CN101683071A - Process for producing 20 percent amitraz emulsifiable concentrate - Google Patents
Process for producing 20 percent amitraz emulsifiable concentrate Download PDFInfo
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- CN101683071A CN101683071A CN200910181861A CN200910181861A CN101683071A CN 101683071 A CN101683071 A CN 101683071A CN 200910181861 A CN200910181861 A CN 200910181861A CN 200910181861 A CN200910181861 A CN 200910181861A CN 101683071 A CN101683071 A CN 101683071A
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- CN
- China
- Prior art keywords
- amitraz
- emulsifiable concentrate
- per ton
- kilograms per
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- QXAITBQSYVNQDR-ZIOPAAQOSA-N amitraz Chemical compound C=1C=C(C)C=C(C)C=1/N=C/N(C)\C=N\C1=CC=C(C)C=C1C QXAITBQSYVNQDR-ZIOPAAQOSA-N 0.000 title claims abstract description 18
- 229960002587 amitraz Drugs 0.000 title claims abstract description 17
- 239000004495 emulsifiable concentrate Substances 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 239000003814 drug Substances 0.000 claims description 5
- 239000008267 milk Substances 0.000 claims description 4
- 210000004080 milk Anatomy 0.000 claims description 4
- 235000013336 milk Nutrition 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 10
- 235000013399 edible fruits Nutrition 0.000 abstract description 8
- 239000000575 pesticide Substances 0.000 abstract description 7
- 241000607479 Yersinia pestis Species 0.000 abstract description 5
- 241000258937 Hemiptera Species 0.000 abstract description 4
- 102000010909 Monoamine Oxidase Human genes 0.000 abstract description 4
- 108010062431 Monoamine oxidase Proteins 0.000 abstract description 4
- 239000000642 acaricide Substances 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract description 2
- 231100000419 toxicity Toxicity 0.000 abstract description 2
- 230000001988 toxicity Effects 0.000 abstract description 2
- 241000238876 Acari Species 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 230000000895 acaricidal effect Effects 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 230000003389 potentiating effect Effects 0.000 abstract 1
- 230000001846 repelling effect Effects 0.000 abstract 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 11
- 239000003905 agrochemical Substances 0.000 description 9
- 235000013305 food Nutrition 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000003912 environmental pollution Methods 0.000 description 3
- 238000003958 fumigation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 230000002940 repellent Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ATHHXGZTWNVVOU-UHFFFAOYSA-N N-methylformamide Chemical compound CNC=O ATHHXGZTWNVVOU-UHFFFAOYSA-N 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- PEYUIKBAABKQKQ-AFHBHXEDSA-N (+)-sesamin Chemical compound C1=C2OCOC2=CC([C@H]2OC[C@H]3[C@@H]2CO[C@@H]3C2=CC=C3OCOC3=C2)=C1 PEYUIKBAABKQKQ-AFHBHXEDSA-N 0.000 description 1
- LNJXZKBHJZAIKQ-UHFFFAOYSA-N 1,1,1,2-tetrachloro-3-(2,3,3,3-tetrachloropropoxy)propane Chemical compound ClC(Cl)(Cl)C(Cl)COCC(Cl)C(Cl)(Cl)Cl LNJXZKBHJZAIKQ-UHFFFAOYSA-N 0.000 description 1
- NFHFNBFYZIJLKZ-UHFFFAOYSA-N Asarinin Natural products CC1(OCC2C1COC2c3ccc4OCOc4c3)c5ccc6OCOc6c5 NFHFNBFYZIJLKZ-UHFFFAOYSA-N 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- STUSTWKEFDQFFZ-UHFFFAOYSA-N Chlordimeform Chemical compound CN(C)C=NC1=CC=C(Cl)C=C1C STUSTWKEFDQFFZ-UHFFFAOYSA-N 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 244000276331 Citrus maxima Species 0.000 description 1
- 235000001759 Citrus maxima Nutrition 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- WLLGXSLBOPFWQV-UHFFFAOYSA-N MGK 264 Chemical compound C1=CC2CC1C1C2C(=O)N(CC(CC)CCCC)C1=O WLLGXSLBOPFWQV-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- UEKQGZQLUMSLNW-UHFFFAOYSA-N Propyl isome Chemical compound C1=C2C(C(=O)OCCC)C(C(=O)OCCC)C(C)CC2=CC2=C1OCO2 UEKQGZQLUMSLNW-UHFFFAOYSA-N 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 240000006413 Prunus persica var. persica Species 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- PEYUIKBAABKQKQ-UHFFFAOYSA-N epiasarinin Natural products C1=C2OCOC2=CC(C2OCC3C2COC3C2=CC=C3OCOC3=C2)=C1 PEYUIKBAABKQKQ-UHFFFAOYSA-N 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a process for producing 20 percent amitraz emulsifiable concentrate, which relates to the field of production and preparation of pesticides. A formulation of the amitraz emulsifiable concentrate comprises the following components: 202 kilograms per ton of raw amitraz, 120 kilograms per ton of emulsifying agent, 100 kilograms per ton of DMF, and 10 kilograms per ton of potentiating agent; and proper amount of dimethyl benzene is complemented. The amitraz emulsifiable concentrate is amitraz series broad spectrum acaricide, is mainly used for inhibiting the activity of monoamine oxidase, has the functions of contact toxicity, feeding resistance and repelling, and also has certain functions of internal absorption and fumigating. The amitraz emulsifiable concentrate is suitable for mites of various crops, and has better prevention effect on homoptera pests. The amitraz emulsifiable concentrate has a good pesticidal effect, avoids uninterrupted alternated use of pesticides, does not pollute the environment, and improves the quality and sanitation quality safety level of fruits.
Description
Technical field:
The present invention relates to the production preparation field of agricultural chemicals, be specifically related to a kind of production technology of 20% amitraz milk oil.
Background technology:
The evil mite is one of key insect of world today's farm-forestry crop.This only at the observed tiny organism of microscopically ability, difficulty of prevention and cure is big, their thorn phyllidium sheets, the tender tip and fruit surface juice, stay many white dots, endanger when serious, can cause a large amount of fallen leaves and shedding, weaken tree vigo(u)r, have a strong impact on output and fruit quality, cause serious biological epidemics for for many years the economic crops such as citrus, orange, shaddock, peach, mao bamboon of China, the output of fruit tree, mao bamboon is descended, quality is impaired.Because evil mite generation overlap, fertility is strong, and breeding amount is big, uses the broad-spectrum insecticide control, not only can kill and wound a large amount of natural enemies, and make it be easy to generate pesticide resistance, and need constantly be used alternatingly agricultural chemicals, cause residue of pesticide to exceed standard easily, reduce fruit quality and hygienic quality level of security, and annual medication number of times reaches 10-20 time, causes the severe contamination of atmosphere, waters, food, and the serious harm human health.
Summary of the invention:
The production technology that the purpose of this invention is to provide a kind of 20% amitraz milk oil, it is that Amitraz is the wide spectrum miticide, mainly is the activity that suppresses monoamine oxidase, have tag, food refusal, repellent action, certain interior suction, fumigation action are also arranged.Be applicable to the harmful mite of all kinds of crops, homoptera pest is also had preventive effect preferably.Good disinsection effect avoids constantly being used alternatingly agricultural chemicals, and is free from environmental pollution, improved fruit quality and hygienic quality level of security.
In order to solve the existing problem of background technology, the present invention is by the following technical solutions: its prescription consists of: the former medicine 202Kg/t of Amitraz, and emulsifier 120Kg/t, DMF100Kg/t, synergist 10Kg/t replenishes an amount of dimethylbenzene and gets final product.
The present invention is that Amitraz is the wide spectrum miticide, mainly is the activity that suppresses monoamine oxidase, have tag, food refusal, repellent action, certain interior suction, fumigation action are also arranged.Be applicable to the harmful mite of all kinds of crops, homoptera pest is also had preventive effect preferably.Good disinsection effect avoids constantly being used alternatingly agricultural chemicals, and is free from environmental pollution, improved fruit quality and hygienic quality level of security.
Embodiment:
This embodiment is by the following technical solutions: its prescription consists of: the former medicine 202Kg/t of Amitraz, and emulsifier 120Kg/t, DMF100Kg/t, synergist 10Kg/t replenishes an amount of dimethylbenzene and gets final product.
Described emulsifier is the stabilizing agent of emulsion, is a class surfactant.The effect of emulsifier is: when it is dispersed in dispersate surperficial, form film or electric double layer, can make disperse phase have electric charge, so just can stop the droplet of disperse phase to condense mutually, make the emulsion of formation more stable.For example, in the former medicine (solid-state) of agricultural chemicals or crude oil (liquid state), add a certain amount of emulsifier, again they are dissolved in the organic solvent, can be made into transparency liquid after mixing, be missible oil.
Described DMF claims N-formyl dimethylamine again, molecular formula: C3H7NO, methylformamide (DMF) is as the solvent of important chemical material and function admirable, and dimethyl formamide is the extremely wide industrial chemicals of a kind of purposes, also is a kind of excellent solvent of having many uses.Dimethyl formamide is good solvent to multiple high polymer such as polyethylene, polyvinyl chloride, polyacrylonitrile, polyamide etc., can be used for wet spinning silk, polyurethane synthetic of synthetic fibers such as polyacrylonitrile fibre; Can be used to produce galecron in the pesticide industry.
The inanimate object activity of described synergist own, but during with certain combined use of pesticides, can increase substantially the auxiliary agent of the virulence and the drug effect of agricultural chemicals.As Butacide, Asarinin, Octachlorodipropyl Ether, synergy phosphorus (SVl), propyl isome, Octacide 264 etc.The correct consumption that uses synergist can reduce agricultural chemicals is alleviated the pesticide resistance of pest, and can be alleviated the toxicity pressure of agricultural chemicals to environment.
Described dimethylbenzene structural formula is: C6H4 (CH3) 2, it is that a kind of colourless transparent liquid is water insoluble, is dissolved in ethanol and ether, and is toxic.Dimethylbenzene is according to the diverse location of two methyl on hydrogenation of six carbocyclic, can be divided into three kinds of paraxylene, ortho-xylene and meta-xylenes, is a kind of unsaturated hydro carbons organic compound.
This embodiment is that Amitraz is the wide spectrum miticide, mainly is the activity that suppresses monoamine oxidase, have tag, food refusal, repellent action, certain interior suction, fumigation action are also arranged.Be applicable to the harmful mite of all kinds of crops, homoptera pest is also had preventive effect preferably.Good disinsection effect avoids constantly being used alternatingly agricultural chemicals, and is free from environmental pollution, improved fruit quality and hygienic quality level of security.
Claims (1)
1, the production technology of 20% amitraz milk oil is characterized in that its prescription consists of: the former medicine 202Kg/t of Amitraz, and emulsifier 120Kg/t, DMF100Kg/t, synergist 10Kg/t replenishes an amount of dimethylbenzene and gets final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910181861A CN101683071A (en) | 2009-07-30 | 2009-07-30 | Process for producing 20 percent amitraz emulsifiable concentrate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910181861A CN101683071A (en) | 2009-07-30 | 2009-07-30 | Process for producing 20 percent amitraz emulsifiable concentrate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101683071A true CN101683071A (en) | 2010-03-31 |
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ID=42046642
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910181861A Pending CN101683071A (en) | 2009-07-30 | 2009-07-30 | Process for producing 20 percent amitraz emulsifiable concentrate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101683071A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102000019A (en) * | 2010-10-19 | 2011-04-06 | 郑州后羿制药有限公司 | Amitraz transdermal agent and preparation method thereof |
| CN102397307A (en) * | 2011-11-19 | 2012-04-04 | 西北农林科技大学 | A kind of compound oil-in-water type cnidium oil nanoemulsion composition and preparation method thereof |
| CN106857549A (en) * | 2015-12-11 | 2017-06-20 | 黄少安 | A kind of insecticide |
| CN109730062A (en) * | 2018-12-29 | 2019-05-10 | 江苏康巴特生物工程有限公司 | A kind of water soluble insecticide and preparation method thereof containing Amitraz |
| CN110122481A (en) * | 2019-05-13 | 2019-08-16 | 佛山市正典生物技术有限公司 | A kind of amitraz milk oil and preparation method thereof |
-
2009
- 2009-07-30 CN CN200910181861A patent/CN101683071A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102000019A (en) * | 2010-10-19 | 2011-04-06 | 郑州后羿制药有限公司 | Amitraz transdermal agent and preparation method thereof |
| CN102000019B (en) * | 2010-10-19 | 2012-07-25 | 郑州后羿制药有限公司 | Amitraz transdermal agent and preparation method thereof |
| CN102397307A (en) * | 2011-11-19 | 2012-04-04 | 西北农林科技大学 | A kind of compound oil-in-water type cnidium oil nanoemulsion composition and preparation method thereof |
| CN106857549A (en) * | 2015-12-11 | 2017-06-20 | 黄少安 | A kind of insecticide |
| CN109730062A (en) * | 2018-12-29 | 2019-05-10 | 江苏康巴特生物工程有限公司 | A kind of water soluble insecticide and preparation method thereof containing Amitraz |
| CN110122481A (en) * | 2019-05-13 | 2019-08-16 | 佛山市正典生物技术有限公司 | A kind of amitraz milk oil and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20100331 |