CN102113523A - High-efficiency mothproofing agent - Google Patents
High-efficiency mothproofing agent Download PDFInfo
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- CN102113523A CN102113523A CN200910245196XA CN200910245196A CN102113523A CN 102113523 A CN102113523 A CN 102113523A CN 200910245196X A CN200910245196X A CN 200910245196XA CN 200910245196 A CN200910245196 A CN 200910245196A CN 102113523 A CN102113523 A CN 102113523A
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- CN
- China
- Prior art keywords
- mothproofing
- efficient
- agent
- mothproofing agent
- camphor
- Prior art date
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 41
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims abstract description 19
- 241000723346 Cinnamomum camphora Species 0.000 claims abstract description 19
- 229960000846 camphor Drugs 0.000 claims abstract description 19
- 229930008380 camphor Natural products 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 230000000694 effects Effects 0.000 claims abstract description 15
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 6
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 claims abstract description 3
- 230000035699 permeability Effects 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 12
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 claims description 9
- 239000002728 pyrethroid Substances 0.000 claims description 8
- VXSIXFKKSNGRRO-MXOVTSAMSA-N [(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;[(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-3-[(e)-3-methoxy-2-methyl-3-oxoprop-1-enyl Chemical class CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1.CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VXSIXFKKSNGRRO-MXOVTSAMSA-N 0.000 claims description 7
- 229940070846 pyrethrins Drugs 0.000 claims description 7
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 claims description 6
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims description 6
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims description 6
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 6
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 5
- YUGWDVYLFSETPE-JLHYYAGUSA-N Empenthrin Chemical compound CC\C=C(/C)C(C#C)OC(=O)C1C(C=C(C)C)C1(C)C YUGWDVYLFSETPE-JLHYYAGUSA-N 0.000 claims description 4
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims description 4
- 229960003500 triclosan Drugs 0.000 claims description 4
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 3
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 claims description 3
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims description 3
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 claims description 3
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 claims description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-M 4-hydroxybenzoate Chemical compound OC1=CC=C(C([O-])=O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-M 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 229910018516 Al—O Inorganic materials 0.000 claims description 3
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims description 3
- 239000005770 Eugenol Substances 0.000 claims description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 3
- 235000011613 Pinus brutia Nutrition 0.000 claims description 3
- 241000018646 Pinus brutia Species 0.000 claims description 3
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims description 3
- 229910018557 Si O Inorganic materials 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- 239000005844 Thymol Substances 0.000 claims description 3
- 235000016720 allyl isothiocyanate Nutrition 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 claims description 3
- 230000003115 biocidal effect Effects 0.000 claims description 3
- 235000000484 citronellol Nutrition 0.000 claims description 3
- 239000013078 crystal Substances 0.000 claims description 3
- 229960002217 eugenol Drugs 0.000 claims description 3
- 238000009472 formulation Methods 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229930007744 linalool Natural products 0.000 claims description 3
- 229920000620 organic polymer Polymers 0.000 claims description 3
- 235000010292 orthophenyl phenol Nutrition 0.000 claims description 3
- 229910052615 phyllosilicate Inorganic materials 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 3
- 235000013599 spices Nutrition 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 229960000790 thymol Drugs 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- 229920006184 cellulose methylcellulose Polymers 0.000 claims description 2
- 230000002147 killing effect Effects 0.000 abstract description 2
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 abstract 4
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 abstract 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 239000004745 nonwoven fabric Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000010409 thin film Substances 0.000 abstract 1
- -1 alkynes valerate Chemical class 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000003814 drug Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 description 1
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 1
- QDZOEBFLNHCSSF-PFFBOGFISA-N (2S)-2-[[(2R)-2-[[(2S)-1-[(2S)-6-amino-2-[[(2S)-1-[(2R)-2-amino-5-carbamimidamidopentanoyl]pyrrolidine-2-carbonyl]amino]hexanoyl]pyrrolidine-2-carbonyl]amino]-3-(1H-indol-3-yl)propanoyl]amino]-N-[(2R)-1-[[(2S)-1-[[(2R)-1-[[(2S)-1-[[(2S)-1-amino-4-methyl-1-oxopentan-2-yl]amino]-4-methyl-1-oxopentan-2-yl]amino]-3-(1H-indol-3-yl)-1-oxopropan-2-yl]amino]-1-oxo-3-phenylpropan-2-yl]amino]-3-(1H-indol-3-yl)-1-oxopropan-2-yl]pentanediamide Chemical compound C([C@@H](C(=O)N[C@H](CC=1C2=CC=CC=C2NC=1)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CC(C)C)C(N)=O)NC(=O)[C@@H](CC=1C2=CC=CC=C2NC=1)NC(=O)[C@H](CCC(N)=O)NC(=O)[C@@H](CC=1C2=CC=CC=C2NC=1)NC(=O)[C@H]1N(CCC1)C(=O)[C@H](CCCCN)NC(=O)[C@H]1N(CCC1)C(=O)[C@H](N)CCCNC(N)=N)C1=CC=CC=C1 QDZOEBFLNHCSSF-PFFBOGFISA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- 239000004150 EU approved colour Substances 0.000 description 1
- 239000005896 Etofenprox Substances 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 101800003906 Substance P Proteins 0.000 description 1
- YXWCBRDRVXHABN-JCMHNJIXSA-N [cyano-(4-fluoro-3-phenoxyphenyl)methyl] 3-[(z)-2-chloro-2-(4-chlorophenyl)ethenyl]-2,2-dimethylcyclopropane-1-carboxylate Chemical compound C=1C=C(F)C(OC=2C=CC=CC=2)=CC=1C(C#N)OC(=O)C1C(C)(C)C1\C=C(/Cl)C1=CC=C(Cl)C=C1 YXWCBRDRVXHABN-JCMHNJIXSA-N 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- YMGUBTXCNDTFJI-UHFFFAOYSA-N cyclopropanecarboxylic acid Chemical compound OC(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-N 0.000 description 1
- LSFUGNKKPMBOMG-UHFFFAOYSA-N cycloprothrin Chemical compound ClC1(Cl)CC1(C=1C=CC=CC=1)C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 LSFUGNKKPMBOMG-UHFFFAOYSA-N 0.000 description 1
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- 229950005085 etofenprox Drugs 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229960003536 phenothrin Drugs 0.000 description 1
- SMKRKQBMYOFFMU-UHFFFAOYSA-N prallethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OC1C(C)=C(CC#C)C(=O)C1 SMKRKQBMYOFFMU-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- 229940070710 valerate Drugs 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A high-efficiency mothproofing agent at least contains two effective mixed matters playing the role of mothproofing under room temperature, and also contains an effective matter with a mildew-proof function. The mixture with the mothproofing function is prepared by mixing camphor, santochlor and other mothproofing agents with pyrethrin. The high-efficiency mothproofing agent also contains an additive convenient for producing a forming agent, namely micromolecule inorganic silicon substance, and can belongs to the powder type, the granulated type, the sheet type, the ball type or the massive agent type. The mothproofing agent is arranged in a bag or a box made of air-permeability paper with air permeability, non-woven fabrics and thin films. The pyrethrin is quick in taking effect, has obvious effect on killing moths, not only remedies the defects of a camphor mothproofing agent, but also greatly reduces input, and is safer and more effective. The camphor and the pyrethrin do not have the mildew-proof effect, so that a mildew-proof agent is added in the mixture of the camphor and the pyrethrin, therefore, the mothproofing agent has the effects of moth and mildew prevention.
Description
Technical field
The invention belongs to mothproofing agent, particularly a kind of efficient mothproofing agent.
Background technology
Because the rate of volatilization of camphor mothproofing agent is slower, long until the time that reaches " effectively ", even cause having dropped into the camphor mothproofing agent, but during the engineering noise in early stage, moth still can activity sting food, and camphor has preferably repellent effect for moth but kills poor effect, when the camphor mothproofing agent is finished using or when finishing using, when in case the camphor concentration in the environment is not enough to the repellent moth, moth also can climb back or recover and continue to sting food, and in order to reach mothproof effect preferably, the injected volume of camphor mothproofing agent is 200g/m at present
3, be not suitable for using than large space.And camphor and pyrethrins do not possess the effect of mildew-resistant.
Summary of the invention
The invention provides a kind of efficient mothproofing agent, it is fast to reach onset speed, and input amount is few, and is safer and more effective, and the effect of mildew-resistant is arranged again
Content of the present invention is:
A kind of efficient mothproofing agent is characterized in that: contain two kinds of working substances that play mothproof effect that can volatilize at normal temperatures at least and mix; And contain working substance with antimildew function.
Mixture with mothproof function is mixing of mothproofing agents such as camphor or paracide and pyrethrins.
Pyrethrins is an empenthrin.
There is the working substance of antimildew function to be: p-hydroxybenzoate, thymol, to face in phenyl phenol, triclosan, o-phenyl phenol, parachlorometaxylenol, 3-methyl-4-isopropyl-phenol or the allyl isothiocyanate mould inhibitor one or more.
Contain in pine camphor, linalool, citronellol or the Eugenol antibiotic property spices one or more in the efficient mothproofing agent.
Contain the additive of being convenient to produce forming agent in the efficient mothproofing agent: little molecule inorganic silicon class material: the diatomite composition is SiO
2, kaolin; Imvite class material: by two-layer Si-O tetrahedron and one deck Al-O octahedron, the phyllosilicate crystal of composition; Organic polymer class material: PVA POLYPROPYLENE GLYCOL, CMC, starch material; Be used in combination above-mentioned one or both.
Efficient mothproofing agent can be powdery, graininess, sheet, spherical or block formulation.
Efficient mothproofing agent is seated in the sack or box that air-permeable paper, nonwoven, film with gas permeability make.
The invention has the beneficial effects as follows: pyrethrins onset speed is fast, and moth is had significant killing effect, has not only remedied the shortcoming of camphor mothproofing agent, can also reduce input amount greatly, and is safer and more effective.
Camphor and pyrethrins do not possess the effect of mildew-resistant, add mould inhibitor in its mixture, and the effect of mildew-resistant can be arranged again in mothproof.
Embodiment:
The normal temperature volatility pyrethroid that adopts among the present invention, as empenthrin (1-acetenyl-2-methyl-2-pentenyl-2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound), in addition, also can select the trans alkynes valerate (dextrorotation-trans-2 of dextrorotation for use, 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid (E)-1-acetenyl-2-methyl-penta-2-alkenyl esters), allethrin (d1-3-pi-allyl-2-methyl-4-oxygen base-2-cyclobutyl d1-cis/anti--chrysanthemate), resmethrin (5-benzyl-3-furyl methyl (1RS)-anti--chrysanthemate), permethrin (3-phenol benzyl (1RS)-cis, instead-3-(2,2-vinyl chloride)-2-dimethyl-cycloprothrin), Etofenprox (2-(the different oxygen phenyl of 4-)-2-methyl-propyl-3-phenol benzyl ether), tetramethrin (1,3,4,5,6,7-cyclohexane-1,3-dioxy base-2-isoindolyl methyl (+)-cis/anti--chrysanthemate), PH (5-(2-propargyl)-3-furyl methyl chrysanthemate), Phenothrin (3-phenol benzyl d-cis/anti--chrysanthemate), prallethrin ((±)-2-methyl-4-oxygen base-3-(2-ethene)-2-cyclobutyl-(±)-cis/anti--chrysanthemate), transfluthrin (2,3,4,5-phenyl tetrafluoride methyl 1R-anti--2,2-dimethyl-3-(2, the 2-DCBP) cycloprothrin), third Flumethrin (2,3,5,6-tetrafluoro-4-methylbenzene methyl 3-(1-acrylic)-2,2-dimethyl cycloprothrin), methoxy benzyl Flumethrin (2,3,5,6-tetrafluoro-4-methoxy benzyl 3-(1-acrylic)-2,2-dimethyl cycloprothrin) etc.But be not limited to these.In addition, when optical isomer that produces owing to the asymmetric carbon atom in the chemical constitution or the geometric isomer due to two key exist, separately isomer separately or any mixture be also contained among the present invention.
Can suitably add antibiotic property spices such as pine camphor, linalool, citronellol, Eugenol among the present invention, mould inhibitors such as o-phenyl phenol, parachlorometaxylenol, 3-methyl-4-isopropyl-phenol, allyl isothiocyanate, colouring agents etc. become multiduty mothproofing agent.
The mould inhibitor that adopts among the present invention has, and p-hydroxybenzoate, thymol, faces phenyl phenol, triclosan etc.But be not limited to these.
Among the present invention for the ease of the production moulding, other additives that can add, as to select little molecule inorganic silicon class material for use can be that the diatomite composition is SiO
2, kaolin, imvite class material are by two-layer Si-O tetrahedron and one deck Al-O octahedron, the phyllosilicate crystal of composition.Organic polymer class Substance P VA POLYPROPYLENE GLYCOL, CMC, materials such as starch, above-mentioned one or more the additive of use also capable of being combined is made into formulations such as powdery, graininess, sheet, spherical, bulk.
Among the present invention, ooze out the pollution that causes, guarantee the volatile quantity of mothproof composition simultaneously, sack or the box that can make by air-permeable paper, ventilative nonwoven, ventilative plastic film in the medicament external packing in order to prevent medicament.
Below the present invention is described in further details, but the present invention is not limited to this.
Embodiment 1
When stirring powdery camphor, slowly add empenthrin, treat that two kinds of raw materials mix the back and are packaged in the sack that ventilative plastic film makes according to certain grammes per square metre, be suspended on sack in the wardrobe or be placed in the collecting bag.If when mixing, add anti-enzyme agent such as a certain amount of triclosan, can also play the effect of mothproof, anti-enzyme economic benefits and social benefits unification.
Embodiment 2
On the basis of embodiment 1, add additive such as CMC and play skeleton function, make mixed material production and processing to become different shape.
Claims (8)
1. an efficient mothproofing agent is characterized in that: contain two kinds of working substances that play mothproof effect that can volatilize at normal temperatures at least and mix; And contain working substance with antimildew function.
2. efficient mothproofing agent according to claim 1 is characterized in that: have the mixture of mothproof function, be mixing of mothproofing agents such as camphor or paracide and pyrethrins.
3. according to the efficient mothproofing agent described in the claim 2, it is characterized in that: pyrethrins is an empenthrin.
4. according to the efficient mothproofing agent described in the claim 1, it is characterized in that: have the working substance of antimildew function to be: p-hydroxybenzoate, thymol, face in phenyl phenol, triclosan, o-phenyl phenol, parachlorometaxylenol, 3-methyl-4-isopropyl-phenol or the allyl isothiocyanate mould inhibitor one or more.
5. according to the efficient mothproofing agent described in claim 1 or 2 or 3 or 4, it is characterized in that: contain in pine camphor, linalool, citronellol or the Eugenol antibiotic property spices one or more in the efficient mothproofing agent.
6. according to claim 1 or 2 or 3 or 4 described efficient mothproofing agents, it is characterized in that: contain the additive of being convenient to produce forming agent in the efficient mothproofing agent: little molecule inorganic silicon class material: the diatomite composition is SiO
2, kaolin; Imvite class material: by two-layer Si-O tetrahedron and one deck Al-O octahedron, the phyllosilicate crystal of composition; Organic polymer class material: PVA POLYPROPYLENE GLYCOL, CMC, starch material; Be used in combination above-mentioned one or both.
7. according to the described efficient mothproofing agent of claim 6, it is characterized in that: efficient mothproofing agent is powdery, graininess, sheet, spherical or block formulation.
8. according to the efficient mothproofing agent described in the claim 7, it is characterized in that efficient mothproofing agent is seated in the sack or box that air-permeable paper, nonwoven, film with gas permeability make.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910245196XA CN102113523A (en) | 2009-12-30 | 2009-12-30 | High-efficiency mothproofing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910245196XA CN102113523A (en) | 2009-12-30 | 2009-12-30 | High-efficiency mothproofing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102113523A true CN102113523A (en) | 2011-07-06 |
Family
ID=44212545
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910245196XA Pending CN102113523A (en) | 2009-12-30 | 2009-12-30 | High-efficiency mothproofing agent |
Country Status (1)
| Country | Link |
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| CN (1) | CN102113523A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352554A (en) * | 2011-07-29 | 2012-02-15 | 苏州卡奇特纺织有限公司 | Mildew preventive for pure silk fabrics |
| CN102792967A (en) * | 2012-08-30 | 2012-11-28 | 源达日化(天津)有限公司 | Normal-temperature mothproofing agent product |
| CN102812966A (en) * | 2012-08-30 | 2012-12-12 | 源达日化(天津)有限公司 | Normal-temperature insect repellent |
| CN104082351A (en) * | 2014-06-03 | 2014-10-08 | 北京化工大学 | Anti-moth agent taking mikania micrantha as carrier and preparation method thereof |
| EP2787817B1 (en) | 2011-12-06 | 2015-09-30 | Unilever N.V. | Microbicidal composition |
| CN108739868A (en) * | 2018-05-30 | 2018-11-06 | 陕西杨凌陕特农业发展有限公司 | A kind of production method of camphor ball |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1047337A (en) * | 1990-04-25 | 1990-11-28 | 杨大魁 | Dry washing agent resisting worm-eating and mildew and preparation method thereof |
| CN1058627A (en) * | 1990-08-03 | 1992-02-12 | 海杰 | Anti-moth paper |
| JPH05170267A (en) * | 1991-12-18 | 1993-07-09 | Okura Ind Co Ltd | Cleaning bag |
| JP2941435B2 (en) * | 1990-12-05 | 1999-08-25 | 日本製紙株式会社 | Precious wood veneered wood flooring that releases the essential oil for a long time |
| CN1242947A (en) * | 1999-08-04 | 2000-02-02 | 中国科学院昆明植物研究所 | Anti-mildew repellent pesticide and preparation method thereof |
| CN1593145A (en) * | 2004-06-24 | 2005-03-16 | 刘静芳 | Mothproof mildew preventive mixture |
| CN101130928A (en) * | 2006-08-25 | 2008-02-27 | 高德康 | Multifunctional eiderdown finishing agent |
-
2009
- 2009-12-30 CN CN200910245196XA patent/CN102113523A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1047337A (en) * | 1990-04-25 | 1990-11-28 | 杨大魁 | Dry washing agent resisting worm-eating and mildew and preparation method thereof |
| CN1058627A (en) * | 1990-08-03 | 1992-02-12 | 海杰 | Anti-moth paper |
| JP2941435B2 (en) * | 1990-12-05 | 1999-08-25 | 日本製紙株式会社 | Precious wood veneered wood flooring that releases the essential oil for a long time |
| JPH05170267A (en) * | 1991-12-18 | 1993-07-09 | Okura Ind Co Ltd | Cleaning bag |
| CN1242947A (en) * | 1999-08-04 | 2000-02-02 | 中国科学院昆明植物研究所 | Anti-mildew repellent pesticide and preparation method thereof |
| CN1593145A (en) * | 2004-06-24 | 2005-03-16 | 刘静芳 | Mothproof mildew preventive mixture |
| CN101130928A (en) * | 2006-08-25 | 2008-02-27 | 高德康 | Multifunctional eiderdown finishing agent |
Non-Patent Citations (2)
| Title |
|---|
| 万国林，等: "防霉驱虫剂对档案库空气质量的影响", 《环境与健康杂志》 * |
| 朱艳静，等: "几种挥发性药物的防霉防蛀效果试验", 《工业微生物》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352554A (en) * | 2011-07-29 | 2012-02-15 | 苏州卡奇特纺织有限公司 | Mildew preventive for pure silk fabrics |
| EP2787817B1 (en) | 2011-12-06 | 2015-09-30 | Unilever N.V. | Microbicidal composition |
| CN102792967A (en) * | 2012-08-30 | 2012-11-28 | 源达日化(天津)有限公司 | Normal-temperature mothproofing agent product |
| CN102812966A (en) * | 2012-08-30 | 2012-12-12 | 源达日化(天津)有限公司 | Normal-temperature insect repellent |
| CN104082351A (en) * | 2014-06-03 | 2014-10-08 | 北京化工大学 | Anti-moth agent taking mikania micrantha as carrier and preparation method thereof |
| CN108739868A (en) * | 2018-05-30 | 2018-11-06 | 陕西杨凌陕特农业发展有限公司 | A kind of production method of camphor ball |
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Application publication date: 20110706 |