供更耐用的可印花产品等。Yet another contemplated surface covering structure 710 is depicted in FIG. 10 , where components corresponding to those previously described are labeled with like numerals within the 700 series. It will be appreciated that this structure is a modification of the structure of Figure 6, wherein the scrim layer 757 [such as polyester, polypropylene, glass, etc. 742 adjoining. It is conceivable that such a structure could be formed by the process depicted and described in Figure 4 if using an in situ ground backing material such as crumb foam or cork, and an adhesive, or if using, for example, recycled A preformed sheet of bonded foam can then be used to form such a structure by the process described in Figure 4A. In such a practice, the scrim feed roll is located upstream of the roll that feeds the stabilizing material, and the second accumulator (or downstream roll that feeds the recycled bonded sheet material) is not operating. The resulting structure provides considerable internal dimensional stability and is particularly suitable for use in items such as carpet tiles, floor tiles, modular products, and the like. For example, the scrim 757 can counteract any shrinkage in the surface material 712, thereby providing a flat or slightly domed product. The additional stabilizing layer 757 can help to remove or remove the textile backing 752, use a lighter face fabric 712, use less composition 716 or 717, provide a more durable printable product, and the like.

在图11中描述了再一个设想的表面覆盖结构810,其中与之前所描述的相对应的部件用800序列之内的相似编号进行标示。可理解的是,该结构是图3中结构的改进,其中在外复合层818和底层之间没有附加层。可设想的是,如果使用原位磨碎的背衬材料例如碎屑泡沫或软木以及粘合剂,则可以通过图4中描绘和描述的过程形成这样的结构,或者如果使用例如再生粘接泡沫的预成型片,则可以通过图4A所述的过程来形成这样的结构。在这样的实践中,处理外复合层的胶粘剂涂布机优选完全未运转。在背衬814中使用其它粘合剂可有助于去除其它胶粘剂层。Yet another contemplated surface covering structure 810 is depicted in FIG. 11 , wherein components corresponding to those previously described are labeled with like numerals within the 800 series. It will be appreciated that this structure is a modification of the structure of Figure 3 in that there are no additional layers between the outer composite layer 818 and the bottom layer. It is conceivable that such a structure could be formed by the process depicted and described in Figure 4 if using an in situ milled backing material such as crumb foam or cork and adhesive, or if using e.g. recycled adhesive foam Such a structure can be formed by the process described in Figure 4A. In such a practice, the adhesive applicator handling the outer composite layer is preferably not running at all. The use of other adhesives in the backing 814 may facilitate removal of other adhesive layers.

可理解的是,如果需要,在任何所描述的实施方式中,在任意层之间可插入一层或多层附加的粘合剂层,例如热熔聚氨酯、聚酯、聚酰胺和/或类似物质。It will be appreciated that, if desired, in any of the described embodiments, one or more additional adhesive layers, such as hot melt polyurethane, polyester, polyamide and/or the like, may be interposed between any of the layers. substance.

因此,举例说明,可在背衬片和邻接的背衬层之间和/或在下面的背衬层和稳定层(如采用)之间和/或在稳定层(如采用)和上覆的背衬层(如存在)之间加入胶粘剂层。同样地,可设想的是,在任何描绘和/或描述的实施方式中,所形成的结构可具有或不具有纤维背衬片。并且,更多粘合剂可涂覆在任何预成型的制品片材如再生粘接泡沫预成型片的表面。此外,可以向或不向具体结构上加入一层或多层附加的顶层(17)或一层或多层底层(15)。Thus, by way of example, it may be between a backing sheet and an adjacent backing layer and/or between an underlying backing layer and a stabilizing layer (if employed) and/or between a stabilizing layer (if employed) and an overlying A layer of adhesive is added between the backing layers (if present). Likewise, it is contemplated that in any of the depicted and/or described embodiments, structures may be formed with or without a fibrous backing sheet. Also, more adhesive can be applied to the surface of any preformed product sheet, such as a recycled adhesive foam preform. Furthermore, one or more additional top layers (17) or one or more bottom layers (15) may or may not be added to the particular structure.

至少某些实施方式或结构的一项设想的益处是能加入大百分比的回收的、可再生的、可回收的、天然的、生物类的、可生物降解的或其它环保或可靠的材料,例如,废品,如回收的挡风雨条、回收的垫子、回收的轮胎、废旧地毯、旧地板、回收的表面覆盖物、加工废品、最终消费前回收物、最终消费后回收物和/或类似物质。同样,可再生资源如软木或木材可单独使用或与回收材料一起使用。仅举例说明,回收的填充材料如表面覆盖物、表面材料、背衬材料、地毯和/或类似物质可被磨碎(或稠化、压碎、剪碎、粉碎、高剪切混合、低温磨碎、研磨和/或进行类似处理),然后在以所需的层关系淀积之前与橡胶颗粒(和/或软木颗粒)及粘合剂掺合。在这样的过程中,磨碎的材料并不熔化,而是形成弹性基体成分,从而形成背衬。因此,由于个体橡胶颗粒(和/或软木颗粒)并未融合,因此可加入相对高含量的废旧地毯、旧地板等而不会对弹性产生负面影响。A contemplated benefit of at least some embodiments or structures is the ability to incorporate large percentages of recycled, renewable, recyclable, natural, bio-based, biodegradable or other environmentally friendly or reliable materials such as , waste such as recycled weatherstripping, recycled rugs, recycled tires, used carpets, used flooring, recycled surface coverings, processing waste, final pre-consumer recycling, final post-consumer recycling, and/or the like. Likewise, renewable resources such as cork or wood can be used alone or with recycled materials. By way of example only, recycled fill materials such as surface coverings, face materials, backing materials, carpet and/or the like may be ground (or densified, crushed, shredded, pulverized, high shear mixed, cryogenically ground crushed, ground, and/or similarly processed), then blended with rubber particles (and/or cork particles) and binder before being deposited in the desired layer relationship. In such a process, the ground material does not melt, but instead forms an elastic matrix component, which forms the backing. Thus, since the individual rubber particles (and/or cork particles) are not fused, relatively high levels of waste carpet, old flooring, etc. can be added without negatively affecting elasticity.

至少某些实施方式或结构的另一项设想的益处是在外复合层中采用的平整织物占最终结构重量的相当小的百分比。该重量百分比通常小于约25%,优选约10%或更小。因此,本发明的表面覆盖物产品本身在没有不适当的纤维组分污染的情况下可多次磨碎并回收作为新背衬材料。在具体例子中,颗粒粘合剂混合物由三分之一软木颗粒、三分之一橡胶颗粒和三分之一回收表面覆盖物颗粒构成。所述的三分之一的比例可基于重量或者体积。例如MDI或MDE粘合剂将三种不同类型的颗粒粘合在一起。Another contemplated benefit of at least some embodiments or structures is that the lay fabric employed in the outer composite layer constitutes a relatively small percentage of the weight of the final structure. This weight percentage is generally less than about 25%, preferably about 10% or less. Thus, the surface covering product of the present invention can itself be ground up and recycled as new backing material multiple times without contamination by unsuitable fiber components. In a specific example, the particle binder mixture is comprised of one third cork particles, one third rubber particles, and one third recycled surface covering particles. The one-third ratio may be based on weight or volume. Binders such as MDI or MDE bind three different types of particles together.

如之前所示,本结构的一种设想的用途是表面覆盖物砖或垫的形式,例如地砖、地板垫等。在图12、13中描绘了示例性的地砖产品900,其具有由外复合层界定的装饰显露表面975,所述外复合层中包含如前所述的装饰纺织品层并覆盖颗粒背衬914。当然,可理解的是,为简洁起见只显示了单层颗粒背衬914,如需要,同样可以采用任何已描述的背衬结构。砖900也可包括选择性的覆盖层977、例如压花等纹理装饰979和增大摩擦的层980。同样,尽管所描述的是方形砖,可设想也可采用其它几何形状例如联锁楔形、波浪饰形等。As previously indicated, one envisaged use of the present structure is in the form of surface covering tiles or mats, such as floor tiles, floor mats and the like. An exemplary floor tile product 900 is depicted in FIGS. 12 and 13 having a decorative exposed surface 975 bounded by an outer composite layer comprising a decorative textile layer as previously described and covering a particle backing 914 . Of course, it will be appreciated that only a single layer of particulate backing 914 is shown for simplicity, and that any of the described backing constructions could likewise be used, if desired. The tile 900 may also include an optional cover layer 977 , a textural decoration 979 such as embossing, and a friction increasing layer 980 . Also, while square tiles are described, it is contemplated that other geometries such as interlocking wedges, corrugations, etc. could be used.

还可设想的是,形成背衬结构的材料自身可用作提供一部分美观怡人的显露表面。举例说明,在图14和15中,描述了表面覆盖物砖或垫结构1000,其具有由外复合层界定的装饰显露表面1075,所述外复合层中包含如前所述的装饰纺织品层并覆盖颗粒背衬1014。如图所示,一部分颗粒背衬1014延伸出外表复合层之外,从而界定了装饰边。这样的结构可用于协助这些砖在表面上放置时形成外观上无缝的铺装,这是因为所有的边缘都具有匹配一致的外观。It is also envisioned that the material forming the backing structure may itself be used to provide a portion of the aesthetically pleasing exposed surface. By way of illustration, in Figures 14 and 15, a surface covering tile or mat structure 1000 is depicted having a decorative exposed surface 1075 bounded by an outer composite layer comprising a decorative textile layer as previously described and The particle backing 1014 is covered. As shown, a portion of the particle backing 1014 extends beyond the outer composite layer, thereby defining a decorative border. Such a structure can be used to assist the tiles to form an apparently seamless pavement when placed on a surface, since all edges have a matched and consistent appearance.

同样,砖1000也可包括选择性的覆盖层1077、例如压花等纹理装饰1079和增大摩擦的层1080。Likewise, the tile 1000 may also include optional cover layers 1077 , textured decorations 1079 such as embossing, and friction-enhancing layers 1080 .

通过使用相对开放的机织或针织结构(包括网或网状稀松布),使得透过显露表面织物可以看到背衬,从而使形成背衬结构的材料也可用于提供一部分美观的显露表面。这些开放织物可单独使用或与外向边界同时使用,任何本文所述的结构、结构或产品的底表面也可具有纹理装饰,例如压花以增大表面摩擦等。The material forming the backing structure can also be used to provide a portion of the aesthetically pleasing revealing surface by using a relatively open woven or knitted structure, including a net or mesh scrim, so that the backing is visible through the revealing surface fabric. These open fabrics can be used alone or with outward facing borders, and the bottom surface of any of the structures, structures or products described herein can also have textured decorations such as embossing to increase surface friction and the like.

根据至少一个可能的实施方式,将由纺织品表面和至少一层结团邻接颗粒层背衬形成的结构固化,切割为地砖坯,着色、印花或染色,然后用膜或成膜组合物涂覆表面,并固化形成澄清透明或至少半透明的膜。纺织品表面、背衬和/或膜可在着色、印花或染色之前、之时或之后形成纹理、进行压花等。According to at least one possible embodiment, the structure formed by the textile surface and at least one backing of the agglomerated adjoining particle layer is cured, cut into adobes, coloured, printed or dyed, and the surface is then coated with a film or film-forming composition, and cure to form a clear transparent or at least translucent film. The textile surface, backing and/or film may be textured, embossed, etc. before, during or after colouring, printing or dyeing.

与以宽幅形式印花或染色随后切砖的方式相反,通过将砖坯或模块坯(modular blank)印花或染色来匹配地印花或染色则更简单易行。具有适合用于着色、印花、染色等的浅色或白色纺织品表面的具背衬地砖坯(纺织品表面、颗粒/粘合剂背衬,具有或不具有附加稳定层、粘合剂层、纺织品背衬、增大摩擦的背衬和/或类似层)可用于着色、染色、印花、形成纹理、处理、压花,从而在其上形成具有相对精度(例如将方形砖坯放在夹具上)的例如图像、图案或图形,由此从而制造例如具有图像、图形或图案的地板,在地砖安装中,这些图像、图形或图案将与相邻地砖的相邻图像、图形或图案匹配。以此方式,大幅图像、图形或图案能分割为多个部分,每一部分在独立的砖上。或者,意图与相邻砖图形的至少某些元素相匹配的砖图形可精确匹配地实现,从而为整体安装提供非常令人愉悦的无缝外观。Printing or dyeing bricks or modular blanks to match is simpler and easier, as opposed to printing or dyeing them in broad format and then cutting them. Backed floor tiles with a light or white textile surface suitable for staining, printing, dyeing, etc. (textile surface, particle/adhesive backing, with or without additional stabilizing layer, adhesive layer, textile backing linings, friction-enhancing backings, and/or similar layers) may be used for coloring, dyeing, printing, texturing, treating, embossing, thereby forming thereon with relative precision (e.g. placing a square adobe on a jig) such as images, patterns or graphics, thereby making for example floors with images, graphics or patterns which, in the installation of floor tiles, will match adjacent images, graphics or patterns of adjacent floor tiles. In this way, a large image, graphic or pattern can be divided into multiple parts, each part on a separate tile. Alternatively, a brick pattern intended to match at least some elements of an adjacent brick pattern may be realized in an exact fit, thereby providing a very pleasing seamless appearance to the overall installation.

类似地,具有用保护性涂层浸透的纺织品显露表面和颗粒/粘合剂背衬的砖坯或模块坯可以进行固化,然后通过例如升华法(例如,染料升华印花、染墨升华印花、喷墨升华印花等)着色、印花、染色和/或进行类似处理,其中染料、墨水、图像、图案、图形等透过保护膜印在纺织品表面上,从而使得透过透明或半透明保护膜可见例如图像、色彩、图案或图形等。通常在聚酯、聚合物或涂覆聚合物的表面上进行。Similarly, a brick or module having a textile exposed surface impregnated with a protective coating and a particle/binder backing can be cured and then processed by, for example, a sublimation process (e.g., dye-sublimation printing, ink-sublimation printing, ink-jet printing). Sublimation printing, etc.) pigmented, printed, dyed and/or similarly processed in which dyes, inks, images, patterns, figures etc. are printed on the surface of the textile through a protective film so that through the transparent or translucent protective film e.g. images are visible , color, pattern or graphics, etc. Typically performed on polyester, polymer or coated polymer surfaces.

例如,在高温下,升华印花中的固体染料可转化为气体而无需变为液体。高温同时也使聚合物膜或织物上的孔开放并允许气体进入。当将物品远离热时,温度降低,聚合物孔关闭而其它复原为固态并成为聚合物膜或织物的一部分。正确完成后,则不会被洗去或褪去,除非实体纤维或涂层受到破坏。For example, at high temperatures, solid dyes in sublimation printing can be converted to gas without becoming liquid. The high temperature also opens up the pores in the polymer film or fabric and allows gas to enter. When the item is removed from heat, the temperature drops, the polymer pores close and the others revert to a solid state and become part of the polymer film or fabric. When done correctly, it will not wash off or fade unless the solid fibers or coating are damaged.

大多数喷墨升华在白色材料(基底)上完成。其原因为墨水在升华时实际上是透明的,从而需要白色背景使之显露。白色因为其不与色彩发生冲突所以是理想的背景。事实上,白色背景增强了色彩。Most inkjet sublimation is done on a white material (substrate). The reason for this is that the ink is actually transparent when sublimated, requiring a white background to show it through. White is an ideal background because it does not clash with colour. In fact, the white background enhances the colors.

根据至少所选的实施方式,白色纺织品、白色涂覆纺织品或白色涂层或膜用作白色基底或背景,位于例如聚酯涂层等澄清或透明聚合物涂层或膜以下,所述澄清或透明聚合物涂层或膜用于在表面覆盖物上进行图像、图案或图形的升华印花。According to at least selected embodiments, a white textile, a white coated textile or a white coating or film is used as a white substrate or background beneath a clear or transparent polymer coating or film such as a polyester coating, the clear or Transparent polymer coatings or films are used for sublimation printing of images, patterns or graphics on surface coverings.

同样,一层或多层其它透明涂层、膜或磨损层可加在聚酯或其它聚合物涂层或膜上。Likewise, one or more other clear coats, films or wear layers may be added over the polyester or other polymeric coating or film.

根据至少所选的实施方式,可以由单一聚合物或聚合物类型构成的层形成表面覆盖物从而有利于回收。例如,表面覆盖物可全部由聚烯烃或全部由聚酰胺组分形成。According to at least selected embodiments, a layer composed of a single polymer or polymer type may form a surface covering to facilitate recycling. For example, the surface covering may be formed entirely of polyolefin or entirely of polyamide components.

根据至少一个实施方式,表面覆盖物的表面和/或背衬满足或者超过例如易燃性、冒烟、毒性、土壤保护、抗微生物、气味、VOC、烟雾密度、丸粒测试(pill test)、耐光性、喷霜、静电、尺寸稳定性、亚琛(Aachen)测试、染料牢固度、耐用性、办公椅脚轮测试、表面重量、高度、柔性、尺寸、翘弯、卷曲、弯曲、偏差、歪斜、高度变化、三维结构变化、防污、耐脏、耐污、可清洁性、商业评定、用户评定、缓冲性、弹性、悬垂、可缝纫性、外观保持、压缩、压缩永久变形、回收含量、可回收含量、可再生材料含量等的工业标准,以及其它工业标准、环境标准、测试评定和/或类似标准。例如,地板覆盖物工业标准和/或规范,更具体而言,商业地板标准、住宅地板标准、工业地板标准(例如医院、教育和/或政府标准)、饭店地板标准、零售地板标准和/或类似标准。According to at least one embodiment, the surface and/or backing of the surface covering meets or exceeds, for example, flammability, smoke emission, toxicity, soil protection, antimicrobial, odor, VOC, smoke density, pill test, Lightfastness, Blooming, Static, Dimensional Stability, Aachen Test, Dye Fastness, Durability, Office Chair Caster Test, Surface Weight, Height, Flex, Size, Warp, Curl, Bend, Deviation, Skew , height change, three-dimensional structure change, stain resistance, stain resistance, stain resistance, cleanability, commercial rating, user rating, cushioning, elasticity, drape, sewability, appearance retention, compression, compression set, recycled content, Industry standards for recyclable content, renewable material content, etc., and other industry standards, environmental standards, test ratings, and/or similar standards. For example, floor covering industry standards and/or specifications, more specifically commercial flooring standards, residential flooring standards, industrial flooring standards (e.g. hospital, educational and/or government standards), restaurant flooring standards, retail flooring standards and/or similar standard.

根据至少一个实施方式,优选颗粒/粘合剂背衬结构或层中的颗粒和/或碎屑为约6mm或更小(粉末或颗粒)。According to at least one embodiment, it is preferred that the particles and/or debris in the particle/binder backing structure or layer be about 6 mm or smaller (powder or granules).

至少一个实施方式的颗粒/粘合剂背衬在约100psi(磅/平方英寸)或更小的压力下固化,优选50psi或更小,更优选25psi或更小,最优选10psi或更小。在碎屑(颗粒)间具有空隙并含有尺寸主要为约2mm至约6mm的碎屑的低压固化颗粒/粘合剂背衬在光滑平整的地毯表面上提供了横向握持。横向握持使表面覆盖物如地板不会移动或移位。具有横向握持的地砖甚至在未进行完全涂覆胶粘剂的安装、可释放的胶粘剂安装、双面胶安装之后,或者甚至在自由摆放或未用胶粘剂的安装之后,仍趋于保持在原位。The particle/adhesive backing of at least one embodiment cures at a pressure of about 100 psi (pounds per square inch) or less, preferably 50 psi or less, more preferably 25 psi or less, most preferably 10 psi or less. A low pressure cured particle/adhesive backing having interstices between the chips (particles) and containing chips primarily in the range of about 2 mm to about 6 mm in size provides lateral grip on smooth, even carpet surfaces. Lateral grip keeps surface coverings like floors from shifting or shifting. Floor tiles with lateral grip tend to stay in place even after installations without full adhesive, releasable adhesives, double-sided tape, or even after free-standing or adhesive-free installations .

至少某些实施方式的颗粒/粘合剂背衬的颗粒或碎屑可选自回收的、可回收的、可再生的、废弃的、副产物、翻新的和/或崭新材料。The pellets/adhesive-backed pellets or scrap of at least some embodiments can be selected from recycled, recyclable, renewable, waste, by-product, refurbished, and/or virgin materials.

优选为在可能的情况下使用回收的、可回收的和/或可再生的材料。例如,优选回收的表面覆盖物、回收的地板、回收的泡沫、回收的橡胶、回收的软木、软木、木材及其组合。回收的地板例如回收的地毯、回收的地毯砖、回收的废旧地毯、回收的地毯、回收的装饰废品(trimwaste)、回收的地毯制造废料等可加工以制造小于约20mm的颗粒或碎屑,优选小于约15mm,更优选小于约10mm,最优选小于约6mm(粉末或颗粒)。虽然可优选消费后的回收物,但也可以使用工业后回收物、可再生、可回收、天然、生物类的、可降解生物类和其它环保或可靠的材料。It is preferred to use recycled, recyclable and/or renewable materials where possible. For example, recycled surface coverings, recycled flooring, recycled foam, recycled rubber, recycled cork, cork, wood, and combinations thereof are preferred. Recycled flooring such as recycled carpet, recycled carpet tile, recycled carpet waste, recycled carpet, recycled trim waste, recycled carpet manufacturing waste, etc. can be processed to produce particles or chips smaller than about 20 mm, preferably Less than about 15 mm, more preferably less than about 10 mm, most preferably less than about 6 mm (powder or granulate). While post-consumer recyclate may be preferred, post-industrial recyclate, renewable, recyclable, natural, bio-based, degradable bio-based, and other environmentally friendly or reliable materials may also be used.

根据至少一个所选的实施方式,本发明可涉及具有纺织品或织物显露表面、装饰层或面和选择性的背衬的表面覆盖物,例如地板覆盖物、墙壁覆盖物、家俱覆盖物等。纺织品显露表面、层或面是选择性地浸透、覆盖和/或涂覆的,或者包括保护性涂层组合物或磨损表面,例如透明树脂或聚合材料。在至少一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬由结团的邻接颗粒部件构成或包括结团的邻接颗粒部件。在至少另一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬由泡沫垫层构成或包括泡沫垫层。在另一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬是颗粒和泡沫的掺合或组合背衬。具体地但非排他性地来说,至少某些本发明的实施方式涉及表面覆盖物,如地板覆盖物,包括但不限于地毯、地毯砖、地板、地砖、小块地毯、区块地毯、长条地毯、垫子、地板垫、稳定宽幅地毯、组合地板、卷材等。表面覆盖物中可包括簇绒、粘绒、针织、机织、非织造、针刺、植绒等纺织品或织物显露表面、表面材料、装饰纺织品层等。纺织品层可用膜或成膜组合物来浸透、覆盖和/或涂覆,所述膜或成膜组合物在固化时理想地为透明或半透明的。或者或另外地,面纱或纤维可包括一种或多种涂层或层,例如透明、半透明和/或有色的涂层或层。例如,面纱可包括芯纱或芯纤维或芯丝或涂覆有一层或多层涂层、覆层、外壳、层、磨损层、膜等的芯材料。另外还希望,膜或成膜组合物或一种或多种涂层或层具有耐磨、耐脏、耐污渍、美学上令人愉悦、可熔合和/或类似性质。在一个实施方式中,纺织品表面可以以覆盖关系设置在由结团颗粒块构成的弹性和/或柔性的背衬上,所述颗粒的例子是不规则颗粒,如新的、回收的、可回收的、可再生的、天然的、生物类的、可生物降解的和/或其它环保或可靠的材料,例如回收地板、泡沫、橡胶和/或软木。纺织品表面和颗粒背衬通常以邻接的关系粘合在一起。选择性的粘合剂层、胶粘剂膜、稳定层、纺织品背衬和/或类似物质可设置在所述颗粒背衬之上、之中或之下。增大摩擦、粘合或有助于安装的材料或涂层可加入到颗粒背衬中和/或加到颗粒背衬的底侧。例如,颗粒背衬可包括增加横向握持、减少滑动等的空隙。或者或另外地,具有增大摩擦的涂层的纺织品或织物背衬可附加在颗粒背衬之下、泡沫背衬之下或者颗粒和泡沫混合或组合背衬之下。还提供了这些表面覆盖物的制造和回收方法。According to at least one selected embodiment, the present invention may relate to surface coverings, such as floor coverings, wall coverings, furniture coverings, etc., having a textile or fabric exposed surface, a decorative layer or face and an optional backing. The textile exposed surface, layer or face is selectively impregnated, covered and/or coated, or includes a protective coating composition or an abrasive surface, such as a transparent resin or polymeric material. In at least one exemplary embodiment, the textile exposed surface is in overlying relationship with a backing that consists of or includes agglomerated contiguous particle components. In at least another exemplary embodiment, the textile exposed surface is in covering relationship with a backing that is comprised of or includes a foam cushion. In another exemplary embodiment, the textile exposed surface is in covering relationship with a backing that is a blend or combination of particles and foam. Specifically, but not exclusively, at least some embodiments of the present invention relate to surface coverings, such as floor coverings, including but not limited to carpets, carpet tiles, floors, floor tiles, rugs, carpet tiles, strips Carpets, rugs, floor mats, stable broadloom, floor tiles, rolls and more. Surface coverings may include tufted, viscoeled, knitted, woven, nonwoven, needle punched, flocked, etc. textile or fabric exposed surfaces, surface materials, decorative textile layers, and the like. The textile layer can be impregnated, covered and/or coated with a film or film-forming composition that is desirably transparent or translucent when cured. Alternatively or additionally, the veil or fibers may include one or more coatings or layers, such as transparent, translucent and/or colored coatings or layers. For example, the face yarn may comprise a core yarn or core fiber or filament or core material coated with one or more coatings, sheaths, sheaths, layers, wear layers, films, and the like. It is also desirable that the film or film-forming composition or one or more coatings or layers be abrasion resistant, stain resistant, stain resistant, aesthetically pleasing, fusible, and/or the like. In one embodiment, the textile surface may be disposed in overlying relationship on an elastic and/or flexible backing composed of agglomerated clumps of particles, examples of which are irregular particles such as new, recycled, recyclable renewable, natural, bio-based, biodegradable and/or other environmentally friendly or reliable materials such as recycled flooring, foam, rubber and/or cork. The textile surface and the particulate backing are usually bonded together in contiguous relationship. Optional adhesive layers, adhesive films, stabilizing layers, textile backings and/or the like may be disposed on, in or below the particulate backing. Materials or coatings that increase friction, adhesion, or aid in fit may be added to the particle backing and/or to the underside of the particle backing. For example, the particle backing can include voids to increase lateral grip, reduce slippage, and the like. Alternatively or additionally, a textile or fabric backing with a friction increasing coating may be affixed under the particle backing, under the foam backing or under a particle and foam hybrid or combination backing. Methods of manufacture and recycling of these surface coverings are also provided.

根据至少一个实施方式,本发明可涉及具有涂覆纱线纺织品显露表面或面和选择性的背衬的表面覆盖物,例如地板覆盖物、墙壁覆盖物、家俱覆盖物等。涂覆纱线纺织品显露表面或面是选择性地浸透、覆盖、涂覆的,或者包括保护涂层组合物或磨损表面,例如至少一种透明树脂或聚合材料。在至少一个示例性实施方式中,涂覆纱线纺织品显露表面与背衬成覆盖关系,所述背衬由结团的邻接颗粒部件构成或包括结团的邻接颗粒部件。在至少另一个示例性实施方式中,涂覆纱线纺织品显露表面与背衬成覆盖关系,所述背衬由泡沫垫层构成或者包括泡沫垫层。在另一个示例性实施方式中,纺织品显露表面与背衬成覆盖关系,所述背衬是颗粒和泡沫的掺合或组合背衬。纺织品表面和颗粒背衬通常以邻接的关系粘合在一起。选择性的胶粘剂膜或层、稳定层、纺织品背衬和/或类似物质可设置在颗粒背衬之上、之中或之下。增大摩擦、粘合或有助于安装的材料或涂层可加入到背衬中和/或加到背衬的底侧。例如,颗粒背衬可包括增加横向握持、减少滑动等的空隙。或者或另外地,具有增大摩擦的涂层、材料、花纹等的毡背衬可附加在颗粒背衬之下或泡沫背衬之下。涂覆面纱可以是涂覆的天然和/或合成纤维或丝或材料纱线,例如涂覆有透明的无色、白色或有色聚烯烃或PVC聚合材料的单纤维或多纤维(短纤纱或丝)挤出纱线,在所述透明的无色、白色或有色聚烯烃或PVC聚合材料上涂覆有透明无色聚合物磨损层或膜,例如高密度聚丙烯。还提供了这些表面覆盖物的制造和回收方法。According to at least one embodiment, the present invention may relate to surface coverings, such as floor coverings, wall coverings, furniture coverings, etc., having a coated yarn textile exposed surface or face and an optional backing. The coated yarn textile exposed surface or face is selectively impregnated, covered, coated, or includes a protective coating composition or abrasive surface, such as at least one transparent resin or polymeric material. In at least one exemplary embodiment, the coated yarn textile exposed surface is in overlying relationship with a backing that consists of or includes agglomerated contiguous particle components. In at least another exemplary embodiment, the coated yarn textile exposed surface is in covering relationship with a backing that is comprised of or includes a foam cushion. In another exemplary embodiment, the textile exposed surface is in covering relationship with a backing that is a blend or combination of particles and foam. The textile surface and the particulate backing are usually bonded together in contiguous relationship. Optional adhesive films or layers, stabilizing layers, textile backings and/or the like may be disposed on, in or below the particulate backing. Materials or coatings that increase friction, adhesion, or aid in fit may be added to the backing and/or to the underside of the backing. For example, the particle backing can include voids to increase lateral grip, reduce slippage, and the like. Alternatively or additionally, a felt backing with a friction increasing coating, material, pattern, etc. may be added under the particle backing or under the foam backing. The coated veil may be a coated natural and/or synthetic fiber or filament or material yarn, such as monofilament or multifiber (spun yarn or Filament) extruded yarn coated with a clear colorless polymer wear layer or film such as high density polypropylene on said clear colorless, white or colored polyolefin or PVC polymeric material. Methods of manufacture and recycling of these surface coverings are also provided.

参考附图中图16至20,并根据至少一些所选的实施方式,面纱、纤维、丝、材料等在例如图1至15或图22至28的任何结构或其变化中显示为涂覆纱线、纤维、丝、材料等。再次参考图16,示例性涂覆纱线1100包括芯纱1102、第一涂层1104和第二涂层1106。例如,芯纱1102是用第一聚合物或树脂1104(例如有色PVC或聚烯烃)涂覆、然后用第二聚合物或树脂1106(例如澄清的聚酯、聚烯烃、丙烯酸或聚氨酯)涂覆的天然和/或合成纱线(例如白色聚酯或聚丙烯)。Referring to Figures 16 to 20 of the drawings, and according to at least some selected embodiments, the veil, fiber, filament, material, etc. is shown as a coated yarn in any configuration or variation thereof such as Figures 1 to 15 or Figures 22 to 28 Thread, fiber, silk, material, etc. Referring again to FIG. 16 , an exemplary coated yarn 1100 includes a core yarn 1102 , a first coating 1104 and a second coating 1106 . For example, core yarn 1102 is coated with a first polymer or resin 1104 (such as colored PVC or polyolefin) and then coated with a second polymer or resin 1106 (such as clear polyester, polyolefin, acrylic, or polyurethane). natural and/or synthetic yarns (such as white polyester or polypropylene).

再次参考图17A和17B,另一种示例性涂覆纱线1200包括芯纱1202和涂层1204。例如,芯纱是用聚合物或树脂1204(例如有色聚酯、聚烯烃、丙烯酸或聚氨酯)涂覆的天然和/或合成纱线(例如有色聚酯或聚烯烃)。优选的是有色纱线是明亮颜色的纱线,如扁平的聚酯纱线,这是因为涂层会使纱线失去光泽。Referring again to FIGS. 17A and 17B , another exemplary coated yarn 1200 includes a core yarn 1202 and a coating 1204 . For example, the core yarn is a natural and/or synthetic yarn (eg, colored polyester or polyolefin) coated with a polymer or resin 1204 (eg, colored polyester, polyolefin, acrylic, or polyurethane). It is preferred that the colored yarn is a brightly colored yarn, such as a flat polyester yarn, because the coating will tarnish the yarn.

再次参考图18,示例性涂覆纱线、纤维、丝或材料1300包括芯纱、芯纤维、芯丝或芯材料1302和涂层1304。例如,芯1302是用聚合物或树脂1304(例如澄清聚酯、聚烯烃、丙烯酸、聚氨酯等)涂覆的天然和/或合成纱线、纤维、丝或材料(例如澄清、白色或有色聚酯、聚丙烯或光学纤维、丝或材料)。Referring again to FIG. 18 , an exemplary coated yarn, fiber, filament, or material 1300 includes a core yarn, core fiber, core filament, or core material 1302 and a coating 1304 . For example, the core 1302 is a natural and/or synthetic yarn, fiber, filament or material (e.g., clear, white or colored polyester) coated with a polymer or resin 1304 (e.g., clear polyester, polyolefin, acrylic, polyurethane, etc.) , polypropylene or optical fibers, filaments or materials).

再次参考图19,示例性涂覆纱线、纤维或丝1400包括芯纱、芯纤维或芯丝1402和涂层1404。例如,芯纱、芯纤维或芯丝1402是用聚合物或树脂1404(例如白色、有色或澄清的聚酯、聚烯烃、丙烯酸、PVC或聚氨酯)涂覆的天然和/或合成纱线、纤维或丝(例如聚酰胺、聚酯或聚烯烃的白色或有色三股(tri-lobal)纤维或丝)。Referring again to FIG. 19 , an exemplary coated yarn, fiber or filament 1400 includes a core yarn, core fiber or filament 1402 and a coating 1404 . For example, the core yarn, core fiber, or core filament 1402 is a natural and/or synthetic yarn, fiber, coated with a polymer or resin 1404, such as white, colored, or clear polyester, polyolefin, acrylic, PVC, or polyurethane. or filaments (eg white or colored tri-lobal fibers or filaments of polyamide, polyester or polyolefin).

再次参考图20,与图16的涂覆纱线1100类似的示例性涂覆纱线1500包括第一芯纱1502、第二涂层1504和第二涂层1506,以及第二芯纱1508及其上的第三涂层1510。例如,芯纱1502、1508各自是用聚合物或树脂1504、1510(例如有色PVC或聚烯烃)涂覆、然后用第二聚合物或树脂1506(例如澄清聚酯、聚烯烃、丙烯酸或聚氨酯)涂覆的天然和/或合成纱线(例如白色聚酯或聚烯烃)。Referring again to FIG. 20, an exemplary coated yarn 1500 similar to coated yarn 1100 of FIG. The third coating 1510 on. For example, core yarns 1502, 1508 are each coated with a polymer or resin 1504, 1510 (such as colored PVC or polyolefin) and then coated with a second polymer or resin 1506 (such as clear polyester, polyolefin, acrylic, or polyurethane). Coated natural and/or synthetic yarns (eg white polyester or polyolefin).

因此,涂覆面纱、纤维、丝、材料等可具有一根或多根单或多芯纱、芯纤维、芯丝或芯材料及一层或多层涂层等。例如,芯材尺寸为约150至5,000旦尼尔,优选约500至2500旦尼尔,单层涂覆的纱线尺寸为约1,000至10,000旦尼尔或更大,优选约2,000至8,000旦尼尔,且双层涂覆纱线尺寸为约2,000至20,000旦尼尔或更大,优选约3,000至18,000旦尼尔。Thus, a coated face yarn, fiber, filament, material, etc. may have one or more single or multiple core yarns, core fibers, core filaments or core materials and one or more layers of coating, etc. For example, the core size is about 150 to 5,000 denier, preferably about 500 to 2500 denier, and the single coated yarn size is about 1,000 to 10,000 denier or greater, preferably about 2,000 to 8,000 denier denier, and the double-coated yarn size is about 2,000 to 20,000 denier or greater, preferably about 3,000 to 18,000 denier.

参考附图中的图21A至21D,至少所选实施方式的面纱、面纤维、面丝等可具有不同的截面形状(横向形状),例如,裂膜纤维(split fiber)1600(半圆形,图21A)、切膜纤维或带1700(矩形,图21B)、椭圆形1800(图21C)、或圆形1900(图21D)。即使显示了所选的形状,也设想了纱线、纤维、丝或材料的其它公知形状。同样,纱线可以是变形、扭曲、膨胀的等。此外,纤维可以是切段纤维或丝、连续丝、单丝等等。Referring to Figures 21A to 21D of the accompanying drawings, at least selected embodiments of veils, face fibers, face threads, etc. may have different cross-sectional shapes (transverse shapes), for example, split fibers (split fibers) 1600 (semicircular, Fig. 21A), slit film fibers or ribbons 1700 (rectangular, Fig. 21B), oval 1800 (Fig. 21C), or circular 1900 (Fig. 21D). Even though selected shapes are shown, other known shapes of yarns, fibers, filaments, or materials are contemplated. Likewise, yarns may be deformed, twisted, swollen, etc. Additionally, the fibers may be staple or filaments, continuous filaments, monofilaments, and the like.

参考附图中的图22,其中与之前所描述的相对应的部件用2000序列之内的相似编号进行标示,织造表面覆盖物结构或产品2010包括织造表面材料2018,其包括通过胶粘剂或预涂层2050而粘附到再生粘接泡沫层2014上的纱线2012。此外,背衬材料2052通过例如火焰层压或原位成型而与泡沫层2014的底部粘附或粘合。再生粘接泡沫背衬结构如下述参考文献中所述:例如美国专利申请09/721,871和09/993,158(美国申请公开号US 2002/0132085)和10/209,050(美国申请公开号US2004/0022991)及授权给Higgins等的英国专利GB 2369294,上述参考文件在此以引用的方式引入,如同在此完全阐述一般。可加入选择性的附加上层或下层2017和2015。Referring to Figure 22 of the drawings, in which parts corresponding to those previously described are designated by like numerals within the series 2000, a woven surface covering structure or product 2010 includes a woven surface material 2018 which includes adhesive or pre-coated Yarn 2012 adhered to layer 2050 of recycled adhesive foam layer 2014. Additionally, backing material 2052 is adhered or bonded to the bottom of foam layer 2014 by, for example, flame lamination or in-situ molding. Recycled bonded foam backing structures are described in the following references: e.g., U.S. Patent Application Nos. 09/721,871 and 09/993,158 (U.S. Application Publication No. US 2002/0132085) and 10/209,050 (U.S. Application Publication No. US 2004/0022991) and British Patent GB 2369294 to Higgins et al., the above reference is hereby incorporated by reference as if fully set forth herein. Optional additional upper or lower layers 2017 and 2015 may be added.

参考图23,其中与之前所描述的相对应的部件用2100序列之内的相似编号进行标示,对于另一种可能优选的实施方式,表面覆盖物2110包括机织或针织的纺织品或织物表面2118,该纺织品或织物表面具有通过预涂层或胶粘剂2150固定就位的纱线或纤维2112,所述纱线或纤维2112与胶粘剂或底漆层2160粘合,依次地,2160与稳定层2142粘合,稳定层2142与泡沫层2114粘合,泡沫层2114与背衬2152粘合。预涂层2150可以例如是乳胶或热熔或聚氨酯类胶粘剂。底漆层2160可以是热熔胶粘剂。预涂层和底漆层可为一体。层2142优选为非织造玻璃垫子,层2114优选为聚氨酯泡沫,层2152可以是非织造聚酯和/或聚丙烯毡。可以加入选择性的上层或下层2117和2115。Referring to FIG. 23 , where parts corresponding to those previously described are numbered like numbers within the sequence 2100, for another potentially preferred embodiment, a surface covering 2110 comprises a woven or knitted textile or fabric surface 2118 , the textile or fabric surface has yarns or fibers 2112 held in place by a precoat or adhesive 2150, said yarns or fibers 2112 are bonded to an adhesive or primer layer 2160, which in turn, 2160 is bonded to a stabilizing layer 2142 Together, the stabilization layer 2142 is bonded to the foam layer 2114, and the foam layer 2114 is bonded to the backing 2152. Precoat 2150 may be, for example, latex or a hot melt or polyurethane-based adhesive. Primer layer 2160 may be a hot melt adhesive. The pre-coat and primer layer can be integrated. Layer 2142 is preferably a nonwoven glass mat, layer 2114 is preferably polyurethane foam, and layer 2152 may be a nonwoven polyester and/or polypropylene mat. Optional upper or lower layers 2117 and 2115 may be added.

这些新或填充泡沫背衬结构在例如美国专利5,545,276;5,948,500;6,203,881和6,468,623中进行描述,上述每篇专利在此以引用的方式引入。These new or filled foam backing structures are described, for example, in US Patent Nos. 5,545,276; 5,948,500; 6,203,881 and 6,468,623, each of which is incorporated herein by reference.

参考图24,其中与之前所描述的相对应的部件用2200序列之内的相似编号进行标示,表面覆盖物2210包括簇绒纺织品或织物表面2218,其具有成簇穿过主要背衬2262的纱线或纤维2212,并用预涂层或胶粘剂2150固定,预涂层或胶粘剂2150与胶粘剂或底漆层2260粘合,依次地,2260与稳定层2142粘合,稳定层2142与泡沫层2214粘合,泡沫层2214与背衬2152粘合。预涂层2150可以例如是乳胶或热熔或聚氨酯类胶粘剂。底漆层2160可以是热熔胶粘剂。预涂层和底漆层可为一体。层2142优选为非织造玻璃垫子,层2214优选为聚氨酯泡沫,层2152可以是非织造聚酯和/或聚丙烯毡。可以加入选择性的上层或下层2217和2215,或者或另外地,在形成簇绒前,用层2217涂覆纱线2212。虽然显示的是单层环绒头,还可以设想采用多层、花式、割绒、环和/或割绒环绒头。Referring to FIG. 24 , where parts corresponding to those previously described are numbered like numbers within the sequence 2200, a surface covering 2210 includes a tufted textile or fabric surface 2218 having yarns tufted through a primary backing 2262. The threads or fibers 2212 are secured with a precoat or adhesive 2150 which is bonded to an adhesive or primer layer 2260 which in turn is bonded 2260 to a stabilizing layer 2142 which is bonded to a foam layer 2214 , the foam layer 2214 is bonded to the backing 2152 . Precoat 2150 may be, for example, latex or a hot melt or polyurethane-based adhesive. Primer layer 2160 may be a hot melt adhesive. The pre-coat and primer layer can be integrated. Layer 2142 is preferably a nonwoven glass mat, layer 2214 is preferably polyurethane foam, and layer 2152 may be a nonwoven polyester and/or polypropylene mat. Optional upper or lower layers 2217 and 2215 may be added, or alternatively or additionally, yarn 2212 may be coated with layer 2217 prior to tufting. While a single layer loop pile is shown, multiple layers, fancy, cut pile, loop and/or cut pile loop piles are also contemplated.

再次参考图22至24,每个结构或复合体的表面可用一层或多层保护层涂覆。在优选实施方式中,面纱是机织然后热粘接(或熔合)的全聚烯烃涂覆纱线(聚烯烃芯纱、聚烯烃涂层),并且,澄清涂层例如高密度聚烯烃或聚酯或丙烯酸的澄清磨损层可加在涂覆纱线上。一种示例性澄清涂层材料是来自DuPont的Surlyn聚合物。优选的是通过挤压涂布来制造涂覆纱线。Referring again to Figures 22 to 24, the surface of each structure or composite may be coated with one or more protective layers. In a preferred embodiment, the face yarn is a fully polyolefin-coated yarn (polyolefin core yarn, polyolefin coating) that is woven and then thermally bonded (or fused), and a clear coating such as high-density polyolefin or polyolefin A clear wear layer of ester or acrylic can be added to the coated yarn. An exemplary clear coat material is Surlyn polymer from DuPont. It is preferred to manufacture the coated yarn by extrusion coating.

参考图25,其中与之前所描述的相对应的部件用2300序列之内的相似编号进行标示,至于另一种可能优选的实施方式,表面覆盖物2310包括割绒纺织品或织物表面2318,所述割绒纺织品或织物表面2318具有成簇穿过主要背衬2362的纱线或纤维2312,并用预涂层或胶粘剂2350固定,预涂层或胶粘剂2350与胶粘剂或底漆层2360粘合,依次地,2360与稳定层2342粘合,稳定层2342与泡沫层2314粘合,泡沫层2314与背衬2352粘合。预涂层2350可以例如是乳胶或热熔或聚氨酯类胶粘剂。底漆层2360可以是热熔胶粘剂。预涂层和底漆层可为一体。层2342优选为非织造玻璃垫子,层2314优选为聚氨酯泡沫,层2352可以是非织造聚酯和/或聚丙烯毡。可以加入选择性的上层或下层2317和2315。Referring to FIG. 25 , wherein parts corresponding to those previously described are designated by like numerals within the sequence 2300, as another possibly preferred embodiment, a surface covering 2310 comprises a cut pile textile or fabric surface 2318, the A cut pile textile or fabric surface 2318 has yarns or fibers 2312 in tufts passed through a primary backing 2362 and secured with a pre-coat or adhesive 2350 bonded to an adhesive or primer layer 2360, in turn , 2360 is bonded to stabilization layer 2342 , stabilization layer 2342 is bonded to foam layer 2314 , and foam layer 2314 is bonded to backing 2352 . Precoat 2350 may be, for example, latex or a hot melt or polyurethane-based adhesive. Primer layer 2360 may be a hot melt adhesive. The pre-coat and primer layer can be integrated. Layer 2342 is preferably a nonwoven glass mat, layer 2314 is preferably polyurethane foam, and layer 2352 may be a nonwoven polyester and/or polypropylene mat. Optional upper or lower layers 2317 and 2315 may be added.

参考图26,其中与之前所描述的相对应的部件用2400序列之内的相似编号进行标示,至于另一种可能优选的实施方式,表面覆盖物2410包括簇绒纺织品或织物表面2418,所述簇绒纺织品或织物表面2418具有成簇穿过主要背衬2462的纱线或纤维2412,并用预涂层或胶粘剂2450固定,预涂层或胶粘剂2450与胶粘剂或底漆层2460粘合,依次地,2460与稳定层2442粘合,稳定层2442与泡沫层2414粘合,泡沫层2414与背衬2452粘合。预涂层2450可以例如是乳胶或热熔或聚氨酯类胶粘剂。底漆层2460可以是热熔胶粘剂。预涂层和底漆层可为一体。层2442优选为非织造玻璃垫子,层2414优选为聚氨酯泡沫,层2452可以是非织造聚酯和/或聚丙烯毡。可以加入选择性的上层或下层2417和2415。Referring to FIG. 26 , wherein parts corresponding to those previously described are designated by like numerals within the sequence 2400, as another possibly preferred embodiment, a surface covering 2410 comprises a tufted textile or fabric surface 2418, the The tufted textile or fabric surface 2418 has yarns or fibers 2412 in tufts passed through a primary backing 2462 and secured with a pre-coat or adhesive 2450 bonded to an adhesive or primer layer 2460, in turn , 2460 is bonded to stabilization layer 2442 , stabilization layer 2442 is bonded to foam layer 2414 , and foam layer 2414 is bonded to backing 2452 . Precoat 2450 may be, for example, latex or a hot melt or polyurethane-based adhesive. Primer layer 2460 may be a hot melt adhesive. The pre-coat and primer layer can be integrated. Layer 2442 is preferably a nonwoven glass mat, layer 2414 is preferably polyurethane foam, and layer 2452 may be a nonwoven polyester and/or polypropylene mat. Optional upper or lower layers 2417 and 2415 may be added.

参考图27,其中与之前所描述的相对应的部件用2500序列之内的相似编号进行标示,非织造表面覆盖结构或产品2510包括非织造表面材料2518,其包括通过胶粘剂或预涂层2550与再生粘接泡沫层2514粘合的纱线2512。此外,背衬材料2552通过例如火焰层合或原位成型与泡沫层2514的底部粘附或粘合,再生粘接泡沫背衬结构如下述参考文献中所述:例如美国专利申请09/721,871和09/993,158(美国申请公开号US 2002/0132085)和10/209,050(美国申请公开号US2004/0022991)及授权给Higgins等的英国专利GB 2369294,上述参考文献在此以引用的方式引入,如同在此完全阐述一样。可以加入选择性的附加上层或下层2517和2515。Referring to FIG. 27 , in which parts corresponding to those previously described are designated by like numerals within the sequence 2500, a nonwoven surface covering structure or product 2510 includes a nonwoven surface material 2518 comprising an adhesive or precoat 2550 with The yarn 2512 bonded to the bonding foam layer 2514 is regenerated. Additionally, the backing material 2552 is adhered or bonded to the bottom of the foam layer 2514 by, for example, flame lamination or in-situ forming, regenerated bonded foam backing structures as described in the following references: e.g., U.S. Patent Application Serial No. 09/721,871 and 09/993,158 (U.S. Application Publication No. US 2002/0132085) and 10/209,050 (U.S. Application Publication No. US2004/0022991) and British Patent GB 2369294 to Higgins et al., the above references are hereby incorporated by reference as if at This is exactly the same as stated. Optional additional upper or lower layers 2517 and 2515 may be added.

参考图28,其中与之前所描述的相对应的部件用2600序列之内的相似编号进行标示,针刺或穿针表面覆盖结构或产品2610包括针刺表面材料2618,所述针刺表面材料2618包括通过胶粘剂或预涂层2650与再生粘接泡沫层26514粘合的纱线2612。此外,背衬材料2652通过例如火焰层合或原位成型与泡沫层2614的底部粘附或粘合,再生粘接泡沫背衬结构如下述参考文献中所述:例如,美国专利申请09/721,871和09/993,158(美国申请公开号US 2002/0132085)和10/209,050(美国申请公开号US 2004/0022991)及授权给Higgins等的英国专利GB2369294中公开,上述参考文献在此以引用的方式引入,如同在此完全阐述一般。可以加入选择性的附加上层或下层2617和2615。Referring to FIG. 28 , in which parts corresponding to those previously described are designated by like numerals within the sequence 2600 , a needled or needled surface covering structure or product 2610 includes a needled surface material 2618 which includes a needled surface material 2618 Included is yarn 2612 bonded to recycled adhesive foam layer 26514 by adhesive or precoat 2650. In addition, the backing material 2652 is adhered or bonded to the bottom of the foam layer 2614 by, for example, flame lamination or in-situ forming, regenerated bonded foam backing structures as described in the following references: e.g., U.S. Patent Application Serial No. 09/721,871 and 09/993,158 (U.S. Application Publication No. US 2002/0132085) and 10/209,050 (U.S. Application Publication No. US 2004/0022991) and British Patent GB2369294 to Higgins et al., which references are hereby incorporated by reference , as fully described here. Optional additional upper or lower layers 2617 and 2615 may be added.

根据所选的特征或实施方式,用于机织涂覆纱线表面材料的优选纱线是具有明亮色彩、平整、单丝聚酯纱线,用含有4%氧化物的HDPP进行涂覆以改善耐磨性,HDPP已经过交联,织物经热粘接以防止纱线滑动。Preferred yarns for weaving coated yarn surface materials, depending on selected features or embodiments, are brightly colored, flat, monofilament polyester yarns coated with HDPP containing 4% oxide to improve Abrasion resistance, HDPP has been cross-linked and the fabric is thermally bonded to prevent yarn slippage.

根据至少一个具体实施方式,背衬是由三层复合体形成,所述三层复合体是火焰层合或胶粘剂粘接而成的玻璃层、缓冲层和毡背衬层的复合体。缓冲层可以是颗粒/粘合剂层、泡沫层、泡沫/颗粒层等等。优选的是复合背衬可用预涂层或胶粘剂层例如热熔胶、乳胶、聚氨酯等与装饰表面粘合。优选热熔预涂层。According to at least one specific embodiment, the backing is formed from a three-layer composite of a flame-laminated or adhesive-bonded composite of a glass layer, a buffer layer, and a felt backing layer. The buffer layer can be a particle/binder layer, a foam layer, a foam/particle layer, and the like. Preferably the composite backing can be bonded to the decorative surface with a pre-coat or layer of an adhesive such as hot melt, latex, polyurethane or the like. Hot melt precoats are preferred.

优选使用精确涂布装置如LACOM涂布机来精确地测量最优预涂层或胶粘剂层,从而将背衬层压到装饰表面上,由此实现所需的簇绒锁定、层压强度、柔性和/或类似性质。优选热熔或聚氨酯胶粘剂。It is preferable to use a precision coating device such as a LACOM coater to precisely measure the optimum pre-coat or adhesive layer to laminate the backing to the decorative surface, thereby achieving the desired tuft lock, lamination strength, flexibility and/or of a similar nature. Hot melt or polyurethane adhesives are preferred.

根据至少所选的实施方式,在装饰表面以下的背衬是与装饰表面粘合的薄的、致密的、柔软的、弹性的背衬层,其间有或没有稳定层。优选重的填料,因为它们能制造致密背衬。也可选磁性或可磁化填料。According to at least selected embodiments, the backing below the decorative surface is a thin, dense, flexible, elastic backing layer bonded to the decorative surface, with or without a stabilizing layer in between. Heavy fillers are preferred because they produce dense backings. Magnetic or magnetizable fillers are also available as an option.

在至少所选的实施方式中,优选的是涂覆纱线的单丝是有色的,涂层是澄清的。涂层可以防止纱线变脏,增加光泽或用作保护膜连续片。纱线可以是复丝的,但在挤出时,松散材料将从纱线中被抽出,因此使用复丝几乎没有优势。丝可以是单色或组成整体的多色,并且可以是各种尺寸或截面形状。优选具有多种可控制的颜色的回收纱线。In at least selected embodiments, it is preferred that the monofilaments of the coated yarn are colored and the coating is clear. Coatings can keep yarns from getting dirty, add luster or serve as a continuous sheet of protective film. The yarn can be multifilament, but during extrusion, the bulk material will be drawn from the yarn, so there is little advantage to using multifilament. The filaments can be monochromatic or multicolored integrally, and can be of various sizes or cross-sectional shapes. Recycled yarns with a variety of controllable colors are preferred.

根据另一背衬例子,形成聚合物泡沫的组合物可用以制造高回收地毯含量的衬背或者高回收地毯含量的高密度衬垫。这可如下实现,将回收地毯的颗粒或碎片分散撒到到聚氨酯泡沫胶糊中,然后或者机械搅拌或者仅仅通过胶糊混合物的旋转翻动将碎片混合到液体泡沫中。另外一种方式,可以在管道输送泡沫通过静态搅拌机时将碎片定量加入到液体泡沫中。这样的过程能获益于较少的空气进入液体泡沫从而使泡沫成为更好的胶粘剂。例如回收地毯、回收地毯块、回收表面覆盖物、回收切边废料、回收聚氨酯泡沫、回收EPDM、回收轮胎橡胶、回收地板、回收塑料、回收玻璃和/或等等的小碎片可以在该过程中使用从而获得衬背和衬垫泡沫中更经济和更高回收含量的背衬。在一个例子中,将25重量%的碎片加入到75重量%的液体泡沫中。优选25/75的重量比或体积比的碎片/泡沫。According to another backing example, the polymeric foam forming composition can be used to make a high recycled carpet content backing or a high recycled carpet content high density pad. This can be accomplished by dispersing particles or chips of recycled carpet into the polyurethane foam glue and then mixing the chips into the liquid foam either by mechanical agitation or simply by rotating the glue mixture. Alternatively, the chips can be dosed into the liquid foam as the foam is piped through a static mixer. Such a process would benefit from less air entering the liquid foam making the foam a better adhesive. Small pieces such as recycled carpet, recycled carpet tile, recycled surface coverings, recycled trimming waste, recycled polyurethane foam, recycled EPDM, recycled tire rubber, recycled flooring, recycled plastic, recycled glass, and/or the like can be in the process The result is a more economical and higher recycled content backing in backing and cushion foams. In one example, 25% by weight chips are added to 75% by weight liquid foam. A weight or volume ratio of chips/foam of 25/75 is preferred.

虽然关于某些可能优选的实施方式和实践,描绘和描述了至少某些方面、特征或实施方式,但应当理解的是所描绘和描述的实施方式和实践仅仅是描述性的,并且本发明并不受限于此。更确切而言,完全可以设想到本发明的改动和变化对于本领域技术人员在阅读以上描述和/或进行本发明的实践时将是显而易见的。因此,本发明将涵盖至少所有这些改动和变化,并且将广泛的范围、实施方式和实施例等包含在以下权利要求及其等价项目的完全范围之内。While at least some aspects, features, or implementations have been depicted and described with respect to certain potentially preferred implementations and practices, it is to be understood that the depicted and described implementations and practices are illustrative only, and that the invention is not intended to Not limited to this. Rather, it is well contemplated that modifications and variations of the invention will become apparent to those skilled in the art from reading the foregoing description and/or practice of the invention. Accordingly, the present invention is to cover at least all such modifications and variations, and to embrace its broad scope, embodiments, examples, etc., within the full scope of the following claims and their equivalents.

在本文中例如指代本发明时使用的词语“包含”和“具有/包括”是用于详细说明存在例如确定的特征、整体、步骤或成分,但并未排除额外存在一种或多种其它特征、整体、步骤、成分及其组和/或等等。The words "comprising" and "having/comprising" used herein, for example, when referring to the present invention are used to specify the presence of, for example, certain features, integers, steps or components, but do not exclude the additional presence of one or more other Features, integers, steps, components and groups thereof and/or the like.

可以理解的是,为清楚起见在各自独立的实施方式中描述的某些特征、方面、实施方式、实例等等也可以在单一实施方式中组合提供。相反,为简洁起见在单一实施方式中描述的各种特征、方面、实施方式、实例也可以各自独立地或者在任何合适的亚组中提供。It is to be appreciated that certain features, aspects, implementations, examples, etc., which are, for clarity, described in separate embodiments, may also be provided in combination in a single embodiment. Conversely, various features, aspects, implementations, examples that are, for brevity, described in the context of a single embodiment, may also be provided independently or in any suitable subgroup.

Claims (14)

1. surface covering; it comprise defined with covering relation be arranged on the single or multiple lift backing appear the surface external composite layer; wherein said external composite layer comprises decorative textile product or tissue layer; described decorative textile product or tissue layer optionally soak into, cover with diaphragm or film-forming composition and apply at least a, and wherein said backing optionally comprises conglomeration particulate mass, foam, foam and particle, felt or its combination that is bonded together with syntople.
2. surface covering as claimed in claim 1, it further comprises the fiber backing sheet that is arranged on the described backing bottom side portion.
3. surface covering as claimed in claim 1, wherein said surface covering is a floor tile.
4. surface covering as claimed in claim 1, wherein said decorative textile product layer are at least a in woven, knitting, non-woven, acupuncture, tufting and the flocked fabric.
5. surface covering as claimed in claim 1, wherein said fabric is formed by coated yarns.
6. surface covering as claimed in claim 1, wherein said decorative textile product layer comprises one deck upside protectiveness wearing layer or film at least.
7. surface covering as claimed in claim 1, wherein said backing are flexible and/or flexible.
8. surface covering as claimed in claim 1, the wherein said surface that appears is arranged on the multilayer backing with covering relation.
9. surface covering as claimed in claim 1, it further comprises one deck stabilized zone at least.
10. surface covering as claimed in claim 1, wherein said backing are at least a in particle backing and the foam-back.
11. a manufacturing has the method for the surface covering of coated yarns textile surface and backing, said method comprising the steps of: for example the particle of rubber and/or foam and/or granulated cork and so on mixes mutually with adhesive or foam, and optionally adds one or more fillers, reagent or compound; With described particle/binder or particle/foam mixture deposit stratification; The textile surface material that optionally applies, covers or soak into is placed on the illuvium, forms sandwich construction; Suppress described sandwich construction, make described adhesive or foam curing with for example heat simultaneously, thereby make the bonding formation backing of described particle and described adhesive or foam, described backing optionally comprises the space between compressed granulate, and wherein said textile surface material and the described backing that optionally applies is bonding.
12. method as claimed in claim 11, the wherein said textile surface material that optionally applies at least a through in stamp or the dyeing at least before or after it is coated.
13. method as claimed in claim 12, the wherein said textile surface material that optionally applies is a sublimation (transfer) printing.
14. method as claimed in claim 11 is wherein added one or more layers additional wearing layer on the described textile surface material that optionally applies.
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CN102833968A (en) * 2011-06-14 2012-12-19 仁宝电脑工业股份有限公司 Method for manufacturing three-dimensional workpiece
CN103827413A (en) * 2011-09-27 2014-05-28 大日本印刷株式会社 Sheet for covering walls of earthquake-resistant structures, method for screening same, and construction method using same
CN107208362A (en) * 2015-01-16 2017-09-26 博优国际集团公司 Method for the covering and acquisition covering of ground, wall or ceiling
CN107429453A (en) * 2015-03-24 2017-12-01 雷亚莱私人有限责任公司 The recycling of used weaving or knitting fabric
CN114829128A (en) * 2019-12-19 2022-07-29 伊斯曼柯达公司 Method for producing light-blocking decorative articles
CN115072471A (en) * 2022-07-21 2022-09-20 常州市巨洋机电有限公司 A kind of conveying mechanism and preparation method for glass fiber cloth
CN116714156A (en) * 2023-06-08 2023-09-08 中国热带农业科学院农产品加工研究所 A bloom barrier film and its preparation method and method for inhibiting rubber bloom

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102833968A (en) * 2011-06-14 2012-12-19 仁宝电脑工业股份有限公司 Method for manufacturing three-dimensional workpiece
CN103827413A (en) * 2011-09-27 2014-05-28 大日本印刷株式会社 Sheet for covering walls of earthquake-resistant structures, method for screening same, and construction method using same
CN103827413B (en) * 2011-09-27 2016-07-06 大日本印刷株式会社 Shatter-proof structure wall sheet material, its screening technique and its construction method
CN107208362A (en) * 2015-01-16 2017-09-26 博优国际集团公司 Method for the covering and acquisition covering of ground, wall or ceiling
CN107429453A (en) * 2015-03-24 2017-12-01 雷亚莱私人有限责任公司 The recycling of used weaving or knitting fabric
CN114829128A (en) * 2019-12-19 2022-07-29 伊斯曼柯达公司 Method for producing light-blocking decorative articles
CN115072471A (en) * 2022-07-21 2022-09-20 常州市巨洋机电有限公司 A kind of conveying mechanism and preparation method for glass fiber cloth
CN115072471B (en) * 2022-07-21 2023-01-17 常州市巨洋机电有限公司 A kind of conveying mechanism and preparation method for glass fiber cloth
CN116714156A (en) * 2023-06-08 2023-09-08 中国热带农业科学院农产品加工研究所 A bloom barrier film and its preparation method and method for inhibiting rubber bloom

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