CN102108638A - Durable, waterproof, oil-proof, antistatic and antibacterial functional coating adhesive and preparation method - Google Patents
Durable, waterproof, oil-proof, antistatic and antibacterial functional coating adhesive and preparation method Download PDFInfo
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- CN102108638A CN102108638A CN 201010585596 CN201010585596A CN102108638A CN 102108638 A CN102108638 A CN 102108638A CN 201010585596 CN201010585596 CN 201010585596 CN 201010585596 A CN201010585596 A CN 201010585596A CN 102108638 A CN102108638 A CN 102108638A
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- 239000011248 coating agent Substances 0.000 title claims abstract description 19
- 238000000576 coating method Methods 0.000 title claims abstract description 19
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000000853 adhesive Substances 0.000 title claims description 13
- 230000001070 adhesive effect Effects 0.000 title claims description 13
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 14
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 14
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims abstract description 14
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 13
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920002635 polyurethane Polymers 0.000 claims abstract description 13
- 239000004814 polyurethane Substances 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 8
- 238000004945 emulsification Methods 0.000 claims abstract description 6
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 6
- 230000008719 thickening Effects 0.000 claims abstract description 6
- 235000019270 ammonium chloride Nutrition 0.000 claims description 15
- -1 acrylyl Chemical group 0.000 claims description 14
- 229960003761 propamidine Drugs 0.000 claims description 14
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 11
- 239000004519 grease Substances 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- VWXLCWNPSOUPPE-UHFFFAOYSA-N (1-amino-2-methylpropylidene)azanium;chloride Chemical compound Cl.CC(C)C(N)=N VWXLCWNPSOUPPE-UHFFFAOYSA-N 0.000 abstract 1
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 239000003292 glue Substances 0.000 abstract 1
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 238000000518 rheometry Methods 0.000 abstract 1
- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 abstract 1
- 239000004753 textile Substances 0.000 description 7
- 230000003115 biocidal effect Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 150000003840 hydrochlorides Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- POCFBDFTJMJWLG-UHFFFAOYSA-N dihydrosinapic acid methyl ester Natural products COC(=O)CCC1=CC(OC)=C(O)C(OC)=C1 POCFBDFTJMJWLG-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
本发明耐久防水、防油、抗静电、抗菌功能型涂层胶及制备方法，由丙烯酸甲酯、丙烯酸正丁酯、甲基丙烯酸缩水甘油酯、甲基丙烯酸烯丙酯、甲基丙烯酸2、2、2-三氟乙酯、丙烯酰氧乙基三甲基氯化铵、脂肪醇聚氧乙烯醚XL90、十六烷基三甲基氯化铵、2、2-偶氮双(2-甲基丙脒)盐酸盐、去离子水、缔合型聚氨酯流平流变剂WT-203，经乳化、引发聚合、增稠工艺制成。Durable waterproof, oil-proof, antistatic, antibacterial functional coating glue and preparation method of the present invention, from methyl acrylate, n-butyl acrylate, glycidyl methacrylate, allyl methacrylate, methacrylic acid 2, 2, 2-trifluoroethyl ester, acryloyloxyethyltrimethylammonium chloride, fatty alcohol polyoxyethylene ether XL90, hexadecyltrimethylammonium chloride, 2, 2- azobis (2- Methylpropionamidine) hydrochloride, deionized water, associative polyurethane leveling rheology agent WT-203, made by emulsification, polymerization initiation, and thickening process.
Description
Technical field
What the present invention relates to is after-finishing of textile products functional form coating adhesive, and the textiles of processing with this gel coating has durable waterproof, grease proofing, antistatic, antibiotic main feature.Its technical characterstic is to contain a plurality of-CF3 group in the main gel molecule of coating adhesive, and is in the polymer chain skin, so it is hydrophobic, oleophobic property good, has good waterproof and oilproof stain resistance; Also have the trimethyl salmiac cation group in the main gel molecular structure, superior antistatic, antibiotic effect can be provided.
Background technology
Prior art realizes waterproof, grease proofing, antistatic, antibacterial effect for making weaving face fabric, pads PROCESS FOR TREATMENT by finishing agent and realizes, its water-wash resistance difference is the shortcoming of generally acknowledging.
In recent years, piece market increases year by year to the demand of functional form coating adhesive, but coating adhesive is the simple function type basically, and durable waterproof, grease proofing, antistatic, antibiotic comprehensive function type coating adhesive do not see that public technology is arranged.
Summary of the invention
The purpose of this invention is to provide a kind of durable waterproof, grease proofing, antistatic, antibacterial functions type coating adhesive and preparation method.
Durable waterproof of the present invention, grease proofing, antistatic, antibacterial functions type coating adhesive:
The raw material weight proportioning:
Methyl acrylate 25-29, n-butyl acrylate 80-88, glycidyl methacrylate 3.0-6.0, allyl methacrylate 1.0-1.8, methacrylic acid 2,2,2-trifluoro ethyl ester 10-15, acrylyl oxy-ethyl-trimethyl salmiac 20-30, fatty alcohol-polyoxyethylene ether XL90 is 6.5-7.8, hexadecyltrimethylammonium chloride 7.0-9.0,2, two (2-methyl-prop amidine) the hydrochloride 1.1-1.9 of 2-azo, deionized water 220-280, association type polyurethane levelling rheological agent WT-203 is 3.5-4.0; Make through emulsification, initiated polymerization, thickening three step process;
The product chemical index is as follows:
Outward appearance: white thick liquid
Ionic: sun
PH value: 5 ± 1
Solid content: 〉=40%
Viscosity: 2500-2800mPa.S.
Fatty alcohol-polyoxyethylene ether XL90 is that the pure and mild reacting ethylene oxide of Guerbet by ten carbon makes, and wherein numeral 90 is meant the molal quantity of oxirane.Fatty alcohol-polyoxyethylene ether XL90 product as BASF AG.
Association type polyurethane levelling rheological agent WT-203 is the modest Shanghai of a moral chemistry Co., Ltd product.
Durable waterproof of the present invention, grease proofing, antistatic, antibacterial functions type coating adhesive preparation method:
The raw material weight proportioning is:
Methyl acrylate 25-29, n-butyl acrylate 80-88, glycidyl methacrylate 3.0-6.0, allyl methacrylate 1.0-1.8, methacrylic acid 2,2,2-trifluoro ethyl ester 10-15, acrylyl oxy-ethyl-trimethyl salmiac 20-30, fatty alcohol-polyoxyethylene ether XL90 is 6.5-7.8, hexadecyltrimethylammonium chloride 7.0-9.0,2, two (2-methyl-prop amidine) the hydrochloride 1.1-1.9 of 2-azo, deionized water 220-280, association type polyurethane levelling rheological agent WT-203 is 3.5-4.0.
The preparation method:
(1) emulsification mix monomer: adding methyl acrylate 25-29 gram, n-butyl acrylate 80-88 gram, glycidyl methacrylate 3.0-6.0 gram, allyl methacrylate 1.0-1.8 gram, methacrylic acid 2,2,2-trifluoro ethyl ester 10-15 gram, acrylyl oxy-ethyl-trimethyl salmiac 20-30 gram, hexadecyltrimethylammonium chloride 7.0-9.0 gram, fatty alcohol-polyoxyethylene ether XL90 are that 6.5-7.8 gram, deionized water 200-280 restrain in the stainless steel still, stirring and emulsifying 30 minutes is made emulsion;
(2) initiated polymerization: get 20% of emulsion total amount, be that the 73.1-91.5 gram adds in the reactor, be warming up to 72-75 ℃, the mixed liquor that adds initator 2, two (2-methyl-prop amidine) the hydrochloride 0.2-0.38 grams of 2-azo and water 10 grams, cause, drip remaining emulsion 292.4-366 gram down at 72-75 ℃ then, drip the mixed liquor of initator 2, two (2-methyl-prop amidine) the hydrochloride 0.9-1.52 grams of 2-azo and water 30 grams simultaneously, 2.5-3.0 hour dropwise, then 82-85 ℃ of insulation 1.5-2.0 hour, be cooled to 40-45 ℃, filter;
(3) emulsion thickening: adding association type polyurethane levelling rheological agent WT-203 is the 3.5-4.0 gram, stirs 1-1.5 hour, filters discharging and gets product.
The present invention selects methyl acrylate, n-butyl acrylate, glycidyl methacrylate, methacrylic acid 2,2,2-trifluoro ethyl ester, allyl methacrylate, acrylyl oxy-ethyl-trimethyl salmiac monomer copolymerization for use, wherein allyl methacrylate contains two polymer functional groups and can construct three dimensional polymeric, crosslinked, insoluble structure, water-wash resistance is good, glycidyl methacrylate glycidol ester group and fabric reactive group (as amino, carboxyl, hydroxyl) reaction, more than two promise coating product water-wash resistances good, the film forming fastness is good; Methacrylic acid 2,2,2-trifluoro ethyl ester contain a plurality of-CF3 group, and are in the polymer chain skin, so it is hydrophobic, oleophobic property is fine, has durable waterproof, grease proofness; The trimethyl salmiac cation group of acrylyl oxy-ethyl-trimethyl salmiac has durable antistatic, antibiotic effect.
The specific embodiment
Embodiment 1
(1) emulsification mix monomer: adding methyl acrylate 25 grams, n-butyl acrylate 80 grams, glycidyl methacrylate 3.0, allyl methacrylate 1.0 grams, methacrylic acid 2,2,2-trifluoro ethyl ester 10, acrylyl oxy-ethyl-trimethyl salmiac 20, fatty alcohol-polyoxyethylene ether XL90 are 6.5 grams, deionized water 220 grams in the stainless steel still, stirring and emulsifying 30 minutes is made emulsion;
(2) initiated polymerization: get 20% of emulsion total amount, promptly 73.1 grams add in the reactor, be warming up to 72-75 ℃, the mixed liquor that adds initator 2, two (2-methyl-prop amidine) hydrochloride 0.2 grams of 2-azo and water 10 grams causes, drip remaining emulsion 292.4 grams down at 72-75 ℃ then, drip the mixed liquor of initator 2, two (2-methyl-prop amidine) hydrochloride 0.9 grams of 2-azo and water 30 grams simultaneously, 3.0 hour dropwise, then 82-85 ℃ of insulation 1.5 hours, be cooled to below 40 ℃, filter;
(3) emulsion thickening: adding association type polyurethane levelling rheological agent WT-203 is 3.5 grams, stirs 1 hour, filters discharging and gets product.
Embodiment 2
The raw material weight proportioning is: methyl acrylate 26 grams, n-butyl acrylate 82 grams, glycidyl methacrylate 4.0, allyl methacrylate 1.2 grams, methacrylic acid 2,2,2-trifluoro ethyl ester 12, acrylyl oxy-ethyl-trimethyl salmiac 22, fatty alcohol-polyoxyethylene ether XL90 is 6.8 grams, hexadecyltrimethylammonium chloride 7.5 grams, 2, two (2-methyl-prop amidine) hydrochloride 1.2 grams of 2-azo, deionized water 245 grams, association type polyurethane levelling rheological agent WT-203 is 3.7 grams; The technical process of producing is with embodiment 1.
Embodiment 3
The raw material weight proportioning is: methyl acrylate 27 grams, n-butyl acrylate 85 grams, glycidyl methacrylate 5.0, allyl methacrylate 1.4 grams, methacrylic acid 2,2,2-trifluoro ethyl ester 13, acrylyl oxy-ethyl-trimethyl salmiac 24,, fatty alcohol-polyoxyethylene ether XL90 is that 7.1 grams, hexadecyltrimethylammonium chloride 8.0 grams, 2, two (2-methyl-prop amidine) hydrochlorides 1.5 grams of 2-azo, deionized water 260 grams, association type polyurethane levelling rheological agent WT-203 are 3.9 grams, the technical process of production is with embodiment 1.
Embodiment 4
The raw material weight proportioning is: methyl acrylate 28 grams, n-butyl acrylate 87 grams, glycidyl methacrylate 5.5, allyl methacrylate 1.6 grams, methacrylic acid 2,2,2-trifluoro ethyl ester 14, acrylyl oxy-ethyl-trimethyl salmiac 27, fatty alcohol-polyoxyethylene ether XL90 are that 7.3 grams, hexadecyltrimethylammonium chloride 8.5 gram, 2, two (2-methyl-prop amidine) hydrochlorides 1.7 grams of 2-azo, deionized water 270 grams, association type polyurethane levelling rheological agent WT-203 are 3.9 grams, and the technical process of production is with embodiment 1.
Embodiment 5
The raw material weight proportioning is: methyl acrylate 29 grams, n-butyl acrylate 88 grams, glycidyl methacrylate 6.0, allyl methacrylate 1.8 grams, methacrylic acid 2,2,2-trifluoro ethyl ester 15, acrylyl oxy-ethyl-trimethyl salmiac 30,, fatty alcohol-polyoxyethylene ether XL90 is that 7.8 grams, hexadecyltrimethylammonium chloride 9.0 grams, 2, two (2-methyl-prop amidine) hydrochlorides 1.9 grams of 2-azo, deionized water 280 grams, association type polyurethane levelling rheological agent WT-203 are 4.0 grams, the technical process of production is with embodiment 1.
This product is applicable to coating on cotton textiles and the synthetic fabrics.
Coating adhesive of the present invention uses experimental example: the calendering of textile base cloth nylon roller, 90 ℃ of pressure 10MPa, temperature are carried out two times coating then on the calendering surface, the thick 1.5mm of coating cutter, 165 ℃ of baking temperatures, 1 minute time.
Testing result:
Testing standard:
GB/T4745-1997 textile fabric surface moisture resistance is measured
The anti-hydrocarbon test of GB/T19977-2005 textiles oil repellent
The evaluation of GB/T20944-2007 textiles-anti-microbial property
The FZ/T01042-1996 textile material antistatic property electrostatic pressure half-life is measured
GB/T8629-2001 washing fastness test condition.
Claims (2)
1. durable waterproof, grease proofing, antistatic, antibacterial functions type coating adhesive is characterized in that:
The raw material weight proportioning:
Methyl acrylate 25-29, n-butyl acrylate 80-88, glycidyl methacrylate 3.0-6.0, allyl methacrylate 1.0-1.8, methacrylic acid 2,2,2-trifluoro ethyl ester 10-15, acrylyl oxy-ethyl-trimethyl salmiac 20-30, fatty alcohol-polyoxyethylene ether XL90 is 6.5-7.8, hexadecyltrimethylammonium chloride 7.0-9.0,2, two (2-methyl-prop amidine) the hydrochloride 1.1-1.9 of 2-azo, deionized water 220-280, association type polyurethane levelling rheological agent WT-203 is 3.5-4.0; Make through emulsification, initiated polymerization, thickening three step process;
The product chemical index is as follows:
Outward appearance: white thick liquid
Ionic: sun
PH value: 5 ± 1
Solid content: 〉=40%
Viscosity: 2500-2800mPa.S.
2. durable waterproof, grease proofing, antistatic, antibacterial functions type coating adhesive preparation method is characterized in that:
The raw material weight proportioning is:
Methyl acrylate 25-29, n-butyl acrylate 80-88, glycidyl methacrylate 3.0-6.0, allyl methacrylate 1.0-1.8, methacrylic acid 2,2,2-trifluoro ethyl ester 10-15, acrylyl oxy-ethyl-trimethyl salmiac 20-30, fatty alcohol-polyoxyethylene ether XL90 is 6.5-7.8, hexadecyltrimethylammonium chloride 7.0-9.0,2, two (2-methyl-prop amidine) the hydrochloride 1.1-1.9 of 2-azo, deionized water 220-280, association type polyurethane levelling rheological agent WT-203 is 3.5-4.0;
The preparation method:
(1) emulsification mix monomer: adding methyl acrylate 25-29, n-butyl acrylate 80-88, glycidyl methacrylate 3.0-6.0, allyl methacrylate 1.0-1.8, methacrylic acid 2,2,2-trifluoro ethyl ester 10-15, acrylyl oxy-ethyl-trimethyl salmiac 20-30, hexadecyltrimethylammonium chloride 7.0-9.0, fatty alcohol-polyoxyethylene ether XL90 are 6.5-7.8, deionized water 200-280 in the stainless steel still, stirring and emulsifying 30 minutes is made emulsion;
(2) initiated polymerization: get 20% of emulsion total amount and add in the reactor, be warming up to 72-75 ℃, the mixed liquor that adds initator 2, two (2-methyl-prop amidine) the hydrochloride 0.2-0.38 of 2-azo and water 10, cause, drip remaining emulsion down at 72-75 ℃ then, drip the mixed liquor of initator 2, two (2-methyl-prop amidine) the hydrochloride 0.9-1.52 of 2-azo and water 30 simultaneously, 2.5-3.0 hour dropwise, then 82-85 ℃ of insulation 1.5-2.0 hour, be cooled to 40-45 ℃, filter;
(3) emulsion thickening: adding association type polyurethane levelling rheological agent WT-203 is 3.5-4.0, stirs 1-1.5 hour, filters discharging and gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105855968A CN102108638B (en) | 2010-12-08 | 2010-12-08 | Durable, waterproof, oil-proof, antistatic and antibacterial functional coating adhesive and preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105855968A CN102108638B (en) | 2010-12-08 | 2010-12-08 | Durable, waterproof, oil-proof, antistatic and antibacterial functional coating adhesive and preparation method |
Publications (2)
| Publication Number | Publication Date |
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| CN102108638A true CN102108638A (en) | 2011-06-29 |
| CN102108638B CN102108638B (en) | 2012-08-22 |
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| CN2010105855968A Expired - Fee Related CN102108638B (en) | 2010-12-08 | 2010-12-08 | Durable, waterproof, oil-proof, antistatic and antibacterial functional coating adhesive and preparation method |
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| CN102787494A (en) * | 2012-07-24 | 2012-11-21 | 苏州市华元化工有限公司 | Solvent-based coating adhesive and its production method |
| CN103073988A (en) * | 2013-01-17 | 2013-05-01 | 杭州电子科技大学 | Preparation method of epoxy resin-modified polyurethane emulsion leather finishing agent |
| CN103073987A (en) * | 2013-01-17 | 2013-05-01 | 杭州电子科技大学 | Preparation method for organic silicon modified polyester type polyurethane emulsion leather finishing agent |
| CN103103795A (en) * | 2013-01-17 | 2013-05-15 | 杭州电子科技大学 | Method for preparing leather finishing agent from polyether polyurethane emulsion |
| CN103215808A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Washable oiliness coating adhesive and preparation method |
| CN103526594A (en) * | 2013-10-23 | 2014-01-22 | 合肥聚合辐化技术有限公司 | Anti-corrosion waterborne polyurethane printing adhesive and preparation method thereof |
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| CN103590249A (en) * | 2013-11-20 | 2014-02-19 | 上海天伟纺织质量技术服务有限公司 | Preparation method of water-repellent and oil-repellent antistatic finishing agent |
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| CN110698584A (en) * | 2019-10-28 | 2020-01-17 | 辽宁恒星精细化工有限公司 | Polyester fabric heat transfer printing pretreatment agent and preparation method thereof |
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