CN102229272A - Production process flow and formula of novel TPU (Thermoplastic Polyurethane) synthetic leather - Google Patents
Production process flow and formula of novel TPU (Thermoplastic Polyurethane) synthetic leather Download PDFInfo
- Publication number
- CN102229272A CN102229272A CN2011101031268A CN201110103126A CN102229272A CN 102229272 A CN102229272 A CN 102229272A CN 2011101031268 A CN2011101031268 A CN 2011101031268A CN 201110103126 A CN201110103126 A CN 201110103126A CN 102229272 A CN102229272 A CN 102229272A
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- synthetic leather
- dry method
- parts
- quality proportioning
- resin
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002649 leather substitute Substances 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 229920002803 thermoplastic polyurethane Polymers 0.000 title abstract description 14
- 239000004433 Thermoplastic polyurethane Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 claims abstract description 45
- 239000004831 Hot glue Substances 0.000 claims abstract description 8
- 239000004033 plastic Substances 0.000 claims abstract description 6
- 229920003023 plastic Polymers 0.000 claims abstract description 6
- 239000004814 polyurethane Substances 0.000 claims description 19
- 229920005989 resin Polymers 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 239000008187 granular material Substances 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 4
- 239000011888 foil Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000002344 surface layer Substances 0.000 claims description 3
- 230000004927 fusion Effects 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 239000002904 solvent Substances 0.000 abstract description 7
- 238000009958 sewing Methods 0.000 abstract description 3
- 238000005520 cutting process Methods 0.000 abstract description 2
- 239000012943 hotmelt Substances 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract 1
- 239000002985 plastic film Substances 0.000 abstract 1
- 229920006255 plastic film Polymers 0.000 abstract 1
- 239000010409 thin film Substances 0.000 abstract 1
- 210000003462 vein Anatomy 0.000 abstract 1
- 239000002759 woven fabric Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 9
- 239000004744 fabric Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 4
- 239000010985 leather Substances 0.000 description 4
- 238000007605 air drying Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011265 semifinished product Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Images
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- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to a production process flow and formula of novel TPU (Thermoplastic Polyurethane) synthetic leather. Vein colors of the surface of the novel TPU synthetic leather produced by using the invention are as rich as that of the conventional synthetic leather; hot melt adhesive on the back is protected by a plastic thin film; during the use, after the plastic film is removed, the unique hot melt adhesive is combined with a high-frequency hot-cutting process and can be perfectly combined with the surfaces of a mesh, a woven fabric and ordinary synthetic leather, so that the quality is more stable, the sense of quality is stronger and the labour-intensive sewing process during the use of the conventional synthetic leather is reduced; meanwhile, no solvent needs to be used in the hot melt jointing process, so that the pollution to the environment is reduced.
Description
Technical field
The present invention relates to a kind of synthetic leather technological process of production and prescription, particularly a kind of new TP U synthetic leather technological process of production and prescription.
Background technology
Current, the synthetic leather product is just becoming following fashion trend, is widely used in every field such as clothes, case and bag, suitcase, furniture, footwear.General PU synthetic leather normally is laminated to the lamellar product that compositions such as nonwoven, looped fabric, weaving cloth or woven cloth form by polyurethane resin composition, its structure comprises base cloth and attached to the polyurethane resin top layer on the base cloth, the top layer is mainly risen to decorate and outward appearance is reached and imitated a natural skin effect of removing from office; General synthetic leather in use all adopts to be sewed up or solvent lamination technology, and at serious day by day present of recruitment famine, labor-intensive sewing process is unfavorable for the development of enterprise; And the glue that conventional laminating type adopts contains organic solvent, is unfavorable for the protection of environment.The objective of the invention is to develop a kind of new TP U synthetic leather, make synthetic leather adopt seamless applying technology in using, avoided the environmental pollution that solvent evaporates caused after solvent uses again.
Summary of the invention
Technical problem to be solved by this invention is to overcome above technical bottleneck, and a kind of new TP U synthetic leather technological process of production and prescription are provided.
For solving the problems of the technologies described above, the present invention realizes as follows:
A kind of new TP U synthetic leather technological process of production of the present invention and prescription, it is characterized in that this technological process of production comprises the steps: at first to choose dystectic TPU film and more low-melting hot-melt adhesive granules, again hot-melt adhesive granules is heated to the liquid condition of complete fusion, evenly be coated on the TPU film back side, to be cooled plaing to a certain degree back compound upward PE plastic foil protected the PUR effect, makes TPU synthetic leather half product; Make new TP U synthetic leather through dry method PU surfacing process again.
Good effect of the present invention: a kind of new TP U synthetic leather technological process of production of the present invention and prescription, the new TP U synthetic leather surface pattern color of utilizing the present invention to make is the same with conventional synthetic leather abundant.Back side PUR is protected by plastic sheeting, in use remove plastic foil after, exclusive PUR is in conjunction with the high frequency heat cutting process, can be with screen cloth, weave cotton cloth and common synthetic leather surface perfect adaptation, quality is more stable, product texture is stronger.Reduce the labour-intensive sewing process in the conventional synthetic leather use, in the hot melt attaching process, need not to use any solvent simultaneously, reduced environmental pollution.
Description of drawings
The present invention is further detailed explanation below in conjunction with the drawings and specific embodiments.
Fig. 1 is the half-finished technological process of production figure of TPU of the present invention
Fig. 2 is a TPU finished product leather process chart of the present invention
The specific embodiment
As shown in Figure 1 and Figure 2, a kind of new TP U synthetic leather technological process of production of the present invention and prescription, its technological process of production is:
Phase I: the technological process of production of TPU semi-finished product base
Select for use fusing point to be higher than 180 ℃ TPU film and the hot-melt adhesive granules of fusing point about about 100 ℃, hot-melt adhesive granules is heated to complete molten condition, evenly be coated on the TPU film back side, be cooled to the compound 0.2-0.3mm thickness PE plastic foil of going up in about about 60 ℃ backs and play the effect of protection PUR, make TPU synthetic leather half product; The thermosol consumption is 50-100g/m
2
Second stage: the technological process of finished product leather
Use the PU resin dissolves in DMF and MEK solvent the dry method lining, preparation dry method surface layer PU mixed liquor; Select for use the dry method adhesive linkage of adhesion strength excellence to use the PU resin dissolves in the MEK solvent, preparation dry method adhesive linkage mixed liquor; With the blade coating mode with dry method lining mixed liquor with (120～180) g/m
2Consumption is coated on the release liners, through 60～80 ℃ heated-air drying, cools off 1～2 minute, gives leather surface lines and color; On epidermal area, apply (150～200) g/m again
2Mixed solution of adhesive layer, prebake after 1 minute is sticked the semi-finished product base, control patch pressure is about 4～6kg/cm2; Carry out release liners after 5 minutes with 60～80 ℃ of heated-air dryings and peel off, the product after peeling off is the finished product leather.Line speed is controlled at 6-8/min.
The dry method lining prescription quality ratio of described second stage is:
Dry method surface layer PU resin: 100 parts
DMF:40～60 part
MEK:40～60 part
Toner: 8～12 parts
Consumption: 120-180g/m
2
The dry method tack coat prescription of described second stage is:
Dry method adhesive linkage PU resin: 100 parts;
MEK:40～60 part;
Consumption: 150-200g/m
2
The proportioning of the best dry method lining prescription of described second stage is:
Dry method lining PU resin: 100 parts;
DMF:40 part;
MEK:40 part;
Toner: 10 parts;
Consumption: 140g/m
2
The proportioning of the best dry method tack coat prescription of described second stage is:
Dry method bonding material PU resin: 100 parts;
MEK:60 part;
Consumption: 200g/m
2
Claims (3)
1. new TP U synthetic leather technological process of production, it is characterized in that: this technological process of production comprises the steps: at first to choose dystectic TPU film and more low-melting hot-melt adhesive granules, again hot-melt adhesive granules is heated to the liquid condition of complete fusion, evenly be coated on the TPU film back side, to be cooled plaing to a certain degree back compound upward PE plastic foil protected the PUR effect, makes TPU synthetic leather half product; Make new TP U synthetic leather through dry method PU surfacing process again.
2. new TP U synthetic leather is characterized in that the quality proportioning of component is:
Dry method lining prescription quality proportioning is:
Dry method surface layer PU resin: 100 parts
DMF:40～60 part
MEK:40～60 part
Toner: 8～12 parts
Consumption: 120-180g/m
2
Dry method tack coat prescription quality proportioning is:
Dry method adhesive linkage PU resin: 100 parts
MEK:40～60 part
Consumption: 150-200g/m
2
3. a kind of new TP U synthetic leather according to claim 2 is characterized in that the best in quality proportioning of component is:
The quality proportioning of best dry method lining prescription is:
Dry method lining PU resin: 100 parts
DMF:40 part
MEK:40 part
Toner: 10 parts
Consumption: 140g/m
2
The quality proportioning of best dry method tack coat prescription is:
Dry method bonding material PU resin: 100 parts
MEK:60 part
Consumption: 200g/m
2
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101031268A CN102229272A (en) | 2011-04-25 | 2011-04-25 | Production process flow and formula of novel TPU (Thermoplastic Polyurethane) synthetic leather |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101031268A CN102229272A (en) | 2011-04-25 | 2011-04-25 | Production process flow and formula of novel TPU (Thermoplastic Polyurethane) synthetic leather |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102229272A true CN102229272A (en) | 2011-11-02 |
Family
ID=44841896
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011101031268A Pending CN102229272A (en) | 2011-04-25 | 2011-04-25 | Production process flow and formula of novel TPU (Thermoplastic Polyurethane) synthetic leather |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102229272A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102493216A (en) * | 2011-12-26 | 2012-06-13 | 李其树 | TPU leather and preparation method thereof |
| CN102535187A (en) * | 2012-01-06 | 2012-07-04 | 福建兰峰制革有限公司 | Production method of crease-free microfiber mirror-surface synthetic leather |
| CN102941696A (en) * | 2012-11-29 | 2013-02-27 | 泉州万华世旺超纤有限责任公司 | Thermal compounding polyurethane thin film and preparation method thereof |
| CN103507379A (en) * | 2012-06-27 | 2014-01-15 | 昆山协润人造皮有限公司 | Preparation method of double-sided leather |
| CN103568387A (en) * | 2013-10-08 | 2014-02-12 | 东莞市雄林新材料科技有限公司 | Wet-type PU (polyurethane) thin film attached with TPU (thermoplastic polyurethane) thin film |
| CN103568450A (en) * | 2012-07-27 | 2014-02-12 | 昆山协润人造皮有限公司 | Manufacturing method of environmental-protection polyurethane wall paper |
| CN104141240A (en) * | 2013-05-10 | 2014-11-12 | 昆山协孚人造皮有限公司 | Environmentally friendly office furniture paper PU production method |
| CN104233843A (en) * | 2014-09-10 | 2014-12-24 | 桐乡市龙翔纺织有限责任公司 | Production process of PU transfer coating leather |
| CN104594065A (en) * | 2015-02-04 | 2015-05-06 | 安安(中国)有限公司 | Method for producing jacquard synthetic leather |
| CN105133372A (en) * | 2015-09-29 | 2015-12-09 | 安徽安利材料科技股份有限公司 | Preparation method of polyurethane synthetic leather used for TPU electronic packages and stationery certificates |
| CN105401459A (en) * | 2015-10-26 | 2016-03-16 | 鹤山市新科达企业有限公司 | Dry-process synthetic leather and preparation method thereof |
| CN106120364A (en) * | 2016-08-30 | 2016-11-16 | 安徽安利材料科技股份有限公司 | A kind of manufacture method of TPU sports play shoes Synthetic Leather |
| CN109624422A (en) * | 2018-11-05 | 2019-04-16 | 安徽安利材料科技股份有限公司 | A kind of TPU high/low temperature film composite webs and preparation method thereof |
| CN114082622A (en) * | 2021-08-04 | 2022-02-25 | 安徽安利材料科技股份有限公司 | TPU composite material and preparation method and application thereof |
| CN114683662A (en) * | 2022-04-15 | 2022-07-01 | 泉州市星达鞋服材料有限公司 | TPU film for hot stamping of clothes and production process thereof |
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| CN1709694A (en) * | 2004-06-17 | 2005-12-21 | 金技五 | Nature fur adhered with fabric or artificial leather |
| CN201036678Y (en) * | 2007-05-18 | 2008-03-19 | 赵国胜 | Improved structure of handle belt |
| CN101545212A (en) * | 2009-04-30 | 2009-09-30 | 江苏东泰聚合材料有限公司 | Hydrolysis resistance chemical leather and manufacturing method thereof |
| CN201346898Y (en) * | 2008-12-09 | 2009-11-18 | 梁坤焕 | Decorative film |
| CN101586311A (en) * | 2009-05-07 | 2009-11-25 | 安安(中国)有限公司 | Production process of environmental protection PU composite leather and formula thereof |
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2011
- 2011-04-25 CN CN2011101031268A patent/CN102229272A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1709694A (en) * | 2004-06-17 | 2005-12-21 | 金技五 | Nature fur adhered with fabric or artificial leather |
| CN201036678Y (en) * | 2007-05-18 | 2008-03-19 | 赵国胜 | Improved structure of handle belt |
| CN201346898Y (en) * | 2008-12-09 | 2009-11-18 | 梁坤焕 | Decorative film |
| CN101545212A (en) * | 2009-04-30 | 2009-09-30 | 江苏东泰聚合材料有限公司 | Hydrolysis resistance chemical leather and manufacturing method thereof |
| CN101586311A (en) * | 2009-05-07 | 2009-11-25 | 安安(中国)有限公司 | Production process of environmental protection PU composite leather and formula thereof |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102493216A (en) * | 2011-12-26 | 2012-06-13 | 李其树 | TPU leather and preparation method thereof |
| CN102535187A (en) * | 2012-01-06 | 2012-07-04 | 福建兰峰制革有限公司 | Production method of crease-free microfiber mirror-surface synthetic leather |
| CN103507379A (en) * | 2012-06-27 | 2014-01-15 | 昆山协润人造皮有限公司 | Preparation method of double-sided leather |
| CN103507379B (en) * | 2012-06-27 | 2015-12-02 | 昆山协润人造皮有限公司 | Two-sided leather preparation method |
| CN103568450B (en) * | 2012-07-27 | 2016-02-24 | 昆山协润人造皮有限公司 | Environmental-protecpolyurethane polyurethane wall paper preparation method |
| CN103568450A (en) * | 2012-07-27 | 2014-02-12 | 昆山协润人造皮有限公司 | Manufacturing method of environmental-protection polyurethane wall paper |
| CN102941696A (en) * | 2012-11-29 | 2013-02-27 | 泉州万华世旺超纤有限责任公司 | Thermal compounding polyurethane thin film and preparation method thereof |
| CN104141240A (en) * | 2013-05-10 | 2014-11-12 | 昆山协孚人造皮有限公司 | Environmentally friendly office furniture paper PU production method |
| CN103568387A (en) * | 2013-10-08 | 2014-02-12 | 东莞市雄林新材料科技有限公司 | Wet-type PU (polyurethane) thin film attached with TPU (thermoplastic polyurethane) thin film |
| CN103568387B (en) * | 2013-10-08 | 2016-04-06 | 东莞市雄林新材料科技股份有限公司 | Wet-type PU sticks on TPU film |
| CN104233843A (en) * | 2014-09-10 | 2014-12-24 | 桐乡市龙翔纺织有限责任公司 | Production process of PU transfer coating leather |
| CN104594065B (en) * | 2015-02-04 | 2017-03-22 | 安安(中国)有限公司 | Method for producing jacquard synthetic leather |
| CN104594065A (en) * | 2015-02-04 | 2015-05-06 | 安安(中国)有限公司 | Method for producing jacquard synthetic leather |
| CN105133372A (en) * | 2015-09-29 | 2015-12-09 | 安徽安利材料科技股份有限公司 | Preparation method of polyurethane synthetic leather used for TPU electronic packages and stationery certificates |
| CN105133372B (en) * | 2015-09-29 | 2017-04-19 | 安徽安利材料科技股份有限公司 | Preparation method of polyurethane synthetic leather used for TPU electronic packages and stationery certificates |
| CN105401459A (en) * | 2015-10-26 | 2016-03-16 | 鹤山市新科达企业有限公司 | Dry-process synthetic leather and preparation method thereof |
| CN106120364A (en) * | 2016-08-30 | 2016-11-16 | 安徽安利材料科技股份有限公司 | A kind of manufacture method of TPU sports play shoes Synthetic Leather |
| CN109624422A (en) * | 2018-11-05 | 2019-04-16 | 安徽安利材料科技股份有限公司 | A kind of TPU high/low temperature film composite webs and preparation method thereof |
| CN109624422B (en) * | 2018-11-05 | 2021-04-20 | 安徽安利材料科技股份有限公司 | TPU high-low temperature film composite mesh cloth and preparation method thereof |
| CN114082622A (en) * | 2021-08-04 | 2022-02-25 | 安徽安利材料科技股份有限公司 | TPU composite material and preparation method and application thereof |
| CN114683662A (en) * | 2022-04-15 | 2022-07-01 | 泉州市星达鞋服材料有限公司 | TPU film for hot stamping of clothes and production process thereof |
| CN114683662B (en) * | 2022-04-15 | 2024-04-26 | 泉州市星达鞋服材料有限公司 | TPU film for garment thermoprinting and production process thereof |
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Application publication date: 20111102 |