CN101978236A - Heat exchanger - Google Patents
Heat exchanger Download PDFInfo
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- CN101978236A CN101978236A CN2009801097035A CN200980109703A CN101978236A CN 101978236 A CN101978236 A CN 101978236A CN 2009801097035 A CN2009801097035 A CN 2009801097035A CN 200980109703 A CN200980109703 A CN 200980109703A CN 101978236 A CN101978236 A CN 101978236A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
- F28F1/24—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely
- F28F1/32—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely the means having portions engaging further tubular elements
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D1/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
- F28D1/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
- F28D1/04—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
- F28D1/047—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being bent, e.g. in a serpentine or zig-zag
- F28D1/0477—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being bent, e.g. in a serpentine or zig-zag the conduits being bent in a serpentine or zig-zag
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- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
Abstract
Description
技术领域technical field
本发明涉及热交换器,尤其涉及适用于使用低压制冷剂的制冷剂回路的热交换器。The present invention relates to heat exchangers, and more particularly to heat exchangers suitable for use in refrigerant circuits using low-pressure refrigerants.
背景技术Background technique
从保护地球环境的观点考虑,有关用于空调装置的制冷剂回路的制冷剂,谋求地球温暖化系数低、不破坏臭氧层的制冷剂,实际上,也开发有与其要求相对应的制冷剂(例如,参照专利文献1)。From the viewpoint of protecting the global environment, refrigerants used in the refrigerant circuits of air-conditioning devices are seeking refrigerants with a low global warming coefficient and no ozone layer damage. In fact, refrigerants corresponding to the requirements have been developed (such as , refer to Patent Document 1).
专利文献1公开的制冷剂(C3HmFn)具有理论上的COP比较高且地球温暖化系数低的特性。但是,本制冷剂的沸点比较高,为所谓的低压制冷剂,因此有可能因热交换器的压力损失而增大压缩机的输入,造成运转效率下降。The refrigerant (C 3 H m F n ) disclosed in
专利文献1:(日本)特开平4-110388号公报Patent Document 1: (Japanese) Unexamined Patent Publication No. 4-110388
发明内容Contents of the invention
本发明的课题在于提供一种热交换器,其适用于使用由分子式用C3HmFn(其中,m=1~5、n=1~5,且m+n=6)表示且分子结构中具有一个双键的制冷剂形成的单一制冷剂或含有所述单一制冷剂的混合制冷剂的制冷剂回路。The object of the present invention is to provide a heat exchanger suitable for use with molecular formulas represented by C 3 H m F n (where m=1 to 5, n=1 to 5, and m+n=6) A refrigerant circuit in which a single refrigerant or a mixed refrigerant containing the single refrigerant is formed by a refrigerant having one double bond in its structure.
第一发明的热交换器,其制冷剂回路使用由分子式用C3HmFn(其中,m=1~5、n=1~5,且m+n=6)表示且分子结构中具有一个双键的有机化合物形成的单一制冷剂或含有所述单一制冷剂的混合制冷剂,具备:多个传热管和多个板状的散热片。传热管形成用于使制冷剂流通的一个或多个制冷剂路径。板状的散热片以隔开规定的间隔重叠的方式排列,多个传热管大致垂直地贯穿其中。铅直方向上相邻的传热管彼此的中心间距离S和传热管的外径D的关系为:2.5<S/D<3.5,制冷剂路径的长度L和传热管的外径D的关系为:0.28×D1.17<L<1.10×D1.17。In the heat exchanger of the first invention, the refrigerant circuit is represented by the molecular formula C 3 H m F n (where m=1 to 5, n=1 to 5, and m+n=6) and the molecular structure has A single refrigerant composed of an organic compound with a double bond or a mixed refrigerant containing the single refrigerant includes a plurality of heat transfer tubes and a plurality of plate-shaped fins. The heat transfer tubes form one or more refrigerant paths for circulating the refrigerant. The plate-shaped fins are arranged to overlap at predetermined intervals, and a plurality of heat transfer tubes penetrates substantially vertically therethrough. The relationship between the distance S between the centers of adjacent heat transfer tubes in the vertical direction and the outer diameter D of the heat transfer tube is: 2.5<S/D<3.5, the length L of the refrigerant path and the outer diameter D of the heat transfer tube The relationship is: 0.28×D 1.17 <L<1.10×D 1.17 .
由于所述制冷剂为低压制冷剂,所以容易受传热管内的压力损失的影响。将该热交换器中的制冷剂路径长度L、传热管的外径D及传热管的中心间距离S的关系设成所述关系式,由此能够将传热管内的制冷剂的压力损失的影响抑制到最小限。Since the refrigerant is a low-pressure refrigerant, it is easily affected by pressure loss in the heat transfer tubes. The relationship between the refrigerant path length L in the heat exchanger, the outer diameter D of the heat transfer tube, and the center-to-center distance S of the heat transfer tube is set as the above relational expression, whereby the pressure of the refrigerant in the heat transfer tube can be expressed as The impact of losses is kept to a minimum.
第二发明的热交换器在第一发明的热交换器的基础上,所述制冷剂为由2,3,3,3-四氟-1-丙烯形成的单一制冷剂或含有所述单一制冷剂的混合制冷剂。In the heat exchanger of the second invention based on the heat exchanger of the first invention, the refrigerant is a single refrigerant formed from 2,3,3,3-tetrafluoro-1-propene or contains the single refrigerant refrigerant mixture.
由2,3,3,3-四氟-1-丙烯形成的单一制冷剂或含有所述单一制冷剂的混合制冷剂为低压制冷剂,因此,容易受传热管内的压力损失的影响,但是,将该热交换器中的制冷剂路径长度L、传热管的外径D及传热管的中心间距离S的关系设成所述关系式,由此能够将传热管内的制冷剂的压力损失的影响抑制到最小限。A single refrigerant formed from 2,3,3,3-tetrafluoro-1-propene or a mixed refrigerant containing the single refrigerant is a low-pressure refrigerant and therefore is easily affected by pressure loss in the heat transfer tube, but , the relationship between the refrigerant path length L in the heat exchanger, the outer diameter D of the heat transfer tube, and the center-to-center distance S of the heat transfer tube is set as the relational expression, thereby the refrigerant in the heat transfer tube can be The influence of pressure loss is suppressed to a minimum.
第三发明的热交换器在第一发明的热交换器的基础上,所述制冷剂为含有2,3,3,3-四氟-1-丙烯和二氟甲烷的混合制冷剂。In the heat exchanger of the third invention, in the heat exchanger of the first invention, the refrigerant is a mixed refrigerant containing 2,3,3,3-tetrafluoro-1-propene and difluoromethane.
含有2,3,3,3-四氟-1-丙烯和二氟甲烷的混合制冷剂为低压制冷剂,因此,容易受传热管内的压力损失的影响,但是,将该热交换器中的制冷剂路径长度L、传热管的外径D及传热管的中心间距离S的关系设成所述关系式,由此能够将传热管内的制冷剂的压力损失的影响抑制到最小限。The mixed refrigerant containing 2,3,3,3-tetrafluoro-1-propene and difluoromethane is a low-pressure refrigerant, so it is easily affected by the pressure loss in the heat transfer tube, however, the The relationship between the refrigerant path length L, the outer diameter D of the heat transfer tubes, and the center-to-center distance S of the heat transfer tubes is set to the above relational expression, whereby the influence of the pressure loss of the refrigerant in the heat transfer tubes can be suppressed to a minimum. .
第四方面发明的热交换器在第一发明的热交换器的基础上,所述制冷剂为含有2,3,3,3-四氟-1-丙烯和五氟乙烷的混合制冷剂。In the heat exchanger of the fourth invention, based on the heat exchanger of the first invention, the refrigerant is a mixed refrigerant containing 2,3,3,3-tetrafluoro-1-propene and pentafluoroethane.
含有2,3,3,3-四氟-1-丙烯和五氟乙烷的混合制冷剂为低压制冷剂,因此,容易受传热管内的压力损失的影响,但是,将该热交换器中的制冷剂路径长度L、传热管的外径D及传热管的中心间距离S的关系设成所述关系式,由此能够将传热管内的制冷剂的压力损失的影响抑制到最小限。The mixed refrigerant containing 2,3,3,3-tetrafluoro-1-propene and pentafluoroethane is a low-pressure refrigerant, so it is easily affected by the pressure loss in the heat transfer tube, however, in this heat exchanger The relationship between the refrigerant path length L of the heat transfer tube, the outer diameter D of the heat transfer tube, and the center-to-center distance S of the heat transfer tube is set to the above relational expression, whereby the influence of the pressure loss of the refrigerant in the heat transfer tube can be suppressed to a minimum. limit.
将第一发明、第二发明、第三发明、第四发明的任一种的热交换器中的制冷剂路径长度L、传热管的外径D及传热管的中心间距离S的关系设成所述关系式,由此能够将传热管内的制冷剂的压力损失的影响抑制到最小限。In the heat exchanger of any one of the first invention, the second invention, the third invention, and the fourth invention, the relationship between the refrigerant path length L, the outer diameter D of the heat transfer tube, and the center-to-center distance S of the heat transfer tube By using the above relational expression, the influence of the pressure loss of the refrigerant in the heat transfer tube can be suppressed to the minimum.
附图说明Description of drawings
图1是空调装置的制冷剂回路;Fig. 1 is the refrigerant circuit of the air conditioner;
图2是本发明的实施方式的热交换器的正面图;2 is a front view of a heat exchanger according to an embodiment of the present invention;
图3是沿图2的A-A线切断时的热交换器的剖面图;Fig. 3 is a sectional view of the heat exchanger when cut along the A-A line of Fig. 2;
图4是表示送风机动力为一定且D=7mm时的S/D和热交换器性能的关系的曲线;Fig. 4 is a curve showing the relationship between S/D and heat exchanger performance when the blower power is constant and D=7mm;
图5(a)是将图2的热交换器的制冷剂路径做成一个时的热交换器的概念图,(b)是将图2的热交换器的制冷剂路径做成两个时的热交换器的概念图,(c)是将图2的热交换器的制冷剂路径从中途形成两个时的热交换器的概念图;Fig. 5(a) is a conceptual diagram of the heat exchanger when the refrigerant path of the heat exchanger in Fig. 2 is made into one, and (b) is a conceptual diagram when the refrigerant path of the heat exchanger in Fig. 2 is made into two A conceptual diagram of the heat exchanger, (c) is a conceptual diagram of the heat exchanger when the refrigerant path of the heat exchanger in Fig. 2 is formed into two halfway;
图6是表示制冷剂路径长度和压力损失的关系的曲线图;Fig. 6 is a graph showing the relationship between refrigerant path length and pressure loss;
图7是表示D=7mm时的制冷剂路径长度和制冷剂侧热传递率及压力损失的关系的曲线图;Fig. 7 is a graph showing the relationship between the refrigerant path length and the refrigerant side heat transfer rate and pressure loss when D = 7mm;
图8是表示D=7mm时的制冷剂路径长度和热交换器性能的曲线图;Fig. 8 is a graph showing refrigerant path length and heat exchanger performance when D = 7mm;
图9是表示制冷剂路径长度L相对于传热管外径D的曲线图;Fig. 9 is a graph showing the refrigerant path length L versus the outer diameter D of the heat transfer tube;
图10是在含有本实施方式的热交换器的制冷剂回路中使用的制冷剂的成分表。Fig. 10 is a composition table of refrigerants used in the refrigerant circuit including the heat exchanger according to the present embodiment.
符号说明Symbol Description
4室外热交换器4 outdoor heat exchangers
6室内热交换器6 indoor heat exchanger
10热交换器10 heat exchangers
11板状散热片11 plate heat sink
12传热管12 heat transfer tubes
具体实施方式Detailed ways
<制冷剂回路><refrigerant circuit>
图1是空调装置的制冷剂回路。空调装置1具有通过制冷剂配管将压缩机2、四路切换阀3、室外热交换器4、膨胀阀5及室内热交换器6连结起来的冷冻回路。图1中,实线和虚线的箭头表示制冷剂的流动方向,空调装置1通过四路切换阀3切换制冷剂的流动方向,由此能够切换暖气运转和冷气运转。在冷气运转时,室外热交换器4变成冷凝器,室内热交换器6变成蒸发器。另外,在暖气运转时,室外热交换器4变成蒸发器,室内热交换器6变成冷凝器。Figure 1 is a refrigerant circuit of an air conditioner. The
在制冷剂回路中,填充有由HFO-1234yf(2,3,3,3-四氟-1-丙烯)和HFC-32(二氟甲烷)两种有机化合物形成的混合制冷剂。本实施方式中使用的制冷剂为由78.2质量%的HFO-1234yf和21.8质量%的HFC-32形成的混合制冷剂。另外,HFO-1234yf的化学式用CF3CFCH2表示,HFC-32的化学式用CH2F2表示。In the refrigerant circuit, a mixed refrigerant composed of two organic compounds, HFO-1234yf (2,3,3,3-tetrafluoro-1-propene) and HFC-32 (difluoromethane), is filled. The refrigerant used in this embodiment is a mixed refrigerant composed of 78.2% by mass of HFO-1234yf and 21.8% by mass of HFC-32. In addition, the chemical formula of HFO-1234yf is represented by CF 3 CFCH 2 , and the chemical formula of HFC-32 is represented by CH 2 F 2 .
<热交换器的结构><Structure of heat exchanger>
图2是本发明的实施方式的热交换器的正面图。图2中,热交换器10为交叉翅片型的热交换器,是图1所示的室外热交换器4及室内热交换器6的基本模型。热交换器10具备散热片11和传热管12。散热片11为薄的铝制的平板,在一枚散热片11上形成有多个穿通孔。传热管12由插入散热片11的穿通孔的直管12a、连结相邻的直管12a的端部彼此的第一U字管12b及第二U字管12c构成。直管12a和第一U字管12b形成为一体,第二U字管12c在直管12a插入散热片11的穿通孔后,通过焊接等连结于直管12a的端部。Fig. 2 is a front view of the heat exchanger according to the embodiment of the present invention. In FIG. 2 , the
(传热管的管外径及中心间距离和热交换器性能的关系)(The relationship between the outer diameter of the tube and the distance between the centers of the heat transfer tube and the performance of the heat exchanger)
图3是沿图2的A-A线切断时的热交换器的剖面图。图3中,直管12a的管外径为D,铅直方向上相邻的传热管12的中心间距离为S。通常,中心间距离S越小,散热片效率越高,但通风阻力增大。反之,中心间距离S越大,散热片效率越低,但通风阻力也减小。另外,所谓散热片效率是指从散热片的全部传热面散发的实际散热量与假定散热片的全部传热面与制冷剂的温度相等时散发的散热量之比。Fig. 3 is a sectional view of the heat exchanger taken along line A-A of Fig. 2 . In FIG. 3 , the outer diameter of the
另外,中心间距离S为一定时,管外径D越大,散热片效率越高,通风阻力增大。反之,管外径D越小,散热片效率越低,通风阻力也减小。即,在管外径D和中心间距离S之间存在用于提高热交换器性能的最佳条件。In addition, when the distance S between centers is constant, the larger the outer diameter D of the tube, the higher the efficiency of the heat sink and the higher the ventilation resistance. Conversely, the smaller the outer diameter D of the tube, the lower the efficiency of the heat sink and the lower the ventilation resistance. That is, there is an optimum condition for improving the performance of the heat exchanger between the tube outer diameter D and the distance S between centers.
图4是表示送风机动力为一定且D=7mm时的S/D和热交换器性能的关系的曲线图。图4中,热交换器性能表示在2.5<S/D<3.5范围高的值,在其范围之外,热交换器性能下降。即,图4表示在外径D和中心间距离S的关系为2.5<S/D<3.5时,使用HFO-1234yf和HFC-32的混合制冷剂的制冷剂回路的室外热交换器4及室内热交换器6得到最佳的热交换器性能。Fig. 4 is a graph showing the relationship between S/D and heat exchanger performance when the blower power is constant and D = 7mm. In FIG. 4 , the heat exchanger performance shows a high value in the range of 2.5<S/D<3.5, and outside this range, the heat exchanger performance deteriorates. That is, FIG. 4 shows that when the relationship between the outer diameter D and the center-to-center distance S is 2.5<S/D<3.5, the
(热交换器的制冷剂路径长度和热交换器性能的关系)(The relationship between the refrigerant path length of the heat exchanger and the performance of the heat exchanger)
图5(a)是将图2的热交换器的制冷剂路径做成一个时的热交换器的概念图,(b)是将图2的热交换器的制冷剂路径做成两个时的热交换器的概念图,(c)是将图2的热交换器的制冷剂路径从中途分成两个时的热交换器的概念图。Fig. 5(a) is a conceptual diagram of the heat exchanger when the refrigerant path of the heat exchanger in Fig. 2 is made into one, and (b) is a conceptual diagram when the refrigerant path of the heat exchanger in Fig. 2 is made into two A conceptual diagram of the heat exchanger, (c) is a conceptual diagram of the heat exchanger when the refrigerant path of the heat exchanger in FIG. 2 is divided into two halfway.
在图5(a)中,由于热交换器10具有一个制冷剂路径,所以称作一路径热交换器101。假如热交换器10具有六个传热管,一个传热管12的长度为H时,一路径热交换器101的制冷剂路径长度大约为6H。In FIG. 5( a ), since the
图5(b)中,热交换器10通过分流器90形成两个制冷剂路径,因此称作二路径热交换器102。二路径热交换器102的制冷剂路径长度大约为一路径热交换器101的一半,约相当于3H。In FIG. 5( b ), the
图5(c)中,将热交换器10的一个制冷剂路径从中途经由分流器90分成为两个制冷剂路径,因此称作一-二路径热交换器103。一-二路径热交换器103由于存在公共的制冷剂路径和独立的制冷剂路径,所以不能简单地计算制冷剂路径长度。于是,求一-二路径热交换器103实际的压力损失,假设为一个制冷剂路径,则求相当于多长的制冷剂路径的压力损失,其值就为制冷剂路径长度。In FIG. 5( c ), one refrigerant path of the
图6是制冷剂路径长度和压力损失的关系的曲线图。例如,图5(c)的一-二路径热交换器103的制冷剂的压力损失为p时,由曲线可知,制冷剂路径长度为3.6H。这样,由一个基本的热交换器10就能够制造制冷剂路径长度不同的、一路径热交换器101、二路径热交换器10及一-二路径热交换器103。换言之,制冷剂路径长度通过变更制冷剂路径的数量而能够设定。Fig. 6 is a graph showing the relationship between refrigerant path length and pressure loss. For example, when the pressure loss of the refrigerant in the one-two path heat exchanger 103 in FIG. 5( c ) is p, it can be seen from the curve that the length of the refrigerant path is 3.6H. In this way, the one-
接着,对制冷剂路径长度和热交换器性能的关系进行说明。即,热交换器性能Q利用热还流率K、传热面积A、及空气和制冷剂的温度差dT,用Q=KA×dT的式子表示。热还流率K为空气侧热阻力和制冷剂侧热阻力的合成阻力的倒数。合成阻力1/K利用空气侧热传递率ha、制冷剂侧热传递率hr、及内外传热面积比R,用1/K=1/ha+R/hr的式子表示。Next, the relationship between the refrigerant path length and the performance of the heat exchanger will be described. That is, the heat exchanger performance Q is expressed by the formula Q=KA×dT using the heat return rate K, the heat transfer area A, and the temperature difference dT between the air and the refrigerant. The heat return rate K is the reciprocal of the combined resistance of the air-side thermal resistance and the refrigerant-side thermal resistance. The combined
减少制冷剂路径的数量、增长制冷剂路径长度时,流过一个制冷剂路径的制冷剂量增加,制冷剂侧热传递率hr提高,但由于压力损失的增加,热交换器入口的蒸发温度升高,因此空气和制冷剂的温度差dT减小,热交换器性能Q下降。When the number of refrigerant paths is reduced and the length of the refrigerant path is increased, the amount of refrigerant flowing through one refrigerant path increases, and the heat transfer rate hr on the refrigerant side increases, but due to the increase in pressure loss, the evaporation temperature at the inlet of the heat exchanger increases , so the temperature difference dT between the air and the refrigerant decreases, and the performance Q of the heat exchanger decreases.
另一方面,在增加制冷剂路径的数量、缩短制冷剂路径长度时,压力损失减小,热交换器入口的蒸发温度下降,空气和制冷剂的温度差dT增大,流过一个制冷剂路径的制冷剂量减少,因此制冷剂侧热传递率hr下降,热交换器性能Q下降。On the other hand, when the number of refrigerant paths is increased and the length of the refrigerant path is shortened, the pressure loss decreases, the evaporation temperature at the inlet of the heat exchanger decreases, and the temperature difference dT between the air and the refrigerant increases, flowing through one refrigerant path The amount of refrigerant is reduced, so the heat transfer rate hr on the refrigerant side decreases, and the performance Q of the heat exchanger decreases.
即,使用HFO-1234yf和HFC-32的混合制冷剂的制冷剂回路的室外热交换器4及室内热交换器6不能用与目前制冷剂(例如,410A制冷剂)对应的室外热交换器及室内热交换器代替,而为了能够实现最佳的热交换器性能,必须在明确了传热管外径D和制冷剂路径长度L的关系的基础上进行设计。That is, the
图7是表示D=7mm时的制冷剂路径长度和制冷剂侧热传递率及压力损失的关系的曲线图,图8是表示D=7mm时的制冷剂路径长度和热交换器性能的曲线图。如图7所示,制冷剂路径长度越短,压力损失越少,但制冷剂侧热传递率也下降。其结果是,如图8所示,由于制冷剂侧热传递率的下降,热交换器性能也下降。另一方面,当逐渐增长制冷剂路径长度时,热交换器性能碰到峰值后下降。即,图8表示存在适合于传热管外径的制冷剂路径长度。Fig. 7 is a graph showing the relationship between the refrigerant path length and the refrigerant-side heat transfer rate and pressure loss when D = 7 mm, and Fig. 8 is a graph showing the refrigerant path length and heat exchanger performance when D = 7 mm . As shown in Figure 7, the shorter the refrigerant path length, the smaller the pressure loss, but the refrigerant side heat transfer rate also decreases. As a result, as shown in FIG. 8 , due to a decrease in the heat transfer rate on the refrigerant side, the performance of the heat exchanger also decreases. On the other hand, when the refrigerant path length is gradually increased, the performance of the heat exchanger reaches a peak and then drops. That is, FIG. 8 shows that there is a refrigerant path length suitable for the outer diameter of the heat transfer tube.
图9是表示制冷剂路径长度L相对于传热管外径D的曲线图。图9中,四角形的黑点表示相对于传热管外径的最佳制冷剂路径长度,相对于传热管外径的制冷剂路径长度的下限值位于y=0.28x1.17的直线上,上限值位于y=1.10x1.17的直线上。即,表示使用HFO-1234yf和HFC-32的混合制冷剂的制冷剂回路的室外热交换器4及室内热交换器6的制冷剂路径长度L设定在0.28×D1.17<L<1.10×D1.17的范围,由此能够得到最佳的热交换器性能。FIG. 9 is a graph showing the refrigerant path length L versus the outer diameter D of the heat transfer tube. In Fig. 9, the square black dot represents the optimal refrigerant path length relative to the outer diameter of the heat transfer tube, and the lower limit value of the refrigerant path length relative to the outer diameter of the heat transfer tube is located on the straight line y=0.28x 1.17 , The upper limit lies on the straight line y= 1.10x1.17 . That is, the refrigerant path length L of the
<制冷剂回路中使用的制冷剂><Refrigerant used in the refrigerant circuit>
(单一制冷剂)(single refrigerant)
在上述实施方式中,作为制冷剂使用由HFO-1234yf和HFC-32两种有机化合物形成的混合制冷剂,但并不仅限于此。例如,图10是在含有本实施方式的热交换器的制冷剂回路中使用的制冷剂的成分表,也可以使用如HFO-1234yf的分子式用C3HmFn(其中,m=1~5、n=1~5,且m+n=6)表示且分子结构中具有一个双键的有机化合物形成的单一制冷剂。In the above-mentioned embodiments, the mixed refrigerant composed of two organic compounds, HFO-1234yf and HFC-32, is used as the refrigerant, but the present invention is not limited thereto. For example, Fig. 10 is a composition table of refrigerant used in the refrigerant circuit including the heat exchanger of this embodiment, and it is also possible to use C 3 H m F n for the molecular formula such as HFO-1234yf (where m=1 to 5. n=1-5, and m+n=6) represents a single refrigerant formed by an organic compound having a double bond in its molecular structure.
具体地说,可以举出图10的上段所示的HFO-1225ye(1,2,3,3,3-五氟丙烯、化学式:CF3-CF=CHF)、HFO-1234ze(1,3,3,3四氟-1-丙烯、化学式:CF3-CH=CHF)、HFO-1234ye(1,2,3,3四氟-1-丙烯、化学式:CHF2-CF=CHF)、HFO-1234zf(3,3,3三氟-1-丙烯、化学式:CF3-CH=CH2)、1,2,2三氟-1-丙烯(化学式:CH3-CF=CF2)、2-四氟-1-丙烯(化学式:CH3-CF=CH2)等。另外,为了说明上的方便,将这些单一制冷剂作为基本制冷剂加以区分。Specifically, HFO-1225ye (1,2,3,3,3-pentafluoropropene, chemical formula: CF 3 -CF=CHF), HFO-1234ze (1,3, 3,3 tetrafluoro-1-propene, chemical formula: CF 3 -CH=CHF), HFO-1234ye (1,2,3,3 tetrafluoro-1-propene, chemical formula: CHF 2 -CF=CHF), HFO- 1234zf (3,3,3 trifluoro-1-propene, chemical formula: CF 3 -CH=CH 2 ), 1,2,2 trifluoro-1-propene (chemical formula: CH 3 -CF=CF 2 ), 2- Tetrafluoro-1-propene (chemical formula: CH 3 -CF=CH 2 ), etc. In addition, these single refrigerants are classified as basic refrigerants for convenience of description.
(混合制冷剂)(mixed refrigerant)
另外,也可以使用由上述基本制冷剂的任一种和图10所示的第二成分的任一种形成的混合制冷剂。例如为与22质量%的HFC-32的混合制冷剂。另外,只要HFC-32的比例为6质量%以上30质量%以下即可,优选为13质量%以上23质量%以下,更优选为21质量%以上23质量%以下。In addition, a mixed refrigerant composed of any of the above-mentioned basic refrigerants and any of the second components shown in FIG. 10 may also be used. For example, it is a mixed refrigerant with 22% by mass of HFC-32. In addition, the ratio of HFC-32 should just be 6 mass % - 30 mass %, Preferably it is 13 mass % - 23 mass %, More preferably, it is 21 mass % - 23 mass %.
另外,也可以是上述基本制冷剂的任一种和10质量%以上的HFC-125(五氟乙烷、CF3-CHF2)的混合制冷剂,另外,HFC-125的比例优选为10质量%以上20质量%以下。In addition, it may be a mixed refrigerant of any one of the above-mentioned basic refrigerants and HFC-125 (pentafluoroethane, CF 3 -CHF 2 ) at 10% by mass or more, and the ratio of HFC-125 is preferably 10% by mass % to 20% by mass.
另外,也可以是上述基本制冷剂的任一种和HFC-134(1,1,2,2-四氟乙烷、CHF2-CHF2)、HFC-134a(1,1,2,2-四氟乙烷、CH2F-CF3)、HFC-143a(1,1,1-三氟乙烷、CH3CF3)、HFC-152a(1,1-二氟乙烷、CHF2-CF3)、HFC-161(氟代乙烷、CH3-CH2F)、HFC-227ea(1,1,1,2,3,3,3-七氟丙烷、CF3-CHF-CF3)、HFC-236ea(1,1,1,2,3,3-六氟丙烷、CF3-CHF-CHF2)、HFC-236fa(1,1,1,3,3,3-六氟乙烷、CF3-CH2-CF3)及HFC-365mfc(1,1,1,3,3-五氟丁烷、CF3-CH2CF2-CH3)的任一种混合制冷剂。In addition, any of the above-mentioned basic refrigerants and HFC-134 (1,1,2,2-tetrafluoroethane, CHF 2 -CHF 2 ), HFC-134a (1,1,2,2- Tetrafluoroethane, CH 2 F-CF 3 ), HFC-143a (1,1,1-trifluoroethane, CH 3 CF 3 ), HFC-152a (1,1-difluoroethane, CHF 2 - CF 3 ), HFC-161 (fluoroethane, CH 3 -CH 2 F), HFC-227ea (1,1,1,2,3,3,3-heptafluoropropane, CF 3 -CHF-CF 3 ), HFC-236ea (1,1,1,2,3,3-hexafluoropropane, CF 3 -CHF-CHF 2 ), HFC-236fa (1,1,1,3,3,3-hexafluoroethane, Any mixed refrigerant of CF 3 -CH 2 -CF 3 ) and HFC-365mfc (1,1,1,3,3-pentafluorobutane, CF 3 -CH 2 CF 2 -CH 3 ).
另外,上述的混合制冷剂为上述基本制冷剂的任一种和HFC系制冷剂的混合制冷剂,但并不仅限于此,也可以是上述基本制冷剂的任一种和碳化氢系制冷剂的混合制冷剂。In addition, the above-mentioned mixed refrigerant is a mixed refrigerant of any one of the above-mentioned basic refrigerants and an HFC-based refrigerant, but is not limited thereto, and may be a mixture of any of the above-mentioned basic refrigerants and a hydrocarbon-based refrigerant. Mixed refrigerant.
具体地说,为上述基本制冷剂的任一种和甲烷(CH4)、乙烷(CH3-CH3)、丙烷(CH3-CH2-CH3)、丙烯(CH3-CH=CH3)、丁烷(CH3-CH2-CH2-CH3)、异丁烷(CH3-CH(CH3)-CH3)、戊烷(CH3-CH2-CH2-CH3)、2-甲基丁烷、及环戊烷(cyclo-C5H10)的任一种的混合制冷剂。Specifically, any of the above-mentioned basic refrigerants and methane (CH 4 ), ethane (CH 3 -CH 3 ), propane (CH 3 -CH 2 -CH 3 ), propylene (CH 3 -CH=CH 3 ), butane (CH 3 -CH 2 -CH 2 -CH 3 ), isobutane (CH 3 -CH(CH 3 )-CH 3 ), pentane (CH 3 -CH 2 -CH 2 -CH 3 ), 2-methylbutane, and a mixed refrigerant of any one of cyclopentane (cyclo-C5H 10 ).
另外,也可以是上述基本制冷剂的任一种和二甲醚(CH3-O-CH3)、二(三氟甲基)硫醚(CH3-S-CH3)、二氧化碳(CO2)及氦(He)的任一种的混合物。In addition, any of the above-mentioned basic refrigerants and dimethyl ether (CH 3 -O-CH 3 ), bis(trifluoromethyl)sulfide (CH 3 -S-CH 3 ), carbon dioxide (CO 2 ) and any mixture of helium (He).
另外,在上述实施方式中,作为制冷剂使用由HFO-1234yf和HFC-32两种制冷剂形成的混合制冷剂,但也可以使用上述基本制冷剂的任一种和上述第二成分的任两种形成的混合制冷剂。例如,优选由52质量%的HFO-1234yf、23质量%的HFC-32、25质量%的HFC-125形成的混合制冷剂。In addition, in the above-mentioned embodiment, a mixed refrigerant composed of two kinds of refrigerants HFO-1234yf and HFC-32 is used as the refrigerant, but any one of the above-mentioned basic refrigerants and any two of the above-mentioned second components may be used. A mixed refrigerant formed. For example, a mixed refrigerant composed of 52% by mass of HFO-1234yf, 23% by mass of HFC-32, and 25% by mass of HFC-125 is preferable.
<特征><feature>
使用热交换器10,作为使用由分子式用C3HmFn(其中,m=1~5、n=1~5,且m+n=6)表示且分子结构中具有一个双键的有机化合物形成的单一制冷剂或含有上述单冷剂的混合制冷剂的制冷剂回路的热交换器。热交换器10具备多个传热管12和多个板状的散热片11。传热管12形成用于使制冷剂流通的一个或多个制冷剂路径。板状的散热片11配置成与空气的流动方向大致平行且多个传热管大致垂直地穿通其中。铅直方向上相邻的传热管彼此的中心间距离S和传热管的外径D的关系为2.5<S/D<3.5,制冷剂回路的长度L和传热管的外径D的关系为0.28×D1.17<L<1.10×D1.17。其结果是,能够将传热管内的制冷剂的压力损失的影响抑制到最小限。另外,所使用的具体的制冷剂为由2,3,3,3-四氟-1-丙烯形成的单一制冷剂或含有上述单一制冷剂的混合制冷剂,或者含有2,3,3,3-四氟-1-丙烯和二氟甲烷的混合制冷剂,或者含有2,3,3,3-四氟-1-丙烯和五氟乙烷的混合制冷剂。The
产业上的利用可能性Industrial Utilization Possibility
如上所述,本发明应用于使用低压制冷剂的制冷剂回路的热交换器。As described above, the present invention is applied to a heat exchanger of a refrigerant circuit using a low-pressure refrigerant.
Claims (4)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008-070356 | 2008-03-18 | ||
| JP2008070356A JP2009222360A (en) | 2008-03-18 | 2008-03-18 | Heat exchanger |
| PCT/JP2009/054999 WO2009116478A1 (en) | 2008-03-18 | 2009-03-16 | Heat exchanger |
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| CN101978236A true CN101978236A (en) | 2011-02-16 |
| CN101978236B CN101978236B (en) | 2012-09-05 |
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| US (1) | US20110011126A1 (en) |
| EP (1) | EP2267392A4 (en) |
| JP (1) | JP2009222360A (en) |
| CN (1) | CN101978236B (en) |
| BR (1) | BRPI0908721A2 (en) |
| WO (1) | WO2009116478A1 (en) |
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| JP5176624B2 (en) * | 2008-03-18 | 2013-04-03 | ダイキン工業株式会社 | Refrigeration equipment |
| KR101966488B1 (en) | 2010-01-27 | 2019-04-05 | 다이킨 고교 가부시키가이샤 | Refrigerant composition comprising difluoromethane(hfc32) and 2,3,3,3-tetrafluoropropene(hfo1234yf) |
| JP2013134024A (en) * | 2011-12-27 | 2013-07-08 | Panasonic Corp | Refrigeration cycle device |
| WO2013160951A1 (en) * | 2012-04-26 | 2013-10-31 | 三菱電機株式会社 | Heat exchanger, method for manufacturing heat exchanger, and air conditioner |
| ES2905258T3 (en) * | 2012-09-04 | 2022-04-07 | Daikin Ind Ltd | Method for filling a mixed refrigerant containing 2,3,3,3-tetrafluoropropene |
| GB2542312A (en) * | 2014-07-18 | 2017-03-15 | Mitsubishi Electric Corp | Refrigeration cycle device |
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| JP2604722B2 (en) * | 1986-06-23 | 1997-04-30 | 松下冷機株式会社 | Flying ube type heat exchanger |
| JPH04110388A (en) * | 1990-08-31 | 1992-04-10 | Daikin Ind Ltd | heat transfer fluid |
| JPH08247576A (en) * | 1995-03-14 | 1996-09-27 | Toshiba Corp | Air conditioner |
| TW340180B (en) * | 1995-09-14 | 1998-09-11 | Sanyo Electric Co | Heat exchanger having corrugated fins and air conditioner having the same |
| JP2001091183A (en) * | 1999-07-21 | 2001-04-06 | Matsushita Refrig Co Ltd | Fin tube type heat exchanger |
| JP2001304783A (en) * | 2000-04-14 | 2001-10-31 | Daikin Ind Ltd | Outdoor heat exchanger, indoor heat exchanger, and air conditioner |
| JP2002147981A (en) * | 2000-11-07 | 2002-05-22 | Kobe Steel Ltd | Heat exchanger tube and finned tube heat exchanger |
| US6460372B1 (en) * | 2001-05-04 | 2002-10-08 | Carrier Corporation | Evaporator for medium temperature refrigerated merchandiser |
| DE10296722B4 (en) * | 2002-02-28 | 2012-07-26 | Lg Electronics Inc. | Heat exchanger for a cooling unit |
| JP2003343942A (en) * | 2002-05-23 | 2003-12-03 | Denso Corp | Evaporator |
| US20040089839A1 (en) * | 2002-10-25 | 2004-05-13 | Honeywell International, Inc. | Fluorinated alkene refrigerant compositions |
| US20080121837A1 (en) * | 2003-10-27 | 2008-05-29 | Honeywell International, Inc. | Compositions containing fluorine substituted olefins |
| US9085504B2 (en) * | 2002-10-25 | 2015-07-21 | Honeywell International Inc. | Solvent compositions containing fluorine substituted olefins and methods and systems using same |
| JP2006503961A (en) * | 2002-10-25 | 2006-02-02 | ハネウェル・インターナショナル・インコーポレーテッド | Compositions based on pentafluoropropene |
| US9005467B2 (en) * | 2003-10-27 | 2015-04-14 | Honeywell International Inc. | Methods of replacing heat transfer fluids |
| US9796848B2 (en) * | 2002-10-25 | 2017-10-24 | Honeywell International Inc. | Foaming agents and compositions containing fluorine substituted olefins and methods of foaming |
| US7279451B2 (en) * | 2002-10-25 | 2007-10-09 | Honeywell International Inc. | Compositions containing fluorine substituted olefins |
| AU2004263669B2 (en) * | 2003-08-06 | 2008-07-31 | Brembana & Rolle S.P.A. | Expanded metal |
| JP2006317010A (en) * | 2004-08-09 | 2006-11-24 | Kiyoshi Yanagimachi | Heat exchanger block |
| US8420706B2 (en) * | 2005-06-24 | 2013-04-16 | Honeywell International Inc. | Foaming agents, foamable compositions, foams and articles containing halogen substituted olefins, and methods of making same |
| TWI657070B (en) * | 2005-06-24 | 2019-04-21 | 美商哈尼威爾國際公司 | Compositions containing fluorine substituted olefins and uses thereof |
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| US7740057B2 (en) * | 2007-02-09 | 2010-06-22 | Xi'an Jiaotong University | Single shell-pass or multiple shell-pass shell-and-tube heat exchanger with helical baffles |
-
2008
- 2008-03-18 JP JP2008070356A patent/JP2009222360A/en active Pending
-
2009
- 2009-03-16 EP EP09722156.8A patent/EP2267392A4/en not_active Withdrawn
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| EP2267392A1 (en) | 2010-12-29 |
| US20110011126A1 (en) | 2011-01-20 |
| CN101978236B (en) | 2012-09-05 |
| EP2267392A4 (en) | 2014-03-26 |
| WO2009116478A1 (en) | 2009-09-24 |
| BRPI0908721A2 (en) | 2020-08-11 |
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