CN102242533A - Method for preparing grease resistant food wrapping paper - Google Patents
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Abstract
本发明公开了一种抗油脂食品包装纸的制备方法,该制备方法包括如下步骤:抗油脂涂料的配制、真空脱气、2~10g/m2涂布与60~110℃烘干各步骤,在抗油脂涂料粗料中,壳聚糖的重量百分含量控制在0.5%~10%,而且,配成的抗油脂涂料粗品中,壳聚糖的重量百分含量为0.5%~10%,乙酸的体积百分含量为0.5%~10%;海藻酸钠的重量百分含量为0.1%~10%;本发明方法得到的抗油脂食品包装纸,其抗油脂值为8~11,本发明方法得到的抗油脂食品包装纸具有成本低、环保、抗油抗水性能好、无毒害等优点。The invention discloses a preparation method of grease-resistant food packaging paper. The preparation method comprises the following steps: preparation of grease-resistant coating, vacuum degassing, coating at 2-10g/ m2 and drying at 60-110°C. In the anti-grease coating crude material, the weight percentage of chitosan is controlled at 0.5% to 10%, and in the prepared anti-grease coating crude product, the weight percentage of chitosan is 0.5% to 10%, The volume percentage of acetic acid is 0.5% to 10%; the weight percentage of sodium alginate is 0.1% to 10%; the oil resistance food wrapping paper obtained by the method of the present invention has an oil resistance value of 8 to 11. The grease-resistant food wrapping paper obtained by the method has the advantages of low cost, environmental protection, good oil and water resistance, non-toxicity and the like.
Description
技术领域 technical field
本发明公开了一种抗油脂食品包装纸的制备方法,属于涂布包装纸制备技术领域。The invention discloses a preparation method of oil-resistant food wrapping paper, which belongs to the technical field of coating wrapping paper preparation.
背景技术 Background technique
在食品包装领域,特别是对于一些油性物品的包装,大多数生产厂家倾向于采用塑料作为原材料。但由于在垃圾的处理过程中,塑料填埋后很难分解,并且焚烧后释放出有毒气体。开发可降解塑料就成为当前科技攻关的重点。但由于材料和技术问题,当前的可降解塑料仍无法完全降解,且成本较高,因而尚未投入大规模的生产和使用。In the field of food packaging, especially for the packaging of some oily items, most manufacturers tend to use plastics as raw materials. However, in the process of garbage disposal, plastics are difficult to decompose after being landfilled, and toxic gases are released after incineration. The development of degradable plastics has become the focus of current scientific and technological research. However, due to material and technical problems, the current degradable plastics still cannot be completely degraded, and the cost is high, so they have not yet been put into large-scale production and use.
目前有利用天然生物材料如大豆蛋白制得的可降解食品包装膜用于油性食品包装,但可食性包装在商业上应用还不够广泛,还不能取代合成高分子塑料薄膜,其原因主要是膜的机械性能差,天然的可食性高分子材料本身具有亲水性,其阻湿性有限,同时其包装热封性和可印刷性等问题还有待解决。At present, there are degradable food packaging films made of natural biological materials such as soybean protein for oily food packaging, but edible packaging is not widely used commercially and cannot replace synthetic polymer plastic films. The mechanical properties are poor, and the natural edible polymer material itself is hydrophilic, and its moisture resistance is limited. At the same time, the problems of its packaging heat sealability and printability have yet to be resolved.
中国专利201495453U公布的防油食品包装纸,包括面纸层、底纸层、3层芯纸层,且芯层之间隔压有防水膜层和防油膜层,面纸层及底纸层均覆盖有施胶剂层。公开号为CN201201764X的专利提供了一种食品包装用防油卡纸。这种防油卡纸由面涂布层、衬层、芯层、底层和防油层构成,防油层为含氟防油剂。以上专利中的防油纸未能提供单层纸基的包装纸的防油性能,且成本高、生产复杂。The oil-proof food packaging paper announced by Chinese patent 201495453U includes a face paper layer, a back paper layer, and a three-layer core paper layer, and a waterproof film layer and an oil-proof film layer are pressed between the core layers, and the face paper layer and the back paper layer are covered. There is a sizing agent layer. The patent whose publication number is CN201201764X provides a kind of oil-proof cardboard for food packaging. The oil-proof cardboard is composed of a surface coating layer, a lining layer, a core layer, a bottom layer and an oil-proof layer, and the oil-proof layer is a fluorine-containing oil-proof agent. The oil-proof paper in the above patents fails to provide the oil-proof performance of the single-layer paper-based wrapping paper, and the cost is high and the production is complicated.
碳氟化合物涂布能提高抗油脂性,被用于生产抗油包装纸,但碳氟化合物价格太高、对人体有害且会改变食物风味,不宜用于食品包装材料中。Fluorocarbon coating can improve the oil resistance and is used to produce oil-resistant packaging paper, but fluorocarbons are too expensive, harmful to the human body and will change the flavor of food, so they are not suitable for use in food packaging materials.
壳聚糖和纸都是环保型材料、可完全降解,从根本上解决环境污染问题。壳聚糖对食品中的钙表现出螯合性能,不会降低食品的营养价值,壳聚糖还具有抗菌性和抗油脂性。海藻酸钠属于天然高分子材料,并具有生物可降解性、无毒性、来源广、成膜性、抗油脂性和价格便宜的优势。Both chitosan and paper are environmentally friendly materials that can be completely degraded, fundamentally solving the problem of environmental pollution. Chitosan exhibits chelating properties for calcium in food without reducing the nutritional value of food. Chitosan also has antibacterial and anti-oil properties. Sodium alginate is a natural polymer material, and has the advantages of biodegradability, non-toxicity, wide source, film-forming property, oil resistance and cheap price.
发明内容 Contents of the invention
本发明的目的是克服现有技术中存在的不足,提供一种成本低、环保、抗油抗水性能好、无毒害、并达到不影响食品风味的抗油脂食品包装纸的制备方法。The purpose of the present invention is to overcome the deficiencies in the prior art and provide a method for preparing grease-resistant food wrapping paper that is low in cost, environmentally friendly, good in oil and water resistance, non-toxic, and does not affect food flavor.
按照本发明提供的技术方案,所述抗油脂食品包装纸的制备方法包括如下步骤:According to the technical scheme provided by the present invention, the preparation method of the anti-grease food packaging paper comprises the following steps:
抗油脂涂料的配制:将壳聚糖、乙酸和海藻酸钠溶解在去离子水中并搅拌均匀,配成抗油脂涂料粗品,在抗油脂涂料粗料中,壳聚糖的重量百分含量控制在0.5%~10%,乙酸的体积百分含量控制在0.5%~10%;海藻酸钠的重量百分含量控制在0.1%~10%;Preparation of anti-grease coating: dissolving chitosan, acetic acid and sodium alginate in deionized water and stirring evenly to make the crude product of anti-grease coating, in the crude material of anti-grease coating, the weight percentage of chitosan is controlled at 0.5% to 10%, the volume percentage of acetic acid is controlled at 0.5% to 10%; the weight percentage of sodium alginate is controlled at 0.1% to 10%;
真空脱气:将配成的抗油脂涂料粗料经真空脱气得到制成抗油脂涂料成品;真空脱气的真空度为0.02-0.05MPa;Vacuum degassing: The finished anti-grease coating is obtained by vacuum degassing the crude anti-grease coating material; the vacuum degree of vacuum degassing is 0.02-0.05MPa;
涂布:选择60~90g/m2的包装原纸,将抗油脂涂料成品在包装原纸的一面进行涂布,抗油脂涂料成品的涂布量为2~10g/m2,得到抗油脂食品包装纸湿料;Coating: Select 60-90g/ m2 of packaging base paper, and coat the finished grease-resistant coating on one side of the packaging base paper. The coating amount of the finished grease-resistant coating is 2-10g/ m2 to obtain grease-resistant food packaging paper wet material;
烘干:将抗油脂食品包装纸湿料放入温度为60~110℃的烘箱中烘烤2~5分钟,得到抗油脂食品包装纸干料。Drying: Put the wet material of the anti-grease food wrapping paper into an oven at a temperature of 60-110°C and bake for 2-5 minutes to obtain the dry material of the anti-grease food wrapping paper.
本发明方法得到的抗油脂食品包装纸,其抗油脂值为6~11,本发明方法得到的抗油脂食品包装纸具有成本低、环保、抗油抗水性能好、无毒害等优点。The oil-resistant food wrapping paper obtained by the method of the invention has an oil-resistant value of 6-11, and the oil-resistant food wrapping paper obtained by the method of the invention has the advantages of low cost, environmental protection, good oil and water resistance, non-toxicity, and the like.
具体实施方式 Detailed ways
下面结合具体实施例对本发明作进一步说明。The present invention will be further described below in conjunction with specific examples.
实施例1Example 1
抗油脂涂料的配制:将5克壳聚糖、5ml乙酸和20克海藻酸钠溶解在去离子水中并搅拌均匀,配成1000ml(约合1000克)抗油脂涂料粗品,在抗油脂涂料粗料中,壳聚糖的重量百分含量控制在0.5%,乙酸的体积百分含量控制在0.5%;海藻酸钠的重量百分含量控制在2%;Preparation of anti-grease coating: Dissolve 5 grams of chitosan, 5 ml of acetic acid and 20 grams of sodium alginate in deionized water and stir evenly to make 1000ml (about 1000 grams) of anti-grease coating crude product. In, the weight percentage of chitosan is controlled at 0.5%, the volume percentage of acetic acid is controlled at 0.5%; the weight percentage of sodium alginate is controlled at 2%;
真空脱气:将配成的抗油脂涂料粗料使用真空脱气机经真空脱气得到制成抗油脂涂料成品;真空脱气的真空度为0.02-0.05MPa;Vacuum degassing: use a vacuum degasser to degas the coarse material of the anti-grease coating to obtain a finished anti-grease coating; the vacuum degree of vacuum degassing is 0.02-0.05MPa;
涂布:选择60~90g/m2的包装原纸,将抗油脂涂料成品在包装原纸的一面进行涂布,抗油脂涂料成品的涂布量为5g/m2,得到抗油脂食品包装纸湿料;Coating: Select 60-90g/ m2 of packaging base paper, and coat the finished grease-resistant coating on one side of the packaging base paper. The coating amount of the finished grease-resistant coating is 5g/ m2 to obtain a wet material of grease-resistant food packaging paper ;
烘干:将抗油脂食品包装纸湿料放入温度为80℃的可控温烘箱中烘烤3分钟,得到抗油脂食品包装纸干料。Drying: Put the wet material of the anti-grease food packaging paper into a temperature-controllable oven with a temperature of 80°C and bake for 3 minutes to obtain the dry material of the anti-grease food packaging paper.
得到的抗油脂食品包装纸干料采用国际通用测试方法[“油滴实验(oil kitTest-TAPPI T 559 pm-96)”]测得其抗油脂值为10。The obtained anti-grease food packaging paper dry material adopts the international general test method ["oil drop test (oil kitTest-TAPPI T 559 pm-96)"] to measure its anti-grease value of 10.
实施例2Example 2
抗油脂涂料的配制:将30克壳聚糖、20ml乙酸和1克海藻酸钠溶解在去离子水中并搅拌均匀,配成1000ml(约合1000克)抗油脂涂料粗品,在抗油脂涂料粗料中,壳聚糖的重量百分含量控制在3%,乙酸的体积百分含量控制在2%;海藻酸钠的重量百分含量控制在0.1%;Preparation of anti-grease coating: Dissolve 30 grams of chitosan, 20 ml of acetic acid and 1 gram of sodium alginate in deionized water and stir evenly to prepare 1000 ml (about 1000 grams) of anti-grease coating crude product. In, the weight percentage of chitosan is controlled at 3%, the volume percentage of acetic acid is controlled at 2%; the weight percentage of sodium alginate is controlled at 0.1%;
真空脱气:将配成的抗油脂涂料粗料使用真空脱气机经真空脱气得到制成抗油脂涂料成品;真空脱气的真空度为0.02-0.05MPa;Vacuum degassing: use a vacuum degasser to degas the coarse material of the anti-grease coating to obtain a finished anti-grease coating; the vacuum degree of vacuum degassing is 0.02-0.05MPa;
涂布:选择60~90g/m2的包装原纸,将抗油脂涂料成品在包装原纸的一面进行涂布,抗油脂涂料成品的涂布量为2g/m2,得到抗油脂食品包装纸湿料;Coating: Select 60-90g/ m2 of packaging base paper, and coat the finished grease-resistant coating on one side of the packaging base paper. The coating amount of the finished grease-resistant coating is 2g/ m2 to obtain a wet material of grease-resistant food packaging paper ;
烘干:将抗油脂食品包装纸湿料放入温度为60℃的可控温烘箱中烘烤5分钟,得到抗油脂食品包装纸干料。Drying: Put the wet material of the anti-grease food packaging paper into a temperature-controllable oven with a temperature of 60°C and bake for 5 minutes to obtain the dry material of the anti-grease food packaging paper.
得到的抗油脂食品包装纸干料采用国际通用测试方法[“油滴实验(oil kitTest-TAPPI T 559 pm-96)”]测得其抗油脂值为8。The obtained anti-grease food packaging paper dry material adopts the international general test method ["oil drop test (oil kitTest-TAPPI T 559 pm-96)"] to measure its anti-grease value of 8.
实施例3Example 3
抗油脂涂料的配制:将100克壳聚糖、100ml乙酸和100克海藻酸钠溶解在去离子水中并搅拌均匀,配成1000ml(约合1000克)抗油脂涂料粗品,在抗油脂涂料粗料中,壳聚糖的重量百分含量控制在10%,乙酸的体积百分含量控制在10%;海藻酸钠的重量百分含量控制在10%;Preparation of anti-grease coating: Dissolve 100g of chitosan, 100ml of acetic acid and 100g of sodium alginate in deionized water and stir evenly to make 1000ml (about 1000g) of crude anti-grease coating. In, the weight percentage of chitosan is controlled at 10%, the volume percentage of acetic acid is controlled at 10%; the weight percentage of sodium alginate is controlled at 10%;
真空脱气:将配成的抗油脂涂料粗料使用真空脱气机经真空脱气得到制成抗油脂涂料成品;真空脱气的真空度为0.02-0.05MPa;Vacuum degassing: use a vacuum degasser to degas the coarse material of the anti-grease coating to obtain a finished anti-grease coating; the vacuum degree of vacuum degassing is 0.02-0.05MPa;
涂布:选择60~90g/m2的包装原纸,将抗油脂涂料成品在包装原纸的一面进行涂布,抗油脂涂料成品的涂布量为10g/m2,得到抗油脂食品包装纸湿料;Coating: Select 60-90g/ m2 of packaging base paper, and coat the finished grease-resistant coating on one side of the packaging base paper. The coating amount of the finished grease-resistant coating is 10g/ m2 to obtain a wet material of grease-resistant food packaging paper ;
烘干:将抗油脂食品包装纸湿料放入温度为110℃的可控温烘箱中烘烤2分钟,得到抗油脂食品包装纸干料。Drying: Put the wet material of the anti-grease food packaging paper into a temperature-controllable oven with a temperature of 110°C and bake for 2 minutes to obtain the dry material of the anti-grease food packaging paper.
得到的抗油脂食品包装纸干料采用国际通用测试方法[“油滴实验(oil kitTest-TAPPI T 559 pm-96)”]测得其抗油脂值为11。The obtained anti-grease food packaging paper dry material adopts the international general test method ["oil drop test (oil kitTest-TAPPI T 559 pm-96)"] to measure its anti-grease value of 11.
本发明的实施例中,包装原纸的另一面可以使用食品包装纸生产领域常规的矿物涂料的进行涂布,常规的矿物涂料中可以使用碳酸钙、高岭土、滑石、瓷土和二氧化钛等颜料,可以从这些物质中适宜选择一种或两种以上;此外,常规的矿物涂料中还包含有分散剂与粘合剂等常用助剂。In an embodiment of the present invention, the other side of the packaging base paper can be coated with conventional mineral coatings in the field of food packaging paper production. Pigments such as calcium carbonate, kaolin, talc, china clay and titanium dioxide can be used in conventional mineral coatings, which can be obtained from It is suitable to select one or more than two of these substances; in addition, conventional mineral paints also contain commonly used additives such as dispersants and binders.
本发明中使用的可控温烘箱、真空脱气机均为常规设备。The temperature-controllable oven and the vacuum degasser used in the present invention are conventional equipment.
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| CN104718324A (en) * | 2012-10-10 | 2015-06-17 | 巴克曼实验室国际公司 | Immobilization of mineral oil in paper food packaging with laccase to prevent migration of mineral oil into food |
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| CN104718324A (en) * | 2012-10-10 | 2015-06-17 | 巴克曼实验室国际公司 | Immobilization of mineral oil in paper food packaging with laccase to prevent migration of mineral oil into food |
| CN104718324B (en) * | 2012-10-10 | 2016-11-09 | 巴克曼实验室国际公司 | Immobilization of mineral oil in paper food packaging with laccase to prevent migration of mineral oil into food |
| CN105518214A (en) * | 2013-09-05 | 2016-04-20 | 盟迪股份公司 | Food wrapping paper and manufacturing method thereof |
| CN103603233A (en) * | 2013-12-05 | 2014-02-26 | 福建希源纸业有限公司 | Food packaging paper and preparation method thereof |
| CN103603233B (en) * | 2013-12-05 | 2016-02-03 | 福建希源纸业有限公司 | A kind of food wrapper and preparation method thereof |
| CN104213473A (en) * | 2014-09-05 | 2014-12-17 | 浙江华川实业集团有限公司 | Mildew-proof antibacterial food packaging paper and preparation method thereof |
| CN106283855A (en) * | 2016-08-22 | 2017-01-04 | 惠州市海研检测技术有限公司 | A kind of biopolymer greaseproof and preparation method thereof |
| CN114316117A (en) * | 2020-09-30 | 2022-04-12 | 四川赛华睿科技有限责任公司 | Fluorine-free treating agent and oil-resistant paper product |
| CN114316117B (en) * | 2020-09-30 | 2023-09-26 | 四川赛华睿科技有限责任公司 | Fluorine-free treating agent and oil-proof paper product |
| WO2023088018A1 (en) * | 2021-11-16 | 2023-05-25 | 中国科学院理化技术研究所 | Aqueous coating having water-proof and oil-proof properties, preparation method therefor and application thereof |
| CN114086421A (en) * | 2021-12-10 | 2022-02-25 | 福州大学 | Fluorine-free waterproof and oil-proof agent and preparation method and application thereof |
| CN114990936A (en) * | 2022-06-21 | 2022-09-02 | 江南大学 | Bio-based waterproof and oilproof packaging paper and preparation method thereof |
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| CN102242533B (en) | 2012-10-10 |
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