CN101987915A - Polymer composite containing polyalcohol and co-stabilizer - Google Patents
Polymer composite containing polyalcohol and co-stabilizer Download PDFInfo
- Publication number
- CN101987915A CN101987915A CN200910160559XA CN200910160559A CN101987915A CN 101987915 A CN101987915 A CN 101987915A CN 200910160559X A CN200910160559X A CN 200910160559XA CN 200910160559 A CN200910160559 A CN 200910160559A CN 101987915 A CN101987915 A CN 101987915A
- Authority
- CN
- China
- Prior art keywords
- hexylidene
- gather
- terephthalamide
- polymeric amide
- adipamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003381 stabilizer Substances 0.000 title claims abstract description 25
- 229920000642 polymer Polymers 0.000 title claims description 30
- 150000005846 sugar alcohols Polymers 0.000 title abstract description 4
- 239000002131 composite material Substances 0.000 title abstract 2
- -1 melamine compound Chemical class 0.000 claims abstract description 196
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- ZRALSGWEFCBTJO-UHFFFAOYSA-N anhydrous guanidine Natural products NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims abstract description 18
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims abstract description 15
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims abstract description 15
- 230000007774 longterm Effects 0.000 claims abstract description 9
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 5
- 150000001408 amides Chemical class 0.000 claims description 87
- 239000000203 mixture Substances 0.000 claims description 67
- 239000000463 material Substances 0.000 claims description 40
- 125000004432 carbon atom Chemical group C* 0.000 claims description 31
- CWZOQCPROMERIV-UHFFFAOYSA-N 4-n-decylbenzene-1,4-dicarboxamide Chemical compound CCCCCCCCCCNC(=O)C1=CC=C(C(N)=O)C=C1 CWZOQCPROMERIV-UHFFFAOYSA-N 0.000 claims description 29
- 125000001931 aliphatic group Chemical group 0.000 claims description 25
- 125000003118 aryl group Chemical group 0.000 claims description 24
- CJAIKQFNMQGKOW-UHFFFAOYSA-N 4-n-dodecylbenzene-1,4-dicarboxamide Chemical compound CCCCCCCCCCCCNC(=O)C1=CC=C(C(N)=O)C=C1 CJAIKQFNMQGKOW-UHFFFAOYSA-N 0.000 claims description 20
- 229920003656 Daiamid® Polymers 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- 239000000178 monomer Substances 0.000 claims description 18
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 15
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 15
- WPXQWTBMMKQBDE-UHFFFAOYSA-N 2-aminoundecanamide Chemical compound CCCCCCCCCC(N)C(N)=O WPXQWTBMMKQBDE-UHFFFAOYSA-N 0.000 claims description 12
- 150000001412 amines Chemical class 0.000 claims description 12
- 238000012360 testing method Methods 0.000 claims description 12
- 230000032683 aging Effects 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 9
- JISVIRFOSOKJIU-UHFFFAOYSA-N hexylidene Chemical group [CH2+]CCCC[CH-] JISVIRFOSOKJIU-UHFFFAOYSA-N 0.000 claims description 9
- 229920000577 Nylon 6/66 Polymers 0.000 claims description 8
- 239000003365 glass fiber Substances 0.000 claims description 8
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 6
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 6
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 6
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 claims description 6
- 229920006139 poly(hexamethylene adipamide-co-hexamethylene terephthalamide) Polymers 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 5
- 239000000314 lubricant Substances 0.000 claims description 5
- 229940059574 pentaerithrityl Drugs 0.000 claims description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 5
- 239000000523 sample Substances 0.000 claims description 5
- 230000003068 static effect Effects 0.000 claims description 5
- POOSGDOYLQNASK-UHFFFAOYSA-N tetracosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC POOSGDOYLQNASK-UHFFFAOYSA-N 0.000 claims description 5
- 239000004953 Aliphatic polyamide Substances 0.000 claims description 4
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 229920003231 aliphatic polyamide Polymers 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- HVCCVSDKZSCLPG-UHFFFAOYSA-N icos-6-ene Chemical compound CCCCCCCCCCCCCC=CCCCCC HVCCVSDKZSCLPG-UHFFFAOYSA-N 0.000 claims description 4
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 4
- HPDAWHPYUNZJMN-UHFFFAOYSA-N octadec-6-ene Chemical compound CCCCCCCCCCCC=CCCCCC HPDAWHPYUNZJMN-UHFFFAOYSA-N 0.000 claims description 4
- 229920006122 polyamide resin Polymers 0.000 claims description 4
- 229920006012 semi-aromatic polyamide Polymers 0.000 claims description 4
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- HOWGUJZVBDQJKV-UHFFFAOYSA-N docosane Chemical compound CCCCCCCCCCCCCCCCCCCCCC HOWGUJZVBDQJKV-UHFFFAOYSA-N 0.000 claims description 3
- 235000010355 mannitol Nutrition 0.000 claims description 3
- 229940043230 sarcosine Drugs 0.000 claims description 3
- 229960002920 sorbitol Drugs 0.000 claims description 3
- 239000000811 xylitol Substances 0.000 claims description 3
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 3
- 235000010447 xylitol Nutrition 0.000 claims description 3
- 229960002675 xylitol Drugs 0.000 claims description 3
- LPKCJFLRJWWIDI-UHFFFAOYSA-N (diaminomethylideneamino)phosphonic acid Chemical compound NC(N)=NP(O)(O)=O LPKCJFLRJWWIDI-UHFFFAOYSA-N 0.000 claims description 2
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims description 2
- OXWYHTHXCLDQCN-UHFFFAOYSA-N 2-(2,3-dihydro-1,4-benzodioxin-3-ylmethyl)guanidine;sulfuric acid Chemical compound OS(O)(=O)=O.C1=CC=C2OC(CNC(=N)N)COC2=C1 OXWYHTHXCLDQCN-UHFFFAOYSA-N 0.000 claims description 2
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- ZZESOJNMRCGYIW-UHFFFAOYSA-N C(CCC1=CC=CC=C1)(=O)NOCCCC Chemical compound C(CCC1=CC=CC=C1)(=O)NOCCCC ZZESOJNMRCGYIW-UHFFFAOYSA-N 0.000 claims description 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- 241000219112 Cucumis Species 0.000 claims description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 claims description 2
- WDZVGELJXXEGPV-YIXHJXPBSA-N Guanabenz Chemical compound NC(N)=N\N=C\C1=C(Cl)C=CC=C1Cl WDZVGELJXXEGPV-YIXHJXPBSA-N 0.000 claims description 2
- 239000004609 Impact Modifier Substances 0.000 claims description 2
- ODKSFYDXXFIFQN-BYPYZUCNSA-N L-arginine Chemical compound OC(=O)[C@@H](N)CCCN=C(N)N ODKSFYDXXFIFQN-BYPYZUCNSA-N 0.000 claims description 2
- 229930064664 L-arginine Natural products 0.000 claims description 2
- 235000014852 L-arginine Nutrition 0.000 claims description 2
- 229920000393 Nylon 6/6T Polymers 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- VCNTUJWBXWAWEJ-UHFFFAOYSA-J aluminum;sodium;dicarbonate Chemical compound [Na+].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O VCNTUJWBXWAWEJ-UHFFFAOYSA-J 0.000 claims description 2
- 229960004980 betanidine Drugs 0.000 claims description 2
- NIVZHWNOUVJHKV-UHFFFAOYSA-N bethanidine Chemical compound CN\C(=N/C)NCC1=CC=CC=C1 NIVZHWNOUVJHKV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- JWPGJSVJDAJRLW-UHFFFAOYSA-N debrisoquin Chemical compound C1=CC=C2CN(C(=N)N)CCC2=C1 JWPGJSVJDAJRLW-UHFFFAOYSA-N 0.000 claims description 2
- 229960004096 debrisoquine Drugs 0.000 claims description 2
- ZZTURJAZCMUWEP-UHFFFAOYSA-N diaminomethylideneazanium;hydrogen sulfate Chemical compound NC(N)=N.OS(O)(=O)=O ZZTURJAZCMUWEP-UHFFFAOYSA-N 0.000 claims description 2
- MJFQUUWPZOGYQT-UHFFFAOYSA-O diaminomethylideneazanium;nitrate Chemical compound NC(N)=[NH2+].[O-][N+]([O-])=O MJFQUUWPZOGYQT-UHFFFAOYSA-O 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims description 2
- 239000005357 flat glass Substances 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 229960004553 guanabenz Drugs 0.000 claims description 2
- ZCVAIGPGEINFCX-UHFFFAOYSA-N guanazodine Chemical compound NC(=N)NCC1CCCCCCN1 ZCVAIGPGEINFCX-UHFFFAOYSA-N 0.000 claims description 2
- 229960004614 guanazodine Drugs 0.000 claims description 2
- ACGDKVXYNVEAGU-UHFFFAOYSA-N guanethidine Chemical compound NC(N)=NCCN1CCCCCCC1 ACGDKVXYNVEAGU-UHFFFAOYSA-N 0.000 claims description 2
- 229960003602 guanethidine Drugs 0.000 claims description 2
- PJJJBBJSCAKJQF-UHFFFAOYSA-N guanidinium chloride Chemical compound [Cl-].NC(N)=[NH2+] PJJJBBJSCAKJQF-UHFFFAOYSA-N 0.000 claims description 2
- XIHXRRMCNSMUET-UHFFFAOYSA-N guanoclor Chemical compound NC(=N)NNCCOC1=C(Cl)C=CC=C1Cl XIHXRRMCNSMUET-UHFFFAOYSA-N 0.000 claims description 2
- JCWFSHNSRREWAZ-UHFFFAOYSA-N henicos-6-ene Chemical compound CCCCCCCCCCCCCCC=CCCCCC JCWFSHNSRREWAZ-UHFFFAOYSA-N 0.000 claims description 2
- PEQVDTIKHXOELW-UHFFFAOYSA-N heptadec-5-ene Chemical compound CCCCCCCCCCCC=CCCCC PEQVDTIKHXOELW-UHFFFAOYSA-N 0.000 claims description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000391 magnesium silicate Substances 0.000 claims description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 2
- 235000019792 magnesium silicate Nutrition 0.000 claims description 2
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 2
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- JYHKRLOUMXMVLU-UHFFFAOYSA-N nonadec-6-ene Chemical compound CCCCCCCCCCCCC=CCCCCC JYHKRLOUMXMVLU-UHFFFAOYSA-N 0.000 claims description 2
- AJCDFVKYMIUXCR-UHFFFAOYSA-N oxobarium;oxo(oxoferriooxy)iron Chemical compound [Ba]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O AJCDFVKYMIUXCR-UHFFFAOYSA-N 0.000 claims description 2
- 229920006396 polyamide 1012 Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- 239000012763 reinforcing filler Substances 0.000 claims 2
- 150000007974 melamines Chemical class 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 abstract description 11
- 229920002647 polyamide Polymers 0.000 abstract description 11
- 229920006119 nylon 10T Polymers 0.000 description 12
- 239000000126 substance Substances 0.000 description 11
- 229920006153 PA4T Polymers 0.000 description 10
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 8
- 229920006115 poly(dodecamethylene terephthalamide) Polymers 0.000 description 8
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 8
- 239000003963 antioxidant agent Substances 0.000 description 7
- 230000003078 antioxidant effect Effects 0.000 description 7
- 150000001721 carbon Chemical group 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229920006111 poly(hexamethylene terephthalamide) Polymers 0.000 description 6
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 5
- 229920006180 poly(hexamethylene terephthalamide)-poly(2-methyl pentamethylene diamine) Polymers 0.000 description 5
- 239000006071 cream Substances 0.000 description 4
- 150000004985 diamines Chemical class 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 229920006128 poly(nonamethylene terephthalamide) Polymers 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 229910021595 Copper(I) iodide Inorganic materials 0.000 description 3
- 229920006152 PA1010 Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 235000001014 amino acid Nutrition 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 235000007715 potassium iodide Nutrition 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- FBPFZTCFMRRESA-KAZBKCHUSA-N D-altritol Chemical compound OC[C@@H](O)[C@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KAZBKCHUSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 description 2
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002530 phenolic antioxidant Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 229960004839 potassium iodide Drugs 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
- 238000002411 thermogravimetry Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- ZWVMLYRJXORSEP-LURJTMIESA-N (2s)-hexane-1,2,6-triol Chemical compound OCCCC[C@H](O)CO ZWVMLYRJXORSEP-LURJTMIESA-N 0.000 description 1
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 1
- VJHDPVWEDUCKRQ-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O.NCCCCCCCCCCCC(O)=O VJHDPVWEDUCKRQ-UHFFFAOYSA-N 0.000 description 1
- HASUJDLTAYUWCO-UHFFFAOYSA-N 2-aminoundecanoic acid Chemical compound CCCCCCCCCC(N)C(O)=O HASUJDLTAYUWCO-UHFFFAOYSA-N 0.000 description 1
- ZSRQMIJBMBDHIE-UHFFFAOYSA-N 2-ethylbutane-1,1-diamine Chemical compound CCC(CC)C(N)N ZSRQMIJBMBDHIE-UHFFFAOYSA-N 0.000 description 1
- AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 description 1
- GAGWMWLBYJPFDD-UHFFFAOYSA-N 2-methyloctane-1,8-diamine Chemical compound NCC(C)CCCCCCN GAGWMWLBYJPFDD-UHFFFAOYSA-N 0.000 description 1
- UFMBOFGKHIXOTA-UHFFFAOYSA-N 2-methylterephthalic acid Chemical compound CC1=CC(C(O)=O)=CC=C1C(O)=O UFMBOFGKHIXOTA-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FBXFSONDSA-N Allitol Chemical compound OC[C@H](O)[C@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-FBXFSONDSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 101100207042 Caenorhabditis elegans unc-94 gene Proteins 0.000 description 1
- 241001214176 Capros Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- SXZYCXMUPBBULW-LECHCGJUSA-N D-(-)-Gulono-gamma-lactone Chemical compound OC[C@@H](O)[C@@H]1OC(=O)[C@H](O)[C@@H]1O SXZYCXMUPBBULW-LECHCGJUSA-N 0.000 description 1
- FBPFZTCFMRRESA-ZXXMMSQZSA-N D-iditol Chemical compound OC[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-ZXXMMSQZSA-N 0.000 description 1
- UNXHWFMMPAWVPI-QWWZWVQMSA-N D-threitol Chemical compound OC[C@@H](O)[C@H](O)CO UNXHWFMMPAWVPI-QWWZWVQMSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 description 1
- HEBKCHPVOIAQTA-IMJSIDKUSA-N L-arabinitol Chemical compound OC[C@H](O)C(O)[C@@H](O)CO HEBKCHPVOIAQTA-IMJSIDKUSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- SRBFZHDQGSBBOR-LECHCGJUSA-N alpha-D-xylose Chemical compound O[C@@H]1CO[C@H](O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-LECHCGJUSA-N 0.000 description 1
- SRBFZHDQGSBBOR-QMKXCQHVSA-N alpha-L-arabinopyranose Chemical compound O[C@H]1CO[C@@H](O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-QMKXCQHVSA-N 0.000 description 1
- 229940059260 amidate Drugs 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 229940058344 antitrematodals organophosphorous compound Drugs 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- QVYARBLCAHCSFJ-UHFFFAOYSA-N butane-1,1-diamine Chemical compound CCCC(N)N QVYARBLCAHCSFJ-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000006208 butylation Effects 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000003262 carboxylic acid ester group Chemical group [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- NWFNSTOSIVLCJA-UHFFFAOYSA-L copper;diacetate;hydrate Chemical compound O.[Cu+2].CC([O-])=O.CC([O-])=O NWFNSTOSIVLCJA-UHFFFAOYSA-L 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 150000007520 diprotic acids Chemical class 0.000 description 1
- FTZSDHHWPWGCDI-UHFFFAOYSA-N dodecanediamide Chemical compound NC(=O)CCCCCCCCCCC(N)=O FTZSDHHWPWGCDI-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- NPUKDXXFDDZOKR-LLVKDONJSA-N etomidate Chemical compound CCOC(=O)C1=CN=CN1[C@H](C)C1=CC=CC=C1 NPUKDXXFDDZOKR-LLVKDONJSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- HRRDCWDFRIJIQZ-UHFFFAOYSA-N naphthalene-1,8-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=CC2=C1 HRRDCWDFRIJIQZ-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- PBLZLIFKVPJDCO-UHFFFAOYSA-N omega-Aminododecanoic acid Natural products NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920006131 poly(hexamethylene isophthalamide-co-terephthalamide) Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229960003487 xylose Drugs 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to an application of polyalcohol with more than two hydroxide radicals and co-stabilizer in increasing long-term thermostability of polyamide composite. The co-stabilizer is selected from melamine compound, guanidine compound and hindered phenol.
Description
Invention field
The polyvalent alcohol and the co-stabilizer that the present invention relates to have more than two hydroxyls are used to improve the said composition long-term thermal stability at high temperature and the purposes of rheological behavior in daiamid composition, described co-stabilizer is selected from following material: melamine compound, guanidine compound and hindered phenol.
Background of invention
Thermostability is a kind of very crucial character to the polymkeric substance that uses in many application.When plastic components (for example, the electric or electron device part of automobile) is exposed to hot conditions following time for a long time, its mechanical property will descend owing to the thermal destruction of polymkeric substance, and this phenomenon is also referred to as thermal ageing.In order to prevent that mechanical property from descending, in polymeric matrix, add the thermal ageing property that various thermo-stabilizers improve polymkeric substance.
Polymeric amide or polyester are stablized by adding thermo-stabilizer (for example phenolic antioxidant, aromatic amine and copper, elemental copper or mixes the mantoquita that forms with potassiumiodide or Potassium Bromide) usually.Stabilization under phenolic antioxidant or aromatic amine are often used in up to 130 ℃.Be applicable to thermostability under higher temperature with KI or KBr blended cuprous iodide, but the thermostable effect deficiency that when application of temperature surpasses 170 ℃, seems.And CuI and potassium halide are very expensive, and because halid existence also may cause some etching problems.The develop rapidly of automotive industry and electronic industry requires polymer materials to have higher thermostability, and the prolonged application temperature of polymeric amide or polyester material need be brought up to 210 ℃, even more up to 230 ℃.It is reported that elemental iron or iron protoxide can improve the long term heat ageing performance of polymeric amide or polyester effectively.Yet the iron powder that uses in expressing technique will not only can cause serious safety problem and scattering problem, but also can cause the mechanical property of polyamide material to descend.
EP 1041109 disclose comprise polyamide resin, fusing point is the daiamid composition of 150 to 280 ℃ polyvalent alcohol, this daiamid composition has good flowability and physical strength and can be used for injecting welding technique.
Press for a kind of polymer composition that excellent its physical properties of high high-temp stability while will can not affect adversely that has.
Summary of the invention
A target of the present invention provides has the purposes that is used to improve the high-temperature stability of said composition more than the polyvalent alcohol of two hydroxyls and co-stabilizer in daiamid composition, and described co-stabilizer is selected from the group of being made up of melamine compound, guanidine compound and hindered phenol.
Detailed Description Of The Invention
In the present invention, if do not clearly state, otherwise per-cent (%) or umber are meant weight percent (wt%) or weight part with respect to daiamid composition.
In the present invention, if do not clearly state, each component or preferred ingredients can make up mutually and form the new composition that is used for new solution.
In the present invention, except as otherwise noted, otherwise the abbreviation that numerical range " a-b " expression a makes up to any real number between the b, wherein a and b are real numbers.For example, the whole real numbers in " 0-5 " have been listed in numerical range " 0-5 " expression herein, and " 0-5 " only to be the breviary of these combinations of values represent.
In the present invention, except as otherwise noted, otherwise the abbreviation that integer numerical range " a-b " expression a makes up to the arbitrary integer between the b, wherein a and b are integers.For example, integer range " 1-N " expression 1,2...N, wherein N is an integer.
In the present invention, except as otherwise noted, otherwise " their combination " represents the multicomponent mixture of each element, for example, and the multicomponent mixture of two kinds, three kinds, four kinds and as many as most probable number MPN purpose composition.
If do not spell out, then used term " a kind of " is meant " at least a " in this specification sheets.
" scope " disclosed herein is the form with the lower limit and the upper limit.Can have one or more lower limits respectively, and one or more upper limit.Given range limits by a selected lower limit and a upper limit.The concrete border that the selected lower limit and the upper limit define scope.All scopes that can limit by this way be inclusive with capable of being combined, promptly any lower limit can be combined to form a scope with any upper limit.For example, at special parameter,, should be appreciated that then 60 to 110 and 80 to 120 scope also can be predicted if listed 60 to 120 and 80 to 110 scope.In addition, if listed minimum extent value 1 and 2 and listed maximum range value 3,4 and 5, then the scope below all can be predicted: 1 to 3,1 to 4,1 to 5,2 to 3,2 to 4 and 2 to 5.
In the present invention, except as otherwise noted, otherwise " guanidine compound " expression contains the compound of following radicals:
In the present invention, except as otherwise noted, otherwise " high temperature " be meant and be equal to or higher than 170 ℃ temperature, preferably is equal to or higher than 210 ℃ temperature.
In the present invention, except as otherwise noted, otherwise " for a long time " be meant equal or be longer than 500 hours, preferably equal or be longer than 1000 hours digestion period.
In the present invention, polymkeric substance can be the polyamide thermoplastic of any routine.
In the present invention, polymeric amide is the polycondensation product of one or more dicarboxylic acid or polycarboxylic acid and one or more diamines, and/or one or more amino acid whose polycondensation products, and/or the ring-opening polymerization product of one or more cyclic lactames.Suitable cyclic lactames is hexanolactam and Ω-laurolactam.Polymeric amide can be full-cream family or half aromatics.
In polymer composition of the present invention, full-cream polyamide is by aliphatic series and alicyclic monomer, and for example diamines, diprotic acid, lactan, amino acid and their reactive equivalent form.Suitable amino acid is the amino dodecylic acid of 11-.Suitable lactan is hexanolactam and Ω-laurolactam.
In the present invention, term " full-cream polyamide " also refers to the multipolymer that formed by two or more this monomers and the blend of two or more full-cream polyamides.Also can use straight chain, side chain and cyclic monomer.
The carboxylic acid monomer who comprises in the whole aliphatic polyamide includes but not limited to aliphatic dicarboxylic acid, for example hexanodioic acid (C6), pimelic acid (C7), suberic acid (C8), nonane diacid (C9), sebacic acid (C10), dodecanedioic acid (C12) and tetradecane diacid (C14).Diamines is selected from the diamines with four or more a plurality of carbon atoms, includes but not limited to butanediamine, hexanediamine, octamethylenediamine, decamethylene diamine, 2-methyl isophthalic acid, 5-pentamethylene diamine, 2-ethyl butanediamine, 2-methyl octamethylenediamine, trimethylammonium hexanediamine and their combination.
Partially aromatic polyamide is the homopolymer that formed by the monomer that contains aromatic group, multipolymer, terpolymer or high-grade polymkeric substance more.One or more aromatic carboxylic acids can be the mixtures of terephthalic acid or terephthalic acid and one or more other carboxylic acids (for example m-phthalic acid, phthalic acid, 2-methyl terephthalic acid and naphthalic acid).In addition, one or more aromatic carboxylic acids can with as top disclosed one or more aliphatic dicarboxylic acids mix.
Preferred polyamide disclosed herein is homopolymer or multipolymer, and wherein the term multipolymer refers to have the polymeric amide of two or more acid amides and/or diamide molecule repeating unit.Homopolymer and multipolymer are determined by their repeating units separately.For multipolymer disclosed herein, repeating unit is listed with the descending of the molar percentage repeating unit that exists in the multipolymer.Following abbreviation is used for determining the monomer and the repeating unit of homopolymer and multipolymer polyamide (PA):
The HMD hexanediamine
The T terephthalic acid
The AA hexanodioic acid
The DMD decamethylene diamine
Capro
-hexanolactam
The DDA sebacic acid
The DDDA dodecanedioic acid
The I m-phthalic acid
TMD 1, the 4-butanediamine
The polymer repeat unit that 4T is formed by TMD and T
The polymer repeat unit that 6T is formed by HMD and TPA
The polymer repeat unit that DT is formed by 2-MPMD and TPA
66 polymer repeat units that form by HMD and AA
The polymer repeat unit that 10T is formed by DMD and TPA
410 polymer repeat units that form by TMD and DDA
510 by 1, the polymer repeat unit that 5-pentamethylene diamine and DDA form
610 polymer repeat units that form by HMD and DDA
612 polymer repeat units that form by HMD and DDDA
6 by
The polymer repeat unit that-hexanolactam forms
11 polymer repeat units that form by the amino undecanoic acid of 11-
12 polymer repeat units that form by 12 amino dodecanoic acid
In one embodiment, daiamid composition comprises one or more polymeric amide that is selected from following material:
(I) organizes polymeric amide, its fusing point is less than 210 ℃, comprise aliphatic series or partially aromatic polyamide, be selected from following material: gather (pentylidene sebacoyl amine) (PA510), gather (pentylidene dodecane diamide) (PA512), gather (ε-Ji Neixianan/hexylidene adipamide) (PA6/66), gather (ε-Ji Neixianan/hexylidene sebacoyl amine) (PA6/610), gather (ε-Ji Neixianan/hexylidene dodecane diamide) (PA6/612), gather (hexylidene tridecane diamide) (PA613), gather (hexylidene pentadecane diamide) (PA615), gather (ε-Ji Neixianan/butylidene terephthalamide) (PA6/4T), gather (ε-Ji Neixianan/hexylidene terephthalamide) (PA6/6T), gather (ε-Ji Neixianan/inferior decyl terephthalamide) (PA6/10T), gather (ε-Ji Neixianan/inferior dodecyl terephthalamide) (PA6/12T), gather (hexylidene sebacoyl amine/hexylidene terephthalamide) (PA610/6T), gather (hexylidene dodecane diamide/hexylidene terephthalamide) (PA612/6T), gather (hexylidene tetradecane diamide/hexylidene terephthalamide) (PA614/6T), gather (ε-Ji Neixianan/hexylidene isophthaloyl amine/hexylidene terephthalamide) (PA6/6I/6T), gather (ε-Ji Neixianan/hexylidene adipamide/hexylidene sebacoyl amine) (PA6/66/610), gather (ε-Ji Neixianan/hexylidene adipamide/hexylidene dodecane diamide) (PA6/66/612), gather (ε-Ji Neixianan/hexylidene adipamide/hexylidene sebacoyl amine/hexylidene dodecane diamide) (PA6/66/610/612), poly-(2-methyl pentylidene adipamide/hexylidene adipamide/hexylidene terephthalamide) (PA D6/66//6T), poly-(2-methyl pentylidene adipamide/hexylidene adipamide) (PA D6/66), gather (inferior decyl sebacoyl amine) (PA1010), gather (inferior decyl dodecane diamide) (PA1012), gather (inferior decyl sebacoyl amine/inferior decyl terephthalamide) (PA1010/10T), poly-(inferior decyl sebacoyl amine/inferior dodecyl sebacoyl amine/inferior decyl terephthalamide/inferior dodecyl terephthalamide (PA1010/1210/10T/12T), gather (the amino undecanoic amide of 11-) (PA11), gather (the amino undecanoic amide of 11-/butylidene terephthalamide) (PA11/4T), gather (the amino undecanoic amide of 11-/hexylidene terephthalamide) (PA11/6T), gather (the amino undecanoic amide of 11-/inferior decyl terephthalamide) (PA11/10T), gather (the amino undecanoic amide of 11-/inferior dodecyl terephthalamide) (PA11/12T), gather (the amino dodecane acid amides of 12-) (PA12), gather (the amino dodecane acid amides of 12-/butylidene terephthalamide) (PA12/4T), gather (the amino dodecane acid amides of 12-/hexylidene terephthalamide) (PA12/6T), gather (the amino dodecane acid amides of 12-/inferior decyl terephthalamide) (PA12/10T), poly-(inferior dodecyl dodecane diamide) (PA1212) and poly-(inferior dodecyl dodecane diamide/inferior dodecyl terephthalamide) (PA1212/12T);
(II) organizes polymeric amide, its fusing point is at least 210 ℃, comprises the aliphatic polyamide that is selected from following material: gather (butylidene adipamide) (PA46), poly-(ε-Ji Neixianan) (PA 6), poly-(hexylidene adipamide/(ε-Ji Neixianan) (PA 66/6), poly-(hexylidene adipamide) (PA 66), gather (hexylidene adipamide/hexylidene sebacoyl amine) (PA66/610), gather (hexylidene adipamide/hexylidene dodecane diamide) (PA66/612), gather (hexylidene adipamide/inferior decyl sebacoyl amine) (PA66/1010), gather (hexylidene sebacoyl amine) (PA610), gather (hexylidene dodecane diamide) (PA612), gather (hexylidene tetradecane diamide) (PA614), poly-(hexylidene n-Hexadecane diamide) (PA616) and poly-(butylidene adipamide/2-methyl pentylidene adipamide) (PA46/D6);
(III) organizes polymeric amide, and its fusing point is at least 210 ℃, comprises
(gg) half aromatic repeating units of 20 to 35 molar percentages, described half aromatic repeating units are derived from the monomer that is selected from one or more following materials:
V. the aromatic dicarboxylic acid and aliphatic diamine that have 8 to 20 carbon atoms with 4 to 20 carbon atoms; And
(hh) the aliphatic repeating unit of 65 to 80 molar percentages, described aliphatic repeating unit are derived from the monomer that is selected from one or more following materials:
Vi. the aliphatic dicarboxylic acid and the described aliphatic diamine that have 6-20 carbon atom with 4 to 20 carbon atoms; And
Vii. the lactan and/or the aminocarboxylic acid that have 4-20 carbon atom; And
Viii. their mixture;
(IV) organizes polymeric amide, comprises
(cc) half aromatic repeating units of 50 to 95 molar percentages, described half aromatic repeating units are derived from the monomer that is selected from one or more following materials:
(i) has the aromatic dicarboxylic acid of 8 to 20 carbon atoms and have the aliphatic diamine of 4 to 20 carbon atoms; And
(dd) the aliphatic repeating unit of 5 to 50 molar percentages, described aliphatic repeating unit are derived from the monomer that is selected from one or more following materials:
The aliphatic dicarboxylic acid and the described aliphatic diamine that (ii) have 6 to 20 carbon atoms with 4 to 20 carbon atoms;
The lactan and/or the aminocarboxylic acid that (iii) have 4 to 20 carbon atoms; And
(iv) their mixture;
(V) organizes polymeric amide, and its fusing point is at least 260 ℃, comprises
(ee) greater than half aromatic repeating units of 95 molar percentages, described half aromatic repeating units is derived from the monomer that is selected from one or more following materials:
(i) has the aromatic dicarboxylic acid of 8 to 20 carbon atoms and have the aliphatic diamine of 4 to 20 carbon atoms;
(ff) be less than the aliphatic repeating unit of 5 molar percentages, described aliphatic repeating unit is derived from the monomer that is selected from one or more following materials:
The aliphatic dicarboxylic acid and the described aliphatic diamine that (ii) have 6 to 20 carbon atoms with 4 to 20 carbon atoms; And
The lactan and/or the aminocarboxylic acid that (iii) have 4 to 20 carbon atoms; And
(iv) their mixture; And
(VI) organizes polymeric amide, it does not have fusing point, is selected from following material: poly-(hexylidene isophthaloyl amine/hexylidene terephthalamide) (6I/6T) and poly-(hexylidene isophthaloyl amine/hexylidene terephthalamide/hexylidene adipamide) (6I/6T/66).
(I) organizes polymeric amide, can have the degree that half aromatic repeating units to fusing point is lower than 210 ℃, and the partially aromatic polyamide of this group has half aromatic repeating units that is less than 40 molar percentages usually.Half aromatic repeating units be defined as derived from be selected from one or more following materials monomeric those: have the aromatic dicarboxylic acid of 8 to 20 carbon atoms and have the aliphatic diamine of 4 to 20 carbon atoms.
Preferred (III) group polymeric amide is selected from following material: gather (butylidene adipamide/butylidene terephthalamide) (PA46/4T), gather (butylidene adipamide/hexylidene terephthalamide) (PA46/6T), poly-(butylidene adipamide/2-methyl pentylidene adipamide/inferior decyl terephthalamide) PA46/D6/10T), gather (hexylidene adipamide/hexylidene terephthalamide) (PA66/6T), poly-(hexylidene adipamide/hexylidene isophthaloyl amine/hexylidene terephthalamide PA66/6I/6T and poly-(hexylidene adipamide/2-methyl pentylidene adipamide/hexylidene terephthalamide (PA66/D6/6T); And most preferred (III) group polymeric amide is PA 66/6T.
Preferred (IV) group polymeric amide is selected from following material: gather (butylidene terephthalamide/hexylidene adipamide) (PA4T/66), gather (butylidene terephthalamide/ε-Ji Neixianan) (PA4T/6), gather (butylidene terephthalamide/hexylidene dodecane diamide) (PA4T/612), gather (butylidene terephthalamide/2-methyl pentylidene adipamide/hexylidene adipamide) (PA4T/D6/66), gather (hexylidene terephthalamide/2-methyl pentylidene terephthalamide/hexylidene adipamide) (PA6T/DT/66), poly-(hexylidene terephthalamide/hexylidene adipamide) PA6T/66, gather (hexylidene terephthalamide/hexylidene sebacoyl amine) (PA6T/610), gather (hexylidene terephthalamide/hexylidene tetradecane diamide) (PA6T/614), gather (nine methylene radical terephthalamides/nine methylene radical sebacoyl amine) (PA9T/910), gather (nine methylene radical terephthalamides/nine methylene radical dodecane diamide) (PA9T/912), gather (the amino undecanoic amide of nine methylene radical terephthalamide/11-) (PA9T/11), gather (the amino dodecane acid amides of nine methylene radical terephthalamide/12-) (PA9T/12), gather (the amino undecanoic amide of inferior decyl terephthalamide/11-) (PA10T/11), gather (the amino dodecane acid amides of inferior decyl terephthalamide/12-) (PA10T/12), gather (inferior decyl terephthalamide/inferior decyl sebacoyl amine) (PA10T/1010), gather (inferior decyl terephthalamide/inferior decyl dodecane diamide) (PA10T/1012), gather (inferior decyl terephthalamide/butylidene adipamide) (PA10T/46), gather (inferior decyl terephthalamide/ε-Ji Neixianan) (PA10T/6), gather (inferior decyl terephthalamide/hexylidene adipamide) (PA10T/66), gather (inferior dodecyl terephthalamide/inferior dodecyl dodecane diamide) (PA12T/1212), poly-(inferior dodecyl terephthalamide/ε-Ji Neixianan) (PA12T/6) and poly-(inferior dodecyl terephthalamide/hexylidene adipamide) (PA12T/66); And most preferred (IV) group polymeric amide is PA6T/66.
Preferred (V) group polymeric amide is selected from following material: poly-(butylidene terephthalamide/2-methyl pentylidene terephthalamide) PA4T/DT, poly-(butylidene terephthalamide/hexylidene terephthalamide) PA4T/6T, poly-(butylidene terephthalamide/inferior decyl terephthalamide) PA4T/10T, poly-(butylidene terephthalamide/inferior dodecyl terephthalamide) PA4T/12T, gather (butylidene terephthalamide/2-methyl pentylidene terephthalamide/hexylidene terephthalamide) (PA4T/DT/6T), gather (butylidene terephthalamide/hexylidene terephthalamide/2-methyl pentylidene terephthalamide) (PA4T/6T/DT), gather (hexylidene terephthalamide/2-methyl pentylidene terephthalamide) (PA6T/DT), poly-(hexylidene adipamide/hexylidene isophthaloyl amine) (PA 6T/6I), poly-(hexylidene terephthalamide/inferior decyl terephthalamide) PA6T/10T, gather (hexylidene terephthalamide/inferior dodecyl terephthalamide) (PA6T/12T), it is poly-that (hexylidene terephthalamide/2-methyl pentylidene terephthalamide/poly-(inferior decyl terephthalamide) (PA6T/DT/10T), gather (hexylidene terephthalamide/inferior decyl terephthalamide/inferior dodecyl terephthalamide) (PA6T/10T/12T), gather (inferior decyl terephthalamide) (PA10T), gather (inferior decyl terephthalamide/butylidene terephthalamide) (PA10T/4T), gather (inferior decyl terephthalamide/2-methyl pentylidene terephthalamide) (PA10T/DT), gather (inferior decyl terephthalamide/inferior dodecyl terephthalamide) (PA10T/12T), it is poly-that (inferior decyl terephthalamide/2-methyl pentylidene terephthalamide/(inferior decyl terephthalamide) (PA10T/DT/12T), gather (inferior dodecyl terephthalamide) (PA12T), poly-(inferior dodecyl terephthalamide)/butylidene terephthalamide) (PA12T/4T), poly-(inferior dodecyl terephthalamide)/hexylidene terephthalamide) PA12T/6T, poly-(inferior dodecyl terephthalamide)/inferior decyl terephthalamide) (PA12T/10T) and poly-(inferior dodecyl terephthalamide)/2-methyl pentylidene terephthalamide) (PA12T/DT) and most preferred (V) group polymeric amide be PA6T/D6.
In a plurality of embodiments, polymeric amide is respectively (I) group polymeric amide, (II) group polymeric amide, (III) group polymeric amide, (IV) group polymeric amide, (V) group polymeric amide or (VI) group polymeric amide.
This polymeric amide also can be the blend of two or more polymeric amide.Preferred blends comprises those that are selected from (I) group and (II) group polymeric amide, (I) group and (III) group polymeric amide, (I) group and (VI) group polymeric amide, (II) group and (VI) group polymeric amide, (II) group and (IV) group polymeric amide, (II) group and (V) group polymeric amide and (IV) group and (V) group polymeric amide.
Preferred blends comprises (II) group and (V) group polymeric amide, and particularly preferred blend comprises poly-(hexylidene adipamide) (PA 66) and poly-(hexylidene terephthalamide/2-methyl pentylidene terephthalamide) (PA 6T/DT).
Preferred blends comprises (II) group and (III) group polymeric amide in addition, and particularly preferred blend comprise poly-(ε-Ji Neixianan) (PA6) and gather (hexylidene adipamide/hexylidene terephthalamide) (PA6,6/6T).
Polyvalent alcohol can be selected from the aliphatic hydroxyl cpd that contains more than two hydroxyls, contain aliphatic series-cycloaliphatic compounds more than two hydroxyls, contain cycloaliphatic compounds, aromatic substance and sugar more than two hydroxyls.
Aliphatic chain in the polyvalent alcohol not only can comprise carbon atom but also can comprise one or more for example heteroatomss of nitrogen, oxygen and sulphur atom that are selected from.The cyclic aliphatic ring that is present in the polyvalent alcohol can be the part of monocycle or two rings or polycyclic system and can be carbocyclic ring or heterocycle.The heterocycle that is present in the polyvalent alcohol can be the part of monocycle or two rings or polycyclic system, and can comprise two or more for example heteroatomss of nitrogen, oxygen and sulphur atom that are selected from.One or more polyvalent alcohols can comprise one or more substituting groups, for example ether, carboxylic acid group, carboxylic acyloxy amido or carboxylic acid ester groups.
The examples of polyhydric alcohols that contains more than two hydroxyls includes but not limited to triol, glycerine for example, TriMethylolPropane(TMP), 2,3-two-(2 '-hydroxyethyl)-hexanaphthene-1-alcohol, hexane-1,2, the 6-triol, 1,1,1-three-(methylol) ethane, 3-(2 '-hydroxyl-oxethyl)-propane-1, the 2-glycol, 3-(2 '-the hydroxyl propoxy-)-propane-1, the 2-glycol, 2-(2 '-hydroxyl-oxethyl)-hexane-1, the 2-glycol, 6-(2 '-the hydroxyl propoxy-)-hexane-1, the 2-glycol, 1,1,1-three-[(2 '-hydroxyl-oxethyl)-methyl]-ethane, 1,1,1-three-[(2 '-the hydroxyl propoxy-)-methyl]-propane, 1,1,1-three-(4 '-hydroxyphenyl)-ethane, 1,1,1-three-(hydroxyphenyl)-propane, 1,1,3-three-(dihydroxyl-3-aminomethyl phenyl)-propane, 1,1,4-three-(dihydroxy phenyl)-butane, 1,1,5-three-(hydroxyphenyl)-3-methylpentane, two-TriMethylolPropane(TMP), ethoxylated trimethylolpropane or propoxylation TriMethylolPropane(TMP); Polyvalent alcohol, for example tetramethylolmethane, dipentaerythritol and tripentaerythritol; And sugar, for example cyclodextrin, D-seminose, glucose, semi-lactosi, sucrose, fructose, wood sugar, pectinose, D-mannitol, D-Sorbitol Powder, D-or L-arabitol, Xylitol, iditol, talitol, allitol, altritol, guilitol, tetrahydroxybutane, threitol and D-gulonic acid-y-lactone or the like.
Preferred polyhydric alcohols comprises those with a pair of hydroxyl, and described hydroxyl is connected to the carbon atom that is separated each other by at least one atom separately.Particularly preferred polyvalent alcohol is that wherein a pair of hydroxyl is connected to those of separately the carbon atom that is separated each other by single carbon atom.
Preferably, the polyvalent alcohol that is used for according to resin combination of the present invention is tetramethylolmethane, dipentaerythritol, tripentaerythritol, two-TriMethylolPropane(TMP), D-mannitol, D-Sorbitol Powder and Xylitol.More preferably, the polyvalent alcohol that is used for according to resin combination of the present invention is dipentaerythritol and/or tetramethylolmethane.Most preferred polyvalent alcohol is a dipentaerythritol.
In a plurality of embodiments, based on the gross weight of described daiamid composition, the content of described polyvalent alcohol in daiamid composition is the 0.25-15 weight percent, is preferably the 0.5-8 weight percent, more preferably the 1-5 weight percent most preferably is the 2-5 weight percent.
Can be used for co-stabilizer of the present invention and comprise guanidine compound.Guanidine compound refers to have the compound of one or more guanidine radicals.The example of guanidine compound includes but not limited to guanidine, Dicyanodiamide (dicyanodiamide), Guanidinium hydrochloride, guanidine sulfate, Guanidinium nitrate, phosphoguanidine, 4-amino-N-guanidine radicals benzsulfamide, N-guanidine radicals-sarcosine, 3-guanidine radicals propionic acid, N-(4-carboxyl phenyl) guanidinesalt hydrochlorate, L-arginine, polyhexamethylene guanidinesalt hydrochlorate, 1,3-diphenylguanidine, betanidine, guanethidine, envacar, Debrisoquine, Vatensol, guanazodine, guanabenz or their combination etc.Preferably, used guanidine compound is Dicyanodiamide, poly-(hexylidene) guanidinesalt hydrochlorate and guanidine radicals-sarcosine etc. in the polymer composition of the present invention.More preferably, the used guanidine compound of the present invention is a Dicyanodiamide.
Another kind of co-stabilizer is the melamine compound that is selected from trimeric cyanamide, melamine cyanurate, Tripyrophosphoric acid trimeric cyanamide, melam, melem and melon.
Another kind of co-stabilizer is a hindered phenol.Hindered phenol is meant the organic compound that contains at least one phenolic group, wherein aromatics part at least one and preferred two with have the position of phenolic hydroxyl group and be substituted as substituent carbon direct neighbor.The substituting group adjacent with hydroxyl is the alkyl that is selected from the alkyl with 1 to 10 carbon atom suitably, and will be preferably tertiary butyl groups.The molecular weight of hindered phenol is suitably at least about 260, preferably at least about 500, more preferably at least about 600.The hindered phenol that most preferably has low volatility (particularly under the processing temperature that molded said preparation adopted, having low volatility), and can further be characterized by and have at least 290 ℃, preferably at least 300 ℃, 320 ℃, 340 ℃, and most preferably at least 350 ℃ 10% weight loss temperature (when with the scanning speed of 10 ℃/min by thermogravimetry (TGA) when measuring).
Suitable hindered phenol compound comprises for example four (methylene radical (3,5-two-(uncle)-butyl-4-hydroxyl hydrogenated cinnamate)) methane, and it can
1010 derive from CIBA Specialty Chemicals, Tarrytown, N.Y (the Ciba company limited in New York Ta Lidun city), and N, N '-hexylidene two (3,5-two-(uncle) butyl-hydroxyl hydrocinnamamide), its also with
1098 derive from CI BA Specialty Chemicals (Ciba company limited).Other suitable hindered phenols comprise 1,3,5-trimethylammonium-2,4,6-three (3,5-two-(uncle)-butyl-4-hydroxybenzyl) benzene and hexamethylene two (3,5-two-(uncle) butyl-4-hydroxyl hydrogenated cinnamate), the two can be respectively with
1330 and 259 derive from CIBA Specialty Chemicals (Ciba company limited).Irganox 1098 is most preferred hindered phenols that are used for composition.
In a preferred embodiment, based on the gross weight of daiamid composition, the content of described co-stabilizer is the 0.25-10 weight percent, is preferably the 0.5-8 weight percent, and more preferably the 1-5 weight percent most preferably is the 2-5 weight percent.
Above-mentioned one or more co-stabilizers also can comprise mantoquita and/or their derivative, for example, and copper halide or neutralized verdigris; Manganous salt and/or their derivative; And their combination.Preferably, mantoquita can be united use with halogenide and/or P contained compound; More preferably, mantoquita can be united use with iodide or bromide; Even more preferably, mantoquita can be united use with potassiumiodide or Potassium Bromide.In the present invention, mantoquita and/or their derivative can also use with one or more thermo-stabilizers, and described one or more thermo-stabilizers are selected from following compound: the phenolic aldehyde antioxidant that is obstructed, hindered amine antioxidant, phosphorus antioxidant or their combination.
In the present invention, polymer composition of the present invention can also comprise other additives that usually use this area, for example antioxidant, static inhibitor, whipping agent, lubricant, impact modifier, softening agent, tinting material and weighting agent.
In the present invention, antioxidant can be any antioxidant that usually use this area.In according to a preferred embodiment of the invention, antioxidant is selected from following material: butylation toluene (BHT), phenyl-B-naphthylamines, alkyl paraquinones, thioether, salol, sulfydryl thioether, sulfo--propionic ester, organo phosphorous compounds, dithio sulphonate, amidate, hydrazine class, aromatic amine compound and their combination.
In the present invention, static inhibitor can be any static inhibitor that usually use this area.In according to a preferred embodiment of the invention, static inhibitor is selected from following compound: quaternary ammonium salt, ethoxylated amine, aliphatic ester and sulfonation paraffin and their combination.
In the present invention, whipping agent can be the normally used any whipping agent in this area.In according to a preferred embodiment of the invention, whipping agent is selected from following material: nitrogen, carbonic acid gas, air, butane, pentane, sherwood oil, methyl chlorofluoride, azobisformamide ABFA, the two isobutyl esters of azo and their combination.
In the present invention, lubricant can be the normally used any lubricant in this area.In a preferred embodiment of the invention, lubricant is selected from aliphatic ester class (for example, the direactive glyceride of lipid acid) and their combination.
In the present invention, softening agent can be the normally used any plasticizer in this area.In a preferred embodiment of the invention, softening agent is selected from following material: terephthalate, phthalic ester, aliphatic dibasic esters, phosphoric acid ester, clorafin and their combination.
In the present invention, weighting agent can be any weighting agent, but is preferably selected from following material: lime carbonate, the glass fibre with circle and non-circular cross sections, sheet glass, granulated glass sphere, carbon fiber, talcum powder, mica, wollastonite, calcined clay, kaolin, diatomite, sal epsom, Magnesium Silicate q-agent, barium sulfate, titanium dioxide, aluminium carbonate sodium, barium ferrite, potassium titanate and their mixture.
Glass fibre with non-circular cross sections is meant the glass fibre with following cross section, and described cross section has the major axis of long slant range in the vertical vertical and cross section taken in correspondence with glass fibre.Non-circular cross sections has in the cross section taken in correspondence perpendicular to the minor axis of long slant range on the direction of major axis.The non-circular cross sections of fiber can have multiple shape, comprises cocoon shape (8 font), rectangle, ellipse, subtriangular, Polygons and rectangle.It should be appreciated by those skilled in the art that cross section can have other shapes.The ratio of the length of major axis and the length of minor axis is preferably between about 1.5: 1 and about 6: 1.This ratio more preferably between about 2: 1 and 5: 1, yet more preferably between about 3: 1 to about 4: 1.Suitable glass fibre has disclosed in EP 0 190 001 and EP 0,196 194.
In an embodiment preferred according to the present invention, daiamid composition is the mixture that melt blending forms, and wherein all component of polymer are through thorough mixing, and all non-polymer compositions are well-dispersed in the polymeric matrix.Any melt-mixing method can be used for mixing component of polymer of the present invention and non-polymer composition.For example, can be to melt mixer with component of polymer and the feeding of non-polymer composition, for example in single screw extrusion machine or twin screw extruder, stirrer, single screw rod or twin screw kneader or the Banbury mixing tank, and to add step can be disposable whole adding or progressively add in batches.When adding component of polymer and non-polymer composition in the mode that progressively adds in batches, a part that at first adds component of polymer and/or non-polymer composition, then with the residual polymer composition and the non-polymeric composition melting mixing that add subsequently, up to obtaining well-mixed composition.When using the filler (for example, long glass fibres) of surplus reason shape, can use pultrusion to prepare enhancing composition.
As mentioned above, have with the polyvalent alcohol of two or more hydroxyls and the daiamid composition of co-stabilizer and can be used for increasing molded or extruded product long-term thermal stability at high temperature prepared therefrom.The long-term thermal stability of goods can assess aging a plurality of cycles test duration of the thick specimen of 4mm by baking oven under a plurality of test experiments temperature.The baking oven probe temperature that is used for composition disclosed herein is the minimum test period of minimum 170 ℃ and 500 hours.Probe temperature and test period can be higher.Behind oven ageing, test the tensile strength and the elongation at break of described specimen according to ISO 527-2/1A testing method, and compare with the not aged contrast of exsiccant when molded (DAM).With the conservation rate that tensile strength relatively is provided of DAM contrast and/or the conservation rate (retention) of elongation at break, and therefore can assess the long term high temperature aging resistance of multiple composition.
In a plurality of embodiments of the present invention, based on the comparison of the unaged contrast of DAM, daiamid composition has at least 50%, and the stretching strength retentivity under preferred at least 60%, at least 70%, at least 80% and at least 90% 170 ℃/500 hours.
Embodiment preferred is to use the polymeric amide that is selected from (II) group polymeric amide, and wherein probe temperature is at least 210 ℃, and test period is at least 90% (comparing with not aged) at least 500 hours and stretching strength retentivity.This has remarkable and beyond thought improvement than the commercially available stable daiamid composition of copper of tradition aspect long-term thermal stability, as disclosed in the example.
On the other hand, the present invention relates to by making resin combination of the present invention be shaped the method for article of manufacture.Examples of articles is film or laminate, trolley part or engine parts or electric component/electronic unit." shaping " is meant any forming technique, for example extrudes, injection-molded, hot-moulded, compression molding or blowing.Preferably, goods are shaped by injection-molded or blowing.
The example of trolley part or engine parts includes but not limited to charge air cooler, rocker cover, exhaust system, gas exhaust duct and intake manifold.Expose a required anti-mechanical illustrative examples as the antagonism long term high temperature, can mention charge air cooler.Charge air cooler is the parts that improve engine combustion efficiency in the vehicle water cooler.The air themperature that charge air cooler reduces engine also increases the density of air after the compression in the turbo-supercharger, thereby makes more air enter cylinder and improve motor efficiency.Because the temperature of the air that enters when the air admission charge air cooler may be higher than 200 ℃, is by at high temperature keeping the composition of good mechanical properties to make in a long time so require these parts.
Further illustrate the present invention below in conjunction with embodiment.Should be appreciated that following embodiment only is used for illustration purpose, is not limited to the present invention.
Material
PA66 is meant by 1,6-hexanodioic acid and 1, and the aliphatic polyamide that the 6-hexanediamine is made, it can trade mark 6
101NC010 is from E.I.DuPont de Nemour s and Company, Wilmington, and Delaware, USA (E.I.Du Pont Company of Wilmington City, Delaware, USA State) is commercially available.
GF is meant NEG 275H short glass fiber.
The Cu stablizer is meant the 7 parts of potassiumiodides in 0.5 part of stearic acid ester type waxes binding agent and the mixture of 1 part of cuprous iodide.
DPE is meant dipentaerythritol.
Method
Complex method
The pill of the polymkeric substance, weighting agent, thermo-stabilizer and other additives that are suitable for listed in following table 1 and the table 2 is fed to the rear portion that the TEM35 corotation changes twin screw extruder.All embodiment and comparative example carry out with the feeding rate of 210rpm, 23kg/h and 290 ℃ cylinder temperature.Melt temperature is 300 ℃.After extruding forcing machine, composition is made into the ball shape.The gross weight that the amount of the composition shown in table 1 and the table 2 is based on thermoplastic compounds is that unit provides with the weight percent.
Physical property
Utilize ISO 527-2 (1A type) to measure tensile modulus and elongation at break.For tensile modulus, speed is 1mm/min; For elongation at break, speed is 5mm/min.
High temperature ageing
As illustrated in table 1 and the table 2, to specimen be treated to drying when molded (DAM), perhaps be oven ageing (AOA).Specimen is not applied other processing.
Table 1
The AOA=oven ageing
Data in table 1 and the table 2 show, are carrying out oven ageing under 210 ℃ after 1000 hours, and the conservation rate of tensile strength is apparently higher than the comparative example of the combination that wherein only has copper stablizer or copper stablizer and co-stabilizer.
Table 2
The AOA=oven ageing
Claims (20)
1. has the purposes that in daiamid composition, is used to increase described daiamid composition long-term thermal stability at high temperature more than the polyvalent alcohol of two hydroxyls and the co-stabilizer that is selected from melamine compound, guanidine compound and hindered phenol.
2. purposes according to claim 1, wherein said daiamid composition also comprises the reinforcing filler of 10 to 60 weight percents.
3. purposes according to claim 1, wherein 4mm test rod and not aged comparing have at least 50% stretching strength retentivity, described test rod is made by described daiamid composition, and in air atmosphere in the baking oven of at least 170 ℃ of probe temperatures aging at least 500 hours test period, and test according to ISO 527-2/1A.
4. purposes according to claim 1, wherein said daiamid composition comprise one or more polymeric amide that is selected from following material:
(I) organizes polymeric amide, its fusing point is lower than 210 ℃, comprise the aliphatic series or the partially aromatic polyamide that are selected from following material: gather (pentylidene sebacoyl amine) (PA510), gather (pentylidene dodecane diamide) (PA512), gather (ε-Ji Neixianan/hexylidene adipamide) (PA6/66), gather (ε-Ji Neixianan/hexylidene sebacoyl amine) (PA6/610), gather (ε-Ji Neixianan/hexylidene dodecane diamide) (PA6/612), gather (hexylidene tridecane diamide) (PA613), gather (hexylidene pentadecane diamide) (PA615), gather (ε-Ji Neixianan/butylidene terephthalamide) (PA6/4T), gather (ε-Ji Neixianan/hexylidene terephthalamide) (PA6/6T), gather (ε-Ji Neixianan/inferior decyl terephthalamide) (PA6/10T), gather (ε-Ji Neixianan/inferior dodecyl terephthalamide) (PA6/12T), gather (hexylidene sebacoyl amine/hexylidene terephthalamide) (PA610/6T), gather (hexylidene dodecane diamide/hexylidene terephthalamide) (PA612/6T), gather (hexylidene tetradecane diamide/hexylidene terephthalamide) (PA614/6T), gather (ε-Ji Neixianan/hexylidene isophthaloyl amine/hexylidene terephthalamide) (PA6/6I/6T), gather (ε-Ji Neixianan/hexylidene adipamide/hexylidene sebacoyl amine) (PA6/66/610), gather (ε-Ji Neixianan/hexylidene adipamide/hexylidene dodecane diamide) (PA6/66/612), gather (ε-Ji Neixianan/hexylidene adipamide/hexylidene sebacoyl amine/hexylidene dodecane diamide) (PA6/66/610/612), poly-(2-methyl pentylidene adipamide/hexylidene adipamide/hexylidene terephthalamide) (PA D6/66//6T), poly-(2-methyl pentylidene adipamide/hexylidene adipamide) (PA D6/66), poly-(inferior decyl sebacoyl amine) (PA1010) gathers (inferior decyl dodecane diamide) (PA1012), gather (inferior decyl sebacoyl amine/inferior decyl terephthalamide) (PA1010/10T), poly-(inferior decyl sebacoyl amine/inferior dodecyl sebacoyl amine/inferior decyl terephthalamide/inferior dodecyl terephthalamide (PA1010/1210/10T/12T), gather (the amino undecanoic amide of 11-) (PA11), gather (the amino undecanoic amide of 11-/butylidene terephthalamide) (PA11/4T), gather (the amino undecanoic amide of 11-/hexylidene terephthalamide) (PA11/6T), gather (the amino undecanoic amide of 11-/inferior decyl terephthalamide) (PA11/10T), gather (the amino undecanoic amide of 11-/inferior dodecyl terephthalamide) (PA11/12T), gather (the amino dodecane acid amides of 12-) (PA12), gather (the amino dodecane acid amides of 12-/butylidene terephthalamide) (PA12/4T), gather (the amino dodecane acid amides of 12-/hexylidene terephthalamide) (PA12/6T), gather (the amino dodecane acid amides of 12-/inferior decyl terephthalamide) (PA12/10T), poly-(inferior dodecyl dodecane diamide) (PA1212) and poly-(inferior dodecyl dodecane diamide/inferior dodecyl terephthalamide) (PA1212/12T); (II) organizes polymeric amide, its fusing point is at least 210 ℃, comprises the aliphatic polyamide that is selected from following material: gather (butylidene adipamide) (PA46), gather (ε-Ji Neixianan) (PA6), it is poly-that (hexylidene adipamide/(ε-Ji Neixianan) (PA66/6), poly-(hexylidene adipamide) (PA 66), gather (hexylidene adipamide/hexylidene sebacoyl amine) (PA66/610), gather (hexylidene adipamide/hexylidene dodecane diamide) (PA66/612), gather (hexylidene adipamide/inferior decyl sebacoyl amine) (PA66/1010), gather (hexylidene sebacoyl amine) (PA610), gather (hexylidene dodecane diamide) (PA612), gather (hexylidene tetradecane diamide) (PA614), poly-(hexylidene n-Hexadecane diamide) (PA616) and poly-(butylidene adipamide/2-methyl pentylidene adipamide) (PA46/D6); (III) organizes polymeric amide, and its fusing point is at least 210 ℃, comprises
(aa) half aromatic repeating units of 20 to 35 molar percentages, described half aromatic repeating units are derived from the monomer that is selected from one or more following materials:
I. the aromatic dicarboxylic acid and aliphatic diamine that have 8 to 20 carbon atoms with 4 to 20 carbon atoms; With
(bb) the aliphatic repeating unit of 65 to 80 molar percentages, described aliphatic repeating unit are derived from the monomer that is selected from one or more following materials:
Ii. the aliphatic dicarboxylic acid and described aliphatic diamine that have 6 to 20 carbon atoms with 4 to 20 carbon atoms; And
Iii. the lactan and/or the aminocarboxylic acid that have 4 to 20 carbon atoms; And
Iv. their mixture;
(IV) organizes polymeric amide, comprises:
(cc) half aromatic repeating units of 50 to 95 molar percentages, described half aromatic repeating units are derived from the monomer that is selected from one or more following materials:
(i) has the aromatic dicarboxylic acid of 8 to 20 carbon atoms and have the aliphatic diamine of 4 to 20 carbon atoms; And
(dd) the aliphatic repeating unit of 5 to 50 molar percentages, described aliphatic repeating unit are derived from the monomer that is selected from one or more following materials:
The aliphatic dicarboxylic acid and the described aliphatic diamine that (ii) have 6 to 20 carbon atoms with 4 to 20 carbon atoms; And
The lactan and/or the aminocarboxylic acid that (iii) have 4 to 20 carbon atoms; And
(iv) their mixture;
(V) organizes polymeric amide, and its fusing point is at least 260 ℃, comprises:
(ee) greater than half aromatic repeating units of 95 molar percentages, described half aromatic repeating units is derived from the monomer that is selected from one or more following materials:
I. the aromatic dicarboxylic acid and aliphatic diamine that have 8 to 20 carbon atoms with 4 to 20 carbon atoms; And
(ff) less than the aliphatic repeating unit of 5 molar percentages, described aliphatic repeating unit is derived from the monomer that is selected from one or more following materials:
Ii. the aliphatic dicarboxylic acid and the described aliphatic diamine that have 6 to 20 carbon atoms with 4 to 20 carbon atoms; And
Iii. the lactan and/or the aminocarboxylic acid that have 4 to 20 carbon atoms; And
Iv. their mixture; And
(VI) organizes polymeric amide, it does not have fusing point, is selected from following material: poly-(hexylidene isophthaloyl amine/hexylidene terephthalamide) (6I/6T) and poly-(hexylidene isophthaloyl amine/hexylidene terephthalamide/hexylidene adipamide) (6I/6T/66).
5. purposes according to claim 4, wherein said polymeric amide are selected from (I) group polymeric amide.
6. purposes according to claim 4, wherein said polymeric amide is selected from (II) group polymeric amide, and wherein said probe temperature is at least 210 ℃, and described test period is at least 500 hours, and compare with not aged, the conservation rate of described tensile strength is at least 90%.
7. purposes according to claim 4, wherein said polymeric amide are selected from (III) group polymeric amide.
8. purposes according to claim 4, wherein said polymeric amide are selected from (IV) group polymeric amide.
9. purposes according to claim 4, wherein said polyamide resin are selected from (V) group polymeric amide.
10. purposes according to claim 4, wherein said polyamide resin are selected from (VI) group polymeric amide.
11. purposes according to claim 4, wherein said polyamide resin comprise two or more blends that is selected from the polymeric amide of following material: (I) group and (II) group polymeric amide; (I) group and (III) polymeric amide; (I) group and (VI) group polymeric amide; (II) group and (VI) group polymeric amide; (II) group and (IV) group polymeric amide; (II) group and (V) group polymeric amide and (IV) group and (V) group polymeric amide.
12. purposes according to claim 1, the wherein said polyvalent alcohol that has more than two hydroxyls is selected from following material: tetramethylolmethane, dipentaerythritol, tripentaerythritol, two-TriMethylolPropane(TMP), D-mannitol, D-Sorbitol Powder and Xylitol.
13. purposes according to claim 1, the wherein said polyvalent alcohol that has more than two hydroxyls is dipentaerythritol and/or tetramethylolmethane.
14. purposes according to claim 1, wherein said thermo-stabilizer is guanidine compound and is selected from following material: guanidine, Dicyanodiamide, Guanidinium hydrochloride, guanidine sulfate, Guanidinium nitrate, phosphoguanidine, 4-amino-N-guanidine radicals benzsulfamide, N-guanidine radicals-sarcosine, 3-guanidine radicals propionic acid, N-(4-carboxyl-phenyl) guanidinesalt hydrochlorate, L-arginine, poly-(hexylidene guanidine) hydrochloride, 1,3-diphenylguanidine, betanidine, guanethidine, envacar, Debrisoquine, Vatensol, guanazodine, guanabenz or its combination etc.; Be preferably selected from Dicyanodiamide and poly-(hexylidene guanidine) hydrochloride.
15. purposes according to claim 1, wherein said co-stabilizer are the melamine compounds that is selected from following compound: trimeric cyanamide, melamine cyanurate, Tripyrophosphoric acid trimeric cyanamide, melam, melem and melon.
16. purposes according to claim 1, wherein said co-stabilizer is the hindered phenol that is selected from following material: four (methylene radical (3,5-two-(uncle)-butyl-4-hydroxyl hydrogenated cinnamate)) methane, N, N '-hexylidene two (3,5-two-(uncle) butyl-hydroxyl hydrocinnamamide), 1,3,5-trimethylammonium-2,4,6-three (3,5-two-(uncle)-butyl-4-hydroxybenzyl) benzene and hexamethylene two (3,5-two-(uncle) butyl-4-hydroxyl hydrogenated cinnamate).
17. purposes according to claim 1, wherein based on the gross weight of described daiamid composition, the content of described polyvalent alcohol is the 0.25-15 weight percent, is preferably the 0.5-8 weight percent, more preferably the 1-5 weight percent most preferably is the 2-5 weight percent.
18. purposes according to claim 1, wherein based on the gross weight of described daiamid composition, the content of described co-stabilizer is the 0.25-10 weight percent, is preferably the 0.5-8 weight percent, more preferably the 1-5 weight percent most preferably is the 2-5 weight percent.
19. purposes according to claim 1, wherein said reinforcing filler is selected from following material: lime carbonate, the glass fibre with circle and non-circular cross sections, sheet glass, granulated glass sphere, carbon fiber, talcum powder, mica, wollastonite, calcined clay, kaolin, diatomite, sal epsom, Magnesium Silicate q-agent, barium sulfate, titanium dioxide, aluminium carbonate sodium, barium ferrite, potassium titanate and their mixture.
20. purposes according to claim 1, wherein said polymer composition also comprise one or more additives that is selected from following material: static inhibitor, whipping agent, lubricant, impact modifier, softening agent and tinting material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910160559A CN101987915B (en) | 2009-07-30 | 2009-07-30 | Polymer composite containing polyalcohol and co-stabilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910160559A CN101987915B (en) | 2009-07-30 | 2009-07-30 | Polymer composite containing polyalcohol and co-stabilizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101987915A true CN101987915A (en) | 2011-03-23 |
| CN101987915B CN101987915B (en) | 2012-09-05 |
Family
ID=43744718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910160559A Expired - Fee Related CN101987915B (en) | 2009-07-30 | 2009-07-30 | Polymer composite containing polyalcohol and co-stabilizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101987915B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106414554A (en) * | 2014-04-15 | 2017-02-15 | 阿科玛法国公司 | Process for the manufacture of thermoplastic materials made of semicrystalline polyamides |
| EP2924066B1 (en) | 2014-03-26 | 2017-04-12 | LANXESS Deutschland GmbH | Polyamide compositions |
| CN107207782A (en) * | 2015-02-05 | 2017-09-26 | 阿科玛法国公司 | Flammable daiamid composition with delay |
| CN109642076A (en) * | 2016-07-29 | 2019-04-16 | 巴斯夫欧洲公司 | Polyamide blend for laser sintering powder |
| CN114517012A (en) * | 2022-03-14 | 2022-05-20 | 金旸（厦门）新材料科技有限公司 | High-appearance antibacterial halogen-free flame-retardant polyamide composite material and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2924067A1 (en) | 2014-03-26 | 2015-09-30 | LANXESS Deutschland GmbH | Polyamide compositions |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1646615A (en) * | 2002-04-10 | 2005-07-27 | 西巴特殊化学品控股有限公司 | Flame retardant coatings |
| CN1839022A (en) * | 2003-08-19 | 2006-09-27 | 索尔维先进聚合物有限责任公司 | Impact-modified polyamide film |
| CN1906246A (en) * | 2003-12-25 | 2007-01-31 | Jsr株式会社 | Thermoplastic elastomer composition, method for producing same and formed article |
-
2009
- 2009-07-30 CN CN200910160559A patent/CN101987915B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1646615A (en) * | 2002-04-10 | 2005-07-27 | 西巴特殊化学品控股有限公司 | Flame retardant coatings |
| CN1839022A (en) * | 2003-08-19 | 2006-09-27 | 索尔维先进聚合物有限责任公司 | Impact-modified polyamide film |
| CN1906246A (en) * | 2003-12-25 | 2007-01-31 | Jsr株式会社 | Thermoplastic elastomer composition, method for producing same and formed article |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2924066B1 (en) | 2014-03-26 | 2017-04-12 | LANXESS Deutschland GmbH | Polyamide compositions |
| CN106414554A (en) * | 2014-04-15 | 2017-02-15 | 阿科玛法国公司 | Process for the manufacture of thermoplastic materials made of semicrystalline polyamides |
| CN107207782A (en) * | 2015-02-05 | 2017-09-26 | 阿科玛法国公司 | Flammable daiamid composition with delay |
| CN109642076A (en) * | 2016-07-29 | 2019-04-16 | 巴斯夫欧洲公司 | Polyamide blend for laser sintering powder |
| CN109642076B (en) * | 2016-07-29 | 2022-01-25 | 巴斯夫欧洲公司 | Polyamide Blends for Laser Sintering Powders |
| CN114517012A (en) * | 2022-03-14 | 2022-05-20 | 金旸（厦门）新材料科技有限公司 | High-appearance antibacterial halogen-free flame-retardant polyamide composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101987915B (en) | 2012-09-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102112525B (en) | Heat-resistant molded or extruded thermoplastic articles | |
| CN104245842B (en) | thermoplastic polyamide composition | |
| EP2459639B1 (en) | Heat resistant polyamide compositions having high amine ends | |
| JP6416870B2 (en) | Heat resistant polyamide composition | |
| KR101391054B1 (en) | Heat― and light―stabilised polyamide composition | |
| CN101987915B (en) | Polymer composite containing polyalcohol and co-stabilizer | |
| KR102251533B1 (en) | Polyamide composition | |
| KR20140053173A (en) | Use of a polyamide chain extending compound as a stabilizing agent | |
| CN102030982B (en) | Polymer composition containing polyol and co-stabilizer | |
| KR20200104882A (en) | High heat resistant polyamide molding blend | |
| EP1943291B1 (en) | Hydrolysis resistant polyamide compositions, and articles formed therefrom | |
| US20140011951A1 (en) | Heat resistant polyamide compositions having high amine ends | |
| EP3656818A1 (en) | Polyamide resin composition and article comprising the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120905 Termination date: 20150730 |
|
| EXPY | Termination of patent right or utility model |