CN101654031A - Stationery pen and preparation method thereof - Google Patents
Stationery pen and preparation method thereof Download PDFInfo
- Publication number
- CN101654031A CN101654031A CN200810120337A CN200810120337A CN101654031A CN 101654031 A CN101654031 A CN 101654031A CN 200810120337 A CN200810120337 A CN 200810120337A CN 200810120337 A CN200810120337 A CN 200810120337A CN 101654031 A CN101654031 A CN 101654031A
- Authority
- CN
- China
- Prior art keywords
- pen
- stationery
- water
- stationery pen
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a stationery pen and a preparation method thereof. The stationery pen comprises a pen body for writing and is characterized in that the pen body for writing is filled with water-based colour ink; and the water-based colour ink comprises 10 to 140 portions of dispersion medium, 10 to 25 portions of foaming agent, 1 to 5 portions of colorant and 10 to 65 portions of water-based adhesive in portion by mass. The preparation method comprises the following steps: stirring and mixing the components uniformly at a room temperature; standing at a constant temperature to preparethe water-based colour ink; and filling the water-based colour ink into the pen body for writing with an automatic filling machine to prepare the stationery pen. After characters are written or pictures are drawn by the stationery pen on a substrate, such as paper, glass and the like, and the substrate is heated at a temperature of between 100 and 150 DEG C for 5 to 10 minutes, the original colourink is dried and expanded, so that the written characters and the drawn pictures have spatial three-dimensional structures.
Description
Technical field
The present invention relates to the preparation method of a kind of stationery pen and relevant printing ink.
Background technology
Stationery pen of the present invention prepares according to the foamed printing principle.Foamed printing is called stereoscopic printing again, can obtain the plastic relief decorative pattern on base material after printing and handling, and can be used for clothes, ornament, wallpaper, the art work and braille point etc.Early stage foamed printing uses CBA, it and thermoplastic resin, plasticizer, mill base and water etc. mix and are mixed with print paste, are printed on the base material, pass through high-temperature baking then, CBA is decomposed, discharge gas, in thermoplastic resin film, form microvesicle, make block letter have third dimension (Zhang Zhonghou etc., the study on the modification of inorganic endothermic type blowing agent sodium acid carbonate; The Henan chemical industry, 2004 (5): 19).Because the decomposition temperature of CBA is generally higher, technique controlling difficulty is big, and the residue of blowing agent is arranged in product simultaneously, influences the performance of product.
Summary of the invention
Primary technical problem to be solved by this invention provides a kind of a kind of stationery pen that makes the literal write or drawing have the space multistory structure, makes writing words or drawing have new artistic effect and individual style.
Another technical problem to be solved by this invention provides a kind of preparation method of above-mentioned stationery pen.
The present invention solves the technical scheme that above-mentioned primary technical problem adopts: a kind of stationery pen, and it includes writes handwriting, it is characterized in that being filled with hydrate colour printing ink in writing handwriting, and hydrate colour printing ink includes:
10～140 parts decentralized medium,
10～25 parts blowing agent,
1～5 part colouring agent,
10～65 parts aqueous binder,
Mass fraction.
As preferably, decentralized medium is a water; Blowing agent is the plastic hollow ball that contains easy vaporization material, and size is at 1～100 mu m range; Its thermal plasticity high polymer with about 70～150 ℃ of softening points of hollow ball is a membranous wall, and the liquid hydrocarbon compound that the internal package boiling point is 70～130 ℃ is as heptane or octane etc.; Colouring agent is pigment and dye paste; Aqueous binder comprises polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, water-soluble poly carbamate and various polymer emulsion, as acrylate copolymer emulsion, can be wherein a kind of, also can be that two or more mixes and uses.
The can of hydrate colour printing ink obtains stationery pen in general writing in the handwriting.Wherein general lettering pen comprises ball pen, pen, correction pen, marking pen, perhaps crayon etc.
The present invention solves the technical scheme that above-mentioned another technical problem adopts: a kind of preparation method of stationery pen, it is characterized in that: at room temperature in reactor, press the decentralized medium that row weight portion ratio adds 10～140 parts successively, 10～25 parts blowing agent, 1～5 part colouring agent, 10～65 parts aqueous binder, in room temperature to 50 ℃ scope, mix, constant temperature leaves standstill again, obtain hydrate colour printing ink, utilize automatic filling machine with the can of hydrate colour printing ink in writing handwriting, obtain stationery pen.
In the time of necessary, aqueous binder needs heating when being dissolved in dispersant, helping its dissolving, and preparation the time, operates in room temperature to 50 ℃ scope.
The expanded by heating mechanism of stationery pen: when with this stationery pen at paper, on the base materials such as glass behind writing words or the drawing, again with base material in 100～180 ℃ of whens heating, one of component wherein---microcapsule foamer begins expanded by heating.Microcapsules are to be membranous wall with about about the 100 ℃ thermal plasticity high polymer of softening point, the liquid hydrocarbon compound that the internal package boiling point is about about 100 ℃, and as heptane, octane etc.When microcapsule foamer began to be heated, liquid hydrocarbon began gasification, made microcapsules begin to expand, because microcapsules membranous wall high polymer also is in soft state under this temperature, therefore whole microcapsules begin to expand.Because the high polymer membranous wall also has good intensity simultaneously, when maximum was arrived in the microcapsules volumetric expansion, the microcapsules after the whole expansion did not still break.In microcapsules are heated the whole process of volumetric expansion, another component of system---decentralized medium water is also in continuous evaporation, and be dispersed in binding agent component---the thermal plasticity high polymer (polyvinyl alcohol of aqueous phase, polyvinylpyrrolidone, polyacrylic acid, water-soluble poly carbamate and various polymer emulsion are as acrylate copolymer emulsion etc.) expand together and it is bundled together with microcapsules, the complete evaporation with moisture falls to become projection rubber-like stereochemical structure again at last.The mill base that adds different colours can obtain the stationery pen of different color.
When with this stationery pen at paper, on the base materials such as glass writing words or the drawing after, again with base material in 100～180 ℃ the heating 2～10 minutes, hydrate colour ink setting originally also expands, and makes literal or the drawing write have the space multistory structure.
In printing ink, increase some an amount of essence, can be fragrant.
Compared with prior art, the invention has the advantages that:, behind writing words or the drawing, again base material was heated 2～10 minutes in 100～180 ℃ on the base materials such as glass at paper, colored ink originally expands and is dry, make literal or the drawing write have the space multistory structure, increased new artistic effect and individual style for writing words or drawing, and adopt physical blowing, blowing temperature is low, the technology controllability is good, and is few to the human influence, and security is good.
The specific embodiment
Below in conjunction with embodiment the present invention is described in further detail.
Embodiment 1
At room temperature in reactor, press row weight portion ratio and add 28 parts of decentralized medium water successively, 11 parts of microcapsule foamers, it is the plastic hollow ball that contains easy vaporization material, size is at 1～100 mu m range, its thermal plasticity high polymer with about 70～150 ℃ of softening points of hollow ball is a membranous wall, the liquid hydrocarbon compound that the internal package boiling point is 70～130 ℃ such as heptane or octane, 5 parts of black color pastes, 56 fens styrene～acrylate copolymer emulsions (containing solid 40%), mixed one hour in stirring at room, constant temperature is static one hour again, obtains extraordinary hydrate colour printing ink.Utilize automatic filling machine with the can of extraordinary hydrate colour printing ink in general lettering pen, obtain the black stationery pen.
Embodiment 2
At room temperature in reactor, press row weight portion ratio and add 140 parts of decentralized medium water successively, add 5 parts of polyvinyl alcohol and 12.5 parts of PVPs, be heated to 90 ℃ and make its dissolving, drop to room temperature, add 14 parts of microcapsule foamers, it is the plastic hollow ball that contains easy vaporization material, size is at 1～100 mu m range, its thermal plasticity high polymer with about 70～150 ℃ of softening points of hollow ball is a membranous wall, the liquid hydrocarbon compound that the internal package boiling point is 70～130 ℃ such as heptane or octane, 2 parts of red mill bases mixed one hour in stirring at room, constant temperature is static one hour again, obtains extraordinary hydrate colour printing ink.Utilize automatic filling machine with the can of extraordinary hydrate colour printing ink in general lettering pen, obtain red stationery pen.
Claims (10)
1, a kind of stationery pen, it includes writes handwriting, it is characterized in that being filled with hydrate colour printing ink in writing handwriting, and hydrate colour printing ink includes:
10～140 parts decentralized medium,
10～25 parts blowing agent,
1～5 part colouring agent,
10～65 parts aqueous binder,
Mass fraction.
2, stationery pen according to claim 1 is characterized in that decentralized medium is a water.
3, stationery pen according to claim 1 is characterized in that blowing agent is the plastic hollow ball that contains easy vaporization material, and size is at 1～100 mu m range.
4, stationery pen according to claim 3 is characterized in that its thermal plasticity high polymer with about 70～150 ℃ of softening points of hollow ball is a membranous wall, the liquid hydrocarbon compound that the internal package boiling point is 70～130 ℃.
5, stationery pen according to claim 4 is characterized in that hydrocarbon compound adopts heptane or octane.
6, stationery pen according to claim 1 is characterized in that colouring agent is pigment and dye paste.
7, stationery pen according to claim 1, it is characterized in that aqueous binder comprises polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, water-soluble poly carbamate and various polymer emulsion such as acrylate copolymer emulsion, can be wherein a kind of, also can be that two or more mixes and uses.
8, stationery pen according to claim 1 is characterized in that lettering pen comprises ball pen, pen, correction pen, marking pen or crayon.
9, a kind of preparation method of stationery pen, it is characterized in that: at room temperature in reactor, press the decentralized medium that row weight portion ratio adds 10～140 parts successively, 10～25 parts blowing agent, 1～5 part colouring agent, 10～65 parts aqueous binder mixes in room temperature to 50 ℃ scope, constant temperature leaves standstill again, obtain hydrate colour printing ink, utilize automatic filling machine with the can of hydrate colour printing ink in writing handwriting, obtain stationery pen.
10, preparation method according to claim 9 is characterized in that: decentralized medium is a water; Blowing agent is the plastic hollow ball that contains easy vaporization material, size is at 1～100 mu m range, its thermal plasticity high polymer with about 70～150 ℃ of softening points of hollow ball is a membranous wall, the liquid hydrocarbon compound that the internal package boiling point is 70～130 ℃, and hydrocarbon compound adopts heptane or octane; Colouring agent is pigment and dye paste, aqueous binder comprises polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, water-soluble poly carbamate and various polymer emulsion such as acrylate copolymer emulsion, can be wherein a kind of, also can be that two or more mixes and uses.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810120337A CN101654031A (en) | 2008-08-22 | 2008-08-22 | Stationery pen and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810120337A CN101654031A (en) | 2008-08-22 | 2008-08-22 | Stationery pen and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101654031A true CN101654031A (en) | 2010-02-24 |
Family
ID=41708568
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200810120337A Pending CN101654031A (en) | 2008-08-22 | 2008-08-22 | Stationery pen and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101654031A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102079901A (en) * | 2010-12-08 | 2011-06-01 | 宋仕良 | Method for manufacturing environmental-protection water-based pigment pen |
| CN104031466A (en) * | 2014-05-04 | 2014-09-10 | 杭州海维特化工科技有限公司 | Anion-foamed aqueous ink and preparation method thereof |
| CN108973368A (en) * | 2017-06-05 | 2018-12-11 | 深圳市力群印务有限公司 | The convex foaming antiforging printing method of heat |
-
2008
- 2008-08-22 CN CN200810120337A patent/CN101654031A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102079901A (en) * | 2010-12-08 | 2011-06-01 | 宋仕良 | Method for manufacturing environmental-protection water-based pigment pen |
| CN102079901B (en) * | 2010-12-08 | 2013-04-24 | 宋仕良 | Method for manufacturing environmental-protection water-based pigment pen |
| CN104031466A (en) * | 2014-05-04 | 2014-09-10 | 杭州海维特化工科技有限公司 | Anion-foamed aqueous ink and preparation method thereof |
| CN104031466B (en) * | 2014-05-04 | 2015-12-09 | 杭州海维特化工科技有限公司 | A kind of negative ion frothed aqueous ink and preparation method thereof |
| CN108973368A (en) * | 2017-06-05 | 2018-12-11 | 深圳市力群印务有限公司 | The convex foaming antiforging printing method of heat |
| CN108973368B (en) * | 2017-06-05 | 2020-09-29 | 深圳市力群印务有限公司 | Thermal convex foaming anti-counterfeiting printing method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4094685A (en) | Expandable polymeric coating compositions | |
| CN107674494B (en) | Environment-friendly ink for making package printing show three-dimensional effect and preparation method thereof | |
| JP7394929B2 (en) | water-based ballpoint pen | |
| CN101831217B (en) | Children colour pen ink | |
| CN106274090A (en) | A kind of aqueous environment protection concora crush resin base carbon ribbon and preparation method thereof | |
| CN112239555A (en) | Film for three-dimensional printing and preparation method thereof | |
| CN101654031A (en) | Stationery pen and preparation method thereof | |
| CN106009892A (en) | Ink composition | |
| CN104817876A (en) | Color-variable printing ink and preparation method thereof | |
| CN109423917B (en) | Microcapsule for carbonless copy paper, preparation method of microcapsule and carbonless copy paper | |
| US8822374B2 (en) | Color-changing marking implement and substrate | |
| CN102166905B (en) | Solid transparent pen refill and preparation method thereof | |
| JP2007510762A5 (en) | ||
| JP2525197B2 (en) | Colored paint composition | |
| KR20080066551A (en) | Burnout printing method which prints burnout pattern on polyester fiber brushed fabric, and burnout printing method which once-inscribes with this printout and expresses a yo-gyo pattern on polyester fiber raising fabric pile | |
| CN106085272A (en) | Heat foamable transfer membrane | |
| CN106149469A (en) | A kind of micro-spray art rice paper | |
| CN110041759A (en) | Photonic crystal ink and its printing process and printed matter | |
| CN108219174A (en) | A kind of composite material of repeatable writing blackness handwriting and preparation method thereof | |
| JP2017014342A (en) | Aqueous paint composition | |
| KR20020053788A (en) | Transfer crayon and pastel crayon comprising sublimatable disperse dye | |
| CN106800830A (en) | The white board pen ink and its colour fading liquid of a kind of easy erasing | |
| KR20170001562A (en) | Thermochromic micro particles and thermochromic ink composition, writing apparatus and smart window using the same | |
| JP2003335995A (en) | Water-based stump ink composition | |
| JP4481479B2 (en) | Method for irreversibly displaying specific temperature by color development and specific temperature display recording medium |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20100224 |