CN101812808A - Formula of hydrolysis-resistant waterborne polyurethane artificial leather and method for manufacturing same - Google Patents
Formula of hydrolysis-resistant waterborne polyurethane artificial leather and method for manufacturing same Download PDFInfo
- Publication number
- CN101812808A CN101812808A CN200910266160A CN200910266160A CN101812808A CN 101812808 A CN101812808 A CN 101812808A CN 200910266160 A CN200910266160 A CN 200910266160A CN 200910266160 A CN200910266160 A CN 200910266160A CN 101812808 A CN101812808 A CN 101812808A
- Authority
- CN
- China
- Prior art keywords
- hydrolysis
- waterborne polyurethane
- formula
- resin solution
- artificial leather
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004814 polyurethane Substances 0.000 title claims abstract description 17
- 230000007062 hydrolysis Effects 0.000 title claims abstract description 14
- 238000006460 hydrolysis reaction Methods 0.000 title claims abstract description 14
- 239000002649 leather substitute Substances 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims abstract description 10
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 33
- 239000011347 resin Substances 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 20
- 238000001035 drying Methods 0.000 claims abstract description 5
- 238000001125 extrusion Methods 0.000 claims abstract description 4
- 239000002344 surface layer Substances 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000004744 fabric Substances 0.000 claims description 9
- 238000005096 rolling process Methods 0.000 claims description 9
- 229920005749 polyurethane resin Polymers 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 7
- 239000013530 defoamer Substances 0.000 claims description 6
- 238000012856 packing Methods 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 239000003607 modifier Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229920001410 Microfiber Polymers 0.000 abstract 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 238000004804 winding Methods 0.000 abstract 2
- 238000004806 packaging method and process Methods 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000003086 colorant Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 206010011376 Crepitations Diseases 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention discloses a formula of hydrolysis-resistant waterborne polyurethane artificial leather and a method for manufacturing the same and relates to waterborne polyurethane adhered with ultrafine fiber base. The method comprises the following steps of: preparing surface material resin solution and bottom material resin solution according to a formula proportion by adopting hydrolysis-resistant and cold-resistant waterborne PU resin, standing the solution for defoaming; opening release paper, coating surface material resin on the release paper, sending the release paper to an oven for drying, and winding; and opening the release paper coated with the surface layer, coating bottom material resin on the release paper, sending the release paper to the oven again until the release paper is semi-dried, rapidly adhering the ultrafine fiber base with the release paper, performing roll extrusion and drying, and finally winding and packaging.
Description
Technical field:
The present invention relates to extremely manufacture method of a kind of hydrolysis-resistant waterborne artificial leather, especially relate to the aqueous polyurethane of a kind of superfine fibre base that fits.
Background technology:
The artificial leather that utilizes polyurethane resin to make can be used in every field such as furniture, clothes, case and bag, footwear, automobiles.Because traditional polyurethane resin polarity is very strong, need strong solvent it could be dissolved with convenient construction, so environment is caused very big harm.Solvent commonly used is DMF, is a kind of poisonous chemicals, grievous injury people's liver organ, and this constitutes a serious threat for the healthy of workman of tannery.
Summary of the invention:
The purpose of this invention is to provide a kind of formula of hydrolysis-resistant waterborne polyurethane artificial leather and manufacture method thereof, it has hydrolysis and cold-resistant characteristics, can reach-20 ℃ of following 80,000 crackless effects, and rerum natura can reach the standard identical with common synthetic leather.
In order to solve the existing problem of background technology, the present invention is by the following technical solutions: adopt the cold-resistant water-based PU resin of a kind of hydrolysis, prepare fabric resin solution and bed material resin solution, standing and defoaming by formula rate.After release liners opened, at first fabric resin is coated on the release liners, sends into oven for drying, rolling then.Once more the release liners of coated surface layer is opened, with bed material resin-coated on, send into baking oven once more, till half-dried, rapidly will super fine base and its applying, and carry out roll extrusion, oven dry, last rolling, packing.
The prescription of described fabric resin solution is: 100 parts of waterborne polyurethane resins, deionized water 0-50 part, thickener 0.1-2 part, levelling agent 0.1-2 part, fluorine modifier 0.1-2 part, color 1-10 part, defoamer 0-5 part; The prescription of described bed material resin solution is: 100 parts of waterborne polyurethane resins, deionized water 0-50 part, thickener 0.1-2 part, color 1-10 part, defoamer 0-5 part.
Preparation process: 1, configuration lining resin solution and bed material resin solution; 2, select the burnishing surface of fabricbase as being coated with charge level; 3, select the release liners of suitable decorative pattern; 4, extension is coated with water-based PU lining on release liners; 5, oven dry lining, temperature is about 125 ℃; 6, hang primer; 7, the oven dry bed material is fitted to half-dried; 8, oven dry artificial leather, rolling, packing.
The present invention has following beneficial effect: soak in 10%NaOH after 24 hours, the surface is flawless; Cold tolerance is good.80,000 folding flawlesses under-20 ℃ of conditions; The adhesion strength height.Peel strength can reach 100N/2.5cm.
The specific embodiment:
This specific embodiment is by the following technical solutions: adopt the cold-resistant water-based PU resin of a kind of hydrolysis, prepare fabric resin solution and bed material resin solution, standing and defoaming by formula rate.After release liners opened, at first fabric resin is coated on the release liners, sends into oven for drying, rolling then.Once more the release liners of coated surface layer is opened, with bed material resin-coated on, send into baking oven once more, till half-dried, rapidly will super fine base and its applying, and carry out roll extrusion, oven dry, last rolling, packing.
The prescription of described fabric resin solution is: 100 parts of waterborne polyurethane resins, 10 parts of deionized waters, 1.2 parts of thickeners, 0.5 part of levelling agent, 0.2 part of fluorine modifier, 5 parts of colors, 0.5 part of defoamer; The prescription of described bed material resin solution is: 100 parts of waterborne polyurethane resins, 20 parts of deionized waters, 2 parts of thickeners, 5 parts of colors, 0.5 part of defoamer.
Preparation process: 1, configuration lining resin solution and bed material resin solution; 2, select the burnishing surface of fabricbase as being coated with charge level; 3, select the release liners of suitable decorative pattern; 4, extension is coated with water-based PU lining on release liners; 5, oven dry lining, temperature is about 125 ℃; 6, hang primer; 7, the oven dry bed material is fitted to half-dried; 8, oven dry artificial leather, rolling, packing.
This specific embodiment is soaked 24 hours in 10%NaOH after, the surface is flawless; Cold tolerance is good.80,000 folding flawlesses under-20 ℃ of conditions; The adhesion strength height.Peel strength can reach 100N/2.5cm.
The specific embodiment two: be that with the specific embodiment one difference deionized water in the prescription of described bed material resin solution is that 20 parts, thickener are 1.5 parts; Other compositions are all identical with the specific embodiment one with prescription.
Claims (4)
1. formula of hydrolysis-resistant waterborne polyurethane artificial leather and manufacture method thereof is characterized in that it adopts the cold-resistant water-based PU resin of a kind of hydrolysis, prepare fabric resin solution and bed material resin solution, standing and defoaming by formula rate.After release liners opened, at first fabric resin is coated on the release liners, sends into oven for drying, rolling then.Once more the release liners of coated surface layer is opened, with bed material resin-coated on, send into baking oven once more, till half-dried, rapidly will super fine base and its applying, and carry out roll extrusion, oven dry, last rolling, packing.
2. a kind of formula of hydrolysis-resistant waterborne polyurethane artificial leather according to claim 1 and manufacture method thereof is characterized in that the prescription of described fabric resin solution is: 100 parts of waterborne polyurethane resins, deionized water 0-50 part, thickener 0.1-2 part, levelling agent 0.1-2 part, fluorine modifier 0.1-2 part, color 1-10 part, defoamer 0-5 part;
3. a kind of formula of hydrolysis-resistant waterborne polyurethane artificial leather according to claim 1 and manufacture method thereof is characterized in that the prescription of described bed material resin solution is: 100 parts of waterborne polyurethane resins, deionized water 0-50 part, thickener 0.1-2 part, color 1-10 part, defoamer 0-5 part.
4. a kind of formula of hydrolysis-resistant waterborne polyurethane artificial leather according to claim 1 and manufacture method thereof is characterized in that its preparation process is: 1, configuration lining resin solution and bed material resin solution; 2, select the burnishing surface of fabricbase as being coated with charge level; 3, select the release liners of suitable decorative pattern; 4, extension is coated with water-based PU lining on release liners; 5, oven dry lining, temperature is about 125 ℃; 6, hang primer; 7, the oven dry bed material is fitted to half-dried; 8, oven dry artificial leather, rolling, packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910266160A CN101812808A (en) | 2009-12-30 | 2009-12-30 | Formula of hydrolysis-resistant waterborne polyurethane artificial leather and method for manufacturing same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910266160A CN101812808A (en) | 2009-12-30 | 2009-12-30 | Formula of hydrolysis-resistant waterborne polyurethane artificial leather and method for manufacturing same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101812808A true CN101812808A (en) | 2010-08-25 |
Family
ID=42620166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910266160A Pending CN101812808A (en) | 2009-12-30 | 2009-12-30 | Formula of hydrolysis-resistant waterborne polyurethane artificial leather and method for manufacturing same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101812808A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102493212A (en) * | 2011-11-11 | 2012-06-13 | 万桦（常州）新材料科技有限公司 | Method for preparing polyester super-fiber |
| CN102731747A (en) * | 2012-07-16 | 2012-10-17 | 青岛新宇田化工有限公司 | Dyeable dry-method artificial leather polyurethane resin, producing method and method for producing artificial leather by polyurethane resin |
| CN103046395A (en) * | 2013-01-10 | 2013-04-17 | 东莞市宏庆皮革制品有限公司 | A kind of preparation method of water-based peeling skin |
| CN103074778A (en) * | 2013-01-10 | 2013-05-01 | 东莞市宏庆皮革制品有限公司 | A kind of preparation method of water-based leather |
| CN103572614A (en) * | 2012-07-24 | 2014-02-12 | 昆山协润人造皮有限公司 | Preparation method of handball leather |
| CN104480726A (en) * | 2014-12-02 | 2015-04-01 | 福建华阳超纤有限公司 | A kind of preparation method of solvent-free automobile microfiber leather |
| CN105442342A (en) * | 2015-11-23 | 2016-03-30 | 东华理工大学 | Plant antibacterial and odor-resistant type polyurethane artificial leather and preparation method thereof |
| CN110042675A (en) * | 2019-04-08 | 2019-07-23 | 温州大学 | A kind of woven fabric bass aqueous post-processing approach entirely |
| CN110714338A (en) * | 2019-09-27 | 2020-01-21 | 浙江大东方椅业股份有限公司 | Preparation method of anti-aging PU fabric |
-
2009
- 2009-12-30 CN CN200910266160A patent/CN101812808A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102493212A (en) * | 2011-11-11 | 2012-06-13 | 万桦（常州）新材料科技有限公司 | Method for preparing polyester super-fiber |
| CN102731747B (en) * | 2012-07-16 | 2015-04-22 | 青岛新宇田化工有限公司 | Dyeable dry-method artificial leather polyurethane resin, producing method and method for producing artificial leather by polyurethane resin |
| CN102731747A (en) * | 2012-07-16 | 2012-10-17 | 青岛新宇田化工有限公司 | Dyeable dry-method artificial leather polyurethane resin, producing method and method for producing artificial leather by polyurethane resin |
| CN103572614B (en) * | 2012-07-24 | 2015-07-22 | 昆山协润人造皮有限公司 | Preparation method of handball leather |
| CN103572614A (en) * | 2012-07-24 | 2014-02-12 | 昆山协润人造皮有限公司 | Preparation method of handball leather |
| CN103074778A (en) * | 2013-01-10 | 2013-05-01 | 东莞市宏庆皮革制品有限公司 | A kind of preparation method of water-based leather |
| CN103046395A (en) * | 2013-01-10 | 2013-04-17 | 东莞市宏庆皮革制品有限公司 | A kind of preparation method of water-based peeling skin |
| CN104480726A (en) * | 2014-12-02 | 2015-04-01 | 福建华阳超纤有限公司 | A kind of preparation method of solvent-free automobile microfiber leather |
| CN104480726B (en) * | 2014-12-02 | 2016-07-06 | 福建华阳超纤有限公司 | A kind of preparation method of solvent-free automobile microfiber leather |
| CN105442342A (en) * | 2015-11-23 | 2016-03-30 | 东华理工大学 | Plant antibacterial and odor-resistant type polyurethane artificial leather and preparation method thereof |
| CN110042675A (en) * | 2019-04-08 | 2019-07-23 | 温州大学 | A kind of woven fabric bass aqueous post-processing approach entirely |
| CN110042675B (en) * | 2019-04-08 | 2021-05-18 | 温州大学 | Microfiber bass full-aqueous post-treatment method |
| CN110714338A (en) * | 2019-09-27 | 2020-01-21 | 浙江大东方椅业股份有限公司 | Preparation method of anti-aging PU fabric |
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| PB01 | Publication | ||
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Open date: 20100825 |