CN101955729B - Polysiloxane topcoat for wind power generation equipment - Google Patents
Polysiloxane topcoat for wind power generation equipment Download PDFInfo
- Publication number
- CN101955729B CN101955729B CN 201010298598 CN201010298598A CN101955729B CN 101955729 B CN101955729 B CN 101955729B CN 201010298598 CN201010298598 CN 201010298598 CN 201010298598 A CN201010298598 A CN 201010298598A CN 101955729 B CN101955729 B CN 101955729B
- Authority
- CN
- China
- Prior art keywords
- percent
- component
- finish paint
- topcoat
- paint according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- -1 Polysiloxane Polymers 0.000 title claims abstract description 43
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 29
- 238000010248 power generation Methods 0.000 title abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 229910000077 silane Inorganic materials 0.000 claims abstract description 13
- 239000000945 filler Substances 0.000 claims abstract description 11
- 239000013008 thixotropic agent Substances 0.000 claims abstract description 6
- 239000002270 dispersing agent Substances 0.000 claims abstract description 5
- 238000009736 wetting Methods 0.000 claims abstract description 5
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 4
- 239000003973 paint Substances 0.000 claims description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 7
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 6
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000006096 absorbing agent Substances 0.000 claims description 5
- 230000035939 shock Effects 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 claims description 2
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- WLDHEUZGFKACJH-UHFFFAOYSA-K amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1N=NC1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-UHFFFAOYSA-K 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 239000010431 corundum Substances 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- UJRDRFZCRQNLJM-UHFFFAOYSA-N methyl 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=CC=CC3=N2)=C1O UJRDRFZCRQNLJM-UHFFFAOYSA-N 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- XQAABEDPVQWFPN-UHFFFAOYSA-N octyl 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OCCCCCCCC)=CC(N2N=C3C=CC=CC3=N2)=C1O XQAABEDPVQWFPN-UHFFFAOYSA-N 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 125000005401 siloxanyl group Chemical group 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 229910002808 Si–O–Si Inorganic materials 0.000 claims 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract description 6
- 239000003960 organic solvent Substances 0.000 abstract description 6
- 238000010276 construction Methods 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 239000012948 isocyanate Substances 0.000 abstract description 3
- 150000002513 isocyanates Chemical class 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- 231100000053 low toxicity Toxicity 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract 1
- 239000000080 wetting agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 6
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000012467 final product Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000004576 sand Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 238000007761 roller coating Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- YFVKHKCZBSGZPE-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-2-(propylamino)propan-1-one Chemical compound CCCNC(C)C(=O)C1=CC=C2OCOC2=C1 YFVKHKCZBSGZPE-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003260 anti-sepsis Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical group COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a polysiloxane topcoat for wind power generation equipment. A component A of the topcoat comprises the following compositions in percentage by mass: 50 to 70 percent of acrylic modified polysiloxane resin, 0.1 to 1 percent of wetting and dispersing agent, 1 to 3 percent of thixotropic agent, 10 to 20 percent of lightfast pigment and filler, 5 to 15 percent of wear-resistant filler, 5 to 15 percent of impact-resistant filler, 0.5 to 2 percent of ultraviolet absorber, 0.1 to 2 percent of leveling agent and 1 to 5 percent of low-toxicity organic solvent; the component B is amino alkoxy silane; and the polysiloxane topcoat is prepared in a mass ratio of the acrylic resin to the amino alkoxy silane of 8-12:1. The topcoat has the advantages of outstanding weather resistance, excellent scratch, impact, wear, low temperature and corrosion resistance, hydrophobicity and low surface energy, has the comprehensive performance not lower than that of the conventional fluorocarbon topcoat for the wind power generation equipment, can form a film with the maximum thickness of 200mu m at one time, can shorten the construction period, has high solid content, is not cured by isocyanate, and is favorable for protecting environment.
Description
Technical field
The present invention relates to a kind of protective system technology, particularly a kind of polysiloxane topcoat for wind power generation equipment.
Background technology
Wind-power electricity generation has become the energy field that the our times various countries competitively develop as a kind of reproducible clean energy.Wind power generating set is positioned at desert, mountain area, seashore and the sea away from the signs of human habitation mostly; need to bear the erosion of the natural causes such as various high wind sand, rainwater, frost, ultraviolet radiation and wave; therefore; in order to ensure wind power plant longer work-ing life, must carry out corrosionproof protection to it.The wind power plant maintenance difficulty is relatively large, for reducing maintenance cost, usually selects the coating of long-effective protection in addition, time to first overhaul is prolonged as far as possible.Adopt at present maximum coatings system systems be coated with in rich zinc primary coat/epoxy micaceous iron/the acroleic acid polyurethane face is coated with, but only has 5～10 years working life, surpasses the working life acrylic polyurethane finish paint and just can be destroyed, barrier propterty descends until disappear.
For guaranteeing the long-effective corrosion effect, high weather-proof finish paint arises at the historic moment.Publication number is take fluorocarbon resin as base-material in the Chinese patent file of CN 101195724A, diisocyanate trimer is that solidifying agent prepares surface insulation varnish paint for wind power generation, publication number is take fluorocarbon resin as base-material in the Chinese patent file of CN 101538434A, HDI biuret and HDI tripolymer are that solidifying agent prepares the wind power plant antisepsis finishing paint, the fluorocarbon coating of the two invention is uses the isocyanic ester normal temperature cured type, and weather resistance is far above acroleic acid polyurethane coating.Yet the fluidization of current ambient temperature curing fluorocarbon resin raw material needs a large amount of strong solvent supports, and the VOC content of fluorine carbon finishing paint can't reduce all the time, in addition need be with poisonous cured with isocyanates, and these do not conform to the environmental protection attribute that wind energy itself has.Therefore, a kind of wind power equipment that is conducive to environment protection and excellent combination property of exploitation is particularly important with finish paint.
Summary of the invention
Technical problem to be solved by this invention provides a kind of polysiloxane topcoat for wind power generation equipment.
For the purpose that realizes solving the problems of the technologies described above, a kind of wind power equipment polysiloxane topcoat of the present invention is that colored paint component, second component are that two kinds of components of solidifying agent component consist of by the first component; Wherein first component quality percentage composition is:
Component B is aminoalkoxy silane.
According to acroleic acid modified polysiloxane resin and aminoalkoxy silane mass ratio 8-12: 1 principle is carried out the proportioning of the first and second components, can use after mixing.
Described wetting dispersing agent is the composition of one or more arbitrary proportions among EFKA4061, EFKA4050, the EFKA4060.
Described thixotropic agent be aerosil, polyethylene wax, polyamide wax, bentonite any.
Described sun-proof color stuffing is the composition of one or more arbitrary proportions in Rutile type Titanium Dioxide, everbright fast red, phthalocyanine blue, organic yellow, carbon black, the process white.
Described wear resistant filler is the composition of one or more arbitrary proportions in silica powder, silicon carbide, the corundum.
Described shock-resistant filler is the composition of one or more arbitrary proportions in mica powder, the talcum powder.
Described UV light absorber is any among TINUVIN 384, TINUVIN 1130, the TINUVIN 328.
Described flow agent is any among BYK-354, BYK-355, the BYK-356.
Described hypotoxicity organic solvent is the composition of 1-Methoxy-2-propyl acetate, one or both arbitrary proportions of N-BUTYL ACETATE.
Described acroleic acid modified polysiloxane resin, by Hydroxylated acrylic resin and siloxanyl monomers polyreaction and get, theoretical Si-O-Si mass content is 10-15% after the modification.
Described second component is aminoalkoxy silane, include but not limited to γ-aminopropyl triethoxysilane, γ-aminopropyltrimethoxysilane, N-β (aminoethyl) γ-aminopropyl triethoxysilane and N-β (aminoethyl) γ-aminopropyltrimethoxysilane, can use separately, also being used in combination of arbitrary proportion.
This coating selection acroleic acid modified polysiloxane resin, aminoalkoxy silane, various color stuffing, auxiliary agent and hypotoxicity organic solvent etc. are by reasonably prescription preparation.Polysiloxane is because its special valence bond structure (Si-O-Si), have the advantages such as high-low temperature resistant, weathering resistance, chemical resistance, wear resistance, hydrophobic nature and low surface energy, but exist intensity low, with the deficiency such as base material bad adhesion, with acrylic resin it is carried out modification and can realize maximizing favourable factors and minimizing unfavourable ones.Be base-material by selecting with the equal acroleic acid modified polysiloxane resin of fluorocarbon resin over-all properties, select UV light absorber that its weathering resistance is strengthened, rational allocation color stuffing kind and ratio are to obtain the paint film over-all properties not second to fluorine carbon finishing paint; Select low viscosity propylene acid modified polysiloxane resin, thixotropic agent and hypotoxicity organic solvent; the rational allocation solidifying agent; realize that height contains and the thick film application admittedly; this polysiloxane topcoat for wind power generation equipment is conducive to environment protection than fluorine carbon finishing paint, and can greatly shorten construction period and improve coating efficiency.
These technical schemes can make up mutually or combination, thereby reach better technique effect.For example, the various selection components of coating can be interosculated.
A kind of wind power equipment of the present invention is as follows with the preparation technology of polysiloxane topcoat:
1, first component (colored paint component) preparation technology is as follows:
1) get aequum vinylformic acid polyorganosiloxane resin and add in the dispersion tank, wetting dispersing agent, the thixotropic agent of aequum added wherein, high speed dispersion 15～20 minutes obtains mixture I;
2) under the stirring at low speed, progressively the surplus stocks such as quantitative sun-proof color stuffing, wear resistant filler, shock-resistant filler, UV light absorber, flow agent are added mixture I, high speed dispersion 10～15 minutes, disperse complete, enter sand mill and be ground to fineness≤30 μ m, with obtaining the first component behind the hypotoxicity organic solvent adjusting viscosity, packing gets final product in proportion.
If the combination of the multiple aminoalkoxy silane of 2 solidifying agent mixes in proportion the solidifying agent of aequum and namely gets the second component; If single aminoalkoxy silane of planting then need not to mix; Then packing gets final product in proportion.
3, first component and component B are mixed by formula rate, slaking approximately after 5-10 minute, namely gets wind power equipment acroleic acid modified polysiloxane finish paint, and this coating can adopt brushing, roller coating and spraying application.For guaranteeing the application outward appearance, recommend to use spraying application, the thickest 200 μ m that reach of paint film.
Wind power equipment polysiloxane topcoat of the present invention, technical indicator and detected result see the following form 1:
Table 1
By adopting technique scheme, the present invention has following beneficial effect:
1, polysiloxane topcoat for wind power generation equipment weather resistance of the present invention is outstanding, anti-ly scrape, shock resistance, wear-resisting, low temperature resistant and excellent anti-corrosion performance, have advantages of that hydrophobic nature and surface energy are low, over-all properties is not second to present wind power equipment fluorine carbon finishing paint;
2, one-pass film-forming reaches as high as 200 μ m, can greatly shorten construction period and improve operating efficiency;
3, solid content is high, without cured with isocyanates, is conducive to environment protection, possesses significantly " efficiently, economy, environmental protection " advantage than fluorine carbon finishing paint.
Embodiment
A kind of wind power equipment of the present invention is specified with embodiment with polysiloxane topcoat, but be not limited to this specific embodiment.Proportioning among the embodiment is calculated according to the mass fraction.
Embodiment 1:
Second: γ-aminopropyl triethoxysilane
First: second=100: 6
Wherein, acroleic acid modified polysiloxane resin, the Si-O-Si theoretical content is 10-15%.
The preparation method is:
1, first component:
1) get aequum vinylformic acid polyorganosiloxane resin and add in the dispersion tank, wetting dispersing agent, the thixotropic agent of aequum added wherein, high speed dispersion 20 minutes obtains mixture I;
2) under the stirring at low speed, the quantitative sun-proof color stuffing that progressively will select, wear resistant filler, shock-resistant filler, UV light absorber, flow agent add mixture I, high speed dispersion 15 minutes, disperse complete, enter sand mill and be ground to fineness≤30 μ m, with obtaining the first component behind the organic solvent adjusting viscosity, packing gets final product in proportion.
If the combination of the multiple aminoalkoxy silane of 2 solidifying agent mixes in proportion the solidifying agent of aequum and namely gets the second component; If solidifying agent is single aminoalkoxy silane of planting, then need not to mix; Then packing gets final product in proportion.
3, first component and component B are mixed by formula rate, slaking approximately after 5-10 minute, namely gets wind power equipment acroleic acid modified polysiloxane finish paint, and this coating can adopt brushing, roller coating and spraying application.For guaranteeing the application outward appearance, recommend to use spraying application.
Prepared coating property meets the technical specification of table 1, and specific targets see Table 2.
Embodiment 2:
Second: γ-aminopropyltrimethoxysilane
First: second=100: 6.5
Wherein, acroleic acid modified polysiloxane resin, the Si-O-Si theoretical content is 10-15%.
The preparation method is with embodiment 1.
Prepared coating property meets the technical specification of table 1, and specific targets see Table 2.
Embodiment 3:
Second: N-β (aminoethyl) γ-aminopropyl triethoxysilane
First: second=100: 6.3
Wherein, acroleic acid modified polysiloxane resin, the Si-O-Si theoretical content is 10-15%.
The preparation method is with embodiment 1.
Prepared coating property meets the technical specification of table 1, and specific targets see Table 2.
Embodiment 4:
Second: N-β (aminoethyl) γ-aminopropyltrimethoxysilane
First: second=100: 5.2
Wherein, acroleic acid modified polysiloxane resin, the Si-O-Si theoretical content is 10-15%.
The preparation method is with embodiment 1.
Prepared coating property meets the technical specification of table 1, and specific targets see Table 2.
Embodiment 5:
Second: γ-aminopropyltrimethoxysilane
First: second=100: 5.1
Wherein, acroleic acid modified polysiloxane resin, the Si-O-Si theoretical content is 10-15%.
The preparation method is with embodiment 1.
Prepared coating property meets the technical specification of table 1, and specific targets see Table 2.
Table 2 embodiment 1-5 coating property
Remarks: testing method and standard such as table 1.
Claims (9)
1. wind power equipment polysiloxane topcoat, it is characterized in that: described finish paint is that colored paint component, second component are that two kinds of components of solidifying agent component consist of by the first component, and wherein first component quality percentage composition is:
Described acroleic acid modified polysiloxane resin, by light Hydroxylated acrylic resin and siloxanyl monomers polyreaction and get, theoretical Si-O-Si content is 10-15%;
Component B is aminoalkoxy silane;
According to acroleic acid modified polysiloxane resin and aminoalkoxy silane mass ratio 8-12: 1 carries out the proportioning of the first and second components, can use after mixing.
2. described finish paint according to claim 1, it is characterized in that: described wetting dispersing agent is the composition of one or more arbitrary proportions among EFKA4061, EFKA4050, the EFKA4060.
3. described finish paint according to claim 1, it is characterized in that: described thixotropic agent is any one in aerosil, polyethylene wax, polyamide wax, the organobentonite.
4. described finish paint according to claim 1, it is characterized in that: described sun-proof color stuffing is the composition of one or more arbitrary proportions in Rutile type Titanium Dioxide, everbright fast red, phthalocyanine blue, organic yellow, carbon black, the process white.
5. described finish paint according to claim 1, it is characterized in that: described wear resistant filler is the composition of one or more arbitrary proportions in silica powder, silicon carbide, the corundum.
6. described finish paint according to claim 1, it is characterized in that: described shock-resistant filler is the composition of one or more arbitrary proportions in mica powder, the talcum powder.
7. described finish paint according to claim 1, it is characterized in that: described UV light absorber is any one among TINUVIN384, TINUVIN 1130, the TINUVIN 328.
8. described finish paint according to claim 1, it is characterized in that: described flow agent is any one among BYK-354, BYK-355, the BYK-356.
9. described finish paint according to claim 1 is characterized in that: described aminoalkoxy silane is the composition of any or arbitrary proportion of γ-aminopropyl triethoxysilane, γ-aminopropyltrimethoxysilane, N-β (aminoethyl) γ-aminopropyl triethoxysilane and N-β (aminoethyl) γ-aminopropyltrimethoxysilane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010298598 CN101955729B (en) | 2010-10-08 | 2010-10-08 | Polysiloxane topcoat for wind power generation equipment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010298598 CN101955729B (en) | 2010-10-08 | 2010-10-08 | Polysiloxane topcoat for wind power generation equipment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101955729A CN101955729A (en) | 2011-01-26 |
| CN101955729B true CN101955729B (en) | 2013-03-27 |
Family
ID=43483331
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010298598 Expired - Fee Related CN101955729B (en) | 2010-10-08 | 2010-10-08 | Polysiloxane topcoat for wind power generation equipment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101955729B (en) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181209A (en) * | 2011-05-25 | 2011-09-14 | 淄博应强化工科技有限公司 | Protective coating for wind wheel blade of wind generating set and preparation method thereof |
| CN102816521B (en) * | 2011-06-10 | 2015-05-13 | 中国石油天然气集团公司 | Long-term corrosion resistance coating for ocean platform steel structure in atmospheric region and manufacture method thereof |
| US8747950B2 (en) * | 2011-12-02 | 2014-06-10 | Ppg Industries Ohio, Inc. | Method of mitigating ice build-up on a substrate |
| CN102604494B (en) * | 2012-02-27 | 2014-04-16 | 江苏科技大学 | Coating for wind power generation blades |
| CN102796446B (en) * | 2012-08-10 | 2014-12-17 | 中山大桥化工企业集团中山智亨实业发展有限公司 | Anti-sandstorm special blade paint |
| CN103788865B (en) * | 2012-11-02 | 2018-05-11 | 中冶建筑研究总院有限公司 | The polysiloxane coating materials and its application method of a kind of toughening modifying |
| CN103073980B (en) * | 2012-12-19 | 2015-08-05 | 洛阳双瑞防腐工程技术有限公司 | There is the no-solvent type elastic metallic paint preparation method of high-heating radiation |
| CN103725129A (en) * | 2013-12-12 | 2014-04-16 | 江苏普兰纳涂料有限公司 | High weather-proof finishing coat for megawatt wind power blade |
| CN103897109A (en) * | 2014-04-14 | 2014-07-02 | 湖北一桥涂料科技有限公司 | Acrylic modified polysiloxane resin and paint containing same |
| CN105482574B (en) * | 2014-10-13 | 2017-08-25 | 立邦工业涂料(上海)有限公司 | A kind of fluorine carbon self-cleaning coating and preparation method |
| CN104946129A (en) * | 2015-07-24 | 2015-09-30 | 上海海悦涂料有限公司 | Polysiloxane heat-reflective topcoat and preparation method thereof |
| CN106280986A (en) * | 2016-08-29 | 2017-01-04 | 山东帝高漆业有限公司 | Double-component fire resistant paint and preparation method |
| CN106675399A (en) * | 2016-12-07 | 2017-05-17 | 陕西宝塔山油漆股份有限公司 | Moisture curable crylic acid modified polysiloxane coating and preparation method thereof |
| CN106675133B (en) * | 2016-12-22 | 2019-09-03 | 中昊北方涂料工业研究设计院有限公司 | A kind of high-hardness acrylate-modified polysiloxane resin and coating based on it |
| CN108676491A (en) * | 2018-05-04 | 2018-10-19 | 砺剑防务技术集团有限公司 | For the anticorrosive paint of metal base, preparation method and metallic substrate surface processing method |
| CN111471362B (en) * | 2020-04-29 | 2021-11-09 | 胡克海 | Ultraviolet ray filters base plate and disinfection stick |
| CN116239811A (en) * | 2023-03-03 | 2023-06-09 | 长沙荣思达科技有限公司 | Outdoor high weather-resistant functional film and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101348611A (en) * | 2008-09-05 | 2009-01-21 | 中国海洋石油总公司 | Acroleic acid modified polysiloxane resin and coating thereof |
| CN101348679A (en) * | 2008-08-28 | 2009-01-21 | 上海大通高科技材料有限责任公司 | Anti-pasting anti-covering coating and preparation thereof |
-
2010
- 2010-10-08 CN CN 201010298598 patent/CN101955729B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101348679A (en) * | 2008-08-28 | 2009-01-21 | 上海大通高科技材料有限责任公司 | Anti-pasting anti-covering coating and preparation thereof |
| CN101348611A (en) * | 2008-09-05 | 2009-01-21 | 中国海洋石油总公司 | Acroleic acid modified polysiloxane resin and coating thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101955729A (en) | 2011-01-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101955729B (en) | Polysiloxane topcoat for wind power generation equipment | |
| CN103725159B (en) | A kind of high-adaptability protective system and preparation method thereof | |
| CN102925041B (en) | Terrace coating and preparation method thereof | |
| CN103146302B (en) | A kind of coating for clear-water concrete protection and construction technology thereof | |
| CN101613564A (en) | A kind of protective coating for wind power generator blade and preparation method thereof | |
| CN101195724B (en) | Surface insulation varnish paint for wind power generation and method for producing the same | |
| CN102559024A (en) | Aqueous polyurethane heat reflection coating and application thereof | |
| CN102127363A (en) | Finish paint for wind driven generator and preparation method thereof | |
| CN107298930A (en) | A kind of preparation of organic silicon polyurea self stratifying coating and application method | |
| CN104893523A (en) | Ultra-low VOC air-drying poly-aspartic paint for engineering machinery | |
| CN102391771A (en) | Thick paste quick-drying type weather-resistant and wear-resistant coating for wind turbine blades and preparation method thereof | |
| CN104098996A (en) | Nano-composite PU (polyurethane) aircraft coating and preparation method thereof | |
| CN103242739A (en) | Steel structure protective paint | |
| CN106381013A (en) | Heavy anti-corrosion coating and application thereof | |
| CN107868567A (en) | Epoxy dust primer, paint form a complete set of thing and application | |
| CN102190942B (en) | Epoxy priming paint used for moisture resisting megawatt wind-power blades and preparation method thereof | |
| CN102863892B (en) | Water-base polyurethane coating for fan blades and preparation method thereof | |
| CN102344739A (en) | Epoxy glass flake heavy-duty coating and preparation method thereof | |
| CN102002318A (en) | Scaly zinc-based inorganic zinc silicate heavy anti-corrosion coating and preparation method thereof | |
| CN103820020A (en) | Antiskid and antiseptic polyurea coating as well as preparation method and application method thereof | |
| CN109439158A (en) | A kind of weather-proof anticorrosive paint of solvent-free polyureas and preparation method | |
| CN103483527B (en) | A kind of quick-drying weathering protective topcoat for polyurea coating and preparation method thereof | |
| CN101343498B (en) | Paint for high-class woodenware artwork and preparation thereof | |
| CN101440254B (en) | Anticorrosion paint for decorating inner and external walls of power station transformer, and preparation thereof | |
| CN110964388A (en) | Polyurea modified anti-pollution coating and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: LUOYANG SHUANGRUI CORROSION PREVENTION ENGINEERING Free format text: FORMER NAME: LUOYANG QIWEI ANTI-CORROSION ENGINEERING MATERIAL CO., LTD. |
|
| CP03 | Change of name, title or address |
Address after: 471822 Henan city of Luoyang province Xin'an County Luo new Industrial Park No. 3 Jia BIOLUX Patentee after: LUOYANG SHUANGRUI SPECIAL PRODUCT Corp. Address before: 471039 No. 21, Xiyuan Road, Luoyang, Henan Patentee before: Luoyang Qiwei Corrosion Protection Engineering Material Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130327 |